• Title/Summary/Keyword: Zinc-Aluminum

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Respondence Between Electrochemicl Fluctuations and Phenomenon for Localized Corrosion of Less-Noble Metals

  • Itoi, Yasuhiko;Take, Seisho;Tsuru, Tooru
    • Corrosion Science and Technology
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    • v.7 no.1
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    • pp.35-39
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    • 2008
  • We have been studying application of electrochemical noise (Fluctuation) analysis for localized corrosion. Foils of Zinc, Aluminum and Magnesium were used as specimens for electrochemical cell simulating localized corrosion. These specimens were dipped in sodium chloride solutions adjusted to each exponent of Hydrogen ion concentration (pH) condition of 5.5, 10, 12 respectively. Time variations of potential and current were measured in those solutions, and simultaneously the surfaces of specimens were observed using microscope with television monitor. Two types of electrochemical cells were arranged for experiments simulated localized corrosion. The fluctuations on trendy component of short-circuited potential and short-circuited current were appeared in synchronization. It was seemed that these fluctuations result from hydrogen evolution on the aluminum active site in the crevice from the microscopic observation. In the case of zinc and magnesium, fluctuations appeared on the trendy component of the corrosion potential. Two types fluctuation were detected. First one is the fluctuation varied periodically. The second one is the random fluctuation. It was seemed that these fluctuations result from generation of corrosion products and hydrogen evolution on the active site in the crevice of zinc and magnesium from the microscopic observation.

Optimization of Friction Stir Spot Welding Parameters of Lap Joint between AA1100 Aluminum Alloy and SGACD Zinc-coated Steel

  • Triwanapong, Surat;Kaewwichit, Jesada;Roybang, Waraporn;Kimapong, Kittipong
    • International Journal of Advanced Culture Technology
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    • v.3 no.1
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    • pp.161-168
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    • 2015
  • This article aims to apply a friction stir spot welding for producing a lap joint of AA1100 aluminum alloy and SGACD zinc coated steel. The experiment was designed by MINITAB and then investigated the relation among the friction spot joint parameters. The experimental results are as follows. The friction spot joining could successively produce the lap joint of AA1100 aluminum alloy and SGACD zinc coated steel. Interaction between the rotate speed, the hold time and the tool insert speed affected to vary the tensile shear strength of the lap joint. The prediction of the optimized welding parameters that indicated the tensile shear strength of 1966 N was the rotated speed of 4000 rpm, the pin hold time of 6 sec, the pin insert rate of 6 mm/min with the S/N ratio of 66.56 that was higher than that of the total mean S/N ratio. The practical experiment of the predicted welding parameters indicated the tensile shear strength of 2165 N and had the S/N ratio of 66.70 that was higher than the predicted tensile shear strength.

Effects of Aluminum and Silicon as Additive Materials for the Zinc Anode in Zn-Air Batteries

  • Lee, Yong-Seok;Ryu, Kwang-Sun
    • Journal of the Korean Electrochemical Society
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    • v.21 no.1
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    • pp.12-20
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    • 2018
  • To solve low cycle efficiency of the zinc anode in Zn-air batteries by corrosion, this study examined the effects of Al as a cathodic protection additive to Zn. The Al-mixed Zn anodes were produced by mixing Zn and Al powder (1, 2, and 3 wt. %). To compare the effects of the Al additive, Si was selected under the same conditions. The morphology and elemental composition of the additives in the Zn were characterized by scanning electron microscopy, energy dispersive X-ray spectroscopy, and inductively coupled plasma - mass spectrometry. The anti-corrosion effects of the Al and Si-mixed Zn anodes were examined by linear polarization. Cyclic voltammetry and charge-discharge tests were conducted to evaluate the electrochemical performance of the Al and Si-mixed Zn anodes. As a result, the Al-mixed Zn anodes showed highest corrosion resistance and cycling performance. Among these, the 2 wt.% Al-mixed Zn anodes exhibited best electrochemical performance.

