• Title/Summary/Keyword: Ytterbium

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Applications of Cross-linked Poly(4-vinylpyridine/styrene) Copolymer supported Ytterbium(III) Triflate in Mannich-type Reaction:Three Component One-pot Synthesis of β-Aminoketones

  • Lee, Sang-Hyeup;Lee, Byoung-Se
    • Bulletin of the Korean Chemical Society
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    • v.30 no.3
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    • pp.551-555
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    • 2009
  • The ytterbium catalyst immobilized on the cross-linked poly(4-vinylpyridine/styrene) copolymer (P/S-Yb) was applied in the Mannich-type, three component one-pot synthesis of $\beta$-aminoketones. This catalytic system showed excellent catalytic activity and selectivity which resulted in the exclusive formation of $\beta$-aminoketone. The applicability of this immobilized catalyst system was shown by the reusability test and again highlighted by the synthesis of a $\beta$-aminoketone library using a broad range of substrates.

Determination of the Isotope Ratio for Metal Samples Using a Laser Ablation/Ionization Time-of-flight Mass Spectrometry

  • Song, Kyu-Seok;Cha, Hyung-Ki;Kim, Duk-Hyeon;Min, Ki-Hyun
    • Bulletin of the Korean Chemical Society
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    • v.25 no.1
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    • pp.101-105
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    • 2004
  • The laser ablation/ionization time-of-flight mass spectrometry is applied to the isotopic analysis of solid samples using a home-made instrument. The technique is convenient for solid sample analysis due to the onestep process of vaporization and ionization of the samples. The analyzed samples were lead, cadmium, molybdenum, and ytterbium. To optimize the analytical conditions of the technique, several parameters, such as laser energy, laser wavelength, size of the laser beam on the samples surface, and high voltages applied on the ion source electrodes were varied. Low energy of laser light was necessary to obtain the optimal mass resolution of spectra. The 532 nm light generated mass spectra with the higher signal-to-noise ratio compared with the 355 nm light. The best mass resolution obtained in the present study is ~1,500 for the ytterbium.

Comparative Experimental Analysis of Thermal Characteristics of Ytterbium-Doped Phosphosilicate and Aluminosilicate Fibers

  • Lee, Seungjong;Vazquez-Zuniga, Luis A.;Lee, Dongyoung;Kim, Hyuntai;Sahu, Jayanta K.;Jeong, Yoonchan
    • Journal of the Optical Society of Korea
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    • v.17 no.2
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    • pp.182-187
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    • 2013
  • We present a comparative experimental analysis of the thermal spectroscopic characteristics of a phosphosilicate (P)-based ytterbium-doped fiber (YDF) against an aluminosilicate (Al)-based YDF in the temperature range of 25 to $150^{\circ}C$. We also characterize the fibers as gain media in a cladding-pumped amplifier configuration. While both fibers exhibit comparable trends in their thermal characteristics, there are noticeable distinctions in the fluorescence lifetime reduction rate and the spectral dependence of the transition cross-sections. The P- and Al-based YDFs present thermal lifetime reduction rates of $0.012%/^{\circ}C$ and $0.026%/^{\circ}C$, respectively. In particular, in the spectral region at ~940 nm, the absorption cross-section of the P-based YDF undergoes significantly less thermal change compared to that of the Al-YDF. In the cladding-pumped amplifier configuration operating at a total gain of 10 dB, the Al-based YDF generally performs betters than the P-based YDF in the temperature range of 25 to $75^{\circ}C$. However, it is highlighted that in the high temperature range of over $75^{\circ}C$, the latter shows a less gain reduction rate than the former, thereby yielding higher relative output power by 3.3% for a 1060-nm signal, for example.

