• Title/Summary/Keyword: Zirconium alloy

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The effect of neutron irradiation on hydride reorientation and mechanical property degradation of zirconium alloy cladding

  • Jang, Ki-Nam;Kim, Kyu-Tae
    • Nuclear Engineering and Technology
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    • v.49 no.7
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    • pp.1472-1482
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    • 2017
  • Zirconium alloy cladding tube specimens were irradiated at $380^{\circ}C$ up to a fast neutron fluence of $7.5{\times}10^{24}n/m^2$ in a research reactor to investigate the effect of neutron irradiation on hydride reorientation and mechanical property degradation. Cool-down tests from $400^{\circ}C$ to $200^{\circ}C$ under 150 MPa tensile hoop stress were performed. These tests indicate that the irradiated specimens generated a smaller radial hydride fraction than did the unirradiated specimens and that higher hydrogen content generated a smaller radial hydride fraction. The irradiated specimens of 500 ppm-H showed smaller ultimate tensile strength and plastic strain than those characteristics of the 250 ppm-H specimens. This mechanical property degradation caused by neutron irradiation can be explained by tensile hoop stress-induced microcrack formation on the hydrides in the irradiation-damaged matrix and subsequent microcrack propagation along the hydrides and/or through the matrix.

Effect of Steady-State Oxidation on Tensile Failure of Zircaloy Cladding

  • Kim, Taeho;Choi, Kyoung Joon;Yoo, Seung Chang;Lee, Yunju;Kim, Ji Hyun
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.20 no.2
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    • pp.161-170
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    • 2022
  • The effect of oxidation time on the characteristics and mechanical properties of spent nuclear fuel cladding was investigated using Raman spectroscopy, tube rupture test, and tensile test. As oxidation time increased, the Raman peak associated with the tetragonal zirconium oxide phase diminished and merged with the Raman peak associated with the monoclinic zirconium oxide phase near 333 cm-1. Additionally, the other tetragonal zirconium oxide phase peak at 380 cm-1 decreased after 100 d of oxidation, whereas the zirconium monoclinic oxide peak became the dominant peak. The oxidation time had no effect on the tube rupture pressure of the oxidized zirconium alloy tube. However, the yield and tensile stresses of the oxidized nuclear fuel cladding tube decreased after 100 d of oxidation. The results of the scanning electron microscopy and transmission electron microscopy were represented with the in-situ Raman analysis result for the oxide characteristics generated on the cladding of spent nuclear fuel.

A TISSUE RESPONSE TO THE TITANIUM ALLOY (Ti-13Zr-6Nb) IN VIVO

  • Kim Chang-Su;Lee Seok-Hyung;Shin Sang-Wan;Suh Kyu-Won;Ryu Jae-Jun
    • The Journal of Korean Academy of Prosthodontics
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    • v.42 no.6
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    • pp.619-627
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    • 2004
  • Statement of problem. Mechanisms of tissue-implant interaction and the effect of the implant surface on the behavior of cells has not yet been clarified. Purpose. This study was performed to investigate the tissue reaction to the titanium alloy submerged into rat peritoneum in vivo. Materials and methods. Titanium alloys (titanium-13Zirconium-6Niobium) were inserted inside the peritoneal cavity of Sprague Dawley rats. After 3 months, the tissue formed around the inserted titanium alloys were examined with a light-microscope. Tissue reaction around the material was analyzed by confocal microscopy to evaluate their biocompatibility in a living body. Results. In in vivo study, foreign body type multinucleated giant cells were found in the fibrous tissue formed as a reaction to the foreign material (4 in 20 cases), but the inflammatory reaction was very weak. After experiment, the contaminants of biomaterials was removed from living tissue. In confocal microscopy, we observed that the staining of vinculin and actin showed mixed appearance. In a few cases, we found that the staining of vinculin and beta-catenin showed the prominent appearance. Conclusion. We found that titanium-13Zirconium-6Niobium alloy was an excellent biomaterial.