Weldability of Low Carbon Steel with Al Coating Condition by Nd:YAG Laser (저탄소강의 알루미늄 도금조건에 따른 Nd:YAG 레이저 용접성)

  • Kim, Jong-Do;Lee, Jung-Han;Kim, Sook-Hwan
    • Journal of Advanced Marine Engineering and Technology
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    • v.31 no.6
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    • pp.736-743
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    • 2007
  • Laser welding has the advantage of high welding speed and Provides low heat distortion Thus laser welding is a very attractive process for joining thin steel sheet and surface treated steel sheet. And the major item in market for surface treated steel sheet is zinc coated steel. However. the laser welding of zinc coated steel is very difficult because of its low boiling point. Compared with zinc, on the other hand, aluminum has a high boiling point. Thus, laser weldability of aluminized steel is better than that of zinc coated steel. Moreover aluminized steel sheet is a material with excellent heat resistance, thermal reflection and corrosion resistance. The results of laser weldability of the aluminized steel for the full penetration welding will be described in this paper We focused on the investigation of the phenomenons caused by coating condition and behavior of aluminum in weld.

Optical properties of Al doped ZnO Nanofibers Prepared by electrospinning (전기방사를 이용한 Al이 첨가된 ZnO 나노섬유의 제조 및 광학 특성평가)

  • Song, Chan-Geun;Yoon, Jong-Won
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.21 no.5
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    • pp.205-209
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    • 2011
  • Zinc oxide has semi-conductivity and super conductivity characteristics. It can be used optically and is applied on many areas such as gas sensor, solar cell and optical waveguide. In this paper, to improve optical characteristics of ZnO, aluminum was added on zinc oxide. Zinc oxide and aluminum zinc oxide was fabricated as nano fiber form. ZnO solution was created by mixing poly vinyl pyrrolidone, ethyl alcohol, and zinc acetate. An Al doped ZnO was created by adding aluminum solution to ZnO sol. By applying these sols on electro spinning method, nano fibers were fabricated. These fibers are heat treated at 300, 500, and $700^{\circ}C$ degrees and were analyzed with X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM) to examine the nano structures. TGA and DSC measurement was also used to measure the change of mass and calorie upon temperature change. The absorbance of ZnO and Al-doped ZnO was carried out by UV-vis measurement.

Reduction of floating Dross in the Zinc Bath (도금욕 부유드로스의 감소)

  • Chang, Seky
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 1999.05a
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    • pp.97-97
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    • 1999
  • Dross formation in the zinc bath is inevitable under any condition as long as coating process on steel strip continues. Thus, bath aluminum and temperature are precisely managed to suppress the increase of dross. Also, excessive dross for normal coating process is generally eliminated physically by bubbling and skimming. Total amount of dross in the bath can be sometimes high enough to cause coating defect. On the other hand, local concentration of dross can make coating defect even with satisfactory level of total amount of dross. Reduction of dross in the bath was attempted by using ceramic foam filter made of mainly alumina. Dross in molten zinc was almost reduced to the levels of solubility of iron and aluminum in molten zinc at $450~460^{\circ}C$. Their solubility levels were confirmed by thermodynamic calculations or DEAL program. Two kinds of filters were tested for dross reduction. One was #20 ppi, porous per inch, and the other #30 ppi filter. Both were effective in reducing the bath dross to the solubility levels at the static state. Bath iron was reduced by 24 wt% and 19 wt% with #20 filter, and by 35 wt% and 29 wt% with #30 filter for GI and GA pot, respectively. Also, ceramic foam filter did not make any harm to the zinc bath composition after filtering test.

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The studies on synthesis of aluminum oxide and boron oxide co-doped zinc oxide(AZOB) powder by spray pyrolysis (분무열분해법(Spray Pyrolysis)에 의한 알루미늄 산화물과 보론 산화물이 함께 도핑된 산화아연(AZOB: $Al_2O_3$ and $B_2O_3$ Co-doped Zinc Oxide)의 분말 제조에 대한 연구)

  • Kim, Sang Hern
    • Journal of the Korean Applied Science and Technology
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    • v.31 no.4
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    • pp.731-739
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    • 2014
  • Aluminum and boron co-doped zinc-oxide(AZOB) powders as transparent conducting oxide(TCO) were prepared by spray pyrolysis at $900^{\circ}C$. The micron-sized AZOB particles were prepared by spray pyrolysis from aqueous precursor solutions for aluminium, boron, and zinc. The micron-sized AZOB particle after the spray pyrloysis underwent post-heat treatment at $700^{\circ}C$ for 2 hours and it was changed fully to nano-sized AZOB particle by ball milling for 24 hours. The size of primary AZOB particle by Debye-Scherrer Equation and surface resistance of AZOB pellet were measured.

