• Title/Summary/Keyword: ZnS: Cu

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Effect of Heavy Metals on the Survival and Population Growth Rates of Marine Rotifer, Brachionus plicatilis (중금속(Cd, Cu, Zn) 농도구배에 따른 윤충류 Brachionus plicatilis의 생존 및 개체군 성장에 미치는 영향)

  • Hwang, Un-Ki;Ryu, Hyang-Mi;Heo, Seung;Chang, Soo-Jung;Lee, Ki-Won;Lee, Ju-Wook
    • Korean Journal of Environmental Biology
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    • v.34 no.4
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    • pp.353-360
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    • 2016
  • Effect of heavy metals(Cd, Cu, Zn) on the survival and population growth rates(PGR) of marine rotifer, Brachionus plicatilis were examined. B. plicatilis were exposed to Cd, Cu and Zn for 24 h to determine their survival and 72 h to determine their PGR. Survival rates in the control groups were greater than 90%. They were decreased with increasing concentrations of Cd, Cu and Zn. Survival rates were reduced in a concentration-dependent manner. Significant reduction in survival rates after exposure to Cd, Cu and Zn at concentration greater than 40.00, 0.13 and $10.00mg\;L^{-1}$, respectively. PGR in the control groups were greater than 0.50. They were decreased with increasing concentrations of heavy metals. PGR were reduced in a concentration-dependent manner. Significant reduction in PGR after exposure to Cd, Cu and Zn occurred at concentration greater than 12.5, 0.06 and $1.00mg\;L^{-1}$, respectively. The order of heavy metal toxicity based on PGR was Cu>Zn>Cd, with $EC_{50}$ (50% Effective Concentration) values of 0.12, 6.15 and $21.41mg\;L^{-1}$, respectively. The lowest-observed-effective-concentrations(LOEC) of PGR after exposure to Cd, Cu and Zn were 12.50, 0.06 and $1.00mg\;L^{-1}$, respectively. The No-observed-effective-concentrations(NOEC) of PGR after exposure to Cd, Cu and Zn were 6.25, 0.03 and $0.01mg\;L^{-1}$, respectively, in marine ecosystems have toxic effects on PGR of B. plicatilis. These results suggest that the PGR of B. plicatilis are useful tool to assess the effect of heavy metals on primary consumers in marine natural ecosystems.

Effects of Dietary Zn Levels and Kinds of Lipid on the Lipid Metabolism in the Rats (식이내 Zn의 수준과 지방의 종류가 흰쥐의 지방대사에 미치는 영향)

  • Hwang, Kyoung-Suk;Kim, Mi-Kyung
    • Journal of Nutrition and Health
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    • v.17 no.2
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    • pp.145-153
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    • 1984
  • This study was performed to investigate the effect of various levels of Zn(0, 30, 3000 ppms) and different kinds of lipid(corn oil, sesame oil or butter.) in the diet upon lipid metabolism and Zn & Cu concentration in various organs and tissues in weanling rats. The results obtained were summarized as following : 1) Food consumptions, body weight gains and F.E.R.s showed no significant differences among groups. 2) The contents of total lipids and total cholesterols in serum tended to increase with increase in lipid saturation and Zn levels. Those in per g liver were higher in butter groups and tended to be higher in low Zn groups. Total lipids contents in per g muscle tended to be higher in butter and high Zn groups, but total cholesterols contents in per g muscle tended to be higher in corn oil and low Zn groups. 3) Liver, serum and fecal Zn concentrations tended to be higher in high Zn groups than other Zn groups. The Cu concentrations in liver and serum tended to be lower in high Zn groups. On the contrary, the Cu concentrations in urine tended to be higher in high Zn groups.

