• International Journal of Advanced Culture Technology
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• 제3권1호
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• pp.13-20
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• 2015

The self-cleaning properties of nano-zinc oxide on cotton fabrics have been investigated. The cotton fabric has been prepared by pad-dry method. The nano-zinc oxide was encapsulated in the polystyrene particle by mini-emulsion process prior used. The loading amount of zinc oxide particles into the mini-emulsion were various from 1% wt to 40%wt. The particles sizes of ZnO-encapsulated polystyrene mini-emulsion were determined using dynamic light scattering. It was showed that the particle size of the mini-emulsion was in the range of 124-205 nm. The topography and morphology of ZnO-encapsulated polystyrene which coated on cotton fabrics was observed using scanning electron microscopy. The crystal structure of ZnO-coated on cotton fabrics was explored by X-ray diffraction spectroscopy. The photocatalytic activities of zinc oxide were present through the self-cleaning properties. The presents of the zinc oxide on cotton fabrics significantly showed the improving of the self-cleaning properties under UV radiation.

• Nuclear Engineering and Technology
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• 제52권9호
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• pp.2078-2084
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• 2020

Magnesium oxide (MgO) and Zinc oxide (ZnO) nanoparticles (NPs) have been successfully synthesized by solid-solid reaction method. The structural properties of ZnO and MgO NPs were studied using X-ray diffraction (XRD) and scanning electron microscopy (SEM). XRD results indicated a formation of pure MgO and ZnO NPs. The mean diameter values of the agglomerated particles were around to be 70 and 50 nm for MgO and ZnO NPs, respectively using SEM analysis. Further, a wide-range of nuclear radiation shielding investigation for gamma-ray and fast neutrons have been studied for Magnesium oxide (MgO) and Zinc oxide (ZnO) samples. FLUKA and Microshield codes have been employed for the determination of mass attenuation coefficients (μ_m) and transmission factors (TF) of Magnesium oxide (MgO) and Zinc oxide (ZnO) samples. The calculated values for mass attenuation coefficients (μ_m) were utilized to determine other vital shielding properties against gamma-ray radiation. Moreover, the results showed that Zinc oxide (ZnO) nanoparticles with the lowest diameter value as 50 nm had a satisfactory capacity in nuclear radiation shielding.

• Bulletin of the Korean Chemical Society
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• 제23권11호
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• pp.1513-1518
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• 2002

Kinetic studies on the water-gas shift reaction catalyzed by magnetite/chromium oxide and copper/zinc oxide were carried out by using an in situ photoacoustic spectroscopic technique. The reactions were performed in a closed-circulation reactor system using a differential photoacoustic cell at total pressure of 40 Torr in the temperature range of 100 to $350^{\circ}C.$ The CO2 photoacoustic signal varying with the concentration of CO2 during the catalytic reaction was recorded as a function of time. The time-resolved photoacoustic spectra obtained for the initial reaction stage provided precise data of CO2 formation rate. The apparent activation energies determined from the initial rates were 74.7 kJ/mol for the magnetite/chromium oxide catalyst and 50.9 kJ/mol for the copper/zinc oxide catalyst. To determine the reaction orders, partial pressures of CO(g) and H2O(g) in the reaction mixture were varied at a constant total pressure of 40 Torr with N2 buffer gas. For the magnetite/chromium oxide catalyst, the reaction orders with respect to CO and H2O were determined to be 0.93 and 0.18, respectively. For the copper/zinc oxide catalyst, the reaction orders with respect to CO and H2O were determined to be 0.79 and 0, respectively.

• 한국재료학회:학술대회논문집
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• 한국재료학회 2007년도 추계학술발표대회 및
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• pp.52.1-52.1
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• 2007

• 대한치과보철학회지
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• 제15권1호
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• pp.43-47
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• 1977

The purpose of this study was to determine human pulp reactions to temporary cements such as zinc oxide-eugenol cement, modified zinc oxide-eugenol cement (Cavitec) and calcium hydroxide cement (Dycal). Deep class V cavities were prepared in the human teeth with ultrahigh-speed handpiece operating at a free running speed of 300,000 r.p.m., using # 701 bur and water spray coolant. The cavities were flushed with water, dried with cotton pellets and filled with zinc oxide-eugenol cement, modified zinc oxide-eugenol cement and calcium hydroxide cement respectively. The teeth were divided into two groups, which one group was extracted after One day and the other was extracted after seven days. The samples were examined with microscope and the findings were as follows; 1. The pulp reactions to temporary cements were generally mild. Among them the reactions were moderate in zinc oxide-eugenol cement and, slight in calcium hydroxide cement. 2. Calcium hydroxide cement may be used properly as temporary cement for the purpose of pulp protection.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2005년도 제36회 하계학술대회 논문집 C
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• pp.1873-1875
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• 2005

