• Title/Summary/Keyword: a transfer resistance

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In-depth Investigation on Interfacial Resistance of Stainless Steel by Using Dynamic Electrochemical Impedance Spectroscopy (Dynamic Electrochemical Impedance Spectroscopy를 이용한 스테인리스 강의 계면 저항 분석)

  • Heo, Jung-Ho;Lee, Yong-Heon;Shin, Heon-Cheol
    • Korean Journal of Metals and Materials
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    • v.47 no.10
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    • pp.644-651
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    • 2009
  • The passivation (or deactivation) of a metal surface during oxide film formation has been quantitatively explored for a ferritic stainless steel by using dynamic electrochemical impedance spectroscopy (DEIS). For this purpose, the electrochemical impedance spectra were carefully examined as a function of applied potential in the active nose region of the potentiodynamic polarization curve, to separate the charge transfer resistance and oxide film resistance. From the discrepancy in the potential dependence between the experimental charge transfer resistance and the semi-empirically expected one, the degree of passivation could be quantitatively estimated. The sensitivity of passivation of the steel surface to anodic potential, which might be the measure of the quality of the oxide film formed under unit driving force or over-potential, decreased by 31% when 3.5 wt% NaCl was added to a 5 wt% $H_2SO_4$ solution.

ANALYSIS OF HEAT TRANSFER PERFORMANCE WITH ASPECT AND FILLING RATIOS IN THERMOSYPHON (열사이펀의 형상비와 충전율에 따른 열전달 성능 해석)

  • Kim, Y.C.;Choi, J.W.;Kim, S.C.
    • Journal of computational fluids engineering
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    • v.20 no.1
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    • pp.92-98
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    • 2015
  • Thermal-fluid analysis is performed numerically to figure out the characteristics of heat transfer in a thermosyphon varying with the aspect ratio of geometry and the filling ratio of working fluid. The computational results are reasonable compared with the experimental data and visualized. The thermal resistance and the convective heat transfer coefficients are evaluated with the aspect ratio of thermosyphon and the filling ratio of working fluid, respectively. In conclusion, the thermal resistance decreases as the length of evaporator increases. However, the variation of a condenser length is nearly independent on the thermal resistance. In order to raise the performance of thermosyphon, the working fluid needs to be filled over 75%. In addition, Nusselt numbers in the evaporator and the condenser show 275 and 304, respectively.

AC Impedance Study of Hydrogen Oxidation and Reduction at Pd/Nafion Interface

  • Song, Seong-Min;Koo, Il-Gyo;Lee, Woong-Moo
    • Journal of Hydrogen and New Energy
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    • v.12 no.3
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    • pp.231-238
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    • 2001
  • Electrocatalytic activity of palladium for hydrogen oxidation and reduction was studied using AC impedance method. The system under study was arranged in electrolytic mode consisting of Pd electrode under study, Pt counter electrode and Nafion electrolyte between them. Two types of Pd electrodes were used - carbon-supported Pd (Pd/C) and Pd foil electrode. Pd/C anode contacting pure hydrogen showed a steady decrease of charge transfer resistance with the increase of anodic overpotential, which is an opposite trend to that found with Pd foil anode. But Pd foil cathode also exhibited a decrease of the resistance with the increase of cathodic overpotential. The relationship between imposition of overpotential and subsequent change of the charge transfer resistance is determined by the ratio of the rate of faradaic process to the rate of mass transportation; if mass transfer limitation holds, increase of overpotential accompanies the increase of charge transfer resistance. Regardless of the physical type of Pd electrode, the anode contacting hydrogen/oxygen gas mixture did not reveal any independent arc originated from local anodic oxygen reduction.

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Heat and mass transfer analysis in air gap membrane distillation process for desalination

  • Pangarkar, Bhausaheb L.;Sane, Mukund G.
    • Membrane and Water Treatment
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    • v.2 no.3
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    • pp.159-173
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    • 2011
  • The air gap membrane distillation (AGMD) process was applied for water desalination. The main objective of the present work was to study the heat and mass transfer mechanism of the process. The experiments were performed on a flat sheet module using aqueous NaCl solutions as a feed. The membrane employed was hydrophobic PTFE of pore size 0.22 ${\mu}m$. A mathematical model is proposed to evaluate the membrane mass transfer coefficient, thermal boundary layers' heat transfer coefficients, membrane / liquid interface temperatures and the temperature polarization coefficients. The mass transfer model was validated by the experimentally and fitted well with the combined Knudsen and molecular diffusion mechanism. The mass transfer coefficient increased with an increase in feed bulk temperature. The experimental parameters such as, feed temperature, 313 to 333 K, feed velocity, 0.8 to 1.8 m/s (turbulent flow region) were analyzed. The permeation fluxes increased with feed temperature and velocity. The effect of feed bulk temperature on the boundary layers' heat transfer coefficients was shown and fairly discussed. The temperature polarization coefficient increased with feed velocity and decreased with temperature. The values obtained were 0.56 to 0.82, indicating the effective heat transfer of the system. The fouling was observed during the 90 h experimental run in the application of natural ground water and seawater. The time dependent fouling resistance can be added in the total transport resistance.

