• Title/Summary/Keyword: Zirconium hydride

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The effect of neutron irradiation on hydride reorientation and mechanical property degradation of zirconium alloy cladding

  • Jang, Ki-Nam;Kim, Kyu-Tae
    • Nuclear Engineering and Technology
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    • v.49 no.7
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    • pp.1472-1482
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    • 2017
  • Zirconium alloy cladding tube specimens were irradiated at $380^{\circ}C$ up to a fast neutron fluence of $7.5{\times}10^{24}n/m^2$ in a research reactor to investigate the effect of neutron irradiation on hydride reorientation and mechanical property degradation. Cool-down tests from $400^{\circ}C$ to $200^{\circ}C$ under 150 MPa tensile hoop stress were performed. These tests indicate that the irradiated specimens generated a smaller radial hydride fraction than did the unirradiated specimens and that higher hydrogen content generated a smaller radial hydride fraction. The irradiated specimens of 500 ppm-H showed smaller ultimate tensile strength and plastic strain than those characteristics of the 250 ppm-H specimens. This mechanical property degradation caused by neutron irradiation can be explained by tensile hoop stress-induced microcrack formation on the hydrides in the irradiation-damaged matrix and subsequent microcrack propagation along the hydrides and/or through the matrix.

Non-Destructive Detection of Hydride Blister in PHWR Pressure Tube Using an Ultrasonic Velocity Ratio Method

  • Cheong Yong-Moo;Lee Dong-Hoon;Kim Sang-Jae;Kim Young-Suk
    • Nuclear Engineering and Technology
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    • v.35 no.5
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    • pp.369-377
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    • 2003
  • Since Zr-2.5Nb pressure tubes have a high risk for the formation of blisters during their operation in pressurized heavy water reactors, there has been a strong incentive to develop a method for the non-destructive detection of blisters grown on the tube surfaces. However, because there is little mismatch in acoustic impedance between the hydride blisters and zirconium matrix, it is not easy to distinguish the boundary between the blister and zirconium matrix with conventional ultrasonic methods. This study has focused on the development of a special ultrasonic method, so called ultrasonic velocity ratio method for a reliable detection of blisters formed on Zr-2.5Nb pressure tubes. Hydride blisters were grown on the outer surface of the Zr-2.5Nb pressure tube using a cold finger attached to a steady state thermal diffusion equipment. To maximize a difference in the ultrasonic velocity in hydride blisters and the zirconium matrix, the ultrasonic velocity ratio of longitudinal wave to shear wave, $V_L/V_S$, has been determined based on the flight time of the longitudinal echo and reflected shear echo from the outer surface of the tubes. The feasibility of the ultrasonic velocity ratio method is confirmed by comparing the contour plots reproduced by this method with those of the blisters grown on the Zr-2.5Nb pressure tubes.

THE EFFECT OF HYDROGEN AND OXYGEN CONTENTS ON HYDRIDE REORIENTATIONS OF ZIRCONIUM ALLOY CLADDING TUBES

  • CHA, HYUN-JIN;JANG, KI-NAM;AN, JI-HYEONG;KIM, KYU-TAE
    • Nuclear Engineering and Technology
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    • v.47 no.6
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    • pp.746-755
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    • 2015
  • To investigate the effect of hydrogen and oxygen contents on hydride reorientations during cool-down processes, zirconium-niobium cladding tube specimens were hydrogen-charged before some specimens were oxidized, resulting in 250 ppm and 500 ppm hydrogen-charged specimens containing no oxide and an oxide thickness of $0.38{\mu}m$ at each surface. The nonoxidized and oxidized hydrogen-charged specimens were heated up to $400^{\circ}C$ and then cooled down to room temperature at cooling rates of $0.3^{\circ}C/min$ and $8.0^{\circ}C/min$ under a tensile hoop stress of 150 MPa. The lower hydrogen contents and the slower cooling rate generated a larger fraction of radial hydrides, a longer radial hydride length, and a lower ultimate tensile strength and plastic elongation. In addition, the oxidized specimens generated a smaller fraction of radial hydrides and a lower ultimate tensile strength and plastic elongation than the nonoxidized specimens. This may be due to: a solubility difference between room temperature and $400^{\circ}C$; an oxygen-induced increase in hydrogen solubility and radial hydride nucleation energy; high temperature residence time during the cool-down; or undissolved circumferential hydrides at $400^{\circ}C$.