Efficient Organic Light-emitting Diodes with Aluminum-doped Zinc Oxide Anodes (알루미늄 도핑된 산화아연 양극을 적용한 고효율 유기발광다이오드)

  • Lee, Ho-Nyeon;Lee, Young-Gu;Jung, Jong-Guk;Lee, Seung-Eui;Oh, Tae-Sik
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.20 no.8
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    • pp.711-715
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    • 2007
  • Properties of organic light-emitting diodes (OLEDs) with aluminum-doped zinc oxide (ZnO:Al) anodes showed different behaviors from OLEDs with indium tin oxide (ITO) anodes according to driving conditions. OLEDs with ITO anodes gave higher current density and luminance in lower voltage region and better EL and power efficiency under lower current density conditions, However, OLEDs with ZnO:Al anodes gave higher current density and luminance in higher voltage region over about 8V and better EL and power efficiency under higher current density over $200mA/cm^2$. These seemed to be due to the differences in conduction properties of semiconducting ZnO:Al and metallic ITO. OLEDs with ZnO:Al anodes showed nearly saturated efficiency under high current driving conditions compared with those of OLEDs with ITO anodes. This meant better charge balance in OLEDs with ZnO:Al anodes. These properties of OLEDs with ZnO:Al anodes are useful in making bright display devices with efficiency.

A Study on the Dependency of Pulsed-DC Sputtered Aluminum-doped Zinc Oxide Thin Films on the Reverse Pulse Time (Pulsed-DC 스퍼터링에서 Reverse Pulse Time에 따른 AZO 박막의 특성 변화에 관한 연구)

  • Ryu, Hyungseok;Zhao, Zhenqian;Kwon, Sang Jik;Cho, Eou Sik
    • Journal of the Semiconductor & Display Technology
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    • v.17 no.4
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    • pp.32-36
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    • 2018
  • For various oxygen($O_2$) to argon(Ar) gas ratio, aluminum-doped zinc oxide(AZO) films were deposited for 3 min at different duty ratio by changing reverse pulse times. As the duty ratio increased, the thickness of the AZO film decreased and the sheet resistance increased. It can be concluded that When sputtering AZO Thin film, oxygen interfered with sputtering. When the reverse time was increased, the thickness of AZO was proportional to the real sputtering time and decreased. From the optical transmittance and sheet resistance, it was possible to obtain a higher figure of merits of AZO at a lower reverse pulse time. Even at the short reversed pulse time, it can be concluded that the accumulated charges on the AZO target are completely cleared. At a lower reverse pulse time, pulsed-DC sputtering of AZO is expected to be used instead of DC sputtering in the deposition of transparent conductive oxide(TCO) films without any degradation in thickness and structural/electrical characteristics.

A Study on the Quantification of Market-Government Response for Import Interruption Risk of Base Metal in Korea (베이스메탈 수입중단에 대한 민관 대응 리스크 물량 산정 연구)

  • Kim, Yujeong
    • Resources Recycling
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    • v.30 no.5
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    • pp.3-9
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    • 2021
  • In Korea, base metals such as lead, zinc, copper, tin, nickel, and aluminum have a polarized supply and demand structure. Despite the presence of world-class producers of lead, zinc, and copper, and their production is insufficient. And there are no domestic producers of tin, nickel, and aluminum, Thus, most of the domestic demand is dependent on imports. Therefore, it is necessary to prepare for the risk of supply interruption, such as the disruption of the import of base metals or interruption of domestic production. In this study, we estimated the quantity required to respond to the risk of import disruption, the quantity to which the market can respond, and the quantity to which the government needs to respond for six base metals (copper, lead, zinc, aluminum, nickel, and tin).