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Synthesis of SnO2 nanowires on one-dimensional carbonization cotton fabric

  • Khai, Tran Van;Shim, Kwang-Bo
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.22 no.1
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    • pp.25-28
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    • 2012
  • Tin-oxide ($SnO_2$) nanowires have been synthesized on one-dimensional (1D) carbonization cotton fabric using chemical vapour deposition method. One-dimensional (1D) carbonization cotton fabric has been synthesized from cotton fabric using annealing process in nitrogen gas at $1000^{\circ}C$. The $SnO_2$ nanowires are single-crystalline rutile structures with 20 nm in diameter and 10 ${\mu}m$ in length. Scanning electron microscopy (SEM), x-ray photoelectron spectroscopy, Raman spectroscopy, transmission electron microscopy and photoluminescence (PL) spectroscopy were utilized to characterize the as-synthesized products.

Phase Separation and their Structures in $BaO-B_2O_3$ Glasses ($BaO-B_2O_3$계 유리의 상분리 현상과 유리의 구조)

  • 채수철;김철영
    • Journal of the Korean Ceramic Society
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    • v.23 no.6
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    • pp.25-32
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    • 1986
  • Phase spearated glass is heterogeneous in microscopic point of view and the heterogeneities affect the structures of glasses. In the present work the phase separation of $BaO-B_2O_3$ glass system was investigated and the effect of $P_2O_5$ on the phase separation and crystallization was also studied in the above system. Experiments such as scanning electron microscopy X-ray diffraction and infrared spectroscopy were performed. Phase separation with $B_2O_3$ rich phase matrix and BaO rich phase droplet was observed for the glasses containing less than 6 mole% of BaO while the opposite morphology of phase separation was found for the glasses containing more than 7 mole% of BaO. Phase separation region was extended up to the glass with 22mole% of BaO when the amount of $P_2O_5$ was increased. The heat-treated glasses crystallized to BaO.$4B_2O_3$$P_2O_5$ hindered the glass from the crystalli-zation.

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Control of a Helicopter in Hover Using the LQG and LQG/LTR Methods (LQG와 LQG/LTR방법을 이용한 헬리콥터의 비행위치 제어)

  • Kim, Jong-Shik;Ma, Sam-Sun;Song, Myong-Hun
    • Journal of the Korean Society for Precision Engineering
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    • v.7 no.1
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    • pp.74-85
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    • 1990
  • The LQG and LQG/LTR compensators have the same structrues in dynamics. The only difference is the values of the design parameters in the two compensators. The design parameters of the LQG and LQG/LTR compensators are selected in the sense of the least-squares error minimi- zation and loop shaping, respectively. In this paper, the LQG and LQG/ LTR design methods are applied to the helicopter in hover which is modeled as a SISO fourth order system. The dynamic characteristics and the perfor- mance of the two control systems are analyzed by the computer simulation. It is found that the LQG/LTR design method is systematic and has good performance in comparision with the LQG design method.

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Optimal Shape of Fillet for Minimum Stress (최소 응력을 갖는 필렛의 형상설계)

  • Kim, Ho-Ryong;Lee, Jang-Yong
    • Journal of the Korean Society for Precision Engineering
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    • v.7 no.4
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    • pp.149-161
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    • 1990
  • In this study, an optimal shape design was performed on a fillet model which is subject to surface traction through minimizing the maximum stress of the fillet. A 2-dimensional quadratic isoparametirc element with 8 nodes was used in stress analysis for finite element method, and Hooke-Jeeves direct search algorithm was adopted for optimi- zation. From the resulting optimal shape, it was found that the maxium von Mises stress on the boundary of fillet was reduced by 36%, compared to other paper in which the cross sectional area of fillet was minimized. In conclusion, a real optimal fillet shape could be obtained in the viewpoint of yielding, and more pratical fillet design could be accomplished.

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Vacuum Gauge Calibration System in Pohang Acccelerator Laboratory (포항가속기 연구소의 진공게이지 교정시스템)

  • 김형종;조복래;이해철;박종도;최우천
    • Journal of the Korean Vacuum Society
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    • v.3 no.4
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    • pp.382-388
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    • 1994
  • 포항가속기연구소에서 사용될 진공게이지 교정시스템이 설계 제작되었다. 이 교정시스템은 동적 교정방법으로 설계되었으며 transfer standard 로서 spinning rotor gauge를 사용하였다. 포항가속기의 저장리에 사용될 모든 진공게이지는 교정시스템으로 교정을 하여 사용할 것이며, 주로 교정할 게이지로 는 Bayard-Alpert(BA) nude ionization gauge와 cold cathode gauge등이 있다. 본 논문에서는 포항가속 기의 진공게이지 교정시스템에 대해서 소개를 하였고 현재까지 BA nude ioni-zation gauge 6대 extractor gauge 1대 high pressure gauge 1대와 cold cathode gauge 5대를 10-4에서 10-4 Torr 범위내 에서 교정하여 그 결과를 보였다.

