• Elastomers and Composites
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• 제39권2호
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• pp.131-141
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• 2004

본 연구에서는 폐기되는 고전압용 전선으로부터 얻어질 수 있는 XLPE(crosslinked polyethylene)의 재활용에 관하여 고찰하였다. XLPE 스크랩 및 폐기물의 분쇄를 위해 약 $100{\mu}m$ 이하부터 약 $1000{\mu}m$까지 입자크기의 조절이 가능한 두 종류의 분쇄기를 사용하였다. 모듈라 치합형 동방향회전 이축 스크류식 압출기(modular intermeshing co-rotating twin screw extruder)를 이용하여 폐 XLPE의 조성, 폐 XLPE의 입자크기 및 종류, 스크류 조합, 매트릭스 수지의 종류(LDPE, HDPE, PP, PS) 조건을 변화시키면서 배합물을 제조하고 그들의 기계적 및 유변학적 특성과 파단면을 조사하였다. 일반적으로 내외 전도층을 포함한 폐 XLPE 배합물의 충격강도는 내외 전도층을 제외한 배합물보다 충격강도가 작은 것으로 나타났다. 또한, XLPE의 함량이 증가하고 입자크기가 작아 질수록 배합물의 충격강도가 증가하였다. 특히, LDPF의 경우 XLPE를 약 80 wt%까지 충전하여도 정상조건의 압출공정이 가능하였다. 스크류조합에 따른 배합물의 충격강도는 니딩디스크 블록(kneading disc block)의 수가 많을수록 높은 값을 나타내었다. 전체적으로 XLPE의 양이 증가할수록 배합물의 용융점도가 증가하였으나, 압출 전단속도 범위에서 shear thinning 경향을 나타내었다. 폐 XLPE를 범용 고분자수지와 혼합할 경우, LDPE, HDPE, PP 및 PS 모든 배합물에서 충격강도가 증가하였다. 특히, PS/XLPE 배합물의 경우에는 충격강도가 2 배정도 향상되는 효과를 보여주었다.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1996년도 추계학술대회 논문집
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• pp.230-233
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• 1996

In this paper, We intended to evaluate characteristics of XLPE/EPDM interface which exists in the cable joint. Because the fault was mainly occurred in this interface. We investigated breakdown characteristics of XLPE/EPDM double layered insulator as a funtion of temperature, pressure, annealing time, kinds of jointmaterial. It was shown that breakdown strength of XLPE/EPDM insulators is higher that of XLPE/XLPE or EPDM/EPDM

• 한국전기전자재료학회논문지
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• 제17권8호
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• pp.904-909
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• 2004

We studied the dielectric properties and voltage dependence on slice XLPE sheet from 22 kV and 154 kV power cables. Interface structures are XLPE/semiconductor and XLPE/water/semiconductor capacitance and tan6 of 22 kV, 154 kV were 52/42 pF and $7.4\times{10}/^{-4}, 2.15\times{10}^{-4}$, respectively in these results, the trend was increased with the increase of temperature the tan$\delta$ of XLPE/semiconductive layer and XLPE/water/ semiconductive layer were increased as compared with that of XLPE Temperature reliability of tan$\delta$ was small.

• 한국전기전자재료학회논문지
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• 제13권5호
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• pp.420-425
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• 2000

Crosslinked polyethlyene/silane crosslinked polyethylene(XLPE/SXLPE) blends were prepared by a twin screw extruder and their water tree growing electrical breakdown and crossinking characteristics were investigated. The water tree characteristics of XLPE were improved by the addition of SXLPE when samples were crosslinked only by the thermorolysis of DCP (dicumyl peroxide). However steam curing process was not good for water tree characteristics. It was also found that the rate of water tree growing of XLPE/SXLPE blend increased when the content of SXLPE was 50%. AC breadown strength slightly increaed by the addition of SXLPE to XLPE when samples were crosslinked only by the thermorolysis of DCP. It was also found that the degree of crosslinking of XLPE/SXLPE blends were higher than that of XLPE in the case of the content without steam crosslinking process.

