• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 2002년도 총회 및 춘계학술발표회
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• pp.62-65
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• 2002

Permeable reactive barriers (PRBs) are in-situ barriers constructed in a subsurface to treat contaminated groundwater using various reactive media. The common reactive medium used in PRB is zero-valent iron, which has been widely used to treat chlorinated solvents (i.e., PCE, TCE). A disadvantage of iron media is high cost. In this study, waste foundry sands were tested to determine the feasibility of their use as a low cost reactive medium. Batch and column tests were conducted with TCE to determine transport parameters and reactivity of the foundry sands. The reactivities of foundry sands for common groundwater contaminants are comparable to or slightly higher than those for Peerless iron, a common medium used in PRBs. In addition, the TOC and clay in foundry sands can significantly retard the movement of target contaminant, which may result in lower effluent concentration of contaminant due to biodegradation. In general, PRBs 1-m thick can be constructed with many foundry sands to treat TCE provided the zero-valent iron content in the foundry sand is higher than 1%.

• 한국물환경학회지
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• 제26권4호
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• pp.557-565
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• 2010

Recently, regulations on toxic compounds in aquatic environment have been strengthened in korea due to the increasing public awareness of the water quality. Typically, these regulations include introduction of emerging toxic compounds and stricter effluent limitations for the already regulated compounds. However, too strict regulations may cause excessive burden on the industry. Therefore it is also important to assess the economic impacts when the new effluent limitation guidelines are introduced. The estimation of the additional cost for the wastewater dischargers to meet the new guidelines are based on the selected treatment technology to handle the hazardous substances and the regulatory levels for effluent limitations. To explore the procedures for cost estimation in enforcing new effluent limitations, a case study was performed specially for 1,4-dichlorobenzene. The pollutants of concern are surveyed for different industrial categories and various treatment technologies. For a given pollutant, the general performances of the treatment technologies are surveyed and a representative technology is selected. For a given technology, the capital cost and annual Operation and Maintenance (O&M) cost was calculated. The calculation of baseline costs to operate ordinary treatment technologies is also important. The ratio between the cost for introducing new treatment process and the baseline cost required for conventional technology was used to evaluate the economic impact on the industry. For 1,4-dichlorobenzene, steam stripping and activated carbon processes were selected as the specific treatment technologies. The cost effects to the regulation of the compound were found to be 6.4% and 14.5% increase in capital cost and O&M cost, respectively, at the flow rate over $2,000m^3/d$ for the categories of synthetic resin and other plastics manufacturing industry. For the case of petrochemical basic compounds manufacturing industry, the cost increases were 5.8% and 12.4%, respectively. It was suggested that cost effect analysis to evaluate the economic impacts of new effluent limitations on the industry is crucial to establish more balanced and reasonable effluent limitations to manage the industrial wastewater containing emerging toxic compounds in the wastewater.

• 한국지반공학회:학술대회논문집
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• 한국지반공학회 2000년도 봄 학술발표회 논문집
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• pp.542-547
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• 2000

It has become interested in the concept of permeable barriers for the containment and/or destruction of contaminated groundwater. The purpose of these trench-like barriers is to provide in situ capture and possibly destruction of the contaminant while preserving groundwater flow to uncontaminated zones. For instance, a trichloreethylene(TCE) plume may be contained by a permeable in which reactive iron reduces TCE to ethylene and ethane, compounds which can be easily biodegraded. The objective of this research is to examine the feasibility of using zero-valent iron as a clean-up media in permeable reactive barrier system. A series of laboratory column tests are performed. The concentration of influent and effluent water and the rate of clean up are analysed from these test results. The experimental result shows that the majority of the contamination in groundwater is removed in the reactor. And it shows the corresponding increase in the concentration of chloride ions through the reactor. Results from this study indicate that permeable reactive barrier containing admixtures of zero-valent iron and other materials can effectively clean up groundwater contaminated with organic compounds.

• Advances in Energy Research
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• 제4권2호
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• pp.147-161
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• 2016

To start with, finding a sustainable method to produce sweet water and electricity by using renewable energies is one of the most important issues at this time. So, experimental and theoretical analysis of the performance of a closed solar powered still, which is jointed to photovoltaic cells and vacuum pump and equipped by nano plate, as the principle stage of zero discharge desalination process is investigated in this project. Major goal of this work is to reuse the concentrated brine of the Mobin petrochemical complex in order to produce potable, sweet water from effluent saline wastewater and generating electricity in the same time by using solar energy instead of discharging them to the environment. It is observed the increase in brackish water temperature increases the average daily production of solar desalination still considerably. Therefore, the nano plate and vacuum pump are added to augment the evaporation rate. The insolation rate, evaporation rate, the average brackish temperature, ambient temperature, density are investigated during a year 2013. In addition to obtain the capacity of solar powered still, the highest and lowest amount of water and electricity generation are reported during a twelvemonth (2013). Results indicate the average daily production is increased 16%, which represents 7.78 kW.h energy saving comparing with traditional solar still.