The effect of zinc oxide as an inhibitor for the corrosion of steel in concrete environment was studied by weight loss measurements, potential-time behaviour and anodic polarization technique. The salient features of the investigation were: in 100% OPC extracts, the passivity of steel was readily destroyed, however extracts containing various concentration of zinc oxide, the passivity of steel was maintained even in the presence of 30,000 ppm of chloride. Alkalinity of concrete was maintained by the addition of zinc oxide. The efficiency of the inhibitor was found to increase with increasing inhibitor concentration. Addition of zinc oxide in the range 3 to 4% by weight of cement was sufficient to protect the rebars.

• 대한화학회지
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• 제37권4호
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• pp.416-422
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• 1993

${\alpha},{\beta}$-구리 및 무금속의 프탈로시아닌을 비이온성 계면활성제를 사용하여 수용액 중에서 산화아연에 흡착시켰더니, 첨가시킨 색소가 모두 흡착되었다. 계면활성제를 사용하지 않고 술폰화된 프탈로시아닌의 나트륨염인 경우는 Langmuir 단분자 흡착성을 나타내었다. 흡착상태에 따른 증감특성을 알기 위하여 진동용량형 표면 전위계를 사용하여 광기전력을 측정하였더니, 산화아연의 고유파장과 프탈로시아닌 색소의 흡수파장에서 높은 광기전력을 나타내었다. 계면활성제를 이용하여 흡착시킨 프탈로시아닌은 산화아연에 대한 피복율(${\theta}_{BET}$)이 약 80%에서 광기전력이 크게 나타났고, 술폰화된 프탈로시아닌은 피복율(${\theta}_{BET}$)이 약 30% 부근에서 광기전력이 증가하는 경향을 나타내었다.

• Restorative Dentistry and Endodontics
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• 제12권2호
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• pp.17-23
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• 1987

The purpose of this study was to evaluate the sealing properties of endodontic cavity filling materials according to the time intervals after filling. Access cavities were prepared in extracted human premolar or molar teeth and filled with caviton, zinc oxide eugenol cement, zinc oxide eugenol cement with a base of gutta percha stopping and gutta percha stopping. After filling at the intervals of immediate, 2 days and 2 weeks the teeth were immersed for 2 weeks in 1% methylene blue solutions. Longitudinal sections were obtained from approximately center of teeth and the depth of dye penetration into the access cavities were observed by 10${\times}$macrolens. The following results were obtained. I. All the materials experimented showed varying depth of dye penetration. 2. Of the material tested, caviton showed the best marginal sealing qualities regardless of the time intervals after filling and the sealing properties of the gutta percha stopping was the worst. 3. Both in zinc oxide eugenol cement and zinc oxide eugenol cement with a base of gutta percha stopping, the fillings allowed to mature for 2 days in normal saline solution showed the best sealing properties and those with no maturing time revealed the worst sealing qualities. 4. The sealing qualities of zinc oxide eugenol cement with a base of gutta percha stopping revealed slightly lower depth of dye penetration than that of zinc oxide eugenol cements.

• 한국결정성장학회지
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• 제34권4호
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• pp.117-124
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• 2024

산화아연 나노입자는 수산기(-OH)가 포함된 에틸렌 글리콜을 이용하여 폴리올 방법으로 제조하였다. 폴리올 방법으로 생성된 아연 화합물은 하이드록시탄산아연(Zinc carbonate hydroxide, Zn₅(OH)₆(CO₃)₂)과 산화아연(ZnO) 결정구조가 혼재함을 확인하였다. 400℃, 600℃ 및 800℃에서 하소하여, 하소 온도 조건에 따른 산화아연 입자 크기, 형상 및 결정성 영향을 확인하였다. 증류수를 이용한 황산 아연 전구체 용액과 에틸렌 글리콜이 첨가된 혼합 용액으로 제조된 황산 아연 전구체 용액을 각각 800℃에서 하소하여 제조된 산화아연 분말을 입도 분석하였다. 전자의 경우 약 404 ± 51 nm의 입자 크기를 갖는 반면, 후자의 경우 약 109 ± 29 nm로 보다 균일한 나노 입자 형태의 산화아연 제조가 가능하였다. 에틸렌 글리콜을 통해 물 분자 영향을 제어하여 직접적인 산화아연 제조 및 나노 입자 크기 형태로 제조가 가능함을 제시하였다.

• 한국재료학회:학술대회논문집
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• 한국재료학회 2007년도 추계학술발표대회 및
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• pp.17.1-17.1
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• 2007