• Title/Summary/Keyword: Zinc

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Field Measurement and Analysis of Fluvial Sediment in the Cheongmi-Stream(II) - Mineralogical and Contaminative Characteristics of Sediment Particles - (청미천에서의 하천 유사 측정 및 분석(II) - 유사의 광물특성 및 오염도 -)

  • 우효섭;이진국
    • Water for future
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    • v.24 no.3
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    • pp.49-60
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    • 1991
  • As a second part of the study entitled "Field Measurement and Analysis of Fluvial Sediment in the Cheongmi-Strea", this study concerns mineralogical and contaminative characteristics of sediment particles collected at Wonbu-Gyo and Hanpyeong-Gyo in the Cheongmi-Stream. The mineralogical analysis of the bed sediment collected reveals that, in general , quarz is the most abundant mineral found in sands with feldspars and rock fragments in the next, which confirms what is known in the literature. The shape factor of sand particles is about 0.7, which also agrees to what is known in the foreign literature. The analysis also reveals that the clay particles collected are composed mainly of illite, kaolinate, and chlorite. The analysis of contamination reveals that there is no substantial difference between the contents of organic material and heavy metals in the surface water and those in the pore water beneath the river bed. It is because the sampling for this analysis was conducted right after the September flood during which the fresh top soil from the upstream watershed replaced the old bed sediment and pore water that would probably be more contaminated. The contents of geavy metals in the bed sediment of sand particles do not exceed those in the soils adjacent to the river. For fine sediment such as clays, however, the contents of heavy metals, especially of mercury and zinc, far exceed those in the soils adjacent to the river. These fine sediments are transported downstream in the form of wash load and deposited in part on flood plains, which could be a new source of contaminants.taminants.

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Study on the Chemical Change of General Composition, Fatty Acids and Minerals of Rapeseed during Germination (발아에 의한 유채의 일반성분, 지방산 및 무기물의 조성변화)

  • Kim, In-Sook;Kwon, Tae-Bong;Oh, Sung-Ki
    • Korean Journal of Food Science and Technology
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    • v.20 no.2
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    • pp.188-193
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    • 1988
  • The objective of this study was to investigate the technical feasibility of producing toxicant-free rapeseed by germination. To this end, rapeseed (Brassica napus L.) was germinated at $25^{\circ}C$ for 120 hours, and the compositional changes of fatty acids and minerals were determined in every 24 hours during germination. Repeseed slightly decreased it's fat content during germination, whereas it showed a tendency to increase protein content. The contents of oleic, erucic, linoleic, linolenic, stearic, palmitic and arachidic acids in rapeseed before germination were found to be 24.6, 15.5, 10.6, 9.5, 1.0, 2.4 and 5.3% respectively. They were gradually decreased until 96 hours and showed a slight increase in 120 hours during germination. However, there was no significant difference in the variation of fatty acids composition in rapeseed during gemination. The content of minerals-phosphorous, calcium, magnesium, zinc, manganese, copper and iron-in rapeseed before germination were 6367, 3068, 2667, 80.3, 26.5, 15.9, and 94.4 ppm respectively and sodium was detected in trace. The mineral contents in rapeseed were gradually decreased in the early period of germination, but showed a slight increase in 120 hours.

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A Study on Urinary N-acetyl-$\beta$-D-glucosaminidase Activities of Office Workers in a Certain Industrial Complex Area (모 공단지역 사무직 근로자들의 요중 N-acetyl-$\beta$-D-glucosaminidase 역가에 관한 연구)

