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Studies on the Determination of Heavy Metal Ions by Flow Injection, the Photochemical Characterization and Polymerization of Eight-Coordinated Complex(Part I): Spectrophotometric Determination of Uranium and Thorium Ions by Flow Injection Analysis using Chrome Azurol S in the Presence of Surfactant (금속이온의 흐름주입법에 의한 정량, 8-배위착물의 광학적 특성 및 중합체에 관한 연구(제1보): 계면활성제 존재하에서 Chrome Azurol S를 사용하여 우라늄 및 토륨이온의 흐름 주입법에 의한 분광광도 정량)

  • Chang, Choo-Hwan;Kang, Sam-Woo;Son, Byung-Chan;Cho, Kwang-Hee
    • Analytical Science and Technology
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    • v.8 no.1
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    • pp.1-7
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    • 1995
  • Spectrophotometric determination of U(VI) and Th(IV) by Flow injection method is described. Chrome Azurol S forms water soluble complexes with U(VI) and Th(IV) in the presence of cethyltrimethylammonium bromide. The maximum adsorption of U(VI) and Th(IV) complexes are at 600nm with molar absorptivity of $2.3{\times}10^5Lmol^{-1}cm^{-1}$ and 611nm with molar absorptivity of $3.8{\times}10^5Lmol^{-1}cm^{-1}$ in acetate buffer medium having pH 5.0 and 5.5. The calibration curves of U(VI) and Th(IV) are linear over the range of 0.1~0.8ppm and the correlation coefficients are ca. 0.9960 and 0.9930 respectively. The detection limits(S/N) are 20ppb for U(VI) and 15ppb for Th(IV). The relative standard deviation are ${\pm}1.8%$ for U(VI) and ${\pm}2.1%$ for Th(IV). The sample throughput was ca. $50hr^{-1}$.

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A study on the Degradation and By-products Formation of NDMA by the Photolysis with UV: Setup of Reaction Models and Assessment of Decomposition Characteristics by the Statistical Design of Experiment (DOE) based on the Box-Behnken Technique (UV 공정을 이용한 N-Nitrosodimethylamine (NDMA) 광분해 및 부산물 생성에 관한 연구: 박스-벤켄법 실험계획법을 이용한 통계학적 분해특성평가 및 반응모델 수립)

  • Chang, Soon-Woong;Lee, Si-Jin;Cho, Il-Hyoung
    • Journal of Korean Society of Environmental Engineers
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    • v.32 no.1
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    • pp.33-46
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    • 2010
  • We investigated and estimated at the characteristics of decomposition and by-products of N-Nitrosodimethylamine (NDMA) using a design of experiment (DOE) based on the Box-Behken design in an UV process, and also the main factors (variables) with UV intensity($X_2$) (range: $1.5{\sim}4.5\;mW/cm^2$), NDMA concentration ($X_2$) (range: 100~300 uM) and pH ($X_2$) (rang: 3~9) which consisted of 3 levels in each factor and 4 responses ($Y_1$ (% of NDMA removal), $Y_2$ (dimethylamine (DMA) reformation (uM)), $Y_3$ (dimethylformamide (DMF) reformation (uM), $Y_4$ ($NO_2$-N reformation (uM)) were set up to estimate the prediction model and the optimization conditions. The results of prediction model and optimization point using the canonical analysis in order to obtain the optimal operation conditions were $Y_1$ [% of NDMA removal] = $117+21X_1-0.3X_2-17.2X_3+{2.43X_1}^2+{0.001X_2}^2+{3.2X_3}^2-0.08X_1X_2-1.6X_1X_3-0.05X_2X_3$ ($R^2$= 96%, Adjusted $R^2$ = 88%) and 99.3% ($X_1:\;4.5\;mW/cm^2$, $X_2:\;190\;uM$, $X_3:\;3.2$), $Y_2$ [DMA conc] = $-101+18.5X_1+0.4X_2+21X_3-{3.3X_1}^2-{0.01X_2}^2-{1.5X_3}^2-0.01X_1X_2+0.07X_1X_3-0.01X_2X_3$ ($R^2$= 99.4%, 수정 $R^2$ = 95.7%) and 35.2 uM ($X_1$: 3 $mW/cm^2$, $X_2$: 220 uM, $X_3$: 6.3), $Y_3$ [DMF conc] = $-6.2+0.2X_1+0.02X_2+2X_3-0.26X_1^2-0.01X_2^2-0.2X_3^2-0.004X_1X_2+0.1X_1X_3-0.02X_2X_3$ ($R^2$= 98%, Adjusted $R^2$ = 94.4%) and 3.7 uM ($X_1:\;4.5\;$mW/cm^2$, $X_2:\;290\;uM$, $X_3:\;6.2$) and $Y_4$ [$NO_2$-N conc] = $-25+12.2X_1+0.15X_2+7.8X_3+{1.1X_1}^2+{0.001X_2}^2-{0.34X_3}^2+0.01X_1X_2+0.08X_1X_3-3.4X_2X_3$ ($R^2$= 98.5%, Adjusted $R^2$ = 95.7%) and 74.5 uM ($X_1:\;4.5\;mW/cm^2$, $X_2:\;220\;uM$, $X_3:\;3.1$). This study has demonstrated that the response surface methodology and the Box-Behnken statistical experiment design can provide statistically reliable results for decomposition and by-products of NDMA by the UV photolysis and also for determination of optimum conditions. Predictions obtained from the response functions were in good agreement with the experimental results indicating the reliability of the methodology used.

