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알루미나 분산 2Y-TZP 세라믹스에서 알루미나 입자크기가 파괴인성에 미치는 영향 (Influence of $Al_2O_3$ Particle Size on the Fracture Toughness of Alumina-dispersed 2Y-TZP Ceramics)

  • 김민정;이종국;이은구;장우양
    • 한국결정학회지
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    • 제11권2호
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    • pp.102-107
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    • 2000
  • 20vol% Al2O3-dispersed 2Y-TZP ceramics was prepared by mixing of 2Y-TZP and Al2O3 powder with different particle sizes, and investigated the influence of Al2O3 particle size and sintering condition on the microstructure and fracture toughness. Sintering conditions of the Al2O3-dispersed 2Y-TZP specimens showed high density at sintering condition of 1350℃ and 1500℃ for 1∼5h, and homogeneous microstructure. The grain size of tetragonal zirconia and the fracture toughness increased with the size of dispersed Al2O3 particle. The highest fracture toughness (∼17.2MPa·m1/2) of all specimens was obtained in the specimens with dispersed Al2O3 particle size of 1.0㎛ and sintered at 1500℃ for 2h.

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Urea와 K2SO4 처리에 의한 복숭아 '미백도'에서 수확 시 과실의 무기성분 농도 및 과피색 변화 (Effects of Urea and K2SO4 treatment on the mineral nutrient concentration and fruit skin color of 'Mibaekdo' peach fruits at harvest)

  • 문병우;윤익구;문영지;남기웅;이영철
    • 현장농수산연구지
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    • 제15권1호
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    • pp.95-105
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    • 2013
  • 복숭아 '미백도'에서 Urea 및 K2SO4를 토양 또는 수체처리하여 토양의 화학성, 과실의 무기성분 농도, 과피색 및 과실품질에 미치는 영향을 조사한 결과는 다음과 같다. 토양의 화학성 중 K의 함량은 경핵기 Urea 162g+K2SO4 188g/주(표준) 토양처리, 수확 20일 전 K2SO4 1.0% 수체살포, Urea 81g+K2SO4 94g/주(반량), Urea 162g+K2SO4 188g 및 Urea 324g+K2SO4 376g/주(배량) 토양처리에서 무처리에 비하여 증가하였다. 엽의 무기성분 농도는 전처리 모두 엽내 T-N, K 및 Ca 농도가 높았으며 Na 농도는 Urea 0.5% 및 K2SO4 1.0% 수체살포가 높았다. 과피내 T-N 농도는 수확 20일 전 Urea 162g+K2SO4 188g 토양처리에서 높았으나 K2SO4 1.0% 수체살포 및 Urea 81g+K2SO4 94g 토양처리에서는 낮았다. 과피 직하과육(1~10mm부위)의 T-N, K, Ca 농도는 Urea 0.5% 수체살포를 제외한 모든 처리에서 높았다. 엽중은 수확 20일 전 Urea 0.5% 수체살포, Urea 162g+K2SO4 188g 및 Urea 324g+K2SO4 376g 토양처리에서 증가하였다. 과중은 수확 20일전 Urea 162g+K2SO4 188g 토양처리에서 현저하게 증가하였다. 과피색(Hunter a값)은 수확 20일 전 K2SO4 1.0% 수체살포, Urea 81g+K2SO4 94g 및 Urea 324g+K2SO4 376g 토양처리에서 과피 적색 향상에 효과적이었다. 당도는 Urea 0.5% 수체살포, K2SO4 1.0% 수확 20일 전 수체살포 및 Urea 162g+K2SO4 188g 경핵기 토양처리에서 증가하였다.

