• 제목/요약/키워드: Y-rich phase

검색결과 482건 처리시간 0.032초

전기선폭발법에 의한 Cu-Ni-P 합금 나노 분말 제조 (Cu-Ni-P Alloy Nano Powders Prepared by Electrical Wire Explosion)

  • 김원백;박제신;서창열;이재천;김정환;오용준
    • 한국분말재료학회지
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    • 제14권2호
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    • pp.108-115
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    • 2007
  • Cu-Ni-P alloy nano powders were fabricated by the electrical explosion of electroless Ni plated Cu wires. The effect of applied voltage on the explosion was examined by applying pulse voltage of 6 and 28 kV, The estimated overheating factor, K, were 1.3 for 6 kV and 2.2 for 28 kV. The powders produced with pulse voltage of 6 kV were composed of Cu-rich solid solution, Ni-rich solid solution, and $Ni_3P$ phase. While, those produced with 28 kV were complete Cu-Ni-P solid solution and small amount of $Ni_3P$ phase. The initial P content of 6.5 at.% was reduced to 2-3 at.% during explosion due to its high vapour pressure.

CaO-Al$_2$O$_3$-SiO$_2$계 슬래그와 스피넬의 반응에 미치는 스피넬중의 MgO함유량의 영향 (Effects of MgO content of Spinel on the Reaction of Spinel with CaO-Al$_2$O$_3$-SiO$_2$ Slag)

  • 조문규;홍기곤
    • 한국세라믹학회지
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    • 제36권4호
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    • pp.410-416
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    • 1999
  • The reactivity of three kinds of spinels which CaO-Al2O3-SiO2 slag was investigated in terms of mineral phases and microstructures. New crystal products were not formed by reaction of 12CaO.7Al2O3 in the slag with spinels and free MgO components was preferenctially dissolved into slag for MgO-rich spinel and stoichiometric spinel. Meanwhile mineral phase was changed from 12CaO.7Al2O3 to CaO.Al2O3 to CaO.2Al2O3 finally to CaO.6Al2O3 having high melting point for Al2O3 -rich spinel. The Fe-oxide component of the slag was taken up by only stoichiometric spinel grains within the spinel clinker and the trapped amount of Fe-oxide was independent of MgO content of MgO in spinel clinker the more th resistance to slag corrosion but the less resistance to slag penetration.

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전하 트랩 형 비휘발성 기억소자를 위한 재산화 산화질화막 게이트 유전악의 특성에 관한 연구 (Characteristics of the Reoxidized Oxynitride Gate Dielectric for Charge Trap Type NVSM)

  • 이상은;박승진;김병철;서광열
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1999년도 추계학술대회 논문집
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    • pp.37-40
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    • 1999
  • For the first time, charge trapping nonvolatile semiconductor memories with the deoxidized oxynitride gate dielectric is proposed and demonstrated. Gate dielectric wit thickness of less than 1 nm have been grown by postnitridation of pregrown thermal silicon oxides in NO ambient and then reoxidation. The nitrogen distribution and chemical state due to NO anneal/reoxidation were investigated by M-SIMS, TOF-SIMS, AES depth profiles. When the NO anneal oxynitride film was reoxidized on the nitride film, the nitrogen at initial oxide interface not only moved toward initial oxide interface, but also diffused through the newly formed tunnel oxide by exchange for oxygen. The results of reoxidized oxynitride(ONO) film analysis exhibits that it is made up of SiO$_2$(blocking oxide)/N-rich SiON interface/Si-rich SiON(nitrogen diffused tunnel oxide)/Si substrate. In addition, the SiON and the S1$_2$NO Phase is distributed mainly near the tunnel oxide, and SiN phase is distributed mainly at tunnel oxide/Si substrate interface.

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시효된 수퍼 2상 스테인리스강의 피로균열 진전시 발생하는 음향방출신호의 시간-주파수 분석 (Time-Frequency Analysis of AE Signals at Fatigue Crack Propagation of Aged Super Duplex Stainless Steels)

  • 남기우;이상기;도재윤;강창룡
    • 한국해양공학회:학술대회논문집
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    • 한국해양공학회 2000년도 추계학술대회 논문집
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    • pp.20-25
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    • 2000
  • lh deleterious Cr, Mo rich -$\sigma$phase is a hard embrittling precipitate, which forms between MU)-900 $^{\circ}C$, often associated with a reduction in both impact properties and corrosion reshame. On this study, After aging at MU) "C, fatigue crack propagation induced by a phase precipitation was evaluated and time-frequency analysis of acoustic emission was conducted It was possible to find fracture mechanism by a phase precipitation due to time-frequency anulysis of acoustic emission signals.nals.

