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Preliminary Study on the Ultramafic Rocks from the Chungnam Province, Korea (충남지역에 분포하는 초염기성암의 기원규명을 위한 기초연구)

  • Wee, Soo-Meen;Choi, Seon-Gyu;So, Chil-Sup
    • Economic and Environmental Geology
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    • v.27 no.2
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    • pp.171-180
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    • 1994
  • Several ultramafic bodies and ultramafic origin talc deposits are distributed in Chungnam province near the contact zone with Ogchun fold belt They occur as discontinued belt form with northeast trending, and most of them are more or less sepentinized. Major, trace, and rare earth elements analyses were made of the ultramafics from the study area to constrain their origin and genetic relationships. Compared to the primitive mantle estimates of privious workers, the correlations defined by the studied rock samples indicate similar Ni but very lower $Al_{2}O_{3}$, CaO and $TiO_{2}$ contents. It is inferred that source material of the studied rocks might be residual mantle which had undergone a large degree of partial melting event. The REE patterns show relatively flat to enriched in LREE (chondrite normalized La/Yb and Sm/Yb ratios are 1.1-5.2 and 1.2-1.6). Several alternative explaination are possible for LREE enrichment patterns in the studied ultramafic rocks such as 1) enrichment due to late stage alteration, 2) enriched pre-melting composition, and 3) mixing of two components. Based on the result, the LREE enrichment characteristic of the studied rocks might be result from the mixture of two geochemically distinct components; one is depleted residual mantle and the other component which determine the abundances of incompatible elements and responsible for the LREE enrichment.

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REE Mineralization and Geology of Chulmasan Area, Taean, Chungchungnamdo (충남 태안 철마산 일대의 지질 및 희토류 광화작용)

  • Yoo, Bong Chul
    • Journal of the Mineralogical Society of Korea
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    • v.32 no.2
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    • pp.127-143
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    • 2019
  • The geology of the Chulmasan area consists of Precambrain Sogeunri formation, granitic gneiss, foliated biotite granite, foliated mica granite, basic dyke and acidic dyke. REE mineralization in the area occurs at granitic gneiss and foliated mica granite. Minerals with minor amounts of REE and Th from granitic gneiss and foliated mica granite are zircon ($Y_2O_3$ 0.00~1.18 wt.%, $Gd_2O_3$ 0.00~0.59 wt.%, $Er_2O_3$ 0.00~0.22 wt.%, $Yb_2O_3$ 0.00~0.34 wt.%, $Lu_2O_3$ 0.00~0.48 wt.%, $ThO_2$ 0.00~0.33 wt.%), thorianite ($Nd_2O_3$ 0.00~0.24 wt.%, $Lu_2O_3$ 0.00~0.26 wt.%), berthierine ($La_2O_3$ 0.04~0.26 wt.%, $Nd_2O_3$ 0.00~0.20 wt.%, $Tb_2O_3$ 0.04~0.12 wt.%, $Dy_2O_3$ 0.17~0.26 wt.%, $Er_2O_3$ 0.33~0.44 wt.%, $Lu_2O_3$ 0.00~0.19 wt.%, $ThO_2$ 0.61~0.93 wt.%), chlorite ($La_2O_3$ 0.44~0.68 wt.%, $Ce_2O_3$ 0.12~0.13 wt.%, $Nd_2O_3$ 0.31~0.44 wt.%, $Eu_2O_3$ 0.03~0.08 wt.%, $Dy_2O_3$ 0.09~0.21 wt.%, $Ho_2O_3$ 0.04~0.14 wt.%, $Er_2O_3$ 0.18~0.32 wt.%, $Lu_2O_3$ 0.07~0.21 wt.%, $ThO_2$ 0.00~0.97 wt.%), biotite ($Nd_2O_3$ 0.02~0.08 wt.%, $Gd_2O_3$ 0.07~0.08 wt.%, $Tb_2O_3$ 0.02~0.07 wt.%, $Dy_2O_3$ 0.35~0.43 wt.%, $Ho_2O_3$ 0.15~0.26 wt.%, $Er_2O_3$ 0.24~0.28 wt.%, $Yb_2O_3$ 0.06~0.18 wt.%, $ThO_2$ 0.00~0.12 wt.%), orthoclase ($Dy_2O_3$ 0.05~0.12 wt.%, $Ho_2O_3$ 0.05~0.06 wt.%, $Er_2O_3$ 0.28 wt.%, $Yb_2O_3$ 0.06~0.12 wt.%) and plagioclase ($Ho_2O_3$ 0.01~0.03 wt.%, $Er_2O_3$ 0.10~0.27 wt.%, $ThO_2$ 0.11~0.13 wt.%). REE minerals (bastnaesite and fergusonite) were sealed fractures in mainly fledspar, mica, zircon, apatite and ilmenite. Therefore, bastnaesite and fergusonite from the Chulmasan area were formed from redissolution/reconcentration of REE-and Th-bearing minerals from granitic gneiss and foliated mica granite at late stage by several igneous activies and metamorphism.