General Linear Group over a Ring of Integers of Modulo k

  • Han, Juncheol
    • Kyungpook Mathematical Journal
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    • 제46권2호
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    • pp.255-260
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    • 2006
  • Let $m$ and $k$ be any positive integers, let $\mathbb{Z}_k$ the ring of integers of modulo $k$, let $G_m(\mathbb{Z}_k)$ the group of all $m$ by $m$ nonsingular matrices over $\mathbb{Z}_k$ and let ${\phi}_m(k)$ the order of $G_m(\mathbb{Z}_k)$. In this paper, ${\phi}_m(k)$ can be computed by the following investigation: First, for any relatively prime positive integers $s$ and $t$, $G_m(\mathbb{Z}_{st})$ is isomorphic to $G_m(\mathbb{Z}_s){\times}G_m(\mathbb{Z}_t)$. Secondly, for any positive integer $n$ and any prime $p$, ${\phi}_m(p^n)=p^{m^2}{\cdot}{\phi}_m(p^{n-1})=p{^{2m}}^2{\cdot}{\phi}_m(p^{n-2})={\cdots}=p^{{(n-1)m}^2}{\cdot}{\phi}_m(p)$, and so ${\phi}_m(k)={\phi}_m(p_1^n1){\cdot}{\phi}_m(p_2^{n2}){\cdots}{\phi}_m(p_s^{ns})$ for the prime factorization of $k$, $k=p_1^{n1}{\cdot}p_2^{n2}{\cdots}p_s^{ns}$.

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Al2O3/SiC Whisker원료 합성 (Synthesis of Al2O3/SiC Whisker)

  • 정광철;주경;전윤석;오근호;김의훈;이석근
    • 한국세라믹학회지
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    • 제26권2호
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    • pp.167-170
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    • 1989
  • Al2O3/SiC composite-material was synthesized by the birth-spread mechanism through the carbothermal reduction reaction of SiO2 in Ha-Dong Kaolin with carbon powder under H2 gas atmosphere at 1300~140$0^{\circ}C$. Average diameter of synthesized SiC whiskers were 1${\mu}{\textrm}{m}$ and aspect ratio (c/a) was 10~100. Al2O3 particles and SiC whiskers were mixed homogeneously in the reacted pellet.

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Photochemical Hydrogen Evolution in K4Nb6O17 Semiconductor Particles Sensitized by Phosphonated Trisbipyridine Ruthenium Complexes

  • Jung, Young-Hee;Shim, Hyun-Kwan;Kim, Hyun-Woo;Kim, Yeong-Il
    • Bulletin of the Korean Chemical Society
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    • 제28권6호
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    • pp.921-928
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    • 2007
  • Three different phosphonated trisbipyridine ruthenium complexes, [(4-CH3-4'-CH2PO(OH)2-2,2'-bipyridine)- (bpy)2Ru]·(PF6)2 (Ru-P1), [(4-CH3-4'-CH2PO(OH)2-2,2'-bipyridine)3Ru]·(PF6)2 (Ru-P2), and [(4,4'-CH2PO- (OH)2-2,2'-bipyridine)3Ru]·(PF6)2 (Ru-P3) were synthesized and their photochemical and electrochemical properties were studied. These ruthenium complexes were strongly adsorbed on the surface of the layered metal oxide semiconductor K4Nb6O17 that was partially acid-exchanged and sensitized up to pH 10, while the carboxylated ruthenium complex, (4,4'-COOH-2,2'-bipyridine)3Ru·Cl2 (Ru-C) that was previously studied was sensitized only below pH 4. The visible light water reduction at K4Nb6O17 that was internally platinized and sensitized by these phosphonated Ru-complexes was comparatively studied using a reversible electron donor iodide.

K_2CO_3$/homopiperazine 수용액의 이산화탄소 흡수 특성 연구 (Study of $CO_2$ Absorption Characteristics in Aqueous K_2CO_3$ Solution with Homopiperazine)

  • 김영은;남성찬;이용택;윤여일
    • 공업화학
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    • 제21권3호
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    • pp.284-290
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    • 2010
  • 본 연구에서는 이산화탄소 포집 기술에 적용할 수 있는 흡수제인 $K_2CO_3$와 homopiperazine (homoPZ)을 이용한 혼합 수용액을 사용하여 이산화탄소 흡수 특성을 연구하였다. 기액 흡수평형(VLE) 장치를 사용하여 60, $80^{\circ}C$에서 이산화탄소 평형분압($P_{CO_2}^*$)과 압력변화를 측정하였고, 40, 60, $80^{\circ}C$에서 반회분식(semi-batch) 흡수 장치를 사용하여 흡수능을 평가하였다. $K_2CO_3$ 수용액의 결정 생성 문제 개선과 $CO_2$ 흡수량 및 흡수속도 증대를 위해 고리형 diamine인 homoPZ를 증진제로 사용하였으며, 기존 연구된 MEA, $K_2CO_3$$K_2CO_3$/piperazine (PZ)과의 성능을 비교 평가하였다. 실험결과 homoPZ를 첨가하였을 경우 $K_2CO_3$ 수용액보다 이산화탄소 평형분압이 낮아져 흡수능이 개선되었으며, 흡수속도는 $60^{\circ}C$에서 약 0.375배, $80^{\circ}C$에서 약 0.343배 향상되었다. $K_2CO_3$/homoPZ 수용액의 $CO_2$ loading capacity는 $60^{\circ}C$에서 $K_2CO_3$/PZ 수용액과 유사하였고, MEA 수용액보다는 우수하였다.

