• Title/Summary/Keyword: absorption spectrum

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Deposition Transfer and Electrical Properties of Arachidic Acid Multilayer Manufacture by LB Method (LB법으로 제작한 Arachidic Acid 다층막의 누적전이와 전기특성)

  • Song, Jin-Won;Lee, Kyung-Sup
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.05a
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    • pp.11-14
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    • 2001
  • We give pressure stimulation into organic thin films and then manufacture a device under the accumulation condition that the state surface pressure is 30[mN/m]. LB layers of Arac. acid deposited by LB method were deposited onto slide glass as Y-type film. The physicochemical properties of the LB films were examined by UV absorption spectrum, SEM and AFM. The structure of manufactured device is Au/arachidic acid/Al. the number of accumulated layers are 3~9. Also. we then examined of the MIM device by means of I-V. The I-V characteristic of the device is measured from -3 to +3[V]. The insulation property of a thin film is better as the distance between electrodes is larger.

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Studies on Structure and Color of the White Antheraea pernyi, Silkworm Cocoon

  • Tao, Ji;Hongde, Liu
    • Natural Product Sciences
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    • v.1 no.1
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    • pp.66-69
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    • 1995
  • Traditional Antheraea pernyi silkworm cocoon is tawny color. The white Antheraea pernyi silkworm cocoons studied here by IR and UV are new breeds of recent breeding. We discovered that the main body of the first grade structure of silk protein in the new white is as same as the one in the traditional tawny Antheraea pernyi silkworm cocoon, yet there are small quantities of cross-linked polymer of gentisic acid and silk protein in the white silkworm cocoons. In spite of the least surviving quantity of the polymer, the white silkworm cocoons are most white and its white color is similar to white Bombyx mori silkworm cocoon.

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A Study on the Displacement Properties of Functional LB Monolayers (기능성 LB단분자막의 변위특성에 관한 연구)

  • Song, Jin-Won;Choi, Young-Il;Lee, Kyung-Sup
    • Proceedings of the KIEE Conference
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    • 2003.10a
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    • pp.114-116
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    • 2003
  • Monolayers of lipids on a water surface have attracted much interest as models of biological membranes, but also as precursors of multilayer systems promising many technical applications. Until now, many methodologies have been developed in order to gain a better understand. Photoisomerization in monolayers of a novel azobenzene compound, azobenzene dendrimer, was investigated for the first time by means of the absorption spectrum and Maxwell displacement current (MDC) technique. Dendrimers are well-defined macromolecules exhibiting a tree-like structure, first derived by the cascade molecule approach. According to the absorption spectrum, trans-to-cis conversion ratio was estimated to the third generation of azobenzene dendrimer deposited onto a glass substrate. Temperature-dependent induced charge with trans-cis isomerization was also measured by means of MDC technique.

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Ordered CdS nanorods- organic hybrid solar cells

  • Kang, Yoon-Mook;Kim, Dong-Hwan
    • New & Renewable Energy
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    • v.1 no.1 s.1
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    • pp.32-36
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    • 2005
  • We studied the optoelectronic properties of hybrid solar cells formed by mixing cadmium sulfide [CdS] nanorods with a conjugated polymer, poly-2-methoxy, 5-[2'-ethy[hexyloxy]-1,4-p-phenylenevinylene[MEH-PPV]. CdS nanorods were grown vertically on Ti substrates by electrochemical deposition through a porous alumina template. Absorption spectrum of the composite layer was the same as the superposition of the absorption spectrum of each individual layer. The photoluminescence signal from MEH-PPV film was reduced as a result of the mixing. The energy conversion efficiency of MEH-PPV improved from $0.0012\%$ to about $0.60\%$ when combined with the vertically aligned CdS nanorods.

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A new red phosphor $BaZr(BO_{3})_{2}$ doped with $Eu^{3+}$ for PDP applications

  • Tian, Lian-Hua;Yu, Byung-Yong;Pyun, Chong-Hong;Mho, Sun-Il
    • 한국정보디스플레이학회:학술대회논문집
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    • 2003.07a
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    • pp.1042-1044
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    • 2003
  • The photoluminescence (PL) properties are studied for a new phosphor $BaZr(BO_{3})_{2}$ doped with $Eu^{3+}$ activator ion. The excitation spectrum shows strong absorption in the vacuum ultraviolet (VUV) region with an absorption band edge at 200 nm. The PL spectrum shows the strongest emission at 615 nm corresponding to the electric dipole $^{5}D_{0}\;{\rightarrow}\;^{7}F_{2}$ transition of $Eu^{3+}$, which results in a good color purity.