  • Kim, Hwa-Sung;Lee, Gap-Soo;Lee, Sung-Soo;Ahn, Kyu-Dong;Lee, Byung-Kook
    • Journal of Preventive Medicine and Public Health
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    • v.27 no.3 s.47
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    • pp.547-556
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    • 1994
  • In order to identify the necessary information of biochemical Indices for renal effect of lead for the early detection in medical surveillance of lead worker, the reference values of urinary N-acetyl-$\beta$-D-glucosaminidase (NAG) activities were studied with 205 office workers in one industrial complex area who were not exposed to lead occupationally. While study variables selected for lead exposure were blood lead (PbB), blood zinc protoporphyrin(ZPP) and $\delta$-aminolevulinic acid (DALA) in urine, those for renal effect were urinary N-acetyl-$\beta$-D-glucosaminidase (NAG), blood urea nitrogen (BUN), serum creatinine(Cr), serum uric acid (Ua), and urinary total protein(U-TP). The results obtained were as follows: 1. The mean values of blood lead, ZPP and DALA in all subjects were $14.39{\pm}4.02{\mu}g/dl,\;21.61{\pm}8.00{\mu}g/dl,\;and\;2.73{\pm}0.90mg/l$ respectively. 2. The mean value of urinary NAG activities in all subjects was $3.51{\pm}2.01U/l$. The mean value of urinary NAG activities, which calculated from NAG activities divided by urinary creatinine concentration (CNAG), was $5.42{\pm}5.53U/g$ creatinine and log-arithmic normal distributed. 3. The reference value of urinary NAG activity was 12.06 U/g creatinine(95% CU=10.57-14.76 U/g creatinine). 4. Logarithmic CNAG(r=0.781 p<0.0l), U-TP(r=0.670 p<0.01) and ZPP(r=0.172 p<0.05) showed statistically significant correlation with CNAG.

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Expression of MEK1 Fusion Protein in Yeast for Developing Cell Based Assay System, a Major Substrate of LeTx (Yeast내에서 MEK1 융합 단백질 발현 및 Lethal Factor 활성 검증)

  • Hwang, Hye-Hyun;Kim, Joung-Mok;Choi, Kyoung-Jae;Park, Hae-Chul;Han, Sung-Hwan;Chung, Hoe-Il;Koo, Bon-Sung;Park, Joon-Shik;Yoon, Moon-Young
    • Korean Journal of Microbiology
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    • v.42 no.3
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    • pp.195-198
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    • 2006
  • Lethal toxin is a critical virulence factor of anthrax. It is composed two protein: protective antigen (PA) and lethal factor (LF). PA binds to specific cell surface receptors and, forms a membrane channel that mediates entry of LF into the cell. LF is a zinc-dependent metalloprotease, which cleaves MKKs [MAPK (mitogen-activated protein kinase) kinases] at peptide bonds very close to their N-termini. In this study, we suggest application of cell-based assays in the early phase of drug discovery, with a particular focus on the use of yeast cells. We constructed MEK1 expression system in yeast to determine LF activity and approached cell-based assay system to screen inhibitors, in which the results covering the construction of LF-substrate in yeast expression vector, expression, and LF-mediated proteolysis of substrate were described. These results could provided the basic steps in design of cell-based assay system with the high efficiency, rapidly and easy way to screening of inhibitors.

Expression of the lux Genes in Escherichia coli for the Basis of Development of Biosensor (바이오센서 개발을 위한 발광 유전자의 대장균에서의 발현 시스템 분석)

  • Cho, Mi-Mi;Kim, Young-Doo;Kang, Kyung-Sook;Kim, Sook-Kyung;Yang, In-Chul;Park, Sang-Ryoul;Lee, Chan-Yong
    • Korean Journal of Microbiology
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    • v.45 no.4
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    • pp.419-424
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    • 2009
  • To provide the basis of biosensor based on the lux genes from bioluminescent bacteria of Photobacterium leiognathi and Vibrio harveyi, we test the expression of lux genes in several strains of Escherichia coli. The expression of the recombinant plasmid of PlXba.pT7-3, containing all lux genes requiring for light emission without adding substrate, in E. coli 43R was so strong to see the blue-green light in single colony as well as in the alginate immobilized cell. In addition, the light intensity was decreased by adding heavy metal ion such as cadmium and zinc ions. These result raise the possibility that a biosensor can be developed using the lux genes system.

