• Title/Summary/Keyword: Woody biomass

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Preparation and Characterization of Hydrophobic Coatings from Carnauba Wax/Lignin Blends

  • BANG, Junsik;KIM, Jungkyu;KIM, YunJin;OH, Jung-Kwon;YEO, wanmyeong;KWAK, Hyo Won
    • Journal of the Korean Wood Science and Technology
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    • v.50 no.3
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    • pp.149-158
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    • 2022
  • To realize the infinite possibilities of materials derived from wood, it is necessary to overcome the weak moisture stability of wood. Thus, the development of an eco-friendly hydrophobic coating agent is essential, and of these, woody biomass-based materials are strongly attractive as coatings. In this study, eco-friendly hydrophobic wood coatings were prepared using carnauba wax purified from palm leaves and sprouts, and kraft lignin. The physicochemical properties of the carnauba wax/lignin blends according to the ratio of carnauba wax and lignin were observed by morphology and functional group change. In addition, the coating performance of carnauba wax/lignin blend coatings was confirmed by measuring the contact angle change. It was found that the addition of lignin could accelerate the atomization of wax particles, and that micro-roughness can be realized when applied to the actual wood surface, to ensure that the coating effect over time lasts longer. In addition, it was confirmed that the addition of lignin increases the hydrogen-bond-based interaction with the wood of the coating, thereby providing better coating stability and increasing the durability of the coating solvent under friction. The carnauba wax/lignin paint developed in this way is eco-friendly because all components are made of wood-based raw materials and have an excellent affinity with wood surfaces. Therefore, it is expected to be applicable to the coating process of wood-plastic composites and timber composites.

Carbon Storage of Natural Pine and Oak Pure and Mixed Forests in Hoengseong, Kangwon (횡성지역 천연 소나무와 참나무류 순림 및 혼효임분의 탄소 저장량 추정)

  • Lee, Sue Kyoung;Son, Yowhan;Noh, Nam Jin;Heo, Su Jin;Yoon, Tae Kyung;Lee, Ah Reum;Sarah, Abdul Razak;Lee, Woo Kyun
    • Journal of Korean Society of Forest Science
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    • v.98 no.6
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    • pp.772-779
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    • 2009
  • This study was conducted to estimate the carbon (C) contents in pure and mixed stands of pine (Pinus densiflora) and oak (Quercus spp.) trees for establishing the C inventory of forest ecosystems. A total of fifteen 20 m${\times}$20 m pure and mixed stands of pine and oak trees were chosen in natural forests in Hoengseong, Kangwon based on the basal area of all trees ${\geq}$ 5 cm DBH: three of 95% of pine and 5% oak trees [pine stand], three of 100% of oak trees [oak stand], and nine of 20 to 70% of pine and 80 to 30% of oak trees [mixed stand]. To estimate C contents in the study stands, biomass in vegetation, forest floor and coarse woody debris (CWD) were calculated and C concentrations in vegetation, forest floor, CWD and soil (0-30 cm) were analyzed. There was no significant difference in vegetation C contents among the stands; 147.6 Mg C/ha for the oak stand, 141.4 Mg C/ha for the pine stand and 115.8 Mg C/ha for the mixed stand. Forest floor C contents were significantly different among the stands (p<0.05); 12.7 Mg/ha for the pine stand, 9.9 Mg/ha for the oak stand, and 8.4 Mg/ha for the mixed stand. However, CWD C contents were not significantly different among the stands (p>0.05); 2.2 Mg/ha for the mixed stand, 1.7 Mg/ha for the oak stand, and 1.1 Mg/ha for the pine stand. Soil C contents up to 30 cm depth were not significantly different among the study stands; 44.4 Mg C/ha for the pine stand, 41.6 Mg C/ha for the mixed stand, and 33.3 Mg C/ha for the oak stand. Total ecosystem C contents were lower in the mixed stand than those in the pure stands, because vegetation C contents which occupied almost total ecosystem C contents were lower in the mixed stand than those in the pure stands; 199.6 Mg C/ha for the pine stand, 192.5 Mg C/ha for the oak stand and 169.1 Mg C/ha for the mixed stand. Lower vegetation C contents in the mixed stand might be influenced by interspecific competition between pine and oak trees and intraspecific competition among the oak trees resulted from high stand density. We suggest that forest management such as thinning to enhance C storage is indispensible for minimizing the competition in forest ecosystems.

