• Title/Summary/Keyword: X7R

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Rietveld Refinement and Crystal Structure of K-Ba Substituted Synthetic Hollandite, ($K_{2x}Ba_{1-x}Cr_2Ti_6O_{16}$) (리트벨트법을 이용한 K-Ba 치환 합성 홀란다이트($K_{2x}Ba_{1-x}Cr_2Ti_6O_{16}$)의 결정구조 연구)

  • 최진범;김태현
    • Journal of the Mineralogical Society of Korea
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    • v.14 no.2
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    • pp.128-136
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    • 2001
  • The K-Ba complete solid solution of 7 synthetic hollandite-type minerals ($K_{2x}$ $Ba_{1-x}$ $Cr_2$/$Ti_{6}$ $O_{16}$ , x=0, 0.1, 0.3, 0.5, 0.7, 0.9, 1.0, respectively) are studied by the X-ray powder diffraction and Rietveld refinement to find structural transformation during substitution of $Ba^{2+}$ by $K^{+}$ in A site of the tunnel structure of hollandite. Rietveld indices indicate that $R_{wp}$ with respect to $R^{exp}$ ($R_{wp}$ $R_{exp}$ ) are in the range of 15.66%/20.90% and 14.74%/l9.37%, $R_{B}$ and S(Goodness of Fitness) are 6.45~8.97%, 1.45~1.63, respectively. Unit cell parameters of synthetic hollandites, space group 14/m, are a=10.1194(2)~10.0599(2)$\AA$, c=2.9572(6)~2.9512(7)$\AA$, and V=302.75~298.66$\AA^{3}$. Rutile formed as an impurity in those with more than 50% K contents in hollandite series. Substitution of Ba by K ion in a tunnel structure results in constant decrease of cell parameters, but is not sufficient enough to change the hollandite structure. Our data indicate that transformation of tetragonal 14/m to lower symmetry of monoclinic 12/m in hollandite structure may at least be affected by other cation substitution in same A site and/or by cation substitution in B site.

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Effects of ${Er_2}{O_3}$ Addition on the Dielectric Properties of Non-reducible $BaTiO_3$-based X7R Dielectrics (${Er_2}{O_3}$첨가가 $BaTiO_3$계 내환원성 X7R 재질의 유전특성에 미치는 효과)

  • Park, Jae-Seong;Hwang, Jin-Hyeon;Han, Yeong-Ho
    • Korean Journal of Materials Research
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    • v.11 no.1
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    • pp.44-47
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    • 2001
  • Effects of $Er_2O_3$ addition on the dielectric properties of non-reducible $BaTi_3$-based X7R dielectrics with Ni electrode have been studied in reducing atmosphere. X7R with moderate temperature-dependence was developed after addition of $Er_2O_3$ with $MnO_2-MgO$; room-temperature dielectric constant and dissipation factor were >2900 and < 1.0%, respectively. The addition of $Er_2O_3$ greater than 3.0 mol% improved the temperature dependence of dielectric properties, but a significant decrease of the dielectric constant at room-temperature was observed. The TCC curves rebated clockwise with increasing MnO$_2$ content at a given additive system, 1.5 mol% $Er_2O_3$ and 2.0 mol% MgO.

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Physiologic Cervical Alignment Change between Cervical Spine X-ray and Computed Tomography

  • Lee, Ho Jin;Kim, Il Sup;Hong, Jae Taek
    • Journal of Korean Neurosurgical Society
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    • v.64 no.5
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    • pp.784-790
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    • 2021
  • Objective : The purpose of this study was to investigate the correlations among various radiological parameters used to determine cervical alignment from cervical spine radiographs (X-CS) and cervical spine computed tomography (CT-CS), both within and between modalities. Methods : This study included 168 patients (≤60 years old) without a definite whole spine deformity who underwent CT-CS and X-CS. We measured occipital slope (O-s), C1 slope, C2 slope, C7 slope, sella turcica - C7 sagittal vertical axis (StC7-SVA), spino-cranial angle, T1 slope, and C27-SVA. We calculated the O-C2 angle, O-C7 angle, and C2-7 angle from the measured parameters and conducted correlation analyses among multiple parameters. Results : The intrinsic correlation features among multiple cervical parameters were very similar for both X-CS and CT-CS. The two SVA parameters (C27-SVA and StC7-SVA) were mainly influenced by the upper cervical slope parameters (r=|0.13-0.74|) rather than the lower slope cervical parameters (r=|0.08-0.13|). The correlation between X-CS and CT-CS for each radiological parameter was statistically significant (r=0.26-0.44) except for O-s (r=0.10) and StC7-SVA (r=0.11). Conclusion : The correlation patterns within X-CS and CT-CS were very similar in this study. The correlation between X-ray and CT was statistically significant for most radiological parameters, and the correlation score increased when the horizontal gaze was consistently maintained. The lower cervical parameters were not statistically associated with translation-related parameters (C2-7 SVA and StC7-SVA). Therefore, the upper cervical segment may be a better predictor for determining head and neck translation.