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Characteristics of Natural Pedo-geochemical Background for Ni, Cu and Zn in Volcanic Soils of Jeju (제주도 화산회토양에서 Ni, Cu 및 Zn의 자연함유량 특성)

  • Lim, Han-Cheol;Moon, Kyung-Hwan;Jeon, Seung-Jong;Chang, Kong-Man;Hyun, Hae-Nam
    • Korean Journal of Soil Science and Fertilizer
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    • v.41 no.3
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    • pp.199-205
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    • 2008
  • This study was carried out to find out causes of high Ni content and characteristics of potential increase of Cu and Zn contents in the soils of Jeju area. Soil samples were collected from 4 series of Alfisols, 35 series of Andisols, 9 series of Entisols, 16 series of Inceptisols, and 1 series of Ultisols, respectively. Parent material (gravel) samples were also collected from the same sites where soil samples were taken. Both soil and parent material samples were analyzed for Ni, Cu, and Zn. The average Ni content of all the soil samples was $79.2mg\;kg^{-1}$, which was exceeded warning standard for Ni against the Soil Conservation Act in Korea, whereas that of Cu and Zn contents were lower than the warning standard for Cu and Zn. The difference of Ni, Cu and Zn content was not consistent depending upon soil color. Ni content in the soil samples from Entisols was particularly high, whereas that from the other soil orders was similar to each other. Cu and Zn contents in the soil samples were similar regardless of the difference in soil order. Ni content in Seongsan Formation(SSF), Cinder cone(C) and acicular Feldspar Olivine Basalt(FOB) was high, while that in Feldspar Basalt(FB) and Trachy Andesite lava(TA) was low. Ni content in the non-agricultural land was higher compared with that in the agricultural land, whereas Cu and Zn contents in the non-agricultural land were significantly lower than that of agricultural land. The topsoil/subsoil ratios for Ni content in most of the soil samples were less than 1, while that for total contents of Cu and Zn in many of the soil samples were larger than 1 indicating potential Cu and Zn accumulation in topsoil by artificial reasons.

Effects of Combined Application of Micronutrients on these Total and Relative Contents, Uptake Amounts, and Mutual Ratios in Orchardgrass and White Clover (Orchardgrass 및 White clover의 단파 및 혼파 재배에서 미량요소(Fe, Mn, Cu, Zn, Mo, B)의 조합시비가 목초의 총 함량, 상대 함량, 탈취량 및 상호비율 변화에 미치는 영향)

  • Jung, Yeun-Kyu
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.24 no.2
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    • pp.93-104
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    • 2004
  • This pot experiment was conducted to investigate the effects of combined micronutrient application($T_1$; control, $T_2$; Fe, $T_3$; Fe+Mn, $T_4$; Fe+Mn+Cu, $T_5$ ; Fe+Mn+Cu+Zn, $T_6$ ; Fe+Mn+Cu+Zn+Mo, T$_{7}$; Fe+Mn+Cu+Zn + Mo + B) on forage performance of pure and mixed cultures of orchardgrass and white clover. The fifth part was concerned with the changes in the total and relative contents, uptake amounts, and mutual ratios. of micronutrients in forages. The results obtained are summarized as follows: 1. The relative contents(total contents of 6 micronutrients = 100%) of Fe and Mn were considerably influenced by the antagonism between Fe and Mn, and also were influenced by the differences in Mn-absorption between orchardgrass and white clover. Compared with pure culture, orchardgrass showed high relative contents of Mn, and low relative contents of Fe and B in mixed culture. White clover, however, tended to be exactly opposed to the above trends. In relative contents, the T$_6$ 6/ resulted generally in decrease of Fe. However the $T_7$ resulted in increase of Mn and B. In addition, the $T_7$ resulted in decrease of Cu and Zn in orchardgrass, and Mo in white clover. 2. In general, there were differences in the tendency between the yield changes and the uptake amounts of micronutrients. General differences have been showed in the uptake amounts and mutual ratios of micronutrients based on the forage species, pure/mixed culture, additional fertilization, and antagonism. The uptake amounts of total micronutrients were generally increased by the treatments with increased combination. In uptake amounts, the $T_7$ resulted in the increase of Mn and B, and decrease of Mo. 3. The mutual ratios of Fe/Mn, Fe/Cu, and Mn/Cu were considerably influenced by the antagonism between Fe and Mn. At the $T_7$ , very low ratio of Fe/Mo affected by the T6 tended to be somewhat improved because of the decrease of Mo content. The poor growth of forages at the $T_6$ was improved by the $T_7$ . This fact was likely to be caused by the adequate B/Mo ratio.

