• Journal of Korea Foundry Society
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• v.22 no.6
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• pp.288-292
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• 2002

Ni-base amorphous alloys were manufactured using melt-spinning and Cu-mold die casting methods. Amorphous formability, the supercooled liquid region before crystallization and mechanical properties were examined. The reduced glass transition temperature and the supercooled liquid region of $Ni_{51} Nb_{20} Zr_9 Ti_9 Co_8 Cu_3$alloy were 0.621 and 46 K respectively. $Ni_{51} Nb_{20} Zr_9 Ti_9 Co_8 Cu_3$ alloy was produced in the rod shape 3mm diameter using the Cu-mold die casting. Hardness, compression strength, elongation and elastic modulus of the alloy were 850 DPN, 2.75 GPa, 1.8% and 150 GPa respectively. Moreover, compression strength of 2.75 GPa was the highest value in the amorphous bulk alloy produced up to now.

• Transactions of the Korean hydrogen and new energy society
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• v.22 no.2
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• pp.168-177
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• 2011

A set of kinetics study on the reduction with $CH_4$, oxidation with steam and oxidation with air was performed for $Fe_2O_3/ZrO_2$. $Fe_2O_3/ZrO_2$ was prepared by aerial oxidation method. The reactivity experiments were performed in a thermogravimetric analyzer (TGA) with different reacting gas concentrations and temperatures. The obtained activation energy of reduction by methane, oxidation by water and oxidation by air are 219 kJ/mol, 238 and 20 respectively.

• Journal of Electrical Engineering and Technology
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• v.6 no.4
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• pp.543-550
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• 2011

Conductive SiC-$ZrB_2$ composites were produced by subjecting a 40:60 (vol%) mixture of zirconium diboride (ZrB2) powder and ${\beta}$-silicon carbide (SiC) matrix to spark plasma sintering (SPS). Sintering was carried out for 5 min in an argon atmosphere at a uniaxial pressure and temperature of 50 MPa and $1500^{\circ}C$, respectively. The composite sintered at a heating speed of $25^{\circ}C$/min and an on/off pulse sequence of 12:2 was denoted as SZ12L. Composites SZ12H, SZ48H, and SZ10H were obtained by sintering at a heating speed of $100^{\circ}C$/min and at on/off pulse sequences of 12:2, 48:8, and 10:9, respectively. The physical, electrical, and mechanical properties of the SiC-$ZrB_2$ composites were examined and thermal image analysis of the composites was performed. The apparent porosities of SZ12L, SZ12H, SZ48H, and SZ10H were 13.35%, 0.60%, 12.28%, and 9.75%, respectively. At room temperature, SZ12L had the lowest flexural strength (286.90 MPa), whereas SZ12H had the highest flexural strength (1011.34 MPa). Between room temperature and $500^{\circ}C$, the SiC-$ZrB_2$ composites had a positive temperature coefficient of resistance (PTCR) and linear V-I characteristics. SZ12H had the lowest PTCR and highest electrical resistivity among all the composites. The optimum SPS conditions for the production of energy-friendly SiC-$ZrB_2$ composites are as follows: 1) an argon atmosphere, 2) a constant pressure of 50 MPa throughout the sintering process, 3) an on/off pulse sequence of 12:2 (pulse duration: 2.78 ms), and 4) a final sintering temperature of $1500^{\circ}C$ at a speed of $100^{\circ}C$/min and sintering for 5 min at $1500^{\circ}C$.