Temperature-dependent axial mechanical properties of Zircaloy-4 with various hydrogen amounts and hydride orientations

  • Bang, Shinhyo;Kim, Ho-a;Noh, Jae-soo;Kim, Donguk;Keum, Kyunghwan;Lee, Youho
    • Nuclear Engineering and Technology
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    • v.54 no.5
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    • pp.1579-1587
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    • 2022
  • The effects of hydride amount (20-850 wppm), orientation (circumferential and radial), and temperature (room temperature, 100 ℃, 200 ℃) on the axial mechanical properties of Zircaloy-4 cladding were comprehensively examined. The fraction of radial hydride fraction in the cladding was quantified using PROPHET, an in-house radial hydride fraction analysis code. Uniaxial tensile tests (UTTs) were conducted at various temperatures to obtain the axial mechanical properties. Hydride orientation has a limited effect on the axial mechanical behavior of hydrided Zircaloy-4 cladding. Ultimate tensile stress (UTS) and associated uniform elongation demonstrated limited sensitivity to hydride content under UTT. Statistical uncertainty of UTS was found small, supporting the deterministic approach for the load-failure analysis of hydrided Zircaloy-4 cladding. These properties notably decrease with increasing temperature in the tested range. The dependence of yield strength on hydrogen content differed from temperature to temperature. The ductility-related parameters, such as total elongation, strain energy density (SED), and offset strain decrease with increasing hydride contents. The abrupt loss of ductility in UTT was found at ~700 wppm. Demonstrating a strong correlation between total elongation and offset strain, SED can be used as a comprehensive measure of ductility of hydrided zirconium alloy.

Improving the Neutronic Characteristics of a Boiling Water Reactor by Using Uranium Zirconium Hydride Fuel Instead of Uranium Dioxide Fuel

  • Galahom, Ahmed Abdelghafar
    • Nuclear Engineering and Technology
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    • v.48 no.3
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    • pp.751-757
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    • 2016
  • The present work discusses two different models of boiling water reactor (BWR) bundle to compare the neutronic characteristics of uranium dioxide ($UO_2$) and uranium zirconium hydride ($UZrH_{1.6}$) fuel. Each bundle consists of four assemblies. The BWR assembly fueled with $UO_2$ contains $8{\times}8$ fuel rods while that fueled with $UZrH_{1.6}$ contains $9{\times}9$ fuel rods. The Monte Carlo N-Particle Transport code, based on the Mont Carlo method, is used to design three dimensional models for BWR fuel bundles at typical operating temperatures and pressure conditions. These models are used to determine the multiplication factor, pin-by-pin power distribution, axial power distribution, thermal neutron flux distribution, and axial thermal neutron flux. The moderator and coolant (water) are permitted to boil within the BWR core forming steam bubbles, so it is important to calculate the reactivity effect of voiding at different values. It is found that the hydride fuel bundle design can be simplified by eliminating water rods and replacing the control blade with control rods. $UZrH_{1.6}$ fuel improves the performance of the BWR in different ways such as increasing the energy extracted per fuel assembly, reducing the uranium ore, and reducing the plutonium accumulated in the BWR through burnup.

Methodology for numerical evaluation of fracture resistance under pinch loading of spent nuclear fuel cladding containing reoriented hydrides

  • Seyeon Kim;Sanghoon Lee
    • Nuclear Engineering and Technology
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    • v.56 no.6
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    • pp.1975-1988
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    • 2024
  • It is important to maintain cladding integrity in spent nuclear fuel management. This study proposes a numerical analysis method to evaluate the fracture resistance of irradiated zirconium alloy cladding under pinch load known to cause Mode-III failure. The mechanical behavior and fracture of the cladding under pinch loading can be evaluated by a Ring Compression Test (RCT). To simulate the fracture of hydride precipitates, zirconium matrix, and Zr/hydride interfaces under the stress field generated by RCT, a micro-structure crack propagation simulation method based on Continuum Damage Mechanics (CDM) has been proposed. Our RCT simulation model was constructed from microscopic images of irradiated cladding. In this study, we developed an automated process to generate a pixel-based finite element model by separating the hydride precipitates, zirconium matrix, and interfaces using an image segmentation method. The appropriate element size was selected to ensure the efficiency and accuracy of a crack propagation simulation. The load-displacement curves and strain energies from RCT were compared and analyzed with the simulation results of different element sizes. The finalized RCT simulation model can be used to establish the failure criterion of fuel rods under pinch loading. The advantages and limitations of the proposed method are fully discussed here.