Contamination Characteristics of Heavy Metals in Indoor, Outdoor and Playground of Schools in the Gochang-Gun, Chonbuk Province of South Korea (전북 고창지역 학교 실내외 환경의 중금속 오염 특성)

  • Kim, Yong-Hwan;Chung, Duk-Ho;Cho, Kyu-Seong
    • Journal of the Korean earth science society
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    • v.27 no.1
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    • pp.73-82
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    • 2006
  • Dust samples were collected from 10 middle and high schools in the Gochang-Gun, Korea. Heavy metal concentrations were determined for the dry-deposited dusts from indoor and outdoor of classroom and playground of each sampling site. Concentrations of Cd, Cu, Pb and Zn in indoor's dusts were highly concentrated. Also concentrations of Cu, Ni, Pb and Zn in outdoor's dusts were highly concentrated. Concentrations of Cd, Cu and Zn in the dusts were much higher than the world average contents in soil and environmental orientation value. These levels are similar to those of the dust samples at middle schools and high schools located in Jeonju-city, Korea. Compared with concentrations of heavy metals in soils and dusts in Korea, the environment of indoor and outdoor of classroom is highly concentrated except for Cu, Zn. The concentrations of playground is less than that of residential dust and main road dust and playground in Jeonju-city. Playground dusts in 1 school exhibited the enhanced heavy metal pollution with a pollution index (Kloke, 1979) greater than 1.0, but indoor and outdoor dusts in 7 schools exhibited the enhanced heavy metal pollution with a pollution index (by Kloke) yester than 1.0.

Behavior of trace metals in Masan Bay, Korea during oxygen deficient period (하계 마산만 혐기성 환경에서의 미량금속의 거동)

  • Jin Y.H.;Kim K.T.;Chung C.S.;Kim S.H.;Yang D.B.;Hong G.H.;Lee K.W.
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.3 no.4
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    • pp.56-64
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    • 2000
  • Behavior of trace metals in Masan Bay, Korea was studied in August 1998 when the oxygen deficient condition occurred. Dissolved Cd and Zn concentration in the surface waters decreased with increasing distance from Masan Harbor. Dissolved concentrations of Cd, Cu Pb and Zn in the surface waters were higher than bottom waters. Particulate(acid-teachable fraction) concentrations of Cu, Cd and Pb in the surface waters of Masan Bay decreased with increasing distance from Masan Harbor. Bottom waters contained higher concentrations of particulate Cd, Cu, Pb and Zn than surface waters. Distribution coefficients between dissolved and particulate phase (K/sub d/) of Cu and Cd decreased with the increasing distance from the Harbor, possibly due to reaction of these elements with sewage-derived particulate matter Al, Zn, Cu, Cd, and Pb in the surface sediment showed relatively high concentration in the inner Masan Bay.

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Background Levels and Daily Intake of As, Cd, Cu, Pb and Zn in White Rice Produced in Korea (우리 나라 백미의 As, Cd, Cu, Pb 및 Zn의 자연함유량과 일일 섭취량 조사)

  • 정명채
    • Economic and Environmental Geology
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    • v.36 no.5
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    • pp.357-363
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    • 2003
  • The objective of this study is to investigate background levels of As and heavy metals (Cd, Cu, Pb and Zn) and their dietary intakes from white rice produced at various provinces in Korea during 2000. Except Jeju-do, sixty-three rice grain samples were taken at 8 provinces and analyzed for the elements using ICP-AES after acid digestion. The average contents of hi, Cd, Cu, Pb and Zn in the samples were 0.126, 0.040, 1.96, 0.361 and 16.6 mg/kg(DW), respectively. These levels are within the ranges of worldwide average concentrations in rice grains reported by various research. Assuming the rice consumption of 256 g/day by overall households in Korea, the amount of daily intake of As, Cd, Cu, Pb and Zn by the rice were estimated to be 32.3, 10.2, 502, 92.4 and 4,250 ${\mu}g$/day, respectively. Those amount of daily intakes of the elements by the rice are within the WHO's guide for trace elements, however, rice consumption is one of the most important sources of dietary intake of As and some heavy metals in Korean population.