Effect of Al Precursor Addition Time on Catalytic Characteristic of Cu/ZnO/Al2O3 Catalyst for Water Gas Shift Reaction (Water Gas Shift 반응을 위한 Cu/ZnO/Al2O3 촉매에서 Al 전구체 투입시간에 따른 촉매 특성 연구)

  • BAEK, JEONG HUN;JEONG, JEONG MIN;PARK, JI HYE;YI, KWANG BOK;RHEE, YOUNG WOO
    • Transactions of the Korean hydrogen and new energy society
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    • v.26 no.5
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    • pp.423-430
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    • 2015
  • $Cu/ZnO/Al_2O_3$ catalysts for water gas shift (WGS) reaction were synthesized by co-precipitation method with the fixed molar ratio of Cu/Zn/Al precursors as 45/45/10. Copper and zinc precursor were added into sodium carbonate solution for precipitation and aged for 24h. During the aging period, aluminum precursor was added into the aging solution with different time gap from the precipitation starting point: 6h, 12h, and 18h. The resulting catalysts were characterized with SEM, XRD, BET surface measurement, $N_2O$ chemisorption, TPR, and $NH_3$-TPD analysis. The catalytic activity tests were carried out at a GHSV of $27,986h^{-1}$ and a temperature range of 200 to $400^{\circ}C$. The catalyst morphology and crystalline structures were not affected by aluminum precursor addition time. The Cu dispersion degree, surface area, and pore diameter depended on the aging time of Cu-Zn precipitate without the presence of $Al_2O_3$ precursor. Also, the interaction between the active substance and $Al_2O_3$ became more stronger as aging duration, with Al precursor presented in the solution, increased. Therefore, it was confirmed that aluminum precursor addition time affected the catalytic characteristics and their catalytic activities.

Bioaccumulation Patterns and Responses of Fleece-flower; Persicaria thunbergii to Cadmium and Lead

  • Kim, In Sung;Kang, Kyung Hong;Lee, Eun Ju
    • The Korean Journal of Ecology
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    • v.25 no.4
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    • pp.253-259
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    • 2002
  • Application of phytoremediation in the polluted area to remove undesirable materials is a complex and difficult subject without detailed investigation and experimentation. We investigated the accumulation patterns of cadmium and lead in plants naturally grown, the bioavailability of plants to accumulate these toxic metals and the responses of P. thunbergii to cadmium and lead. The soil samples contained detectable lead (<$17.5_\mu$g/g), whereas cadmium was not detected in the soils of study area. The whole body of Persicaria thunbergii contained detectable lead (<320.$8_\mu$g/g/g) but cadmium was detected only in the stem (<7.$4_\mu$g/g/g) and root (<10.$4_\mu$g/g/g) of P. thunbergii. Cadmium was not detected in Trapa japonica and Nymphoides peltata, whereas lead was detected in T. japonica (<323.$7_\mu$g/g/g) and N. peltata (<177.$5_\mu$g/g/g). Correlation coefficient between lead content in soil and in these plant samples represented positive correlation. The total content of lead in each plant sample increased in the order of N. peltata$\leq$P. thunbergii

Effect of metals(Cd & Zn) and its nitrogen compounds on growth of bacteria isolated from the three tributaries and lower reach(Mulgum) of the Nakdong River (낙동강 하류(물금)와 세 지류에서 분리된 우점 세균의 증식에 미치는 금속(Cd & Zn) 및 그 질소 화합물의 영향)