High Temperature Properties of $Si_3N_4-Re$Silicon Oxynitride (Re=Y, Yb, Er, La) Ceramics

  • Park, Heon-Jin;Lee, June-Gunn;Kim, Young-Wook;Cho, Kyeong-Sik
    • The Korean Journal of Ceramics
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    • v.5 no.3
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    • pp.211-216
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    • 1999
  • Four different $\beta-Si_3N_4$ ceramics with silicon oxynitrides $[Y_10(SiO_4)_6N_2, Yb_4Si_2N_2O_7, Er_2Si_3N_4O_3, \;and La_{10}(SiO_4)_6N_2$, respectivley] as secondary phases have been fabricated by hot-pressing the $Si_3N_4-Re_4Si_2N_2O_7$ (Re=Y, Yb, Er, and La) compositions at $1820^{\circ}C$ for 2h under a pressure of 25 MPa. The high temperature strength and oxidation behavior of the hot-pressed ceramics were characterized and compared with those of the ceramics fabricated from $Si_3N_4-Si_2O_7$ compositions. The $Si_3N_4-Re_4Si_2N_2O_7$composition investigated herein showed comparable high temperature strength to those from $Si_3N_4-Re_2Si_2O_7$ compositions. Si3N4 ceramics from a $Si_3N_4-Y_4Si_2N_2O_7$ composition showed the highest strength of 877 MPa at $1200^{\circ}C$ among the compositions. All $Si_3N_4$ ceramics investigated herein showed a parabolic weight gain with oxidation time at $1400^{\circ}C$ and the oxidation products of the ceramics were $SiO_2$ and $Re_2Si_2O_7$. The $Si_3N_4-Re_4Si_2N_2O_7$ compositions showed inferior oxidation resistance to those from $Si_3n_4-Re_2Si_2O_7$ compositions, owing to the incompatibility of the secondary crystalline phases of those ceramics with $SiO_2$, the oxidation product of Si3N4.Si3N4 ceramics from a $Si_3N_4-Er_4Si_2N_2O_7$ composition showed the best oxidation resistance of 0.375mg/$\textrm{cm}^2$ after oxidation at $1400^{\circ}C$ for 102 h in air among the compositions.

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The Wondong magmatic system : its petrochemical evolution (원동 마그마계 : 암석화학적 진화)

  • 황상구
    • The Journal of the Petrological Society of Korea
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    • v.6 no.3
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    • pp.166-184
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    • 1997
  • The Wondong caldea is a deeply eroded structure that offers spectacular exposures through the core and margins of a resurgent caldera. The Wondong Tuff and the postcollapse intrusions range from medium-silica rhyolite to rhyodacite in composition and the postcollapse lava and tuff, preresurgent and resurgent intrusions also range from medium-silica rhyolite to an-desite, which jump to gap dacite composition. The continuous compositional zonations generally define a large stratified magma system in the postcollapse and resurgent magma chamber. Isotopic and trace element evidence suggest that the compositional zonations might have resulted from the differentiations from crystal fractionations of a parental andesitic magma, accompanying a little contamination from the crustal assimilations near the chamber roof and wall. But chemically and isotopically distinct late intusions might have resulted from emplacement of any different magma batch.

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Estimation of Genetic Parameters for Economic Traits in Korean Native Chickens (재래닭 경제 형질에 대한 유전모수 추정)