Drug Resistance and R. Plasmids of Enterobacteria Isolated from Bovine Udder Infections (젖소 유방염유래(乳房炎由來) 장내세균(腸內細菌)의 약제내성(藥劑耐性) 및 R. Plasmids)

  • Park, Cheong Kyu
    • Korean Journal of Veterinary Research
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    • v.21 no.1
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    • pp.25-31
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    • 1981
  • A total of 250 enteric bacteria (148 Escherichia coli, 41 Klebsiella pneumoniae, 46 Enterobacter spp. and 15 Proteus spp.) isolated from bovine udder infections in 1979 through 1980 were examined for drug resistance and prevalence of R. plasmids. The drug tested were streptomycin (SM), kanamycin (KM), ampicillin (AP), chloramphenicol (CP), tetracycline (TC), gentamicin (GM), oxolinic acid (OA) and nalidixic acid (NA). The detection of R. plasmids was performed with Escherichia coli ML 1410 NAr as the recipient. Of the 148 Escherichia coli isolated, 68(45.9%) were found to be resistant to one or more drugs tested, and about 50% of the resistant strains were multiply resistant. of the 68 drugresistant strains, 13(19.1%) were found to carry R. plasmids which were capable of performing a conjugal transfer. CP resistance was transfered together with the other resistance. Of 41 strains of Klebsiella pneumoniae isolated, 90.2% were resistant to the drugs, alone or in combination thereof. Strains resistant to AP and TC were 63.4%, and 48.8%, respectively. R. plasmids were detected in 78.4% of the drug-resistant strains, and these strains transfered all or a part of their drug resistance pattern. AP and CP resistance were transfered in 100% of AP and CP-resistant strains. Eleven (37.9%) of 29 R. plasmids showed a thermosensitive transfer. Of the 46 strains of Enterobacter spp. isolated, 37(80.4%) were resistant to the drugs tested. A high percentage of resistance was noted for AP(65.2%). All strains resistant to four or more drugs transferred their resistances to Escherichia coli ML 1410, but strains resistant to three or fewer drugs did not transfer the resistances. All of the 15 Proteus strains isolated were resistant to more than two drugs. of them, 6 were quadruple resistance to SM, KM, CP and TC, and 9 were double one to AP and TC. Three (20.0%) of the drug-resistant isolates had R.plasmids conferring AP and TC resistance. GM, OA and NA of the drugs tested were very active to all of 250 Gram-negative enteric bacteria isolated from bovine udder infections.

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A Study on the Effect of Resonant Coil Size and Load Resistance on the Transmission Efficiency of Magnetic Resonance Wireless Power Transfer System (공진 코일의 크기와 부하 저항이 자계 공명 무선 전력 전송 장치의 전달 효율에 주는 영향에 관한 연구)

  • Park, Jeong-Heum
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.26 no.7
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    • pp.45-51
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    • 2012
  • In this paper, the wireless power transfer system using the magnetic resonance was designed and the effect of resonant coil radius and load resistance to this system was analyzed by the circuit analysis method. As a result, the calculated transmitted-power is similar to measured one, and the coil size has a small effect to the coupling coefficients in the resonant frequency band. In addition, the fact that the calculated transmitted-power according to the source frequency is similar to measured one confirms that the circuit analysis methode in this paper is valid. The input side transmission efficiency ${\eta}_i$ including only the loss in the power transfer circuit is almost 90[%] with the large coil in the 10[cm] transfer distance, and 65[%] with the small coil in 1[cm]. The source side transmission efficiency ${\eta}_s$ is 30~40[%] at both coil when load resistance below 4.7[${\Omega}$] has been connected. Considering that the maximum ${\eta}_s$ is 50[%], this is valid in the practical applications.