  • Park, Jae-Rim;Son, Yeon-Ju;Ha, Kyung;Park, Joong-Chul
    • Journal of Environmental Science International
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    • v.11 no.3
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    • pp.183-189
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    • 2002
  • Investigation was carried out to observe the dominant bacteria and the effect of metals(Cd & Zn) and its nitrate compound on growth of bacteria isolated from the three tributaries and lower reach of the Nakdong River. Mean CFU(log$_{10}$) level was highest in Kumho River(8.30 CFU), Nam River, Hwang River, and Mulgum followed. Staphylococcus xylosus, Staph. lentus, Pasteurella pneumotropica, Aeromonas hydrophilla were dominant species in each study site. Cadmium powder and Zinc powder showed strong effect to inhibit the growth of Micrococcus spp., Pasteurella pneumotropica, Aeromonas hydrophilla. But, nitrate compounds of Cd and Zn(Cd(NO$_3$)$_2$4$H_2O$, Zn(NO$_3$)$_2$6$H_2O$) did not clearly show the strong effect to inhibit the growth of dominants.s.

Structural and Optical Properties of ZnS Thin Films Fabricated by Using RF Sputtering and Rapid Thermal Annealing Process for Buffer Layer in Thin Film Solar Cells (박막태양전지 버퍼층 적용을 위해 RF 스퍼터링 및 급속열처리 공정으로 제작한 황화아연 박막의 구조적 광학적 특성)

  • Park, Chan-Il;Jun, Young-Kil
    • The Journal of the Korea institute of electronic communication sciences
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    • v.15 no.4
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    • pp.665-670
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    • 2020
  • Buffer layer in CIGS thin-film solar cells improves energy conversion efficiency through band alignment between the absorption layer and the window layer. ZnS is a non-toxic II-VI compound semiconductor with direct-transition band gaps and n-conductivity as well as with excellent lattice matching for CIGS absorbent layers. In this study, the structural and optical properties of ZnS thin films, deposited by RF magnetron sputtering method and subsequently performed by the rapid thermal annealing treatment, were investigated for the buffer layer. The zincblende cubic structures along (111), (220), and (311) were shown in all specimens. The rapid thermal annealed specimens at the relatively low temperatures were polycrystalline structure with the wurtzite hexagonal structures along (002). Rapid thermal annealing at high temperatures changed the polycrystalline structure to the single crystal of the zincblende cubic structures. Through the chemical analysis, the zincblende cubic structure was obtained in the specimen with the ratio of Zn/S near stoichiometry. ZnS thin film showed the shifted absorption edge towards the lower wavelength as annealing temperature increased, and the mean optical transmittance in the visible light range increased to 80.40% under 500℃ conditions.

Studies on the Effects of Several Amendments on the Uptake of Cd, Cu and Zn by Rice Plant (수도(水稻)의 중금속(重金屬) 흡수(吸收) 경감(經感)에 대(對)한 몇가지 개량제(改良劑)의 효과(效果))

  • Kim, Bok-Jin
    • Korean Journal of Environmental Agriculture
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    • v.6 no.1
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    • pp.25-30
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    • 1987
  • This study was conducted to find out the effect of several improvers such as triple super phosphate, slaked lime, wollastonite and gypsum for reducing Cd content in brown rice. Several improvers were applied to two different types of soils which are contaminated with copper-zinc mine wasted and sludge.(Soil I contained Cd : 7.88, Cu : 57.9, Zn : 175.0 ppm, Soil II contained Cd : 3.95, Cu : 30.2, Zn :124.0 ppm) In general, effects of improvers on reducing content of Cd, Cu and Zn in brown rice were greater in soil I than soil II. In soil I, the Cd content of brown rice was reduced to 0.4ppm below by application of triple superphosphate, fused phosphate, slaked lime and gypsum, 98, 225, 190 and 276Kg/10a, respectively. Triple superphosphate was more effective than fused phosphate in reducing uptake of Cd, Cu and Zn by applying them as an equal amount of phosphorous, also to equal alkalinity, slaked lime had the highest effect. Negatively linear effect was found between soil pH and Cd and Zn content in brown rice. As to above results, it was no doubt that triple superphosphate, fused phosphate and slaked lime would be applied to reduced heavy metals in brown rice. The slaked lime, triple super phosphate and fused phosphate were available to reduce uptake of Cd, Cu and Zn by rice plant grown in the soil contaminated with mine waste and sludge.

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