• Bulletin of the Korean Chemical Society
• /
• v.35 no.8
• /
• pp.2403-2409
• /
• 2014

Absolute isotope ratio is a critical constituent in determination of atomic weight. To measure the absolute isotope ratio using a mass spectrometer, mass discrimination factor, $f_{MD}$, is needed to convert measured isotope ratio to real isotope ratio of gas molecules. If the $f_{MD}$ could be predicted, absolute isotope ratio of a chemical species would be measureable in absence of its enriched isotope pure materials or isotope references. This work employed gravimetrically prepared isotope mixtures of argon (Ar) to obtain $f_{MD}$ at m/z of 40 in the magnetic sector type gas mass spectrometer (gas/MS). Besides, we compare the nitrogen isotope ratio of nitrogen trifluoride ($NF_3$) with that of nitrogen molecule ($N_2$) decomposed from the same $NF_3$ thermally in order to identify the difference of $f_{MD}$ values in extensive m/z region from 28 to 71. Our result shows that $f_{MD}$ at m/z 40 was $-0.044%{\pm}0.017%$ (k = 1) from measurement of Ar artificial isotope mixtures. The $f_{MD}$ difference in the range of m/z from 28 to 71 is observed $-0.12%{\pm}0.14%$ from $NF_3$ and $N_2$. From combination of this work and reported $f_{MD}$ values by another team, IRMM, if $f_{MD}$ of $-0.16%{\pm}0.14%$ is applied to isotope ratio measurement from $N_2$ to $SF_6$, we can determine absolute isotope ratio within relative uncertainty of 0.2 %.

• The Bulletin of The Korean Astronomical Society
• /
• v.37 no.2
• /
• pp.82.1-82.1
• /
• 2012

GRB100205A is a Gamma Ray Burst (GRB) which is suspected to be at redshift z=11-13 due to its very red H-K color($(H-K)_{vega}=2.1{\pm}0.5$). We observed a field centered at GRB100205A with Wide Field Camera (WFCAM) at United Kingdom Infrared Telescope (UKIRT) in Hawaii, in order to search a quasar that could be located around the GRB. The images were obtained in J, H, and K filters covering a square area of $0.78deg^2$. Our J-, H-, and K-band data reach the depths of 22.5, 22.1, and 21.0 mag (Vega) at $5{\sigma}$, respectively. Also using z-band image observed by CFHT, we find 8 candidates that have colors consistent with a quasar at z=11-13(non-detection in z-, J-band and $(H-K)_{vega}$ > 1.6). However, the shallow depths of J-, H-band are not enough to verify their true nature. Instead, we identify many red objects to be old or dusty galaxies at $z{\geq}3$. The number density of such objects appears about twice or more than that of the field of Cosmological Evolution Survey (COSMOS) and Ultra Deep Survey (UDS) of UKIRT Infrared deep sky survey (UKIDSS). On scales between 0.18' and 15' the correlation function is well described by a power law with an exponent of ${\approx}-0.9$ and this implies that those objects are like galaxies. It is interesting that many red galaxies exist in the region where the GRB was detected.

• The Korean Journal of Applied Statistics
• /
• v.32 no.2
• /
• pp.291-300
• /
• 2019

This study investigates the characteristics of evaluation measures for classification models on a binary response variable in order to evaluate their suitability for use. Six measures are considered: Accuracy, Sensitivity, Specificity, Precision, F-measure, and the Heidke's skill score (HSS). Evaluation measures are reformulated using x(ratio of actually 1), y(ratio predicted by 1), z(ratio of both actual and predicted by 1) from the confusion matrix. We suggest two necessary conditions to assess the suitability of the evaluation measures. The first condition is that the measure function is constant for x and y in the case of a random model. The second condition is that the measure function is increasing for z and decreasing for x and y. Since only HSS satisfies the two conditions, that is always appropriate as an evaluation measure for the classification model on the binary response variable, and the other measures should be used within a limited range.

• Journal of Digital Convergence
• /
• v.19 no.1
• /
• pp.217-228
• /
• 2021

This study was to identify generational difference of values of life and factors influencing turnover of Korean nurses. Total 294 nurses of generation-X, Y, and Z participated. Analysis of variance(ANOVA) and Multiple Regression Analyse was conducted. The result of the study was that Gen-X and Y nurses considered family life as the most important thing in life and Importance of work was the next by Gen-X and leisure time by Gen-Y. However, Gen-Z nurses regarded leisure time as the most important. These findings indicate that influencing factors on turnover of Korean nurses were different by nurses generations. These results indicates that it is necessary to develop different strategies by generations in order to manage turnover issues for Korean nurses.

