• 제목/요약/키워드: Zs

검색결과 69건 처리시간 0.032초

지르코늄 메조기공 구조체의 합성조건 변화에 따른 인 제거 특성 (Removal Characteristics of Phosphorus at Synthetic Variation of Zirconium Mesoporous Structure)

  • 이상협;이병천;이관용;최용수;박기영
    • 한국물환경학회지
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    • 제21권6호
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    • pp.637-642
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    • 2005
  • The focus of this study was to examine the phosphorus removal characteristic by zirconium mesoporous structured material synthesized on various conditions. The zirconium sulfate-surfactant mesoporous structured material(ZS) was synthesized by hydro-thermal synthesis. The material has regular hexagonal array of surfactant micelles and sulfate ion ($HSO_4{^-}$). We confirmed that sulfate ion in zirconium mesoporous structured material can be ion-exchanged with phosphate ion ($H_2PO_4{^-}$) in phosphoric acid solution. On the X-ray diffraction (XRD) pattern of ZS, three peaks which shows the important characteristics of hexagonal crystal lattice were observed at (100), (110) and (200). The transmission electron micrograph (TEM) show high crystallization with pore size about $47{\AA}$. The maximum adsorption capacity of ZS was as great as 3.2 mmol-P/g-ZS. From the adsorption isotherm, correlation coefficients were higher for the Langmuir isotherm than the Freundlich isotherm. With the respect of chain length of surfactant, the adsorption capacity for phosphate synthesized with C12 was higher than C16 and C18. The highest amount of adsorbed phosphate on ZS was observed at the surfactant-to-zirconium molar ratio of 0.5 to 1.

지르코니아 투명도 및 두께에 따른 레진 시멘트의 중합률 (The degree of conversion of dual-cured resin cement as a function of transmittance and thickness)

  • 노형록;주규지;선금주
    • 대한치과기공학회지
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    • 제38권3호
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    • pp.193-199
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    • 2016
  • Purpose: The purpose of this study was to know of photopolymerization effect of self-etch dual-cured resin cement on different transmittance and thickness of zirconia disks. Methods: The two types of transparent and opaque zirconia speciments were prepared. The five speciments of each groups were seperated with 0.5mm and 1.0mm thickness. Degree of conversion(DC) were studied by FT-IR spectroscopy using ATR method before and after irradidaion for 40 sec. Results: The relative DC was showed the higher results of ZS5 as compared with ZS10 (p < 0.05). And OP5 and OP10 were lower results than ZS10 (p < 0.05). Conclusion: The photopolymerization effect of dual-cured resin cement were affected by the transmittance and thickness of zirconia.

Effects of subsequent curing on chloride resistance and microstructure of steam-cured mortar

  • Hu, Yuquan;Hu, Shaowei;Yang, Bokai;Wang, Siyao
    • Advances in concrete construction
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    • 제9권5호
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    • pp.449-457
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    • 2020
  • The influence of subsequent curing on the performance of fly ash contained mortar under steam curing was studied. Mortar samples incorporated with different content (0%, 20%, 50% and 70%) of Class F fly ash under five typical subsequent curing conditions, including standard curing (ZS), water curing(ZW) under 25℃, oven-dry curing (ZD) under 60℃, frozen curing (ZF) under -10℃, and nature curing (ZN) exposed to outdoor environment were implemented. The unsteady chloride diffusion coefficient was measured by rapid chloride migration test (RCM) to analyze the influence of subsequent curing condition on the resistance to chloride penetration of fly ash contained mortar under steam curing. The compressive strength was measured to analyze the mechanical properties. Furthermore, the open porosity, mercury intrusion porosimetry (MIP), x-ray diffraction (XRD) and thermogravimetric analysis (TGA) were examined to investigate the pore characteristics and phase composition of mortar. The results indicate that the resistance to chloride ingress and compressive strength of steam-cured mortar decline with the increase of fly ash incorporated, regardless of the subsequent curing condition. Compared to ZS, ZD and ZF lead to poor resistance to chloride penetration, while ZW and ZN show better performance. Interestingly, under different fly ash contents, the declining order of compressive strength remains ZS>ZW>ZN>ZD>ZF. When the fly ash content is blow 50%, the open porosity grows with increase of fly ash, regardless of the curing conditions are diverse. However, if the replacement amount of fly ash exceeds a certain high proportion (70%), the value of open porosity tends to decrease. Moreover, the main phase composition of the mortar hydration products is similar under different curing conditions, but the declining order of the C-S-H gels and ettringite content is ZS>ZD>ZF. The addition of fly ash could increase the amount of harmless pores at early age.