Stabilization and Physical Properties of Ruddlesden-Popper Phase $Sr_3Mn_{2-x}Fe_xO_{7-\delta}(x{\leq}0.3)$ (Ruddlesden-Popper 상 $Sr_3Mn_{2-x}Fe_xO_{7-\delta}(x{\leq}0.3)$의 안정화 및 물성에 관한 연구)

  • Song, Min-Seok;Lee, Jai-Yeoul
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.07b
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    • pp.790-793
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    • 2004
  • 이중의 망간 perovskite 블록을 가진 Ruddlesden-Popper 상(R-P phase) $Sr_3Mn_2O_7$ 은 공기중에서 불안정하다. 본 연구에서는 망간 이온 자리에 철 이온을 소량 치환 함으로써 R-P 상을 안정화 시켰으며 이들의 결정구조는 X-선회절 데이터를 이용하여 Rietveld 법으로 정밀화하였다. 안정화에 필요한 Fe 이온의 양은 약 x=0.15로 나타났으며 Fe이온의 양이 증가함에 따라 쉽게 안정화 되었다. 자화율 측정결과 x=0.20 시료는 120K에서 paramgnetic-antiferromagnetic 전이를 나타내었고 이 전이 온도는 치환되는 Fe이온의 양이 증가함에 따라 감소하는 경향을 나타내었다.

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The electrical properties according to rare-earth and glass frit content of high voltage mutilator chip capacitor with X7R properties (고압용 X7R 적층 칩 캐패시터의 희토류 및 유리프릿 첨가에 따른 전기적 특성)

  • Yoon, Jung-Rag;Lee, Serk-Won
    • Proceedings of the KIEE Conference
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    • 2007.11a
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    • pp.92-93
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    • 2007
  • X7R 고압용 적층 칩 캐패시터 제작을 위한 내환원성 유전체 조성물에서 희토류인 $Er_2O_3$을 0.6 mol% 첨가한 후 유리프릿 첨가시소결특성 및 절연저항이 향상됨을 확인 할 수 있었다. 회토류인 $Er_2O_3$을 첨가시 유전율 및 절연저항이 감소하는 경향을 보이나 $85^{\circ}C$ 영역에서 온도특성을 향상시키는 것을 확인하였으며 고압 적층 칩 캐패시터 제작시 온도 특성이 우수한 재료를 개발 할 수 있었다.

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P2X7 Receptor-mediated Membrane Blebbing in Salivary Epithelial Cells

  • Hwang, Sung-Min;Koo, Na-Youn;Choi, Se-Young;Chun, Gae-Sig;Kim, Joong-Soo;Park, Kyung-Pyo
    • The Korean Journal of Physiology and Pharmacology
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    • v.13 no.3
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    • pp.175-179
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    • 2009
  • High concentrations of ATP induce membrane blebbing. However, the underlying mechanism involved in epithelial cells remains unclear. In this study, we investigated the role of the P2X7 receptor (P2X7R) in membrane blebbing using Par C5 cells. We stimulated the cells with 5 mM of ATP for 1${\sim}$2 hrs and found the characteristics of membrane blebbing, a hallmark of apoptotic cell death. In addition, 500 ${\mu}M$ Bz-ATP, a specific P2X7R agonist, induced membrane blebbing. However, 300 ${\mu}M$ of Ox-ATP, a P2X7R antagonist, inhibited ATP-induced membrane blebbing, suggesting that ATP-induced membrane blebbing is mediated by P2X7R. We found that ATP-induced membrane blebbing was mediated by ROCK I activation and MLC phosphorylation, but not by caspase-3. Five mM of ATP evoked a biphasic $[Ca^{2+}]_i$ response; a transient $[Ca^{2+}]_i$ peak and sustained $[Ca^{2+}]_i$ increase secondary to ATP-stimulated $Ca^{2+}$ influx. These results suggest that P2X7R plays a role in membrane blebbing of the salivary gland epithelial cells.