Evaluation and design of Multi-layered thin films with EMP simulation (EMP simulation을 활용한 다층 박막의 평가 및 설계)

  • Kim, Jun-Sik;Jang, Gun-Ik
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.06a
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    • pp.312-312
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    • 2009
  • 본 연구에서는 Thermal evaporator(저항 가열 식 진공 증착법) 장비를 활용하여 ZnS/$Na_3AlF_6$/ZnS/Cu-$0.25\lambda$, ZnS/$CaF_2$/ZnS/Cu-$0.25\lambda$의 다층 박막을 glass 기판위에 증착하였다. 증착 전에 EMP(Essential Macleod Program)을 활용하여 광학적 특성을 simulation하였으며 다층 박막 제작 후 Spectrophotometer를 사용하여 반사율 및 색상을 CIE $L^*a^*b^*$ 좌표에 표시하여 고 굴절 물질에 따른 광학적 특성을 EMP simulation과 비교하였다. AES depth profile을 분석하여 막의 두께 및 층간 확산여부에 관하여 관측 하였다. 저굴절 물질을 Na3AlF6로 사용하였을 경우 simulation과 결과 값 모en purple 계통의 색상을 나타냈으며 CaF2를 사용하였을 경우 simulation은 purple 계통의 색상, 결과값은 red-yellow 계통의 색상으로 나타났다.

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White Electroluminescent Device Implementation and Its Electrical and Optical Properties (백색 전계 발광소자의 구현과 전기 .광학적 특성)

  • 양종경;김종욱;김진만;노승수;박홍용;이종찬;박대희
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.343-346
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    • 2001
  • To implementation of white electroluminescnet device in this paper, two methods were tried without synthesis of new white EL phosphor. At first, ZnS:Mn,Cl was mixed with ZnS:Cu from 20 to 50 weight percents. Second, ZnS:Mn,Cl was mixed with blue dye from 0 to 1.2 weight percents. The devices for experiments were measured as following; current-voltage, emission spectrum, brightness-voltage and CIE coordinate system and frequency properties.

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ZnO/Cu/Al2O3 transparent heaters fabricated by magnetron sputtering (마그네트론 스퍼터링법으로 제조된 ZnO/Cu/Al2O3 투명 면상 발열체 연구)

  • Min, Changheum;Choi, Dooho
    • Journal of the Korean institute of surface engineering
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    • v.55 no.5
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    • pp.284-291
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    • 2022
  • Herein, we studied ultrathin Cu-layer-based transparent heaters embedded between a ZnO underlayer and an Al2O3 overlayer. The anti-reflecting functions for the ZnO and Al2O3 layers by independently varying the layer thicknesses, with the Cu layer thickness fixed at 8.5 nm. The smallest visible light transmittance of 11.1% was achieved when the overlayer and underlayer thicknesses were 90 and 30 nm, respectively. We conducted electrically driven Joule heating test for the Cu layers having thicknesses of 8.5 nm (Rs: 14.7 Ohm/sq.) and 19 nm (Rs: 3.4 Ohm/sq.). External voltages were increased with an interval of 2 V until irreversible failures occurred at temperatures of ~390 ℃ and 550 ℃, respectively. At each voltage increase before heater failures, the heater exhibited superior thermal response with the heater temperatures reaching over 90% of the final temperatures. The heaters also showed excellent reproducibility when turning on and off the heater repeatedly.