Method of Developing Contents for U-Learning (u-러닝에 적합한 콘텐츠 개발 방안)

  • Ahn, Seong Hun
    • The Journal of Korean Association of Computer Education
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    • v.9 no.6
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    • pp.53-64
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    • 2006
  • In this paper, I described a guide of developing contents to present the direction of developing contents for u-learning. After surveying a character of Ubiquitous computing and u-learning, I described a guide of developing contents which is composed 17 items in 5 fields. This guide is checked by experts and staffs to test a validity and reliability. As a result, It is proven having the validity and reliability. I expect it to guide the direction of developing contents for u-learning. Also, It will contribute to make effective contents which will not affected by technical development and can use continuously because of foreseeing the technical development of future.

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Fabrication and Measurement of Triple U-shaped slot Microstrip Antenna in 5GHz band (5GHz 대역에서 트리플 U-슬롯 모양의 마이크로스트립 안테나 설계 및 제작)

  • Kang, Moon-Kyou;Jung, Yoo-Keun;Ju, Jeong-Min;Jeong, Gyey-Teak;Yoon, Joong-Han;Kwak, Kyung-Sup
    • Journal of IKEEE
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    • v.8 no.1 s.14
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    • pp.86-95
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    • 2004
  • In this paper, we designed, fabricated, and measured antenna results consisting of previous research, that can handle from wireless using-LAN U-shaped slot antenna of HiperLAN bandwidth to ISM band of HiperLAN 1/2 & 5 GHz bandwidth. We presented a new model that structuresof basic U-shaped slot added the same thing twice.After the foam layer is inserted between ground plane and substrate, we got enough bandwidth for VSWR<1.5. The antenna gain was $6.27{\sim}9.82dBi$. The radiation pattern got a stable pattern in frequency bandwidth.

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Effect of Antioxidants on In Vitro Development of Korean Native Cattle Embryos Derived from In Vitro Fertilization (항산화제 첨가가 한우 체외 수정란의 체외 배발달에 미치는 영향)

  • 문승주;김은국;김재홍;명규호;선상수
    • Journal of Embryo Transfer
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    • v.14 no.3
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    • pp.219-224
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    • 1999
  • The effect of several potential antioxidants were examined as a means of increasing the in vitro development of in vitro matured and in vitro fertilized oocytes into morulae and blastocysts. Korean native cattle embryos after in vitro fertilization were cultrued for 7 days at 38.5$^{\circ}C$ in CR1aa containing varing concentration of the antioxidants in a gas phases consisting of 5% CO2, 95% humidified air. The results obtained were summarized as follows; The proportion of embryos developed to morulae and blastocysts in CR1aa containing 2.5uM $\alpha$-tocopherol(11.0% and 6.0%) was significantly higher than those of 0, 5.0, and 7.5uM $\alpha$-tocopherol (P<0.05). concentration of 50uM L-ascorbic acid (7.5% blastocysts) did affect the proportion of embryos developing into blastocystes(P>0.05). Addition of 200uM cysteamine was significantly higher than those of 0, 100 and 300uM (P<0.05). When the fertilized oocytes were cultured at 0. 200, 400 and 600uM of selenium for 168 hrs, the morulae rates were 12.2, 5.2, 16.0 and 16.1% respectively, and addition of 200uM selenium was significantly higher than those of 0, 400, 600uM (P<0.05). These results suggested that the addition of $\alpha$-tocopherol, L-ascorbic acid, cysteamine and selenicum can enhanced development to the morulae and blastocysts of in vitro derived fertilized oocytes.

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U-slot Microstrip Antenna with U-shaped Parasitic Patches (U-형태의 기생 패치를 가지는 U-슬롯 마이크로스트립 안테나)

  • Kim, Ji-Hyung;Oh, Don-Jin;Park, Ik--Mo;Park, Yong-Bae
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.20 no.5
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    • pp.428-434
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    • 2009
  • In this paper, we propose an U-slot microstrip antenna with the U-shaped parasitic patches. U-slot and parasitic patches make two resonant frequencies and one additional resonant frequency, respectively, so that the impedance band-width of the antenna is expanded. The size of radiator part is $64{\times}53\;mm^2$ and the entire size of the antenna is $150{\times}150{\times}11.5\;mm^3$. The measured bandwidth is $1.85{\sim}2.40\;GHz$. Thus, our antenna can be used for DCS1900, WCDMA and WiMax services. The radiation characteristic is almost same in the bandwidth, the beam width is about $60^{\circ}$, and the gain is more than 7 dBi.

