• Title/Summary/Keyword: ZnO/ZnS

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Thin film transistor with pulsed laser deposited ZnO active channel layer (펄스 레이저 증착법으로 제작한 ZnO를 채널층으로 한 박막트랜지스터)

  • Shin, P.K.;Kim, C.J.;Song, J.H.;Kim, S.J.;Kim, J.T.;Cho, J.S.;Lee, B.S.;Ebihara, Kenji
    • Proceedings of the KIEE Conference
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    • 2005.07c
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    • pp.1884-1886
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    • 2005
  • KrF 펄스 레이저 증착법(pulsed laser deposition: PLD)으로 ZnO 박막을 증착하여 평판 디스플레이 소자 구동용 박막 트랜지스터(thin film transistor) 소자를 제작하였다. 전도성이 높은 실리콘웨이퍼(c-Si, 하부전극) 기판 위에 LPCVD 법으로 silicon nitride 박막을 절연막으로 형성하고, 다양한 공정 조건에서 펄스 레이저 증착법으로 제작한 ZnO 박막을 증착하여 채널층으로 하였으며, Al 박막을 증착하고 패터닝하여 소스 및 드레인 전극으로 하였다. ZnO 박막의 증착 시에 기판 온도를 다양하게 조절하고 산소 분압을 변화시켜 ZnO 박막의 특성을 조절하였다. 제작된 박막의 표면특성은 AFM(atomic force microscopy)로 분석하고, 결정특성은 XRD(X-ray diffraction)로 조사하였다. ZnO 박막의 전기적 특성은 Hall-van der Pauw 법으로 측정하였고, 광학 투과도(optical transparency)를 UV-visible photometer로 조사하였다. ZnO-TFT 소자는 $10^6$ 수준의 on-off ratio와 $2.4{\sim}6.1cm^2/V{\cdot}s$의 전계효과이동도(field effect mobility)를 보였다.

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The Properties Characterization of ZnO Thin Film Grown by RF Sputtering (RF스퍼터링법으로 제작한 ZnO박막의 특성평가)

  • Jung, S.M.;Chong, K.C.;Choi, Y.S.;Kim, D.Y.;Kim, C.S.;Yi, Jun-Sin
    • Proceedings of the KIEE Conference
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    • 1997.07d
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    • pp.1433-1435
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    • 1997
  • ZnO shows the properties of wide conductivity variation, high optical transmittance, and excellent piezoelectricity. Using these properties of ZnO, the material applications were extended to sensors, SAW filters, solar cells, and display devices. This paper investigated transmittance influencing factors for thin film ZnO grown by RF magnetron sputtering. The growth rate and structural investigation were carried out in conjunction with optical transmittance characteristics of thin film ZnO. The glass substrate temperature of $175^{\circ}C$ exhibited a preferential crystallization along (002) orientation. Transmittance of ZnO film deposited at the substrate temperature of $175^{\circ}C$ showed higher than 92%. An active sputter gas was investigated with a variation of $O_2$ partial pressure from 0 to 10% in an Ar atmosphere. ZnO film grown in 100% Ar gas shows that a reduced transmittance of 82% at the short wavelengths and decreased resistivity value. As the partial pressure of $O_2$ gas increased, the optical transmittance was increased above 90% at the short wavelengths, however, resistivity was drastically increased to higher than $10^4{\Omega}$-cm.

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A Study of Thin-Film Transistor with Mg0.1Zn0.9O/ZnO Active Structure (Mg0.1Zn0.9O/ZnO 활성층 구조의 박막트랜지스터 연구)

  • Lee, Jong Hoon;Kim, Hong Seung;Jang, Nak Won;Yun, Young
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.27 no.7
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    • pp.472-476
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    • 2014
  • We report the characteristics of thin-film transistor (TFT) to make the bi-channel structure with stacked $Mg_{0.1}Zn_{0.9}O$ (Mg= 10 at.%) and ZnO. The ZnO and $Mg_{0.1}ZnO_{0.9}O$ thin films were deposited by radio frequency (RF) co-sputter system onto the thermally oxidized silicon substrate. A total thickness of active layer was 50 nm. Firstly, the ZnO thin films were deposited to control the thickness from 5 nm to 30 nm. Sequentially, the $Mg_{0.1}ZnO_{0.9}O$ thin films were deposited to change from 45 nm to 20 nm. The bi-layer TFT shows more improved properties than the single layer TFT. The field effect mobility and subthreshold slope for $Mg_{0.1}ZnO_{0.9}O$/ZnO-TFT are $7.40cm^2V^{-1}s^{-1}$ and 0.24 V/decade at the ZnO thickness of 10 nm, respectively.

