• Title/Summary/Keyword: Yb

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Characterization of Extracellular \alpha-galactosidase Produced by Streptomyces sp. YB-4. (균체외 \alpha-galactosidase를 생산하는 Streptomyces sp. YB-4의 분리 및 효소 특성)

  • 김소영;조기행;김창진;박동진;윤기홍
    • Microbiology and Biotechnology Letters
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    • v.30 no.4
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    • pp.332-338
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    • 2002
  • A strain YB-4 producing the extracellular $\alpha$-galactosidase was isolated from soil, and has been identified as Streptomyces sp. on the basis of its cultural, morphological and physiological properties. The partially purified $\alpha$-galactosidase was most active on paranitrophenyl-$\alpha$-D-galactopyranoside at pH 6.0 and 6$0^{\circ}C$. The enzyme retained 90% of its maximum activity between pH 4.0 and pH 10.0 after pre-incubation for 1 h. The enzyme was able to hydrolyze oligomeric substrates such as melibiose, raffinose and stachyose to liberate galactose residue, indicating that the $\alpha$-galactosidase of Steptomyces sp. YB-4 hydrolyzed $\alpha$-1,6 linkage.

Growth, structure and SHG properties of Li, Mo-containing huntite-borates $YbAl_3(BO_3)_4$

  • K. Shimamura;V.l. Chani;T. Fukuda
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.8 no.2
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    • pp.205-210
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    • 1998
  • $Li^+$ and $Mo^{6+}$ containing huntite borates $YbAl_3(BO_3)_4$were grown by spontaneous crystallization. All crystal show only the huntite-borate phase detected by X-ray powder diffraction analysis. On the basis of the data of the composition analysis, the occupation mechanism of each cation in the huntite structure has been discussed. $Li^+$ and $Mo^{6+}$ containing $YbAl_3(BO_3)_4$shows a six times higher intensity of the green light SHG detected by the powder technique than YAl_3(BO_3)_4$.

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Microwave Sol-Gel Derived NaGd(MoO4)2:Ho3+/Yb3+ Phosphors and Their Upconversion Photoluminescence Properties

  • Lim, Chang Sung
    • Transactions on Electrical and Electronic Materials
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    • v.18 no.6
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    • pp.364-369
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    • 2017
  • Double molybdate $NaGd_{1-x}(MoO_4)_2:Ho^{3+}/Yb^{3+}$ phosphors with proper doping concentrations of $Ho^{3+}$ and $Yb^{3+}$ ($x=Ho^{3+}+Yb^{3+}$, $Ho^{3+}=0$ and 0.05, and $Yb^{3+}=0$, 0.35, 0.40, 0.45, and 0.50) were successfully synthesized using the microwave sol-gel method. Well-crystallized particles formed after heat-treatment at $800^{\circ}C$ for 16 h showed fine and homogeneous morphologies with particle sizes of $1{\sim}3{\mu}m$. The spectroscopic properties were examined using photoluminescence emission and Raman spectroscopy. Under excitation at 980 nm, the upconversion doped samples exhibited strong yellow emissions, from the combination of strong emission bands at 545 nm and 655 nm in the green and red spectral regions, respectively. The strong 545 nm emission band in the green region corresponded to the $^5S_2/^5F_4{\rightarrow}^5I_8$ transition in the $Ho^{3+}$ ions, while the strong 655 nm band in the red region appeared because of the $^5F_5{\rightarrow}^5I_8$ transition in the $Ho^{3+}$ ions. The pump power dependence and the Commission Internationale de L'Eclairage chromaticity of the upconversion emission intensity were evaluated in detail.

Growth of Young Sea Bass Lateolabrax japonicus in the Eelgrass Beds of Gamak and Yeoja Bays in Relation to Environmental Variables (가막만과 여자만의 잘피밭에 서식하는 농어(Lateolabrax japonicus) 유어의 성장 및 환경과의 관계)

  • Kim, Jin-Koo;Ryu, Jung-Hwa;Kim, Jeong Bae;Lee, Won-Chan;Kim, Hyung Chul;Moon, Seong Yong;Kim, Hee Yong
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.48 no.6
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    • pp.920-928
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    • 2015
  • This study aims to reveal the relationship between growth of young sea bass and environmental variables in two adjacent eelgrass beds. Fishes were collected from Gamak Bay (GB) and Yeoja Bay (YB) on the southern coast of Korea from February 2006 to February 2007 using a dragnet (15 m in length and 3 m in width). During the study period, a total of 367 individuals of young sea bass Lateolabrax japonicus were collected from GB (171 inds.) and YB (196 inds.). Significant differences were observed in the occurrence periods and growth patterns of young sea bass, as well as in environmental variables between GB and YB. Young sea bass were collected from April to December in GB, but from April to July in YB. These differences may be associated with differences in eelgrass density, leaf width, and zooplankton density between GB and YB.