Economic Injury Levels for the Rice Leaffolder Cnaphalocrocis medinalis (Lepidoptera: Pyralidae) in the Rice Paddy Field (벼 혹명나방(Cnaphalocrocis medinalis)의 경제적 피해수준)

  • Lee, Geon-Hwi;Park, Chae-Hoon;Choi, Man-Young;Seo, Hong-Yul;Bae, Soon-Do;Choi, Yong-Soo
    • Korean journal of applied entomology
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    • v.45 no.3 s.144
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    • pp.327-331
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    • 2006
  • This study was carried out to determine the economic injury level of the rice leaffolder,Cnaphalocrocis medinalis G.. The damage aspects of rice plant (at tilling stage) by leaf folders at different larval density per plant were studied in pot experiment (24 cm in diameter, 18 cm in height). One leaf folder consumed 6-7 leaves during larval stage. The damage by leaf folders was simulated by cutting off 0, 10, 30, 50, 70, and 90% of leaves before and after heading stage July 15th (at panicle initiation stage) and August 15th (at milk stage), respectively. When leaves were cut before the heading of rice, the linear relationships between the leaf cutting rate (X) and each factors of yield (Y) were as following; for grain maturity it was Y = -9.379X + 83.630 ($R^{2}=0.493$),\;Y = 0.139X + 0.490 ($R^{2}=0.925$) for yield, and Y = -4.880X + 81.116 ($R^{2}=0.665$) for head rice. When leaves were cut after the heading of rice, it was Y = -23.0l4X + 83.589 ($R{2}=0.915$), for grain maturity, Y=0.141X + 3.466 ($R^{2}=0.842$) for yield, and Y = -13.795X + 81.964 ($R^{2}=0.898$) for head rice. We found that when leaf cutting after the heading stage caused more damage than before the heading in terms of yield and yield components. Based on theses results the economic threshold level was estimated to be 30% and 7% leaf loss before and after heading stage.

The Reliability and Electric Properties of High Voltage Multilayer Ceramic Capacitor According to Dielectric Materials (유전체 원료에 따른 고압용 적층칩 캐패시터 신뢰성 및 전기적 특성)

  • Yoon, Jung-Rag;Park, Jung-Won
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.11a
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    • pp.21-22
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    • 2007
  • 내환원성을 가지는 (Ca,Sr)(ZrTi)$O_3$계 C0G 원료와 코어 쉘 구조를 가지는 $BaTiO_3$계 X7R 원료를 적용하여 고압용 적층 칩 캐패시터를 제작하여 내부전극 형상 및 원료에 따른 신뢰성 밑 전기적 특성을 연구하였다. C0G 특성의 원료는 X7R 원료에 비해 단위 두께당 내전압이 감소하는 경향이 적었으며 내전압 특성도 우수하게 나타났다. 또한, 내부 전극 설계에 있어 floating에 따른 영향은 C0G, X7R 특성 원료 모두 향상된 전기적 특성과 신뢰성을 가짐을 확인 할 수 있었다.

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Effect of the electrical properties on the green sheet thickness and stacking layer of high capacitance X7R MLCC (박막 그린시트의 두께 및 적층 층수에 따른 X7R 고용량 MLCC의 전기적 특성)

  • Yoon, Jung-Rag;Woo, Byung-Chul;Lee, Sek-Won;Lee, Heun-Young
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.07a
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    • pp.300-302
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    • 2005
  • X7R 특성을 가지는 적층 칩 캐패시터 제작시 그린시트의 두께에 따라 유전율, 절연파괴 전압. C-V특성이 변화되며 특히, 그린시트의 두께는 C-V특성에 중요한 인자임을 확인할 수 있었다. 적층수 증가에 따른 특성 검토시 80층 이상부터 재료의 물성 변화로 예상되는 특성을 볼 수 있으며 특히 전류-전압특성에서의 층수 증가에 따른 영향을 몰 때 유전체 조성 및 공정조건을 최적화하여야 함을 확인하였다.

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