TASK-1 Channel Promotes Hydrogen Peroxide Induced Apoptosis

  • Yun, Ji-Hyun;Kim, Seung-Tae;Bang, Hyo-Weon
    • The Korean Journal of Physiology and Pharmacology
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    • 제9권1호
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    • pp.63-68
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    • 2005
  • Hydrogen peroxide ($H_2O_2$) causes oxidative stress and is considered as an inducer of cell death in various tissues. Two-pore domain $K^+$ ($K_{2p}$) channels may mediate $K^+$ efflux during apoptotic volume decreases (AVD) in zygotes and in mouse embryos. In the present study, we sought to elucidate linkage between $K_{2p}$ channels and cell death by $H_2O_2$. Thus $K_{2p}$ channels (TASK-1, TASK-3, TREK-1, TREK-2) were stably transfected in HEK-293 cells, and cytotoxicity assay was preformed using cell counting kit-8 (CCK-8). Cell survival rates were calculated using the cytotoxicity assay data and dose-response curve was fitted to the $H_2O_2$ concentration. Ionic currents were recorded in cell-attached mode. The bath solution was the normal Ringer solution and the pipette solution was high $K^+$ solution. In HEK-293 cells expressing TREK-1, TREK-2, TASK-3, $H_2O_2$ induced cell death did not change in comparison to non-transfected HEK-293. In HEK-293 cells expressing TASK-1, however, dose-response curve was significantly shifted to the left. It means that $H_2O_2$ induced cell death was increased. In cell attached-mode recording, application of $H_2O_2$ (300μM) increased activity of all $K_{2p}$ channels. However, a low concentration of $H_2O_2$ ($50{\mu}M$) increased only TASK-1 channel activity. These results indicate that TASK-1 might participate in $K^+$ efflux by $H_2O_2$ at low concentration, thereby inducing AVD.

Study on Properties of Ag and PbO Doped $YBa_2Cu_3O_x$

  • Son, Dea-Wha;Fan, Zhanguo
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2003년도 하계학술대회 논문집 Vol.4 No.1
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    • pp.593-596
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    • 2003
  • A proposed way to prepare $YBa_2Cu_3O_y$ wires or tapes is that Ag is used as substrate and melting point of $YBa_2Cu_3O_y$ is decreased to lower than the melting point of silver ($961\;^{\circ}C$). Therefore after the deposition of $YBa_2Cu_3O_y$ film on Ag substrate, the heat treatment can be carried out below the Ag melting point. Silver (Ag) and Lead oxide(PbO) were selected to be additives for $YBa_2Cu_3O_y$. Different Ag and PbO contents were added in $YBa_2Cu_3O_y$, the melting points of which were measured by DTA. In order to guarantee that the superconductivity of $YBa_2Cu_3O_y$ was not reduced after Ag and PbO added into $YBa_2Cu_3O_y$, their superconductivities were measured. It is proved that as additives, both Ag and PbO can reduce the melting point of $YBa_2Cu_3O_y$. For Ag doped $YBa_2Cu_3O_y$, $T_c$ is about 93K and ${\Delta}Tc$ is $2{\sim}3K$. For PbO doped $YBa_2Cu_3O_y$, $T_c$ is $88K{\sim}92K$ and ${\Delta}T_c$ is $11{\sim}12K$. When 10 wt% of Ag and 10 wt% PbO were added in $YBa_2Cu_3O_y$, the melting point of the mixture of $YBa_2Cu_3O_y$ (80 wt%), Ag (10 wt%) and PbO (l0 wt%) is $943^{\circ}C$. The transition temperatures ($T_c$) of the sample is 91.8 K.

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