SiC와 TiO2 첨가에 따르는 ZrO2의 기계적 특성 및 균열 치유 (Mechanical Characteristics and Crack-Healing of ZIRCONIA(ZrO2) Composite Ceramics with SiC and TiO2)

  • 남기우
    • 대한기계학회논문집A
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    • 제40권3호
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    • pp.267-273
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    • 2016
  • 본 연구에서는 부분 안정화 지르코니아(Z)와 자기치유능력을 부여하기 위하여 SiC와 $TiO_2$를 첨가한 5종류의 복합 지르코니아(ZS, ZST1, ZST2, ZST3, ZST5)를 소결하여, 기계적 특성과 열처리에 의한 균열 치유 가능성을 평가하였다. 6종류 지르코니아 세라믹스의 비커스 경도는 큰 차이가 없으며, 부분 안정화 지르코니아에 SiC 첨가(ZS)는 급격한 굽힘강도의 저하가 나타났지만, $TiO_2$의 첨가(ZST1, ZST2, ZST3, ZST5)는 강도가 향상하였다. 이는 SiC 및 $TiO_2$의 첨가의 따른 결정화의 영향이라 판단된다. 최고 굽힘 강도를 나타내는 균열 치유 조건에서 지르코니아 단상체는 비커스 균열이 남았으나, SiC가 첨가된 4종류는 비커스 균열이 관찰되지 않아 균열이 치유되었다.

산초(Zanthoxylum schinifolium) 추출물과 초피(Zanthoxylum piperitum) 정유의 꽁치과메기 산패 억제 효과 (Suppressive Effects of the Extract of Zanthoxylum schinifolium and Essential Oil from Zanthoxylum piperitum on Pacific Saury, Coloabis saira Kwamegi)

  • 조성희;권은혜;오승희;우미희
    • 한국식품영양과학회지
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    • 제38권12호
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    • pp.1753-1759
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    • 2009
  • 본 연구는 산초 잎의 에탄올 추출물과 초피 과피에서 얻은 정유를 과메기 제조 시 처리하였을 때 산패 억제와 품질 향상 효과를 조사하였다. 산초의 에탄올 추출물(ZS)은 1% 에탄올에, 초피 정유(ZP)는 20% 에탄올에 용해시켜 길이로 2등분하여 탈수시킨 꽁치 1 kg 당 산초 추출물은 0, 0.125, 0.25, 1 ppm 되게, 초피 정유는 0, 0.25, 0.5, 1, 2 ppm 되게 분무하여 과메기를 자연 건조하여 제조하고 다층 필름포장제로 진공 포장하였다. 포장된 과메기를 실험 시까지 -20${^{\circ}C}$에 보관하였다가 개봉한 후 4${^{\circ}C}$ 냉장고에서 1, 3, 7일 보관하며 산패 정도와 아민류의 변화, 관능검사를 실시하였다. 과메기의 산가, 과산화물가 및 TBA값은 개봉 후 보관기간이 길어질수록 증가하였으며 산초 추출물 0.125 ppm 이상, 초피 정유 0.25 ppm에서 효과가 나타났으며 이 효과는 농도 의존적이며 보관기간이 길어질수록 더 뚜렷하였다. 산초 추출물과 초피 정유 처리에 의하여 과메기 내의 dimethylamine과 trimethylamine(TMA)의 증가도 억제하였으며 trimethylamine oxide의 함량은 높게 유지되었고 3일 보관한 과메기에서 TMA<4.5 mg/100 g을 유지시킬 수 있는 산초 추출물의 농도는 0.25 ppm, 초피 정유는 0.5 ppm이었다. 3일 보관된 과메기에 대한 관능검사 결과 초피정유를 0.5-1ppm 처리한 시료에서 가장 좋은 점수를 나타내었다. 결론적으로 소량의 산초추출물과 초피 정유는 과메기의 산패를 억제하여 품질을 개선시키는 효과가 있다고 사료된다.