Design of Zr-7Si-xSn Alloys for Biomedical Implant Materials (생체의료용 임플란트 소재를 위한 Zr-7Si-xSn 합금설계)

  • Kim, Minsuk;Kim, Chungseok
    • Journal of the Korean Society for Heat Treatment
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    • v.35 no.1
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    • pp.8-19
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    • 2022
  • The metallic implant materials are widely used in biomedical industries due to their specific mechanical strenth, corrosion registance, and superior biocompatability. These metallic materials, however, suffer from the stress-shielding effect and the generation of artifacts in the magnetic resonance imaging exam. In the present study, we develope a Zr-based alloys for the biomedical implant materials with low elastic modulus and low magnetic susceptibility. The Zr-7Si-xSn alloys were fabricated by an arc melting process. The elastic modulus was 24~31 GPa of the zirconium-based alloy. The average magnetic susceptibility value of the Zr-7Si-xSn alloy was 1.25 × 10-8cm3g-1. The average Icorr value of the Zr-7Si-xSn alloy was 0.2 ㎂/cm2. The Sn added zirconium alloy, Zr-7Si-xSn, is very interested and attractive as a biomaterial that reduces the stress-shielding effect caused by the difference of elastic modulus between human bone and metallic implant.

Effect of Microstructure and Alloying Element on the ISCC Characteristics of Zr Cladding (Zr 피복관의 ISCC 특성에 미치는 미세조직 및 첨가원소의 영향)

  • Park, Sang Yoon;Choi, Byoung Kwon;Lee, Myung Ho;Kim, Jun Hwan;Jeong, Yong Hwan
    • Journal of the Korean Society for Heat Treatment
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    • v.18 no.3
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    • pp.164-171
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    • 2005
  • Iodine-Induced Stress Corrosion Cracking (ISCC) properties of Zircaloy-4 and HANA4 developed in KAERI for the high burn-up nuclear fuel cladding were evaluated. To confirm the effect of final heat treatment on ISCC resistance of Zr-alloy, stress relieved and recrystallized specimens were prepared and tested. With the pre-cracked specimen at internal surface, ISCC crack propagation rates and threshold stress intensity factor ($K_{ISCC}$) based on the fracture mechanics were measured by internal pressurization test at $350^{\circ}C$ in iodine environment. $K_{ISCC}$ of Zircaloy-4 and HANA4 cladding were $3.3MPa{\cdot}m^{1/2}$ and $4.4MPa{\cdot}m^{1/2}$, respectively. Pitting corrosion at the crack surface was observed and it seemed that TG crack propagation was derived from the pitting.

Assessment of the efficiency of a pre- versus post-acquisition metal artifact reduction algorithm in the presence of 3 different dental implant materials using multiple CBCT settings: An in vitro study

  • Shahmirzadi, Solaleh;Sharaf, Rana A.;Saadat, Sarang;Moore, William S.;Geha, Hassem;Tamimi, Dania;Kocasarac, Husniye Demirturk
    • Imaging Science in Dentistry
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    • v.51 no.1
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    • pp.1-7
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    • 2021
  • Purpose: The aim of this study was to assess artifacts generated in cone-beam computed tomography (CBCT) of 3 types of dental implants using 3 metal artifact reduction (MAR) algorithm conditions (pre-acquisition MAR, post-acquisition MAR, and no MAR), and 2 peak kilovoltage (kVp) settings. Materials and Methods: Titanium-zirconium, titanium, and zirconium alloy implants were placed in a dry mandible. CBCT images were acquired using 84 and 90 kVp and at normal resolution for all 3 MAR conditions. The images were analyzed using ImageJ software (National Institutes of Health, Bethesda, MD) to calculate the intensity of artifacts for each combination of material and settings. A 3-factor analysis of variance model with up to 3-way interactions was used to determine whether there was a statistically significant difference in the mean intensity of artifacts associated with each factor. Results: The analysis of all 3 MAR conditions showed that using no MAR resulted in substantially more severe artifacts than either of the 2 MAR algorithms for the 3 implant materials; however, there were no significant differences between pre- and post-acquisition MAR. The 90 kVp setting generated less intense artifacts on average than the 84 kVp setting. The titanium-zirconium alloy generated significantly less intense artifacts than zirconium. Titanium generated artifacts at an intermediate level relative to the other 2 implant materials, but was not statistically significantly different from either. Conclusion: This in vitro study suggests that artifacts can be minimized by using a titanium-zirconium alloy at the 90 kVp setting, with either MAR setting.