• Restorative Dentistry and Endodontics
• /
• v.35 no.1
• /
• pp.51-58
• /
• 2010

Dental composites have improved significantly in physical properties over the past few decades. However, polymerization shrinkage and stress is still the major drawback of composites, limiting its use to selected cases. Much effort has been made to make low shrinking composites to overcome this issue and silorane-based composites have recently been introduced into the market. The aim of this study was to measure the volumetric polymerization shrinkage kinetics of a silorane-based composite and compare it with conventional methacrylate-based composites in order to evaluate its effectiveness in reducing polymerization shrinkage. Five commercial methacrylate-based (Beautifil, Z100, Z250, Z350 and Gradia X) and a silorane-based (P90) composites were investigated. The volumetric change of the composites during light polymerization was detected continuously as buoyancy change in distilled water by means of Archemedes' principle, using a newly made volume shrinkage measurement instrument. The null hypothesis was that there were no differences in polymerization shrinkage, peak polymerization shrinkage rate and peak shrinkage time between the silorane-based composite and methacrylate-based composites. The results were as follows: 1. The shrinkage of silorane-based (P90) composites was the lowest (1.48%), and that of Beautifil composite was the highest (2.80%). There were also significant differences between brands among the methacrylate-based composites. 2. Peak polymerization shrinkage rate was the lowest in P90 (0.13%/s) and the highest in Z100 (0.34%/s). 3. The time to reach peak shrinkage rate of the silorane-based composite (P90) was longer (6.7 s) than those of the methacrylate-based composites (2.4-3.1 s). 4. Peak shrinkage rate showed a strong positive correlation with the product of polymerization shrinkage and the inverse of peak shrinkage time (R = 0.95).

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.19 no.6
• /
• pp.280-290
• /
• 2018

This study was a non-equivalence-based Quasi experimental study comparing the difference in communication ability, emotional intelligence (EQ), self-esteem, and interpersonal abilities between an experimental group with communication training and a non-control group. The subjects of the study were nurses working for D university hospital located in C city and comprised an experimental group of 21 people and a control group of 21 people. From April to May 2017, the experimental group took communication training programs, which were designed to improve communication capacity, emotional intelligence, self-esteem, and interpersonal ability for a total of four sessions (for 2 hours a week), and pre-post examination was conducted for the validity of the study. For data analysis, the SPSS for Windows 23 was used for the mean and standard deviation of pre-post tests, and U-test of the independent sample Mann-Whitney and the Wilcoxon code order test of the corresponding sample were carried out. The study results indicate that, compared with the control group, the experimental group showed communication capacity (Z=-3.361, p<.05), emotional intelligence (Z=-2.209, p<.05), self-esteem (Z=-1.633, p<.05), and interpersonal relationship (Z=-2.577, p<.05). After the communication training program, scores of communication capacity, emotional intelligence (EQ), self-esteem, and interpersonal competence of the experimental group increased significantly, and all hypotheses were supported. These results suggest that nurses' use of communication training experience in performing nursing work in a clinical setting would improve communication skills, emotional intelligence (EQ), self-esteem, and interpersonal skills and provide therapeutic communication and effective nursing, thereby enhancing patients' satisfaction and contributing to the improvement of nursing quality.

• Journal of Information Management
• /
• v.42 no.3
• /
• pp.71-94
• /
• 2011

Query by visual example is the principal query paradigm for expressing queries in a content-based image retrieval environment. Query by image and query by sketch have long been purported as being viable methods of query formulation yet there is little empirical evidence to support their efficacy in facilitating query formulation. The ability of the searcher to express their information problem to an information retrieval system is fundamental to the retrieval process. The aim of this research was to investigate the query by image and query by sketch methods in supporting a range of information problems through a usability experiment in order to contribute to the gap in knowledge regarding the relationship between searchers' information problems and the query methods required to support efficient and effective visual query formulation. The results of the experiment suggest that query by image is a viable approach to visual query formulation. In contrast, the results strongly suggest that there is a significant mismatch between the searchers information problems and the expressive power of the query by sketch paradigm in supporting visual query formulation. The results of a usability experiment focusing on efficiency (time), effectiveness (errors) and user satisfaction show that there was a significant difference, p<0.001, between the two query methods on all three measures: time (Z=-3.597, p<0.001), errors (Z=-3.317, p<0.001), and satisfaction (Z=-10.223, p<0.001). The results also show that there was a significant difference in participants perceived usefulness of the query tools Z=-4.672, p<0.001.