Development of Heat Exchanger for Fermentation Heat Utilization from Waste Woody Biomass (목질계 폐바이오메스의 발효열이용 열교환기의 개발)

  • Cho, Nam-Seok;Choi, Tae-Ho;Kim, Hong-Eun;Lee, Suk-Ho;Lee, Chung-Koo
    • Journal of the Korean Wood Science and Technology
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    • v.37 no.1
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    • pp.94-104
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    • 2009
  • It is urgently required to develop the production of fermentation-heat energy from the waste agricultural and forest biomass and its effective heat exchanging system for the supply of warm water to rural households and greenhouses. In this study 3 helical-type and 1 plate-type heat exchangers using 3 different waste biomasses [e.g. hardwood (HW) sawdust (100%), softwood (SW) sawdust : HW sawdust (50 : 50) and HW sawdust : grass (90 : 10)] were applied in order to find out the best heat recovery system. The heat exchanger was basically considered to improve the overall heat recovery efficiency, to minimize heat loss and to simplify manufacturing, assembling and breaking up the fermenting beds. The helical-type heat exchanger (HX-H3) installed in fermenting bed of HW sawdust : grass (90 : 10) showed relatively higher temperature profiles, in particular mid- and upper-parts than lower and surface parts during 45-day fermentation process. The maximum temperature was ranged from $40^{\circ}C$ to $65^{\circ}C$ with average $60^{\circ}C$. The water temperature of tank outlet was ranged to $33{\sim}48^{\circ}C$ during whole measuring periods. By the way plate-type one (HX-P) installed in same biomass compositional fermenting bed showed $64.5{\sim}76.5^{\circ}C$ at center part, and $43{\sim}56^{\circ}C$ and $42{\sim}58^{\circ}C$, water tank and tank outlet temperatures, respectively, during 100 day measurement. It could be concluded that the plate-type heat exchanger (HX-P) provides not only the effective heating for the rural households and greenhouses, but also having the best heat recovery performance, easy manufacturing, assembling and breaking up the systems.

The Dynamics of CO2 Budget in Gwangneung Deciduous Old-growth Forest: Lessons from the 15 years of Monitoring (광릉 낙엽활엽수 노령림의 CO2 수지 역학: 15년 관측으로부터의 교훈)

  • Yang, Hyunyoung;Kang, Minseok;Kim, Joon;Ryu, Daun;Kim, Su-Jin;Chun, Jung-Hwa;Lim, Jong-Hwan;Park, Chan Woo;Yun, Soon Jin
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.23 no.4
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    • pp.198-221
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    • 2021
  • After large-scale reforestation in the 1960s and 1970s, forests in Korea have gradually been aging. Net ecosystem CO2 exchange of old-growth forests is theoretically near zero; however, it can be a CO2 sink or source depending on the intervention of disturbance or management. In this study, we report the CO2 budget dynamics of the Gwangneung deciduous old-growth forest (GDK) in Korea and examined the following two questions: (1) is the preserved GDK indeed CO2 neutral as theoretically known? and (2) can we explain the dynamics of CO2 budget by the common mechanisms reported in the literature? To answer, we analyzed the 15-year long CO2 flux data measured by eddy covariance technique along with other biometeorological data at the KoFlux GDK site from 2006 to 2020. The results showed that (1) GDK switched back-and-forth between sink and source of CO2 but averaged to be a week CO2 source (and turning to a moderate CO2 source for the recent five years) and (2) the interannual variability of solar radiation, growing season length, and leaf area index showed a positive correlation with that of gross primary production (GPP) (R2=0.32~0.45); whereas the interannual variability of both air and surface temperature was not significantly correlated with that of ecosystem respiration (RE). Furthermore, the machine learning-based model trained using the dataset of early monitoring period (first 10 years) failed to reproduce the observed interannual variations of GPP and RE for the recent five years. Biomass data analysis suggests that carbon emissions from coarse woody debris may have contributed partly to the conversion to a moderate CO2 source. To properly understand and interpret the long-term CO2 budget dynamics of GDK, new framework of analysis and modeling based on complex systems science is needed. Also, it is important to maintain the flux monitoring and data quality along with the monitoring of coarse woody debris and disturbances.

Thermo-chemical Conversion of Poplar Wood (Populus alba × glandulosa) to Monomeric Sugars by Supercritical Water Treatment (초임계수에 의한 현사시나무의 당화 특성)

  • Choi, Joon-Weon;Lim, Hyun-Jin;Han, Kyu-Sung;Choi, Don-Ha
    • Journal of the Korean Wood Science and Technology
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    • v.34 no.6
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    • pp.44-50
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    • 2006
  • To characterize thermo-chemical feature of su gar conversion of woody biomass poplar wood (Populus alba${\times}$glandulosa ) by sub- and supercritical water was treated for 60s under subcritical (23 MPa, 325 and $350^{\circ}C$) and supercritical (23 MPa, 380, 400, and $425^{\circ}C$) conditions, respectively. Among degradation products undegraded poplar wood solids existed in aqueous products. As the treatment temperature increased, the degradation of poplar wood was enhanced and reached up to 83.1% at $425^{\circ}C$. The monomeric sugars derived from fibers of poplar wood by sub- and supercritical treatment were analyzed by high performance anionic exchange chromatography (HPAEC). Under the subcritical temperature ranges, xylan, main hemicellulose component in poplar wood, was preferentially degraded to xylose, while cellulose degradation started at the transition zone between sub and supercritical conditions and was remarkably accelerated at the supercritical condition. The highest yield of monomeric sugars amounts to ca. 7.3% based on air dried wood weight (MC 10%) at $425^{\circ}C$.