• 대한환경공학회지
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• 제30권6호
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• pp.628-636
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• 2008

축산폐수를 처리하기 위한 2상 혐기성소화(TPAD)공정을 생물학적 질소제거공정(BNR)과 결합하여 운전하였다. 질산화된 유출수를 TPAD 공정의 산생성 반응조로 반송할 경우 탈질반응이 산생성 반응에 미치는 영향과 효율을 관찰하였다. 질산화된 유출수의 반송은 유입된 COD의 VFA로의 전환율을 향상시켰다. 질산화된 유출수에 적응된 산생성 슬러지의 산생성 속도는 적응되지 않은 슬러지보다 6배 빠른 것으로 관찰되었다. 탈질반응은 생성된 VFA를 탄소기질로써 사용하였지만 산생성 활성도를 향상시킬 수 있었다. 탈질속도는 COD/N비에 영향을 받았지만, 질산성 질소에 대한 산생성 슬러지의 적응여부에 더욱 지배적인 영향을 받는 것으로 나타났다. 산생성 슬러지에 의한 탈질반응은 0차 반응을 보였으며 탈질속도는 1.31$\sim$1.90 mg/L$\cdot$h이었다. 반면, 질산화된 유출수에 적응된 산생성 슬러지의 탈질속도는 3.30 mg/L$\cdot$h로 거의 2배가 빠른 것으로 나타났다. COD/N비 10에서 1g의 질산성 질소를 탈질반응에 의해 제거하는데 소비된 COD의 양론비는 5.1$\sim$6.4 범위이었다.

• 한국미생물·생명공학회지
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• 제47권4호
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• pp.585-595
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• 2019

Analysis of bacterial communities based on their 16S rDNA sequences revealed the predominance of Proteobacteria (Aeromonas sp., Acinetobacter sp. and Thaueraamino aromatica sp.) and uncultured bacterium in activated sludge from the effluent treatment plant (ETP) of Mother Dairy, Calcutta (India). Each isolate was used for bioremediation of dairy wastewater with simultaneous conversion of nitrogenous pollutants into ammonia. A consortium developed using seven of these isolates and three Bacillus strains from different environmental origins could reduce 93% nitrate with simultaneous production of ammonia (626 ㎍/100 ml) within 20 h in non-aerated, immobilized conditions as compared to 82% nitrate reduction producing 2.4 ㎍/100 ml ammonia in 96 h with extensive aeration in a conventional ETP. The treated ammonia-rich effluent could be used instead of freshwater and fertilizer during cultivation of mung bean with 1.6-fold increase in grain yield. The ETP with the surrounding agricultural land makes this process a zero liquid discharge technology for using the biofertilizer generated. In addition, the process requires minimal energy supporting sustained environmental health. This method is thus proposed as an alternative approach for small-scale dairy ETPs.

• Membrane and Water Treatment
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• 제7권1호
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• pp.39-53
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• 2016

In this study, polysufone (PSf) was used as a base polymer to synthesize sulfonated polysulfone (SPSf) and aminated polysulfone (APSf) as cation and anion exchange polymers, respectively. Then the ion exchange polymers were coated onto the surface of commercial carbon electrodes. To compare the capacitive deionization (CDI) and membrane capacitive deionization (MCDI) processes, the pristine carbon electrodes and ionic polymer coated electrodes were tested under various operating conditions such as feed flow rate, adsorption time at fixed desorption time, and feed concentration, etc., in terms of effluent concentration and salt removal efficiency. The MCDI was confirmed to be superior to the CDI process. The performance of MCDI was 2-3 times higher than that of CDI. In particular, the reverse desorption potential was a lot better than zero potential. Typically, the salt removal efficiency 100% for 100 mg/L NaCl was obtained for MCDI at feed flow rate of 15 ml/min and adsorption/desorption time of 3 min/1 min and applied voltages 1.0 V for adsorption and -0.3 V for desorption process, and for 500 mg/L, the salt removal efficiency 91% was observed.

