• Title/Summary/Keyword: Wet-reduction process

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A Study on the Comparison of the Construction Process between the PC Modular Construction Method Using 3D Infill and the Existing Construction Method (3D Infill을 활용한 PC 모듈러공법과 기존공법과의 시공프로세스 비교 연구)

  • Chung, Joon-Soo;Lim, Seok-Ho;Yang, Hyeon-Jeong
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2023.05a
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    • pp.87-88
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    • 2023
  • In accordance with changes in the domestic construction environment, interest in off-site construction methods (factory-manufactured construction methods) including modular construction methods is rapidly increasing. Among various off-site (OSC) construction methods, the front runner is the steel-based box-type modular construction method. Compared to the existing wet construction method, the steel modular construction method is increasing in terms of securing economic feasibility by shortening the construction period and increasing the prefabrication rate. However, due to the recent rise in raw materials and a sharp rise in the exchange rate, the economic feasibility of the wet method is deteriorating compared to the wet method. Therefore, a hybrid between 9-Matrix-based OSC construction methods is considered as a solution, away from the steel-box type combination, and a comparative study of the construction process between each construction method is being conducted. It was analyzed that the PC modular construction method shortened the construction period by 9% compared to the existing steel modular construction method. On the other hand, when comparing the construction period of the Gayang-dong demonstration complex calculated assuming that all modules are applied, it is estimated that there will be a 12% reduction in construction period compared to the steel modular method and a whopping 43% compared to the RC method.

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Growth and Characteristics of Near-UV LED Structures on Wet-etched Patterned Sapphire Substrate

  • Cheong, Hung-Seob;Hong, Chang-Hee
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.6 no.3
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    • pp.199-205
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    • 2006
  • Patterned sapphire substrates (PSS) were fabricated by a simple wet etching process with $SiO_2$ stripe masks and a mixed solution of $H_2SO_4$ and $H_3PO_4$. GaN layers were epitaxially grown on the PSS under the optimized 2-step growth condition of metalorganic vapor deposition. During the 1st growth step, GaN layers with triangular cross sections were grown on the selected area of the surface of the PSS, and in the 2nd growth step, the GaN layers were laterally grown and coalesced with neighboring GaN layers. The density of threading dislocations on the surface of the coalesced GaN layer was $2{\sim}4\;{\times}\;10^7\;cm^{-2}$ over the entire region. The epitaxial structure of near-UV light emitting diode (LED) was grown over the GaN layers on the PSS. The internal quantum efficiency and the extraction efficiency of the LED structure grown on the PSS were remarkably increased when compared to the conventional LED structure grown on the flat sapphire substrate. The reduction in TD density and the decrease in the number of times of total internal reflections of the light flux are mainly attributed due to high level of scattering on the PSS.

Kinetics of Cr(VI) Sorption/Reduction from Aqueous Solution on Activated Rice Husk

  • El-Shafey, E.I.;Youssef, A.M.
    • Carbon letters
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    • v.7 no.3
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    • pp.171-179
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    • 2006
  • A carbonaceous sorbent was prepared from rice husk via sulphuric acid treatment. After preparation and washing, the wet carbon with moisture content 85% was used in its wet status in this study due to its higher reactivity towards Cr(VI) than the dry carbon. The interaction of Cr(VI) and the carbon was studied and two processes were investigated in terms of kinetics and equilibrium namely Cr(VI) removal and chromium sorption. Cr(VI) removal and chromium sorption were studied at various initial pH (1.6-7), for initial Cr(VI) concentration (100 mg/l). At equilibrium, maximum Cr(VI) removal occurred at low initial pH (1.6-2) where, Cr(III) was the only available chromium species in solution. Cr(VI) removal, at such low pH, was related to the reduction to Cr(III). Maximum chromium sorption (60.5 mg/g) occurred at initial pH 2.8 and a rise in the final pH was recorded for all initial pH studied. For the kinetic experiments, approximate equilibrium was reached in 60-100 hr. Cr(VI) removal data, at initial pH 1.6-2.4, fit well pseudo first order model but did not fit pseudo second order model. At initial pH 2.6-7, Cr(VI) removal data did not fit, anymore, pseudo first order model, but fit well pseudo second order model instead. The change in the order of Cr(VI) removal process takes place in the pH range 2.4-2.6 under the experimental conditions. Other two models were tested for the kinetics of chromium sorption with the data fitting well pseudo second order model in the whole range of pH. An increase in cation exchange capacity, sorbent acidity and base neutralization capacity was recorded for the carbon sorbent after the interaction with acidified Cr(VI) indicating the oxidation processes on the carbon surface accompanying Cr(VI) reduction.