  • Kim, Hyo-Sun;Kim, Si-Dong;Lee, Seung-Soo;Kang, Bo-Suk;Lee, Jung-Gyu;Cho, Kwang-Hyun
    • Korean Journal of Poultry Science
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    • v.37 no.2
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    • pp.125-130
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    • 2010
  • This study was conducted to estimate heritabilities, genectic and phenotypic correlations on economic traits in three strains of Korean Native chickens (KNC) : Black (B), Red Brown (RB) and Yellow Brown (YB). The data used in this study were collected from 2000 to 2007 in the National Institute of Animal Science and a total number was 14,421 birds. The effect of the strains analysis showed that the strain B were greater than the other strains for body weight at 150 days and 270 days. The number of egg production at 270 days of the strain YB was higher than the other strains. The estimated heritabilities age at $1^{st}$ egg, body weight at 150 days, egg weight at $1^{st}$ egg, body weight at 270 days, egg weight at 270 days and number of egg production at 270 days were 0.32, 0.50, 0.31, 0.43, 0.48 and 0.69 for strain B; were 0.42, 0.41, 0.19, 0.48, 0.44 and 0.76 for strain RB; were 0.44, 0.52, 0.24, 0.54, 0.51 and 0.66 for strain YB respectively, The genetic and phenotypic correlations were also estimated.

Solvent Extraction of Heavy Rare Earth Elements Using PC88A from Synthesis Solution of Low Concentration Rare Earth Solution (저농도 희토류 용액으로부터 PC88A를 이용한 중희토류의 용매추출 연구)

  • Ahn, Nak-Kyoon;Im, Byoungyong;Lee, Jieun;Park, Jae Ryang;Lee, Chan-Gi;Park, Kyung-Soo
    • Resources Recycling
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    • v.26 no.4
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    • pp.26-33
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    • 2017
  • The behavior on the solvent extraction of heavy rare earths (HRE) by using PC88A was confirmed to demonstrate the possibility of recovery on the HRE from industrial wastewater, which consist of low concentration rare earth. We verified the extraction behavior of the HRE through a change of equilibrium pH, extractant concentration and A/O ratio, and also confirmed the stripping behavior depending on the type of mineral acids. At equilibrium pH 1.0, extraction of rare earth (RE) was completed from 95% to 100%. In all extraction conditions, it tend to be extracted in order of high atomic number. When A/O ratio was 10/1, Yb and Tm were concentrated at the maximum and increased 6-fold and 3-fold compared to initial concentration, respectively. To confirm the stripping behavior of the RE, three mineral acids were applied to the organic phase and consequently rate of stripping was increased in order of $HNO_3$, $H_2SO_4$ and HCl.

Linearly Polarized 1-kW 20/400-㎛ Yb-doped Fiber Laser with 10-GHz Linewidth (선편광된 10 GHz 선폭의 1 kW급 20/400-㎛ 이터븀 첨가 광섬유 레이저)

  • Jung, Yeji;Jung, Minwan;Lee, Kangin;Kim, Taewoo;Kim, Jae-Ihn;Lee, Yongsoo;Cho, Joonyong
    • Korean Journal of Optics and Photonics
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    • v.32 no.3
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    • pp.120-125
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    • 2021
  • We have developed a linearly polarized high-power Yb-doped fiber laser in the master oscillator power amplifier (MOPA) scheme for efficient spectral beam combining. We modulated the phase of the seed laser by pseudo-random binary sequence (PRBS), with the bit length optimized to suppress stimulated Brillouin scattering (SBS), and subsequently amplified seed power in a 3-stage amplifier system. We have constructed by coiling the polarization-maintaining (PM) Yb-doped fiber, with core and cladding diameters of 20 ㎛ and 400 ㎛ respectively, to a diameter of 9-12 cm for suppression of the mode instability (MI). Finally, we obtained an output power of 1.004 kW with a slope efficiency of 83.7% in the main amplification stage. The beam quality factor M2 and the polarization extinction ratio (PER) were measured to be 1.12 and 21.5 dB respectively. Furthermore, the peak-intensity difference between the Rayleigh signal and SBS signal was observed to be 2.36 dB in the backward spectra, indicating that SBS is successfully suppressed. In addition, it can be expected that the MI does not occur because not only there is no decrease in slope efficiency, but also the beam quality for each amplified output is maintained.

Analytical Study of Polarization Spectroscopy for the Jg=0 → Je=1 Transition

  • Noh, Heung-Ryoul
    • Journal of the Optical Society of Korea
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    • v.17 no.3
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    • pp.279-282
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    • 2013
  • This work presents a theoretical study on the analytical calculation of the lineshape of polarization spectroscopy (PS) for the transition line $5s^2\;^1S_0{\rightarrow}5s5p\;^1P_1$ of $^{88}Sr$. From the obtained analytical form of the PS spectrum, we were able to identify how the saturation affected the lineshape of the PS spectrum. The results obtained will be useful for polarization spectroscopy experiments using the alkaline-earth atoms such as Sr or Yb.