Design of A Dual-resonance PIFA Using U-Type Slot (U-형 슬랏을 이용한 이중 공진 PIFA 설계)

  • Kim, Yoon-Ho;Rhee, Joong-Geun;Kim, Jung-Hun;Jang, Tae-Heon
    • Journal of the Institute of Electronics Engineers of Korea TC
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    • v.47 no.11
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    • pp.77-83
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    • 2010
  • This paper presents the dual resonance PIFA(Planar Inverted F-Antenna) which satisfies the requirements of the 802.11n standard at both 2.4 GHz and 5 GHz frequency bands. Patch for 2.4 GHz and U-Type slot for 5 GHz were used for dual resonance, respectively. In this paper, the characteristics of an antenna were investigated by varying locations of short plate and feed point, the width of the short plate, the thickness and the location of U-Type slot. To investigate the characteristics of the PIFA, HFSS(High Frequency Structure Simulation) for the simulation was used. And the measurement results of a fabricated PIFA were compared with the simulated ones. The measurement and simulation results show that good dual resonance characteristics as the thickness of U-type slot decreases and when the location of U-type slot is far from the feed point.

A Study on Five Levels of Security Risk Assessment Model Design for Ensuring the u-Healthcare Information System (u-헬스케어시스템의 정보보안 체계 확보를 위한 5단계 보안위험도 평가모델 설계)

  • Noh, Si Choon
    • Convergence Security Journal
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    • v.13 no.4
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    • pp.11-17
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    • 2013
  • All u-Health system has security vulnerabilities. This vulnerability locally(local) or network(network) is on the potential risk. Smart environment of health information technology, Ad-hoc networking, wireless communication environments, u-health are major factor to increase the security vulnerability. u-health care information systems user terminal domain interval, interval public network infrastructure, networking section, the intranet are divided into sections. Health information systems by separating domain specific reason to assess vulnerability vulnerability countermeasure for each domain are different. u-Healthcare System 5 layers of security risk assessment system for domain-specific security vulnerability diagnosis system designed to take the security measures are needed. If you use this proposed model that has been conducted so far vaguely USN-based health information network security vulnerabilities diagnostic measures can be done more systematically provide a model.

AB INITIO CALCULATIONS OF STRONGLY CORRELATED ELECTRONS: ANTIFERROMAGNETIC GROUND STATE OF $UO_2$

  • YUN YOUNSUK;KIM HANCHUL;KIM HEEMOON;PARK KWANGHEON
    • Nuclear Engineering and Technology
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    • v.37 no.3
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    • pp.293-298
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    • 2005
  • We have performed the density functional theory calculations of $UO_2$ using the spin-polarized generalized gradient approximation (SP-GGA) and the SP-GGA+U approach. The SP-GGA+U approach correctly predicts the insulating electronic structure with antiferromagnetic ordering, but the SP-GGA calculations predict metallic behavior. The cohesive properties obtained from the SP-GGA+U calculations are in good agreement with the available experimental results and previous calculations. The spin-polarized local density of states shows that the antiferromagnetic ordering of $UO_2$ is governed by 5f orbitals of uranium ion. Our calculations demonstrate that the strong correlation of U 5f electrons should be taken into account for a reliable description of $UO_2$ physics.

Broadband U-Shaped RFID Tag Antenna with Near-Isotropic Characteristic (광대역에서 일정한 준 등방성 특성을 가지는 U-형태의 RFID 태그 안테나)

  • Lee, Sang-Woon;Jung, Hak-Joo;Choo, Ho-Sung;Park, Ik-Mo
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.20 no.5
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    • pp.480-492
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    • 2009
  • In this paper, we proposed a broadband U-shaped RFID tag antenna with near-isotropic characteristic at UHF band. The proposed tag antenna is composed of the U-shaped half wavelength dipole and a rectangular shaped feed. The rectangular shaped feed that is located inside U-shaped dipole is connected for conjugate impedance matching with the commercial tag chip. A better constant gain deviation characteristic in the operating frequency band is achieved by inserting a rectangular slit in the lower center of the U-shaped antenna body. On the condition of VSWR<2, the tag antenna had the measured bandwidth of 10.36%, from 860.5 to 954.5 MHz, and 9.84%, from 864.5 to 954 MHz, for antenna without slit and with slit, respectively. On the condition of VSWR<5.8, the tag antennas had the measured bandwidth of 15.78%, from 835.5 to 979.5 MHz, and 15.89%, from 837 to 981.5 MHz, for antenna without slit and with slit, respectively. The difference between the maximum and minimum gain deviations of tag antenna without slit in the operating frequency band is 0.53 dB since the maximum and minimum gain deviations are 3.86 dB and 3.33 dB, respectively. Whereas the difference between the maximum and minimum gain deviations of tag antenna with slit in the operating frequency is 0.06 dB since the maximum and minimum gain deviations are 3.60 dB and 3.54 dB, respectively.