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Fabrication of Er-doped Sodium Borosilicate Glass Films Using Aerosol Flame Deposition Method (Aerosol Flame Deposition법을 이용한 Er-doped Sodium Borosilicate 유리박막 제작에 관한 연구)

  • 문종하;정형곤;이정우;박강희;박현수;김병훈
    • Journal of the Korean Ceramic Society
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    • v.37 no.2
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    • pp.117-121
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    • 2000
  • Er-doped sodiumborosilicate glass films for waveguides amplifier were fabricated by Aerosol Flame Deposition(AFD) method. Al2O3 was added to sodium borosilicate glass films to suppress the formation of crystalline phase and control the refractive index. the formation of crystalline phase was suppressed above Al2O3 of 6 wt%. As the amount of Al2O3 increased from 2 to 12 wt% the refractive index of glass films increased lineary from 1.4595 up to 1.4710. After the core of 77SiO2-15B2O3-8Na2O+6 wt%Al2O3+8wt%Er2O3 was coated on the buffer layer of 77SiO2-15B2O3-8Na2O+6 wt%Al2O3, the core was etched by reactive ion etching. The absorption spectrum of 3 cm waveguide amplifier showed two peaks of 1530 and 1550 nm.

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New Red Phosphor with the Improved Color Purity for PDP Applications

  • Mho, Sun-Il
    • 한국정보디스플레이학회:학술대회논문집
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    • 2002.08a
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    • pp.257-259
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    • 2002
  • As a new host material for a red phosphor for PDP applications, has studied (Y,Gd)$Al_3(BO_3)_4$ which gives non-centrosymmetric sites for $Eu^{3+}$ activators. Vacuum ultraviolet (VUV) excitation spectrum of new red phosphor (Y,Gd)$Al_3(BO_3)_4$:$Eu^{3+}$ has two broad bands. One band with the absorption edge at ca. 168 nm is the band-gap absorption of aluminoborate and the other broad band centered 240 nm is the charge transfer transition between $Eu^{3+}$ and the neighboring oxygen anions. The PL spectrum shows the strongest emission at 617 nm due to the electric dipole $^5D_0{\rightarrow}^7F_2$ transition of $Eu^{3+}$, whose luminescent chromaticity is (0.67, 0.33).

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Easy and Simple Synthesis of CdSe Nanocrystals: The Effect of Reaction Temperature for The Determination of Nanoparticle Size (간편한 CdSe 나노 입자의 합성: 입자크기를 결정하는 반응온도의 효과)

  • Kim, Sungjin
    • Journal of Integrative Natural Science
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    • v.2 no.3
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    • pp.219-223
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    • 2009
  • Easy and simple synthesis of CdSe nanocrystals was achieved through sol-gel process. CdSe nanocrystals were synthesized from the reaction of cadmium oxide and selenium in the prescence of trioctylphosphine oxide, tributylphosphine, octadecene, octadecylamine, and stearic acid. The effect of reaction temperature for the determination of size of CdSe nanocrystals was investigated after the addition of selenium. The reaction temperature for the growth of CdSe nanocrystals was increased by every $20^{\circ}C$ from 170 to 190, 210, 230, 250, 270, and $290^{\circ}C$. When the reaction temperature was higher, the absorption wavelength in the absorption spectrum was increased which indicated that the size of CdSe nanocrystals was increased. The emission wavelength in the photoluminescence spectrum was increased from 438 to 489, 542, 591, 643, 692, and 745 nm, as the size of CdSe nanocrystals was increased. The control of the reaction temperature illustrated that the color tuning of emission wavelength were successfully obtained.

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A Study on the Physical Properties of Functional LB Monolayers (기능성 LB단분자막의 물성에 관한 연구)

  • Song, Jin-Won;Shin, Hoon-Kyu;Lee, Kyung-Sup
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.11a
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    • pp.404-407
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    • 2003
  • Monolayers of lipids on a water surface have attracted much interest as models of biological membranes, but also as precursors of multilayer systems promising many technical applications. Until now, many methodologies have been developed in order to gain a better understand. Photoisomerization in monolayers of a novel azobenzene compound, azobenzene dendrimer, was investigated for the first time by means of the absorption spectrum and Maxwell displacement current (MDC) technique. Dendrimers are well-defined macromolecules exhibiting a tree-like structure, first derived by the cascade molecule approach. According to the absorption spectrum, trans-to-cis conversion ratio was estimated to the third generation of azobenzene dendrimer deposited onto a glass substrate. Temperature-dependent induced charge with trans-cis isomerization was also measured by means of MDC technique.

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Synthesis and fluorescent property investigation of novel fluoroionophores

  • Huang, Zhi Bin;Wang, Zhi Ping;Kang, Tai-Jong;Kwon, Young-Hwan;Kim, Sung-Nam;Chang, Seung-Hyun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.07a
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    • pp.428-429
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    • 2005
  • Novel fluoroionophore of dibenzothiazolyl-dibenzo-crown ethers were synthesized from diformal-dibenzo 18-crown-6 (24-crown-8) with 2-aminothiophenol, and they were characterizated by $^1H$-NMR, $^{13}C$-NMR, IR spectrum, Mass spectrum, elemental analyses, respectively. The fluorescent properties of the newly synthesized crown ether were examined with $Li^+$, $Na^+$, $K^+$, $Rb^+$, $Cs^+$, $NH_4^+$ and $CF_3COOH$, respectively. With protonation using $CF_3COOH$, the absorption bands of the new crown ethers are further blue shifted, the maximum emission wavelengths further red shifted.

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