Synthesis of ZnO Powder by Precipitation method and Its Cathodoluminescence Properties (침전법에 의한 ZnO 분체합성 및 그 형광특성)

  • 김봉철;박지훈;신효순;이석기;이병교
    • Journal of the Korean Ceramic Society
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    • v.35 no.2
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    • pp.107-114
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    • 1998
  • ZnO powder as phosphor was prepared by precipitation method with zinc acetate and ammonia solution and the size and shapes of precipitates were examined with variation of pH and concentration of solution. Its cathodoluminesence properties was evaluated with various heat tratment condition. Optimum con-dition for uniform precipitates was 11.8 of pH and 0.4M of concentration. ZnO:Zn phosphor was obtained by heat treatment of precipitates in reduction atmosphere using ZnS powder. With addition of 20wt% ZnS and 1 hour firing at 1000$^{\circ}C$ the highest cathodoluminescence was obtained.

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Alanysis of the Optical Properties of p-type ZnO Thin Films Doped by P based on Ampouele-tube Method (Ampoule-tube 법으로 Phosphorus를 도핑한 P형 ZnO 박막의 광학적 특성 분석)

  • Yoo, In-Sung;Oh, Sang-Hyun;So, Soon-Jin;Park, Choon-Bae
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.11a
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    • pp.145-146
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    • 2006
  • The most Important research topic in the development of ZnO LED and LD is the production of p-type ZnO thin film that has minimal stress with outstanding stoichiometric ratio. In this study, Phosphorus diffused into the undoped ZnO thin films using the ampoule-tube method for the production of p-type znO thin films. The undoped ZnO thin films were deposited by RF magnetron sputtering system on $GaAs_{0.6}P_{0.4}$/GaP and Si wafers. 4N Phosphorus (P) was diffused into the undoped ZnO thin films in ampoule-tube which was performed and $630^{\circ}C$ during 3hr. We found the diffusion condition of the conductive ZnO films which had p-type properties with the highest mobility of above 532 $cm^2$/Vs compared with other studies PL spectra measured at 10K for the purpose of analyzing optical properties of p-type ZnO thin film showed strong PL intensity in the UV emission band around 365nm ~ 415nm and 365nm ~ 385nm.

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Deterioration Characteristics of ZnO Surge Arrester Blocks for Power Distribution Systems Due to Impulse Currents (임펄스전류에 의한 배전용 ZnO 피뢰기 소자의 열화특성)

  • Lee, Bok-Hee;Cho, Sung-Chul;Yang, Soon-Man
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.27 no.3
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    • pp.79-86
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    • 2013
  • In order to analyze the electrical performance of ZnO surge arresters stressed by the combined DC and AC voltages that are generated in DC/AC converter systems, the leakage current properties of ZnO surge arrester blocks deteriorated by impulse currents were investigated. The test specimens were deteriorated by the 8/$20{\mu}s$ impulse current of 2.5kA and the leakage currents flowing into the deteriorated zinc oxide(ZnO) arrester blocks subjected to the combined DC and power frequency AC voltages are measured. As a result, the leakage currents flowing through deteriorated ZnO surge arrester blocks were higher than those flowing through the fine ZnO surge arrester blocks and the larger the injection number of 8/$20{\mu}s$ impulse current of 2.5kA is, the greater the leakage current is. The leakage current-voltage curves(I-V curves) of the fine and deteriorated ZnO surge arrester blocks stressed by the combined DC and AC voltages show significant difference in the low conduction region. Also the cross-over phenomenon is observed at the voltage close to the knee of conduction on plots of I-V curves.