• Journal of the korean academy of Pediatric Dentistry
• /
• v.46 no.4
• /
• pp.353-361
• /
• 2019

The aim of this study was to evaluate the color stability of bulk-fill and conventional resin composites with respect to different storage media and thickness of composites. Filtek™ Z250 and Filtek™ Z350XT were evaluated as conventional resin composites. Filtek™ Bulk-fill Posterior Restorative and Tetric^® N-Ceram Bulk Fill were evaluated as bulk-fill resin composites. CIE L^*a^*b^* values of baseline were measured after 24 hours of storage in distilled water, and each resin composite group was divided into three subgroups and stored in distilled water, red wine, and coffee media respectively. Again after 1, 7 and 28 days of immersion, color changes (ΔE^*) were calculated using the CIE L^*a^*b^* values. The greatest ΔE^* was observed in red wine for all resin composites, and the mean color changes were ranked in the increasing order of distilled water, coffee, red wine. Filtek™ Z350XT exhibited the greatest color change in all media, followed by Filtek™ Bulk-fill Posterior Restorative. Filtek™ Z250 and Tetric^® N-Ceram Bulk Fill followed with similar mean color change values. According to the 2 different thicknesses of 2 mm and 4 mm of bulk-fill resin composites, there was no thickness-related difference on color changes.

• The Korean Journal of Applied Statistics
• /
• v.5 no.2
• /
• pp.243-254
• /
• 1992

In the present study two sets of unbalanced two-way cross-classification data with and without empty cell(s) were used to evaluate empirically the various sums of squares in the analysis of variance table. Searle(1977) and Searle et.al.(1981) developed a method of computing R($\alpha$\mid$\mu, \beta$) and R($\beta$\mid$\mu, \alpha$) by the use of partitioned matrix of X'X for the model of no interaction, interchanging the columns of X in order of $\alpha, \mu, \beta$ and accordingly the elements in b. An alternative way of computing R($\alpha$\mid$\mu, \beta$), R($\beta$\mid$\mu, \alpha$) and R($\gamma$\mid$\mu, \alpha, \beta$) without interchanging the columns of X has been found by means of,$(X'X)^-$ derived, using $W_2 = Z_2Z_2-Z_2Z_1(Z_1Z_1)^-Z_1Z_2$. It is true that $R(\alpha$\mid$\mu,\beta,\gamma)\Sigma = SSA_W and R(\beta$\mid$\mu,\alpha,\gamma)\Sigma = SSB_W$ where $SSA_W$ and means analysis and $R(\gamma$\mid$\mu,\alpha,\beta) = R(\gamma$\mid$\mu,\alpha,\beta)\Sigma$ for the data without empty cell, but not for the data with empty cell(s). It is also noticed that for the datd with empty cells under W - restrictions $R(\alpha$\mid$\mu,\beta,\gamma)_W = R(\mu,\alpha,\beta,\gamma)_W - R(\mu,\alpha,\beta,\gamma)_W = R(\alpha$\mid$\mu) and R(\beta$\mid$\mu,\alpha,\gamma)_W = R(\mu,\alpha,\beta,\gamma)_W - R(\mu,\alpha,\beta,\gamma)_W = R(\beta$\mid$\mu) but R(\gamma$\mid$\mu,\alpha,\beta)_W = R(\mu,\alpha,\beta,\gamma)_W - R(\mu,\alpha,\beta,\gamma)_W \neq R(\gamma$\mid$\mu,\alpha,\beta)$. The hypotheses $H_o : K' b = 0$ commonly tested were examined in the relation with the corresponding sums of squares for $R(\alpha$\mid$\mu), R(\beta$\mid$\mu), R(\alpha$\mid$\mu,\beta), R(\beta$\mid$\mu,\alpha), R(\alpha$\mid$\mu,\beta,\gamma), R(\beta$\mid$\mu,\alpha,\gamma), and R(\gamma$\mid$\mu,\alpha,\beta)$ under the restrictions.

• KSCE Journal of Civil and Environmental Engineering Research
• /
• v.34 no.6
• /
• pp.1765-1777
• /
• 2014

This study evaluated PMM (Probability Matching Method) for parameter estimation of the Z - R relation. As a first step, the sensitivity analysis was done to decide the threshold number of data pairs and the data interval for the development of a histogram. As a result, it was found that at least 1,000 number of data pairs are required to apply the PMM for the parameter estimation. This amount of data is similar to that collected for two hours. Also, the number of intervals for the histogram was found to be at least 100. Additionally, it was found that the matching the first-order moment is better than the cumulative probability, and that the data pairs comprising 30 to 100% are better for the PMM application. Finally, above findings were applied to a real rainfall event observed by the Bislsan radar and optimal parameters were estimated. The radar rain rate derived by applying these parameters was found to be well matched to the rain gauge rain rate.