소아의 기도 폐쇄 평가에서 impulse oscillometry system과 폐활량 측정법의 비교 (A comparison between impulse oscillometry system and spirometry for spirometry for detecting airway obstruction in children)

  • 허혜영;곽지희;김형윤;정다운;신윤호;한만용
    • Clinical and Experimental Pediatrics
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    • 제51권8호
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    • pp.842-847
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    • 2008
  • 목 적 : 기도 폐쇄의 평가를 위해 측정하는 $FEV_1$은 대상 환자의 협조를 필요로 하기 때문에 6세 이전의 소아에서는 검사하기 어렵다. 이에 본 연구에서는 소아에서 IOS의 유용성을 검정하기 위해 IOS와 폐활량 측정법의 $FEV_1$을 비교하였다. 방 법 : 병력상 천식이 의심되어 폐활량 측정법과 IOS를 이용해서 폐기능 검사 및 메타콜린 기관지 유발 검사를 실시한 환자 174명을 대상으로 하였다. 대상군은 기관지 과민성 지표인 $PC_{20}$ 농도에 따라 두 군으로 나누었고, 이들의 기저 폐 기능, 기관지 유발검사 후의 변화율, $FEV_1$과 IOS 지표의 상관관계를 알아보았다. 결 과 : 기저 폐기능 지표 중 X5, R5는 $PC_{20}$ 양성군과 음성군간에 유의한 차이를 보였지만, $FEV_1$, $FEV_1$ % 예측치, $FEV_1_-Zs$은 유의한 차이가 없었다. $FEV_1$은 X5 (r=0.45, P<0.01), R5 (r=-0.69, P<0.01)와 상관관계를 보였고, $FEV_1_-Zs$ 역시 X5_Zs (r=-0.26, P<0.01), R5_Zs (r=-0.31, P<0.01)와 상관관계를 보였다. 메타콜린 유발검사 후 $FEV_1$과 X5의 변화율은 두 군간에 유의한 차이를 보였다(P<0.05). 결 론 : IOS 지표는 기저 폐 기능 검사에서 기관지 과민성으로 분류한 환자를 $FEV_1$보다 민감하게 구분 지을 수 있었고, IOS 지표와 $FEV_1$의 상관관계가 높았다.

Stability of pUC-Derived Plasmids with a Fluorescence Marker in Pectobacterium carotovorum subsp. carotovorum and subsp. betavasculorum

  • Hur, Woon-Yung;Roh, Eun-Jung;Oh, Chang-Sik;Han, Man-Wi;Lee, Seung-Don;Kim, Doo-Ho;Heu, Sung-Gi
    • The Plant Pathology Journal
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    • 제25권3호
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    • pp.286-290
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    • 2009
  • The stability of three different kinds of pUC-derived plasmids, pDsRed, pZsYellow, and pGFPuv, was investigated in Pectobacterium strains to utilize those plasmids as tracers. All three plasmids pDsRed, pZsYellow and pGFPuv showed their specific colors in Pectobacterium strains. Especially, the plasmid pDsRed conferred bright pink colonies on the Pectobacterium strains. When the bacteria lost the plasmid pDsRed, the colonies turned white, suggesting that the plasmid could be a good marker system for Pectobacterium strains on different environmental conditions. The effect of the antibiotic pressure on the stability of the plasmid was different depending on the host bacteria. P. carotovorum subsp. betavasculorum was more sensitive to the antibiotic pressure than P. carotovorum subsp. carotovorum Pcc21. However, temperature change significantly affected plasmid stability on both Pectobacterium strains. Almost all strains lost the plasmids with the shift in temperature from $28^{\circ}C$ to $37^{\circ}C$. Presence of the plasmids did not affect bacterial pathogenicity on their own host plants. Among three plasmids, pZsYellow was not useful as a marker because the yellow fluorescent proteins from pZs Yellow were interfered with the yellow natural fluorescence of the plant tissues induced by the defense system. Since the red color of DsRed can be seen with naked eyes, plasmid pDsRed was applicable as a marker. However, the color change was slow so that additional manipulation to increase the expression speed was necessary. Plasmid pGFPuv could serve as a perfect marker without any problem, tracing the reproduction and spread of the plant pathogens perfectly.

산초열매의 채집 시기별 일반성분, 지방산 및 정유성분 조성 변화 (Studies on Proximate Composition, Fatty Acids and Volatile Compounds of Zanthoxylum schinifolium Fruit According to Harvesting Time)