Electrical and Physical Characteristics of Nickel Silicide using Rare-Earth Metals (희토류 금속을 이용한 니켈 실리사이드의 전기 및 물리적 특성)

  • Lee, Won-Jae;Kim, Do-Woo;Kim, Yong-Jin;Jung, Soon-Yen;Wang, Jin-Suk
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.21 no.1
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    • pp.29-34
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    • 2008
  • In this paper, we investigated electrical and physical characteristics of nickel silicide using rare-earth metals(Er, Yb, Tb, Dy), Incorporated Ytterbium into Ni-silicide is proposed to reduce work function of Ni-silicide for nickel silicided schottky barrier diode (Ni-silicided SBD). Nickel silicide makes ohmic-contact or low schottky barrier height with p-type silicon because of similar work function (${\phi}_M$) in comparison with p-type silicon. However, high schottky barrier height is formed between Ni-silicide and p-type substrate by depositing thin ytterbium layer prior to Ni deposition. Even though the ytterbium is deposited below nickel, ternary phase $Yb_xN_{1-x}iSi$ is formed at the top and inner region of Ni-silicide, which is believed to result in reduction of work function about 0.15 - 0.38 eV.

Theoretical Analysis of Impact of Q-switch Rise Time on Output Pulse Performance in an Ytterbium-doped Actively Q-switched Fiber Laser (이터븀 첨가 능동형 Q-스위칭 광섬유 레이저에서 Q-스위치 상승 시간이 출력 펄스에 미치는 영향에 대한 이론적 분석)

  • Jeon, Jinwoo;Lee, Junsu;Lee, Ju Han
    • Korean Journal of Optics and Photonics
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    • v.24 no.2
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    • pp.58-63
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    • 2013
  • A theoretical analysis of the impact of rise time of a Q-switch on the output pulse performance is carried out in an Ytterbium-doped actively Q-switched fiber laser. The finite difference time domain (FDTD) method is used to numerically simulate the Q-switched fiber laser. It is shown that stable Gaussian-like pulse shape can be generated when the Q-switch rise time is increased and pulse repetition rate is enlarged.

Effect of Deposition Parameter and Mixing Process of Raw Materials on the Phase and Structure of Ytterbium Silicate Environmental Barrier Coatings by Suspension Plasma Spray Method (서스펜션 플라즈마 스프레이 코팅법으로 제조된 Ytterbium Silicate 환경차폐코팅의 상형성 및 구조에 미치는 증착인자 및 원료혼합 공정의 영향)

  • Ryu, Ho-lim;Choi, Seon-A;Lee, Sung-Min;Han, Yoon-Soo;Choi, Kyun;Nahm, Sahn;Oh, Yoon-Suk
    • Journal of Powder Materials
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    • v.24 no.6
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    • pp.437-443
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    • 2017
  • SiC-based composite materials with light weight, high durability, and high-temperature stability have been actively studied for use in aerospace and defense applications. Moreover, environmental barrier coating (EBC) technologies using oxide-based ceramic materials have been studied to prevent chemical deterioration at a high temperature of $1300^{\circ}C$ or higher. In this study, an ytterbium silicate material, which has recently been actively studied as an environmental barrier coating because of its high-temperature chemical stability, is fabricated on a sintered SiC substrate. $Yb_2O_3$ and $SiO_2$ are used as the raw starting materials to form ytterbium disilicate ($Yb_2Si_2O_7$). Suspension plasma spraying is applied as the coating method. The effect of the mixing method on the particle size and distribution, which affect the coating formation behavior, is investigated using a scanning electron microscope (SEM), an energy dispersive spectrometer (EDS), and X-ray diffraction (XRD) analysis. It is found that the originally designed compounds are not effectively formed because of the refinement and vaporization of the raw material particles, i.e., $SiO_2$, and the formation of a porous coating structure. By changing the coating parameters such as the deposition distance, it is found that a denser coating structure can be formed at a closer deposition distance.

A study on gold wire-thin film welding using laser (레이저를 이용한 골드 와이어-박막 용접에 관한 연구)

  • Park, K.W.;Na, S.J.
    • Proceedings of the Korean Society of Laser Processing Conference
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    • 2006.06a
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    • pp.108-111
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    • 2006
  • Recently, mobile information devices, such as cellular phone, PDA(Personal Digital Assistant, PDA) are getting smaller and thinner. Accordingly, ultra precision welding technology is required to manufacture the high performance system for use in the telecommunication industry. In this study, we propose the laser micro welding process. Using ytterbium fiber laser, a wide range of experiments have been carried out for the gold wire-to-gold thin film welding.

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