A Study on the ZnO Supported Silica Gel (ZnO가 담지된 실리카 겔 연구)

  • Kim, S.Y.;Kim, M.Y.;Ju, C.S.
    • Journal of Power System Engineering
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    • v.15 no.4
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    • pp.75-78
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    • 2011
  • There are various types of materials used in electronic industry, such as electrode material, conductor, insulator, anode, cathode and semiconductor. Electrode material type is Cu, Ti, ZnO and so on. Especially if we use mixed ZnO in soil cement or silica gel, we can have advantages in ice road to prevent freezing. We have great impact if we use supported in inorganic substances like silica gel. In this paper we have studied that ZnO supported silica gel and its properties. Zinc acetate dissolved in distilled water were loaded on the silica gel by the reaction with ammonia at $80^{\circ}C$. And we investigated particle structures of ZnO by scanning electron microscopy(SEM) and X-ray diffraction(XRD).

Thermal evaporation에 의해 성장된 ZnO nanorod의 합성 온도에 따른 특성 평가

  • An, Cheol-Hyeon;Han, Won-Seok;Gang, Si-U;Kim, Yeong-Lee;Choe, Mi-Gyeong;Gong, Bo-Hyeon;Kim, Dong-Chan;Jo, Hyeong-Gyun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.11a
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    • pp.62-62
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    • 2007
  • ZnO 박막이 성장된 Si기판을 이용하여 Thermal evaporation을 사용하여 온도에 따라 합성된 1-D의 구조의 ZnO nanorods의 형상과 특성에 대하여 연구를 하였다. 합성온도는 $700^{\circ}C{\sim}900^{\circ}C$를 사용하였고 온도가 낮아짐에 따라 Vertical한 1-D ZnO가 합성이 되는 것을 알 수 있었다. 특히, $700^{\circ}C$에서 합성된 1-D ZnO는 ~100nm의 폭을 가지고 800nm의 길이의 Nanorods로 성장이 되는 것을 알 수 있었고, 상온 PL측정을 통해 온도가 증가함에 따라 O 결핍 또는 Zn의 과잉에 의한 Deep level emission이 증가하는 것을 알 수 있었다.

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Dry Etching Behaviors of ZnO and $Al_2O_3$ Films in the Fabrication of Transparent Oxide TFT for AMOLED Display Application

  • Yoon, S.M.;Hwang, C.S.;Park, S.H.;Chu, H.Y.;Cho, K.I.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08b
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    • pp.1273-1276
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    • 2007
  • We provide a newly developed dry etching process for the fabrication of ZnO-based oxide TFTs. The etching characteristics of ZnO (active layer) and $Al_2O_3$ (gate insulator) thin films were systematically investigated when the etching gas mixtures and their mixing ratios were varied in the heliconplasma etching system.

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Synthesis of ZnS:Mn-Gly-C60 Nanocomposites and Their Photocatalytic Activity of Brilliant Green

  • Li, Jiulong;Ko, Weon Bae
    • Elastomers and Composites
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    • v.53 no.2
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    • pp.75-79
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    • 2018
  • ZnS:Mn-glycine (ZnS:Mn-Gly) nanocomposites were synthesized by capping ZnS:Mn nanocomposites with glycine. Zinc sulfate heptahydrate ($ZnSO_4{\cdot}7H_2O$), glycine ($C_2H_5NO_2$), manganese sulfate monohydrate ($MnSO_4{\cdot}H_2O$), and sodium sulfide ($Na_2S$) were used as the source reagents. $ZnS:Mn-Gly-C_{60}$ nanocomposites were obtained by heating the ZnS:Mn-Gly nanocomposites and fullerene ($C_{60}$) at a 2:1 mass ratio in an electric furnace at $700^{\circ}C$ for 2 h. X-ray diffraction (XRD) was used to characterize the crystal structure of the synthesized nanocomposites. The photocatalytic activity of the $ZnS:Mn-Gly-C_{60}$ nanocomposites was evaluated, via the degradation of brilliant green (BG) dye under 254 nm irradiation, with a UV-vis spectrophotometer.