Study on Evaluation of Carbon Emission and Sequestration in Pear Orchard (배 재배지 단위의 탄소 배출량 및 흡수량 평가 연구)

  • Suh, Sanguk;Choi, Eunjung;Jeong, Hyuncheol;Lee, Jongsik;Kim, Gunyeob;Sho, Kyuho;Lee, Jaeseok
    • Korean Journal of Environmental Biology
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    • v.34 no.4
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    • pp.257-263
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    • 2016
  • Objective of this study was to evaluate the carbon budget on 40 years old pear orchard at Naju. For carbon budget assessment, we measured the soil respiration, net ecosystem productivity of herbs, pear biomass and net ecosystem exchange. In 2015, pear orchard released about $25.6ton\;CO_2\;ha^{-1}$ by soil respiration. And $27.9ton\;CO_2\;ha^{-1}$ was sequestrated by biomass growth. Also about $12.6ton\;CO_2\;ha^{-1}$ was stored at pruning branches and about $5.2ton\;CO_2\;ha^{-1}$ for photosynthesis of herbs. As a result, 25.6 ton of $CO_2$ per ha is annually released to atmosphere. At the same time about 45.7 ton of $CO_2$ was sequestrated from atmosphere. When it sum up the amount of $CO_2$ release and sequestration, approximately $20.1ton\;CO_2\;ha^{-1}$ was sequestrated by pear orchard in 2015, and it showed no significant differences with net ecosystem exchanges ($17.8ton\;CO_2\;ha^{-1}\;yr^{-1}$) by eddy covariance method with the same period. Continuous research using various techniques will help the understanding of $CO_2$ dynamics in agroecosystem and it can be able to present a new methodology for assessment of carbon budget in woody crop field. Futhermore, it is expected that the this study can be used as the basic data to be recognized as a carbon sink.

Comparison of Quality Characteristics of Woodpellet Manufactured from Pinus densiflora S. et Z. and Pinus rigida Mill (소나무와 리기다소나무를 사용하여 제조한 목재펠릿의 품질 특성 비교)

  • Seo, Jun-Won;Lee, Eung-Su;Kang, Chan-Young;Kim, Si-Bak;Yoon, Yong Han;Park, Heon
    • Journal of the Korean Wood Science and Technology
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    • v.43 no.3
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    • pp.374-380
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    • 2015
  • The quality characteristics of the woodpellet manufactured from two domestic pines (Pinus densiflora S. et Z. and Pinus rigida Mill.) were investigated for the efficient energy use of woody biomass resources. Properties of woodpellets such as moisture content, heating value, ash content, apparent density and durability were determined by using the standard test method of woodpellets of Korea Forest Research Institute (KFRI) and elemental analysis. The results of elemental analysis for C, H, O and N showed 61.42% carbon, 5.56% hydrogen, 32.87% oxygen, and 0.15% nitrogen for Pinus densiflora S. et Z. and 61.03% carbon, 5.96% hydrogen, 32.83% oxygen, and 0.18% nitrogen for Pinus rigida Mill. No significant difference between Pinus densiflora S. et Z. and Pinus rigida Mill was observed on elemental analysis. Heating values of each woodpellet were ranged from 19.00 to 19.42 MJ/kg which satisfied the first grade quality standard (${\geq}18.0MJ/kg$) by KFRI. The ash contents of woodpellet were slightly different between Pinus densiflora S. et Z. and Pinus rigida Mill., and satisfied the first grade quality standard (${\leq}0.7%$) by KFRI. Apparent density of woodpellet (Pinus densiflora S. et Z.) was passed the first grade standard level (${\geq}640kg/m^3$), and woodpellets from Pinus rigida Mill. satisfied the second grade quality of the standard. The moisture contents of each woodpellet were satisfied by the first grade quality standard (${\leq}10%$). The durability of woodpellet (Pinus densiflora S. et Z.) was passed the third grade level (${\geq}95%$), but Pinus rigida Mill. woodpellet was insufficient to satisfy the quality standard.