Integral Analysis of the Effects of Non-absorbable gases on the Heat Mass Transfer of Laminar Falling Film

  • Kim, Byong-Joo
    • International Journal of Air-Conditioning and Refrigeration
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    • v.6
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    • pp.56-66
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    • 1998
  • The absorption process of water vapor in a liquid film is an important process in LiBr-Water absorption system. The composition of the gas phase, in which a non-absorbable gas is combined with the absorbate, influences the transport characteristics. In the present work, the absorption processes of water vapor into aqueous solutions of lithium bromide in the presence of non-absorbable gas are investigated. The continuity, momentum, energy and diffusion equations for the solution film and gas are formulated in integral forms and solved numerically. It is found that the mass transfer resistance in gas phase increases with the concentration of non-absorbable gas. However the primary resistance to mass transfer is in the liquid phase. As the concentration of non-absorbable gas in the absorbate increases, the interfacial temperature and concentration of absorbate in solution decrease, which results in the reduction of absorption rate. The reduction of mass transfer rate is found to be significant for the addition of a small amount of non-absorbable gas to the pure vapor, especially at the outlet of tube where the non-absorbable gas accumulates. At higher non-absorbable gas concentration, the decrease of absorption rate seems to be linear to the concentration of non-absorbable gas.

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Load-Transfer Analysis by Considering Coupled Soil Resistance (말뚝-지반 상호작용을 고려한 수정된 하중전이함수법 제안)

  • Seol, Hoon-Il;Jeong, Sang-Seom;Kim, Young-Ho
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.28 no.6C
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    • pp.359-366
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    • 2008
  • The load distribution and deformation of pile subjected to axial loads are evaluated by a load-transfer method. The emphasis is on quantifying the effect of coupled soil resistance that is closely related to the ratio of pile diameter to soil modulus $(D/E_s)$ and the ratio of total shaft resistance against total applied load $(R_s/Q)$, in rock-socketed drilled shafts using the coupled load-transfer method. The proposed analytical method that takes into account the soil coupling effect was developed using a modified Mindlin's point load solution. Through comparisons with field case studies, it was found that the proposed method in the present study estimated reasonable load transfer behavior of pile and coupling effects due to the transfer of shaft shear loading, and thus represents a significant improvement in the prediction of load deflections of drilled shafts.

Evaluation on Sensitivity and Approximate Modeling of Fire-Resistance Performance for A60 Class Deck Penetration Piece Using Heat-Transfer Analysis and Fire Test

  • Park, Woo Chang;Song, Chang Yong
    • Journal of Ocean Engineering and Technology
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    • v.35 no.2
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    • pp.141-149
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    • 2021
  • The A60 class deck penetration piece is a fire-resistance apparatus installed on the deck compartment to protect lives and to prevent flame diffusion in the case of a fire accident in a ship or offshore plant. In this study, the sensitivity of the fire-resistance performance and approximation characteristics for the A60 class penetration piece was evaluated by conducting a transient heat-transfer analysis and fire test. The transient heat-transfer analysis was conducted to evaluate the fire-resistance design of the A60 class deck penetration piece, and the analysis results were verified via the fire test. The penetration-piece length, diameter, material type, and insulation density were used as the design factors (DFs), and the output responses were the weight, temperature, cost, and productivity. The quantitative effects of each DF on the output responses were evaluated using the design-of-experiments method. Additionally, an optimum design case was identified to minimize the weight of the A60 class deck penetration piece while satisfying the allowable limits of the output responses. According to the design-of-experiments results, various approximate models, e.g., a Kriging model, the response surface method, and a radial basis function-based neural network (RBFN), were generated. The design-of-experiments results were verified by the approximation results. It was concluded that among the approximate models, the RBFN was able to explore the design space of the A60 class deck penetration piece with the highest accuracy.

An analysis on the solidification process of alloy casting with a contact resistance (접촉 열저항을 고려한 합금주조의 응고과정 해석)

  • Kim, W.S.;Lee, K.S.;Im, I.T.;Kim, K.S.
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.21 no.1
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    • pp.57-67
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    • 1997
  • The solidification process of Al 4.5%Cu alloy is numerically studied in the presence of contact resistance between mold and cast. Natural convection is considered in the liquid and mushy regions. The porosity approach is applied to the mushy zone modeling and linear variation of the solid fraction on the temperature is assumed. Results show that the mushy region is wider in the case with a contact resistance compared to the perfect contact condition. The temperature of the cast with a temporal variation in the contact heat transfer coefficient changes very rapidly in the early stage of the casting process compared to that with constant contact heat transfer coefficient.