Microwave Sol-Gel Derived NaLa(MoO4)2 Yellow Phosphors Doped with Ho3+/Yb3+ and Upconversion Photoluminescence

  • Lim, Chang Sung
    • Korean Journal of Materials Research
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    • v.26 no.1
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    • pp.29-34
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    • 2016
  • $NaLa_{1-x}{(MoO_4)}_2$:$Ho^{3+}/Yb^{3+}$ phosphors with the correct doping concentrations of $Ho^{3+}$ and $Yb^{3+}$ ($x=Ho^{3+}+Yb^{3+}$, $Ho^{3+}=0.05$ and $Yb^{3+}=0.35$, 0.40, 0.45 and 0.50) were successfully synthesized by the microwave-modified sol-gel method. Well-crystallized particles formed after heat-treatment at $900^{\circ}C$ for 16 h showed a fine and homogeneous morphology with particle sizes of $3-5{\mu}m$. The optical properties were examined using photoluminescence emission and Raman spectroscopy. Under excitation at 980 nm, the UC intensities of the doped samples exhibited strong yellow emissions based on the combination of strong emission bands at 545-nm and 655-nm emission bands in green and red spectral regions, respectively. The strong 545-nm emission band in the green region corresponds to the $^5S_2/^5F_4{\rightarrow}^5I_8$ transition in $Ho^{3+}$ ions, while the strong emission 655-nm band in the red region appears due to the $^5F_5{\rightarrow}^5I_8$ transition in $Ho^{3+}$ ions. Pump power dependence and Commission Internationale de L'Eclairage chromaticity of the upconversion emission intensity were evaluated in detail.

Mixed Lanthanide Shift Reagents (혼합 란탄족 Shift Reagents)

  • Man-Ho Lee;Charles N. Reilley
    • Journal of the Korean Chemical Society
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    • v.26 no.1
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    • pp.24-30
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    • 1982
  • Contact-only (COM) and dipolar-only (DOM) mixtures of the lanthanide shift reagents were prepared based on the Fi and Gi values deduced using individual Ln$(fod)_3$ (Ln = Pr, Nd, Eu, and Yb) and 4-picoline. The $F_i$ and $G_i$ values obtained directly by COM 1 and by DOM 1, which were appropriate mixture of Pr$(fod)_3$ and Eu$(fod)_3$, agreed well with those values obtained by experiments using individual Ln$(fod)_3$ shift reagents. Ei and Gi values obtained directly by COM 2 and by DOM 2, which were mixtures of Nd$(fod)_3$ and Yb$(fod)_3$, deviated from the expected values. The error was traced to the behavior of the ytterbium complexes.

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A study on the structural and electric properties of fluorinated $YBa_2Cu_3O_{7-y}$ (불소화된 $YBa_2Cu_3O_{7-y}$ 초전도체의 구조적, 전기적 성질에 관한 연구)

  • 김재욱;김채옥
    • Electrical & Electronic Materials
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    • v.9 no.4
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    • pp.404-409
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    • 1996
  • The structural and electric properties of $Y_{1-x}$YbF$_{x}$Ba$_{2}$Cu$_{3}$O$_{7-y}$(x=0.0, 0.1, 0.2, 0.3, 0.4, 0.5 and 0.6) have been investigated by using XRD(X-ray diffraction), TMA(thennomechanical analysis), NMR(nuclear magnetic resonance) analysis and four probe method. $Y_{1-x}$YbF$_{x}$Ba$_{2}$Cu$_{3}$O$_{7-y}$ samples were prepared by conventional solid-state reaction method using $Y_{2}$O$_{3}$, BaCO$_{3}$, CuO and YbF$_{3}$ power. TMA and high temperature XRD results shows that orthorhombic to tetragonal phase transition occurs in the unfluorinated 1-2-3 sample while the phase change is not observed in the fluorinated 1-2-3 samples. Superconducting transition temperature(T$_{c}$) increases with increasing YbF$_{3}$ content ; T$_{c}$, of the sample reaching maximum of 102K for x=0.3, and then decreases with further increasing YbF$_{3}$ content. The structural analysis and T$_{c}$ results shows that the fluorine doping stabilize the orthorhombic phase, together with the increase in T$_{c}$.}$ c/.TEX> c/.