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Simultaneous water and energy saving of wet cooling towers, modeling for a sample building

  • Ataei, Abtin;Choi, Jun-Ki;Hamidzadeh, Zeinab;Bagheri, Navid
    • Advances in environmental research
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    • v.4 no.3
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    • pp.173-181
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    • 2015
  • This article outlines a case study of water and energy savings in a typical building through a modelling process and analysis of simultaneous water-energy saving measures. Wet cooling towers are one of the most important equipments in buildings with a considerable amount of water and energy consumption. A variety of methods are provided to reduce water and energy consumption in these facilities. In this paper, thorough the modeling of a typical building, water and energy consumption are measured. Then, After application of modern methods known to be effective in saving water and energy, including the ozone treatment for cooling towers and shade installation for windows, i.e. fins and overhangs, the amount of water and energy saving are compared with the base case using the Simergy model. The annual water consumption of the building, by more than 50% reduction, has been reached to 500 cubic meters from 1024 cubic meters. The annual electric energy consumption has been decreased from 405,178 kWh to 340,944 kWh, which is about 16%. After modeling, monthly peak of electrical energy consumption of 49,428 has dropped to 40,562 kWh. The reduction of 18% in the monthly peak can largely reduce the expenses of electricity consumption at peak.

Synthesis of TiC/Co Composite Powder by the Carbothermal Reduction Process (환원/침탄공정에 의한 TiC/Co 복합분말 합성)

  • Lee, Gil-Geun;Ha, Gook-Hyun
    • Journal of Powder Materials
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    • v.16 no.5
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    • pp.310-315
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    • 2009
  • Ultra-fine TiC/Co composite powder was synthesized by the carbothermal reduction process without wet chemical processing. The starting powder was prepared by milling of titanium dioxide and cobalt oxalate powders followed by subsequent calcination to have a target composition of TiC-15 wt.%Co. The prepared oxide powder was mixed again with carbon black, and this mixture was then heat-treated under flowing argon atmosphere. The changes in the phase, mass and particle size of the mixture during heat treatment were investigated using XRD, TG-DTA and SEM. The synthesized oxide powder after heat treatment at 700$^{\circ}C$ has a mixed phase of TiO$_2$ and CoTiO$_3$ phases. This composite oxide powder was carbothermally reduced to TiC/Co composite powder by the solid carbon. The synthesized TiC/Co composite powder at 1300$^{\circ}C$ for 9 hours has particle size of under about 0.4 $\mu$m.

Performance Analysis of Upgrading Process with Amine-Based CO2 Capture Pilot Plant