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카올리나이트의 상전이반응 과정 연구 (An Investigation of the Transformation Sequence from Kaolinite to Mullite)

  • 이수정;김윤중;문희수
    • 한국광물학회지
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    • 제11권1호
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    • pp.32-44
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    • 1998
  • The transformation sequence of kaolinite to mullite is examined with new electron diffraction data obtained mainly by an energy filtering transmission electron microscope. Kaolinite is transformed finally into mullite and cristobalite through several steps of continuous reactions by heating, which result in metakaolinite, microcrystalline spinel-type phase and amorphous silica. Metakaolinite maintains a short-range order in its structure ven at $920^{\circ}C$. Spinel phase results from a topotactictransformation of metakaolinite apart from the breakdown of metakaolinite structure. the first strong exothermic peak on DTA curve is mainly due to the extraction of amorphous silica from metakaolinite and the gradual nucleation of mullite. Metakaolinite decomposes around$ 940^{\circ}C$ to mullite that doesn't show a clear crystallographic relationship to the parent metakaolinite structure. However, spinel phase produced previously is maintained. The initially formed spinel and mullite phases are suggested to be Al-rich, but progressively gain Si in their structures at higher temperatures. Spinel phase decomposes completely through a second weak exothermic reaction promoting the growth of mullite, and crystallization of amorphous silica to cristobalite.

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Flooding Stress-Induced Glycine-Rich RNA-Binding Protein from Nicotiana tabacum

  • Lee, Mi-Ok;Kim, Keun Pill;Kim, Byung-gee;Hahn, Ji-Sook;Hong, Choo Bong
    • Molecules and Cells
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    • 제27권1호
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    • pp.47-54
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    • 2009
  • A cDNA clone for a transcript preferentially expressed during an early phase of flooding was isolated from Nicotiana tabacum. Nucleotide sequencing of the cDNA clone identified an open reading frame that has high homology to the previously reported glycine-rich RNA-binding proteins. The open reading frame consists of 157 amino acids with an N-terminal RNA-recognition motif and a C-terminal glycine-rich domain, and thus the cDNA clone was designated as Nicotiana tabaccum glycine-rich RNA-binding protein-1 (NtGRP1). Expression of NtGRP1 was upregulated under flooding stress and also increased, but at much lower levels, under conditions of cold, drought, heat, high salt content, and abscisic acid treatment. RNA homopolymer-binding assay showed that NtGRP1 binds to all the RNA homopolymers tested with a higher affinity to poly r(G) and poly r(A) than to poly r(U) and poly r(C). Nucleic acid-binding assays showed that NtGRP1 binds to ssDNA, dsDNA, and mRNA. NtGRP1 suppressed expression of the fire luciferase gene in vitro, and the suppression of luciferase gene expression could be rescued by addition of oligonucleotides. Collectively, the data suggest NtGRP1 as a negative modulator of gene expression by binding to DNA or RNA in bulk that could be advantageous for plants in a stress condition like flooding.

$Pb(Zn_{1/3}Nb_{2/3})O_3-Pb(Fe_{1/2}Nb_{1/2})O_3$계에서의 Perovskite상의 안정성 및 유전특성 (Stabilization of the Perovskite Phase and Dielectric Properties in the System $Pb(Zn_{1/3}Nb_{2/3})O_3-Pb(Fe_{1/2}Nb_{1/2})O_3$)

  • 김정욱;최성철;이응상
    • 한국세라믹학회지
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    • 제32권3호
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    • pp.295-304
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    • 1995
  • Stabilization of the perovskite phase and sequence of reactions occuring during calcination were studied with solid solutions formed between Pb(Zn1/3Nb2/3)O3 and Pb(Fe1/2Nb1/2)O3. In the PZN-PFN composition of equal molar ratio, rhombohedral type pyrochlore phase (Pb2Nb2O7) and PbO-rich distorted cubic type pyrochlore phase (Pb3Nb2O8) were coexisted as intermediate phases at temperatures below 85$0^{\circ}C$, and these phases transformed to a stable cubic type pyrochlore phase, Pb3Nb4O13 solid solution and a perovskite solid solution at temperatures above 85$0^{\circ}C$. The major stable phase as increasing sintering temperatures was a perovskite phase in this binary system and prominent suppression of the pyrochlore phase was achieved by substituting Zn2+ with Fe3+ or by increasing sintering temperature. The composition containing 20mol% PZN possessed the best dielectric properties, and the dissipation factor was lower than 5% in all compositions.