• 조명전기설비학회논문지
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• 제22권4호
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• pp.114-120
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• 2008

일반적으로 22.9[kV] 이하의 케이블은 가교폴리에틸렌(XLPE)을 절연체로 사용하고 있다. XLPE내부의 결함으로 인한 사고로 경제적 및 인명피해가 발생한다. 이러한 사고에 대한 처리 기준이 마련이 되어 있지 않아 사고처리의 체계화가 시급히 필요한 실정이다. 본 연구에서는 XLPE 케이블의 사고 요인이 되는 전기적 열화현상에 대한 자료구축을 위하여 XLPE에 곡율반경이 $10[{\mu}m]$인 침천극을 삽입하여 절연파괴, 트리형상 및 연면방전 시료를 제작하였다. 단시간 파괴는 AC 60[Hz]의 전압을 1[kV/sec] 상승하였으며, 장기과전의 경우 AC 60[Hz]의 전압을 12[kV] 및 17[kV]를 인가하여 전기적 열화 특성에 대하여 실험을 하였다.

• 한국전기전자재료학회논문지
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• 제17권8호
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• pp.893-897
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• 2004

In this paper, we studied the mechanical and thermal properties on slice XLPE sheet from 22 kV and 154 kV power cables. Interface structures are XLPE/semiconductor and XLPE/water/semiconductor. We evaluated mechanical property, thermal analysis, moisture analysis. Based on mechanical and thermal properties of the 22 kV XLPE sheet, elongation, mechanical strength, and melting point were evaluated to be 485.48 %, 1.74 kgf/$\textrm{mm}^2$ and $102.48^{\circ}C$, respectively. It was also evaluated from the mechanical and thermal properties of 154 kV XLPE sheet that elongation, mechanical strength, and melting point are 507.81 %, 1.8 kgf/$\textrm{mm}^2$, $106.9^{\circ}C$, respectively. A region shows a rapid increase in tension strength, and B region only shows increase in elongation under 1.0 kgf/$\textrm{mm}^2$, C region shows increase in both elongation and tension strength. Difference of melting point came from the chain of XLPE polymer and the difference of crystallization. Moisture density of semiconductor showed 800 ∼ 1200 ppm before extrude, 14000 ∼24000 ppm after extrude. These values were higher than the moisture density of XLPE (300∼560) ppm.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2001년도 하계학술대회 논문집
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• pp.897-900
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• 2001

Space charge distributions in silane crosslinked polyethylene (SXLPE)/ crosslinked polyethylene (XLPE) laminates was investigated using a pulsed electroacoustic (PEA) method. XLPE shows heterocharge while SXLPE shows homocharge. Positive charge is accumulated at the interface of SXLPE/XLPE laminate when applied electric field is more than 20 kV/mm. The charge profile at various temperatures was also acquired using temperature-controllable PEA system. Although applied electric field is only 8.6 kV/mm, positive interfacial charge starts to appear near 50$^{\circ}C$.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1998년도 추계학술대회 논문집
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• pp.203-206
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• 1998

Effects of types of semicon compounds on electrical properties of XLPE were investigated. The amounts of charge of XLPE were changed with the contents of additive included in semicon electrodes, but homocharge in cathode was observed. In the aging experiment under high voltage, it was found that semiconductive layer with high impurity contents played an important role in the decrease of ACBD strength of XLPE.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1996년도 추계학술대회 논문집
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• pp.287-290
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• 1996

The behaviour of interfacial charge in EPDM/XLPE laminates has been investigated by measuring charge distributions using a pulsed electroacoustic (PEA) method. Homocharge develops in EPDM while heterocharge develops in XLPE. A broadly interfacial charge peak is observed at EPDM/XLPE interface. When EPDM /XLPE laminates are treated in high temperature for different times, the amount and polarity of interfacial charge are changed.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1997년도 추계학술대회 논문집
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• pp.109-111
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• 1997

In this paper, we have evaluated temperature, electric field, Pressure dependency and dielectric properties of EPDM XLPE and EPDM/XLPE\`s interface. Temperature dependency of EPDM had great influence with dielectric properties, but pressure and applied voltage of EPDM had no effect on dielectric properties. Dielectric properties of XLPE were influenced by not only temperature but also pressure and applied voltage. We knowed that dielectric properties of EPDM/XLPE were trended toward tendency of those of EPDM