• Korean Chemical Engineering Research
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• v.51 no.2
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• pp.208-213
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• 2013

Zirconium hydroxide was synthesized by varying the aging time of the zirconyl chloride octahydrate at $100^{\circ}C$ in aqueous solution and the resulting hydroxides were calcined at $700^{\circ}C$ for 6 h to obtain the crystalline $ZrO_2$. The materials used in this study were characterized by differential thermal analysis (DTA), X-ray diffraction (XRD), $N_2$-sorption, transmission electron microscopy (TEM), $NH_3$ temperature-programmed desorption ($NH_3$-TPD), $CO_2$-TPD and iso-propanol TPD analyses to correlate with catalytic activity for the dehydration of iso-propanol. The pure tetragonal $ZrO_2$ phase was obtained after 24 h aging of zirconium hydroxide and successive calcination at $700^{\circ}C$. The increase of aging time showed the production of smaller particle size $ZrO_2$ resulting that the higher specific surface area and total pore volume. $NH_3$-TPD results revealed that the relative acidity of the catalysts increased along with the increase of aging time. On the other hand, the results of $CO_2$-TPD showed the reverse trend of $NH_3$-TPD results. The best catalytic activity for the dehydration of iso-propanol to propylene was shown over $ZrO_2$ catalyst aged for 168 h which had the highest $S_{BET}$ ($178\;m^2\;g^{-1}$). The catalytic activity could be correlated with high surface area, relative acidity and easy desorption of iso-propanol.

• Resources Recycling
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• v.17 no.5
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• pp.28-36
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• 2008

The effect of attrition scrubbing on the recovery of platinum group metals (PGMs) from automobile catalytic converters has been investigated. Catalytic converters were first crushed into particles less than 2 mm and attrition scrubbed in the range of 60 min, and then they were sieved with several screens. The catalyst layer, $\gamma$-alumina, was dislodged from the surface of the supporting matrix into fine particles less than $45{\mu}m$ by attrition scrubbing. The fraction of fine particles less than $45{\mu}m$ increased as the residence time for attrition scrubbing increased. The composition of the fine fraction obtained at a residence time of 40 min was $CeO_2$ 19.3%, $ZrO_2$ 1.9% and PGMs 419 ppm. In the fine fraction, the recovery of y-alumina increased proportionally to the residence time. Simultaneously, the recovery rates of $CeO_2$, $ZrO_2$ and PGMs increased to 82.9%, 78.7% and 78.9%, respectively. The production of the fine fraction less than $45{\mu}m$ and the recovery of $\gamma$-alumina increased when the solid concentration and initial feed size increased. Therefore, the attrition scrubbing as the comminution and separation process was concerned to be effective for the recovery of catalyst layer from ceramic supporting matrix by physical impact and shearing action between particles in the scrubbing vessel.

• Korean Chemical Engineering Research
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• v.54 no.3
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• pp.394-403
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• 2016

$H_2$ production by chemical looping is an efficient method to convert hydrocarbon fuel into hydrogen with the simultaneous capture of concentrated $CO_2$. This process involves the use of an iron based oxygen carrier that transfers pure oxygen from oxidizing gases to fuels by alternating reduction and oxidation (redox) reactions. The enhanced reactivities of copper oxide doped iron-based oxygen carrier were reported, however, the fundamental understandings on the interaction between $Fe_2O_3$ and CuO are still lacking. In this study, we studied the effect of dopant of CuO to $Fe_2O_3/ZrO_2$ particle on the morphological changes and the associated reactivity using various methods such as SEM/EDX, XRD, BET, TPR, XPS, and TGA. It was found that copper oxide acted as a chemical promoter that change chemical environment in the iron based oxygen carrier as well as a structural promoter which inhibit the agglomeration. The enhanced reduction reactivity was mainly ascribed to the increase in concentration of $Fe^{2+}$ on the surface, resulting in formation of charge imbalance and oxygen vacancies. The CuO doped $Fe_2O_3/ZrO_2$ particle also showed the improved reactivity in the steam oxidation compared to $Fe_2O_3/ZrO_2$ particle probably due to acting as a structural promoter inhibiting the agglomeration of iron species.