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고온가압소결된 $TiB_{2}$에서의 철을 함유한 석출물 (Fe-rich precipitates in hot-pressed $TiB_{2}$)

  • Kwang Bo Shim;Keun Ho Auh;Brian Ralph
    • 한국결정성장학회지
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    • 제6권3호
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    • pp.431-438
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    • 1996
  • 투과전자현미경을 이용하여 고온가압소결된 $TiB_{2}$의 미세구조를 분석하였다. Ionbeam thinning에 의해서 준비된 박편시편은 육방정계 $TiB_{2}$의 결정학적 이방성에 기인한 특징을 보여주었다. 이들 시편에서 철분 불순물은 결정입 3중점, 결정입계 그리고 결정내에 2차상을 형성하는 것으로 확인되었고, 결정입 3중점이나 결정입계 혹은 matrix에서 유리하게 배향된 결정입에 coherence or semi-coherence한 특징을 나타내었다.

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아로니아 추출물 및 아로니아 안토시아닌분획의 항산화 활성 효과 (Antioxidant Activities of Acidic Ethanol Extract and the Anthocyanin Rich Fraction from Aronia melanocarpa)

  • 임정대;차환수;정명근;최리나;최덕주;윤예리
    • 한국식품조리과학회지
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    • 제30권5호
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    • pp.573-578
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    • 2014
  • The objective of this study was to investigate the antioxidant activities and anthocyanin profiles in the anthocyanin rich fraction (ARFAM) of Aronia melanocarpa, which are considered functional substances and are available as food coloring agents in Korea. Anthocyanins were identified by reversed-phase C18 column chromatography and HPLC-DAD-ESI/MS analysis. The antioxidative activity of the acidic ethanol extract (AME) and the anthocyanin-rich fraction (ARFAM) was determined by scavenging of the diphenylpicrylhydrazyl (DPPH) radical, the hydroxy radical, and the superoxide anion in addition to reducing power using a commercial antioxidant as a reference.

급속냉각된 Nd-Fe(-Co)와 Sm-Co(-Fe)계 Laves 화합물의 미세조직과 자기특성 (Microstructure and Magnetic Properties of Rapidly Solidified Nd-Fe(-Co) and Sm-Co(-Fe) Laves Compounds )

  • 이우영;최승덕;양충진
    • 한국자기학회지
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    • 제1권1호
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    • pp.17-24
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    • 1991
  • $NdFe_2$, $Nd{(Fe_{0.5})}_2$, $SmCo_2$$Sm{(Fe_{0.5}Co_{0.5})}_2$ 조성의 Laves 화합물을 급속냉각기술에 의하여 제조하였다. 저온자기특성을 조사한 결과 $Nd{(Fe_{0.5}Co_{0.5})}_2$, $SmCo_2$$Sm{(Fe_{0.5}Co_{0.5})}_2$ 조성의 Laves 화합물은 강자성의 거동을 보이며 결정구조는 모두 C15의 단일상으로 존재하였으며, $NdFe_2$ 조성의 급냉합금은 일종의 spin reorientation 거동을 보였다. $NdFe_2$ 조성의 급냉합금은 화학조성식 $NdFe_7$의 준안정상과 Nd-rich상으로 구성됨을 알았다. $NdFe_2$ 급냉합금을 열처리 하면 $NdFe_7$$Nd_2Fe_{17}$과 Nd-Fe-O상으로 변태하였다. $Sm{(Fe_{0.5}Co_{0.5})}_2$ Laves 화합물의 보자력은 상온에서 4kOe이며 큐리온도는 $400^{\circ}C$로 측정된다. 또한 $Nd{(Fe_{0.5}Co_{0.5})}_2$ Laves 화합물은 상온에서 $2.8\;{\mu}_B/f.u.의$ 자기모멘트를 보유한다.

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