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The Study on a Semi-automated Mapping System (반자동 지도입력 시스템기술 개발 연구)

  • 윤재경;이기혁;우창헌;이경자;김수용
    • Spatial Information Research
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    • v.3 no.1
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    • pp.19-27
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    • 1995
  • In this paper, a semi-automated mapping system, which can produ¬ce digital maps by using information acquired from pre-processing procedure, was introduced. To get a binary edge image, which is very important in vectori¬zation process, we applied adaptive smoothing and connection preserving thresho¬Iding algorithm. In mapper program, binary images are converted to vectors and for in-core data structure, extended PR quad tree was used. These procedures are dispatched to personal computers and workstations and through network resource sharing, the whole process was unified and simplified.

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Preparation of 2,9-Dimethyl-6H,13H-dibenzo[d,i][1,6]dithiecin-7,14dlone by Sodium Azide-Promoted Cyclodimeri-zation of o-Acylthiophenacyl Chloride

  • Yu, Seong U;Kim, Min Gyeong;Lee, Gi Jeong
    • Bulletin of the Korean Chemical Society
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    • v.21 no.8
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    • pp.797-800
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    • 2000
  • The reaction of o-acylthiophenacyl chloride 5a with onc equivalent ofsodium azide in aqueous acetone at-10~ $-5^{\circ}C$ gave 2,9-dimethyl-6H,I3H-dibenzo[d,i][1,6]dithiecin-7,14-dione 7(10%),acyclic dimer 8(64%),and tri-mer 9 (8%). Dimer 8 and trimer 9 we re converted readily to 7 under the similar conditions at room temperature in yields of 72% and 53%,respectivel. Also, one pot synthesis of 7 (64%, 45%) from the reaction of 5a or 5b with two equivalents of sodium azide at room temperature was very successful.

Theoretical Studies on the Gas-Phase Alkylation of Delocalized Ambident Anions with Methyl Fluoride

  • 이익춘;박형연;한인숙;김창곤;김찬경;이본수
    • Bulletin of the Korean Chemical Society
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    • v.20 no.5
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    • pp.559-566
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    • 1999
  • Gas-phase alkylations of delocalized ambident anions, Y---CH---X- where X, Y=CH2, O, or S, have been investigated theoretically at the MP2/6-31+G*//MP2/6-31+G* and QCISD/6-31+G*//MP2/6-31+G* lev-els. O-and S-alkylations (X=O and S) are more favored kinetically by ΔE^≠ = 4.6 and 9.8 kcal mol-1 than the respective C-alkylations even though they are thermodynamically less favored by 22.4 and 6.0 kcal mol-1 respectively. It was found that the transition structures for the C-alkylations are imbalanced due to the endoergic rehybridi-zation of the carbon center from sp2 to sp3 which leads to premature bond contraction of the C-Y bond and delayed bond stretching of the C-X bond. In the O-, or S-alkylation, such endoergic process is not required since the σ-lone pair on O or S is involved in the initial stage of alkylation. The imbalanced TSs for the C-alkylation are accompanied by higher intrinsic barriers and deformation energies.

A Spatial Analysis on the Socio-Cultural Level of Informatization Aspects (정보화 차원의 사회 ${\cdot}$ 문화 발전 수준에 대한 공간 분석)

  • Yoo, Yeong-Jun
    • Journal of the Korean Geographical Society
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    • v.31 no.3
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    • pp.529-541
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    • 1996
  • The Korean economy has recently changed from industry-based economy toward information-based one, empha-sizing on information utiliation and technological development. It is important to examine the background for the incoming information society and spatial aspect of infromation, because informati-zation process itself contains spatial features like spatial concentrtion and dispersion. This paper generally focuses on the socio-cultural aspects of the informati-zation aspects. The main questions are as follows: 1) what are the ain questions of the exsisting Korean case studies on the informatization; 2) how can we find the charateristics of spatial concentration of informatization by informatization indices; 3) is there any relationship between the degree of informatiztion and regional development? The results of this study can be found in the following facts: (1) The exsisting studies cannot be generallized as spatial analysis on the informatization In general, they focus only a single aspect of information industry or information job. Futhermore, their spatial unit of analysis is limited to provincial level, rather thn city-level micro study. (2) There are big differences between the Capital region, especially Seoul, and others with regard to the socio-cultural aspects of informatiation. Such informatization is concentrated in Seoul. Inchon and Kyeonggi-do, which are the better positions in information intensive activities. (3) The regional differences for the level of informatization are much bigger than those for the level of welfare, suggesting that the informatization tends to concentrate in specified large cities like Seoul. It is clear the Korea is now entering the initial stage of information society.

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