  • 배성문;진영민;정은호;김만배;신현열;노치웅;이승철
    • 한국약용작물학회지
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    • 제19권1호
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    • pp.1-8
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    • 2011
  • Biological characteristics of 5 Zanthoxylum schinifolium (Zs) fruits such as Z1 (early August), Z2 (middle August), Z3 (middle September), Z4 (early October) and Z5 (middle October) according to harvesting time were evaluated. As fruits ripened, average weight of Zs increased from 4.8mg (Z1) to 50.7mg (Z5), while moisture contents decreased from 74.6% (Z1) to 55.2% (Z5). Crude fat contents of the fruits during ripening increased from 1% (Z1) to 10.6% (Z5). The major fatty acids in Zs were palmitic (C16:0), palmitoleic (C16:1), oleic (C18:1), and linoleic (C18:2) acids. Linoleic acid (C18:2) was a main fatty acid in Z1 and Z2, whereas oleic acid (C18:1) was found as a main one in the other Zs. The ratio of unsaturated fatty acid to total fatty acids increased from 60% (Z1) to 80% (Z3~Z5) during ripening. Among ripening stages, Z4 had the highest contents of total fatty acids ($3,355{\mu}g/g$) and total unsaturated fatty acids ($2,753{\mu}g/g$). Forty six volatile compounds in Zs were also identified. The major volatile compounds were ${\alpha}-pinene$, ${\beta}-myrcene$, ${\beta}-ocimene$, 2-nonanone, estragole, 2-undecanone, and ${\beta}-caryophyllene$. Major volatile components of Z1 were ${\beta}-ocimene$ (20.8 peak area %) and ${\alpha}-pinene$ (9.7 peak area %). In Z2, estragole (30.1 peak area %) was a main volatile compound, but the contents of ${\alpha}-pinene$ (0.4 peak area %), ${\beta}-myrcene$ (0.3 peak area %), and ${\beta}-ocimene$ (0.6 peak area %) were lower than those in Z1. Especially, estragole used as perfumes and as a food additive for flavor was drastically increased to 91.2 (Z3) and 92% (Z4) as fruits ripened.

Ziziphus spina christifor Sustainable Agroforestry Farming in Arid Land of Khartoum State of Sudan

  • Mustafa Abdalla Nasre Aldin;Hussein Alawad Seid Ahmed;Mohamed El Mukhtar Ballal;Adil Mahgoub Farah
    • Journal of Forest and Environmental Science
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    • 제39권1호
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    • pp.20-26
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    • 2023
  • Cow pea (Vigna unguiculata) was intercropped with Ziziphus spina-christi as summer forage in two consecutive seasons of 2017 and 2018. The aims to find out suitable agroforestry practice for saline soils of Khartoum State. And to investigate effect of tree spacing on forage biomass yield under semi -irrigated systems. Completely randomized block design with 3 replicates was conducted for this trial. Thus Z.spina-christi that fixed at 4×4 m was intercropped with cowpea at 1 m and 1.5 m spacing from trees trunk. Tree growth parameters were measured in terms of tree height, tree collar diameter, tree crown diameter and fruit yield per tree. While crop were parameters were determined in terms of plant height, number of plant, forage biomass yield per ha and land equivalent ratio. Soil profile of 1×1 m and 1.5 m depth was excavated and its features were described beside its chemical and physical properties were analyzed for 0-10 cm, 0-30 cm, and 30-60 cm and 60-100 cm layers. The results revealed that soil pH, CaCO3, SAR, ESP, and EC ds/m were increased by increasing soil depths. Meanwhile tree growth in terms of tree height was significant in the first season 2017 when compared with tree collar diameter and tree crown diameter. Also significant differences were recorded for tree growth when compared with sole trees in the second season in 2018. Tree fruit showed marked variations between the two seasons, but it was higher under intercropping particularly at ZS2. Crop plant height was highly significant under sole cropping than intercropping in first season in 2017. In contrast forage biomass yield was significant under intercropping in ZS1 and ZS2 treatments. Land equivalent ratio was advantageous under this agroforestry system particularly under ZS2. Thus it recorded 5 and 9 for ZS2 in the two consecutive seasons respectively. Therefore, it is feasible to introduce this agroforestry system under such arid lands to provide summer forage yield of highly nutritive value and low cost for animals feed as well as to increase farmers' income and to halt desertification and to sequester carbon.

Amino Silane, Vinyl Silane, TESPD, ZS(TESPD/Zinc Complex) Effects on Carbon Black/Clay Filled Chlorobutyl Rubber(CIIR) Compounds Part II: Effects on Soft Clay/Carbon Black Filled Compounds

  • Kim, Kwang-Jea
    • Carbon letters
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    • 제10권2호
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    • pp.109-113
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    • 2009
  • Various silanes, amino silane, vinyl silane, TESPD, and ZS (TESPD/zinc soap complex), are added into chlorinated isobutylene-isoprene copolymer (CIIR)/soft clay/carbon black (CB). The vulcanization characteristics, the processability, and the mechanical properties are measured. In soft clay/CB filled CIIR system, there are no significant changes in Mooney viscosity among compounds. Vinyl silane added compound shows a low extrusion torque. All the silane added compounds shows an increased modulus. The mechanical properties are significantly increased when the S2 is added into CIIR/soft clay/CB compounds.