• 한국물환경학회지
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• 제26권3호
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• pp.377-386
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• 2010

Introduction of TBELs into Korean environmental regulatory system for wastewater may require very careful considerations and appropriate modifications of the TBELs applied in US. The Korean regulations for wastewater are based on uniform regulatory criteria for wastewater effluent discharge and are quite different from the individual permit system in US. In addition, the toxic pollutants regulated in Korea are much less than those in US. Therefore, the effects of TBELs application on the pollutants reduction and the economic feasibility should be carefully assessed for different categories of wastewater sources. In this study, the applicability of TBELs for the industrial categories of Korea was discussed. The TBELs were derived for a sample category, the pulp paper paperboard manufacture, based on the previously reported analytical data from 52 facilities of the domestic pulp paper paperboard manufacture in Korea. It was suggested that the BAT effluent limitations were BOD 30 mg/L, $COD_{Mn}$ 40 mg/L, SS 40 mg/L, T-N 30 mg/L and T-P 4 mg/L and that the allowable effluent loads were $0.31{\sim}1.75kgCOD_{Mn}/ton$-products. Due to the limitation of insufficient data, there were difficult to obtain the important factors to derive more systematic and accurate limitation standards for the pollutants such as the 'Long Term Average (LTA)', the 'Product Normalized Discharge Flow (PNDF)', and the 'Variability Factor (VF)'. However, as the first trial of TBELs determination based on the all available analytical data reported, the procedure and the outcome of the study may provide valuable insight on application of TBELs in Korea.

• 한국물환경학회지
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• 제26권1호
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• pp.1-9
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• 2010

Technology-Based Effluent Limitations (TBELs) is a permit limits for a pollutant that is based on the capability of a treatment technology to reduce the pollutant to a certain concentration. Widely practiced for regulations of industrial wastewater in US, TBELs has been accepted as an effective means that can achieve balanced goals between complete elimination of pollutants discharge and economic feasibility for industries. The review of TBELs application in US and the applicability of TBELs to the domestic industry categories was given in three papers. In the first paper, the development and practices of TBELs in US were reviewed including case studies. The developments of TBELs in US in the four major categories, the metal products & machinery, the petroleum refining, the porcelain enameling and the meat & poultry products were reviewed. The applicability of TBELs to the domestic industrial categories was also assessed. In the second paper, the pollution loads analysis for domestic industrial wastewater was conducted based on risk assessment indicator using Toxic Weighting Factors (TWFs). This is an essential part to determine the priority of TBELs application for the domestic industrial categories. In the last paper, the application of TBELs to the domestic industries was demonstrated through a case-study for the pulp/paper/paperboard category. Direct application of TBELs of US into the Korean regulation system may not be desirable because the specific goals and the environment for the regulations for the two countries may not be identical. For example, unlike US, Korea does not adopt the individual permit system for pollution sources. However, among the unproductive and exhaustive controversies over the uniform regulations regardless of the industrial categories in Korea, the introduction of the principles of TBELs are inevitable and more extensive study for applications of TBELs optimized for Korean regulation system will be necessary.

• Membrane and Water Treatment
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• 제9권1호
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• pp.17-21
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• 2018

A series of laboratory scale experiments were performed to investigate the feasibility of membrane separation technology for natural rubber (NR) wastewater treatment and reuse. Three types of spiral wound membranes were employed in the cross-flow experiments. The NR wastewater pretreated by sand filtration and cartridge filtration was forced to pass through the ultrafiltration (UF), nanofiltration (NF) and reverse osmosis (RO) membranes successively. The UF retentate, which containing abundant proteins, can be used to produce fertilizer, while the NF retentate is rich in quebrachitol and can be used to extract quebrachitol. The permeate produced by the RO module was reused in the NR processing. Furthermore, about 0.1wt% quebrachitol was extracted from the NR wastewater. Besides, the effluent quality treated by the membrane processes was much better than that of the biological treatment. Especially for total dissolved solids (TDS) and total phosphorus (T-P), the removal efficiency improved 53.11% and 49.83% respectively. In addition, the removal efficiencies of biological oxygen demand (BOD) and chemical oxygen demand (COD) exceeded 99%. The total nitrogen (T-N) and ammonia nitrogen (NH4-N) had approximately similar removal efficiency (93%). It was also found that there was a significant decrease in the T-P concentration in the effluent, the T-P was reduced from 200 mg/L to 0.34 mg/L. Generally, it was considered to be a challenging problem to solve for the biological processes. In brief, highly resource utilization and zero discharge was obtained by membrane separation system in the NR wastewater treatment.