• Journal of the Korean Society for Heat Treatment
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• v.8 no.4
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• pp.333-339
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• 1995

The reduction and diffusion process(R-D process) is an economical way to produce the functional materials which contain rare-earth elements and has been applied to the production of rare-earth magnet meterials($SmCo_5$, $Nd_{15}Fe_{77}B_8$), magneto-optical(MO) target materials and hydrogen storage alloy, etc. However, because of difficult to control of the final composition, the R-D process has not been applied to production of the 2-17 type rare earth permanent magnet materials which contain several elements. Therefore, this work was as a basic study for the production of the 2-17 type rare earth permanent materials with composition $Sm(Co_{0.72}Fe_{0.21}Cu_{0.05}Zr_{0.03})_{7.9}$ by the R-D process, the following were mainy examined ; the amount of metallic calcium as a reductant, homogenization condition of the alloy after the R-D reaction, masuring of magnetic properties of the sample after step aging. The sample prepared by the R-D process contained a little more oxygen than that prepared by the melting method, however, showed almost the same magnetic properties.

• Korean Journal of Soil Science and Fertilizer
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• v.49 no.6
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• pp.635-643
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• 2016

Wine consumers desire to drink a high quality wine. For producing high quality wine, high quality soil is required. Conventionally, soil quality is assessed qualitatively. Using traditional laboratory methods, quantitative data can be obtained for management purpose, but it is time consuming and expensive. Therefore, new technology aims to address these limitations, namely portable X-Ray fluorescence spectrometers (pXRF). This instrument can be used directly in the field, requires no soil sample preparations, and can simultaneously measure a wide range of elements qualitatively that are useful for pedological studies. The chemical composition (Ca, Fe, Ti and Zr) of soils at Tallavera Grove vineyard in New South Wales, Australia, was studied using a pXRF. The analysis of the soil's elemental concentration (i.e. Ca and Fe) using pXRF supports management decisions. Measuring the soil's Ca concentration can be used to identify Ca-rich parent materials (limestone). The limestone indicates good soil conditions for vine production. Fe content was used to identify areas of texture-contrast soils or soil with accumulation of clays in the B horizon. In addition, a soil weathering index was calculated using elemental concentrations (i.e. Ti and Zr) to explore the history of soil formation for making decision of management. This index showed that the soil in the vineyard was affected by two processes: the deposition of materials from elsewhere (Aeolian transport or soil erosion) and mixing of materials from upslope.

• Journal of Soil and Groundwater Environment
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• v.27 no.1
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• pp.17-24
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• 2022

This work examined the effect of mixing transition metal-based additives [FeCl₃, Fe-containing paper mill sludge (PMS), CoCl₂·H₂O, ZrO₂, and α-Fe₂O₃] on the thermochemical conversion of coffee waste (CW) in carbon dioxide-assisted pyrolysis process. Compared to the generation amounts of syngas (0.7 mole% H₂ & 3.0 mole% CO) at 700℃ from single pyrolysis of CW, co-pyrolysis in the presence of Fe- or Zr-based additives resulted in the enhanced production of syngas, with the measured concentrations of H₂ and CO ranging 1.1-3.4 mole% and 4.6-13.2 mole% at the same temperature, respectively. In addition, α-Fe₂O₃ biochar possessed the adsorption capacity of As(V) (19.3 mg g^-1) comparable to that of ZrO₂-biochar (21.2 mg g^-1). In conclusion, solid-type Fe-based additive can be highly considered as an efficient catalyst to simultaneously produce syngas (H₂ & CO) as fuel energy resource and metal-biochar as sorbent.

• Transactions of the Korean hydrogen and new energy society
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• v.22 no.4
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• pp.443-450
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• 2011

The three-reactor chemical-looping process (TRCL) for the production of hydrogen from natural gas is attractive for both $CO_2$ capture and hydrogen production. In this study, redox property of $Fe_2O_3$ and $WO_3$ supported with $ZrO_2$ and $MgAl_2O_4$ were studied with temperature programmed oxidation/reduction (TPO/R) experiment. All metal oxides were prepared by ball mill method. Metal oxides supported with $ZrO_2$ showed the good redox property in TPO and TPR tests. Reduction behavior was matched well the theoretical reduction mechanism. Metal oxides supported with $MgAl_2O_4$ formed a solid solution ($MgFe_{0.6}Al_{1.4}O_4$, $MgWO_4$). $Fe_2O_3$ showed more narrow reaction range and lower reaction temperature than $WO_3$.