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Electrical Properties of BaTiO3 Thick Films Fabricated by Screen-printing Method

  • Ahn, Byeong-Lib;Lee, Sung-Gap
    • Transactions on Electrical and Electronic Materials
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    • v.8 no.4
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    • pp.149-152
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    • 2007
  • [ $(Ba_{0.6}Sr_{0.3}Ca_{0.1})TiO_3$ ](BSCT) thick films doped with 0.1 mol% $MnCO_3\;and\;Yb_2O_3(0.1{\sim}0.7mol%)$ were fabricated by the screen printing method on the alumina substrates. And the structural and electrical properties as a function of $Yb_2O_3$ amount were investigated. The exothermic peak was observed at around $680^{\circ}C$ due to the formation of the poly crystalline perovskite phase. The lattice constants of the BSCT thick film doped with 0.7 mol% is 0.3994 nm. The specimen doped with 0.7 mol% $Yb_2O_3$ showed dense and uniform grains with diameters of about $4.2{\mu}m$. The average thickness of all BSCT thick films was approximately $70{\mu}m$. Relative dielectric constant and dielectric loss of the specimen doped with 0.7 mol% $Yb_2O_3$ were 2823 and 3.4%, respectively. The Curie temperature of the BSCT thick films doped with 0.1 mol% $Yb_2O_3$ was $46^{\circ}C$.

Thermoelectric Properties of P-type (Ce1-zYbz)0.8Fe4-xCoxSb12 Skutterudites

  • Choi, Deok-Yeong;Cha, Ye-Eun;Kim, Il-Ho
    • Korean Journal of Metals and Materials
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    • v.56 no.11
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    • pp.822-828
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    • 2018
  • P-type Ce/Yb-filled skutterudites were synthesized, and their charge transport and thermoelectric properties were investigated with partial double filling and charge compensation. In the case of $(Ce_{1-z}Yb_z)_{0.8}Fe_4Sb_{12}$ without Co substitution, the marcasite ($FeSb_2$) phase formed alongside the skutterudite phase, but the generation of the marcasite phase was inhibited by increasing Co concentration. The electrical conductivity decreased with increasing temperature, exhibiting degenerate semiconductor behavior. The Hall and Seebeck coefficients were positive, which confirmed that the specimens were p-type semiconductors with holes as the major carriers. The carrier concentration decreased as the concentration of Ce and Co increased, which led to decreased electrical conductivity and increased Seebeck coefficient. The thermal conductivity decreased due to a reduction in electronic thermal conductivity via Co substitution, and due to decreased lattice thermal conductivity via double filling of Ce and Yb. $(Ce_{0.25}Yb_{0.75})_{0.8}Fe_{3.5}Co_{0.5}Sb_{12}$ exhibited the greatest dimensionless figure of merit (ZT = 0.66 at 823 K).

Enhanced Blue Emission in Er3+/Yb33+ Doped Glass-ceramics Containing Ag Nanoparticles and ZnO Nanocrystals

  • Bae, Chang-hyuck;Lim, Ki-Soo
    • Current Optics and Photonics
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    • v.3 no.2
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    • pp.135-142
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    • 2019
  • We report the precipitation of ZnO nanocrystals, Ag-clusters, and Ag nanoparticles in Ag/Er/Yb doped borate glasses by furnace annealing and $CO_2$ laser annealing. The XRD analysis revealed the precipitation of ZnO and Ag phases. The absorption spectra, the TEM and energy dispersive spectroscopy (EDS) revealed the incorporation of Er and Yb ions into ZnO nanocrystals formed by a laser technique and showed the surface plasmon band of Ag nanoparticles. The down-converted blue emission intensity of $Er^{3+}$ ions obtained under 365 nm excitation was enhanced by more than a hundred times in the glass treated by furnace annealing, mainly due to the energy transfer from Ag-clusters. Moreover, we discussed the contribution of Ag nanoparticles and defects to emission characteristics in the glasses treated by two annealing techniques. Up-conversion emissions of the $Er^{3+}$ ions under 980 nm excitation were enhanced due to the incorporation of $Er^{3+}$ and $Yb^{3+}$ ions into ZnO nanocrystals after thermal treatments.