• Title/Summary/Keyword: Zinc-Aluminum

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Gas Sorption Analysis of Metal-organic Frameworks using Microresonators (마이크로진동자 기반 금속유기골격체의 기체 흡탈착 분석)

  • Kim, Hamin;Choi, Hyun-Kuk;Kim, Moon-Gab;Lee, Young-Sei;Yim, Changyong
    • Applied Chemistry for Engineering
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    • v.33 no.1
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    • pp.11-16
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    • 2022
  • Metal-organic frameworks (MOFs) are porous materials with nano-sized pores. The degree of gas adsorption and pore size can be controlled according to types of metal ions and organic ligands. Many studies have been conducted on MOFs in the fields of gas storage and separation, and gas sensors. For rapid and quantitative gas adsorption/desorption analyses, it is necessary to form various MOF structures in uniform films on a sensor surface. In this review, some of representative direct methods for uniformly synthesizing MOFs such as MIL-53 (Al), ZIF-8, and Cu-BDC from anodized aluminum oxide, zinc oxide nanorods, and copper thin films, respectively on the surface of a microresonator are highlighted. In addition, the operation principle of quartz crystal microbalance and microcantilever, which are representative microresonators, and the interpretation of signals that change when gas is adsorbed to MOFs are covered. This is intended to enhance the understanding of gas adsorption/desorption analysis of MOFs using microresonators.

Growth Response and Nutrient Content of Cowpea Sprouts Based on Growth Temperature and Genetic Resources (재배온도 및 유전자원에 따른 동부나물 생장반응 및 영양성분 변화)

  • Kim, Dong-Kwan;Kim, Young-Min;Chon, Sang-Uk;Rim, Yo-Sup;Choi, Jin-Gyung;Kwon, Oh-Do;Park, Heung-Gyu;Shin, Hae-Ryong;Choi, Kyeong-Ju
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.59 no.3
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    • pp.332-340
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    • 2014
  • The purpose of this study was to establish the optimal growth temperature and to select genetic resources for production of cowpea sprouts. Seowon was treated between $15^{\circ}C$ and $30^{\circ}C$ at intervals of $3^{\circ}C$ to investigate growth temperature. Twelve resources, including Seowon, IT154149, IT154153, Tvu7426, and Tvu7778, were used for cultivating sprouts at a temperature of $27^{\circ}C$. The yield ratio of cowpea sprouts was highest at $27^{\circ}C$ (657%), and was reduced when growth temperature was decreased. The hard seed rate was lower when the growth temperature was increased. Vitamin C content was highest at $24^{\circ}C$ (2.85 mg/g), ranged between 2.15 and 2.29 mg/g at other growth temperatures, and increased with the length of the growth period. The inorganic component content of cowpea sprouts did not vary based on growth temperature, while the amino acid content increased with increasing growth temperature between $15^{\circ}C$ and $24^{\circ}C$, and then subsequently decreased as growth temperature rose from $24^{\circ}C$ to $30^{\circ}C$. IT154153 had the highest yield ratio of cowpea sprouts per genetic resource (647%), followed by Seowon (615%), and Tvu7426 (608%). Genetic resources with a higher yield ratio had smaller seeds, a thinner seed coat, and superior germinability. The inorganic components found at highest concentrations in the cowpea sprouts were potassium, magnesium, calcium, sodium, iron, molybdenum, and zinc (in that order). In comparison to raw seeds, the protein, calcium, zinc, molybdenum, and iron content in the cowpea sprouts was higher, while the content of aluminum and boron was lower.

Effects of Air Pollution and Acid Precipitation on Soil pH and Distribution of Elements in Forest Ecosystem (대기오염(大氣汚染) 및 산성우(酸性雨)가 삼림생태계(森林生態系)의 토양산도(土壤酸度) 및 양료분포(養料分布)에 미치는 영향(影響))

  • Lee, Soo Wook;Min, Ill Sik
    • Journal of Korean Society of Forest Science
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    • v.78 no.1
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    • pp.11-25
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    • 1989
  • Four regions have been selected and surveyed to investigate the effects of air pollution and acid deposition on forest ecosystem. They were Seoul as urban region, Yeochon and Ulsan as industrialized region, and Kangwondo as uncontaminated region. Soil pH and the distribution of elements were analyzed in process of time for three years as well as by distance from pollution sources. In general, forest soils acidified in process of time from pollution sources to suburban areas. Hydrogen ion concentration in forest soils increased in 1988 as much as 60% of that in previous year. Average soil pH values in coniferous forest were 4.45 in Seoul, 4.54 in Yeochon, 4.81 in Ulsan, and 6.03 in Kangwondo. Forest soil pH increased with the distance from pollution sources to suburban areas at constant rate within short ranges (up to 30 km) and at decreasing rate within long ranges (up to 200 km). On the contrary, sulfur content in soils decreased every year except in Yeochon region. Base saturation of forest soils in polluted regions were all below 20% level compared with 70% in Kangwondo region. Active aluminum content in soils increased with the soil acidification at the highest rate in Yeochon, and the next in Ulsan and Seoul. Heavy metal content such as copper and zinc in tree tissues were the lowest in Kangwondo region, and the next in Yeochon, Seoul and Ulsan.

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Monitoring of Hazardous Metals Migrated from Home-Cooking Utensils (홈베이킹 조리기구에서 용출되는 유해금속 실태조사)

  • Park, Sung-Hee;Kim, Myung-Gil;Son, Mi-Hui;Seo, Mi-Young;Jang, Mi-Kyung;Ku, Eun-Jung;Chae, Sun-Young;Park, Yong-Bae
    • Journal of Food Hygiene and Safety
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    • v.36 no.3
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    • pp.264-270
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    • 2021
  • In this study we investigated the elution level of lead (Pb), cadmium (Cd), arsenic (As), zinc (Zn), nickel (Ni), antimony (Sb), germanium (Ge), aluminum (Al) and hexavalent chromium (Cr6+) from 69 home-cooking utensils into a food stimulants. The results of migration testing according to the Korea standards and specifications for utensils, containers and packages showed values the allowable migrantion limits. Al was detected in all 7 utensil materials with the average concentration ranging from 0.002-5.989 mg/L. According to the migration conditions for (180℃, 30 min), the average concentration of Al in paper was 7.2 times higher than 25℃, 10 min (P<0.05). The results of migration testing at 180℃, 30 min were also below the allowable migrantion limits. When comparing with the provisional tolerable weekly intake (PTWI) of Al, the estimated weekly intakes (EWI) accounted for 0.000-0.045% for Al.