  • Kwak, No-Sang;Lee, Junghyun;Lee, Dong Woog;Lee, Ji Hyun;Shim, Jae-Goo
    • KEPCO Journal on Electric Power and Energy
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    • v.4 no.1
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    • pp.33-38
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    • 2018
  • This study applied upgrades to the processes of a 10 MW wet amine $CO_2$ capture pilot plant and conducted performance evaluation. The 10 MW $CO_2$ Capture Pilot Plant is a facility that applies 1/50 of the combustion flue gas produced from a 500 MW coal-fired power plant, and is capable of capturing up to 200 tons of $CO_2$. This study aimed to quantitatively measure efficiency improvements of post-combustion $CO_2$ capture facilities resulting from process upgrades to propose reliable data for the first time in Korea. The key components of the process upgrades involve absorber intercooling, lean/rich amine exchanger efficiency improvements, reboiler steam TVR (Thermal Vapor Recompression), and lean amine MVR (Mechanical Vapor Recompression). The components were sequentially applied to test the energy reduction effect of each component. In addition, the performance evaluation was conducted with the absorber $CO_2$ removal efficiency maintained at the performance evaluation standard value proposed by the IEA-GHG ($CO_2$ removal rate: 90%). The absorbent used in the study was the highly efficient KoSol-5 that was developed by KEPCO (Korea Electric Power Corporation). From the performance evaluation results, it was found that the steam consumption (regeneration energy) for the regeneration of the absorbent decreased by $0.38GJ/tonCO_2$ after applying the process upgrades: from $2.93GJ/ton\;CO_2$ to $2.55GJ/tonCO_2$. This study confirmed the excellent performance of the post-combustion wet $CO_2$ capture process developed by KEPCO Research Institute (KEPRI) within KEPCO, and the process upgrades validated in this study are expected to substantially reduce $CO_2$ capture costs when applied in demonstration $CO_2$ capture plants.

Quality of Recycled Fine Aggregate using Neutral Reaction with Sulfuric Acid and Low Speed Wet Abrader

  • Kim, Ha-Seog;Lee, Kyung-Hyun;Kim, Jin-Man
    • Journal of the Korea Institute of Building Construction
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    • v.12 no.5
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    • pp.490-502
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    • 2012
  • The use of recycled aggregate, even for low-performance concrete, has been very limited because recycled aggregate, which contains a large amount of old mortar, is very low in quality. To produce a high-quality recycled aggregate, removing the paste that adheres to the recycled aggregate is very important. We have conducted research on a complex abrasion method, which removes the component of cement paste from recycled fine aggregate by using both a low-speed wet abrasion crusher as a mechanical process and neutralization as chemical processes, and well as research on the optimal manufacturing condition of recycled fine aggregates. Subsequently, we evaluated the quality of recycled fine aggregate manufactured using these methods, and tested the specimen made by this aggregate. As a result, it was found that recycled fine aggregates produced by considering the aforementioned optimal abrasion condition with the use of sulfuric acid as reactant showed excellent quality, recording a dry density of 2.4 and an absorption ratio of 2.94. Furthermore, it was discovered that gypsum, which is a reaction product occurring in the process, did not significantly affect the quality of aggregates. Furthermore, the test of mortar using this aggregate, when gypsum was included as a reaction product, showed no obvious retarding effect. However, the test sample containing gypsum recorded a long-term strength of 25.7MPa, whereas the test sample that did not contain gypsum posted a long-term strength of 29.4MPa. Thus, it is thought to be necessary to conduct additional research into the soundness and durability because it showed a clear reduction of strength.

Synthesis of WO3/TiO2 catalysts from different tungsten precursors and their catalytic performances in the SCR (텅스텐(W) 원료에 따른 WO3/TiO2 SCR 촉매의 제조 및 촉매능)

  • Lee, Byeong Woo;Lee, Jin Hee
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.24 no.5
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    • pp.213-218
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    • 2014
  • An investigation of the influence of $WO_3$ addition with different precursors and preparation methods on the phase formation and selective catalytic reduction (SCR) efficiency of anatase-$TiO_2$ powders has been carried out. An anatase-$TiO_2$ synthesized by precipitation process was used as a catalyst support. For $WO_3(10wt%)/TiO_2$, the W loading to the $TiO_2$ support led to the lower in anatase to rutile transition temperature to ${\sim}900^{\circ}C$ from $1200^{\circ}C$ of the $TiO_2$ support alone. In the case of $WO_3(10wt%)/TiO_2$ SCR powders obtained from a wet process with ammonium meta-tungstate (AMT) precursor, the highest $NO_X$ conversion efficiency was achieved at $450^{\circ}C$ remaining high efficiency at $500^{\circ}C$, while the same composition prepared from a dry process with $WO_3$ addition showed the lowered efficiency with temperature after reaching the efficiency maximum at $350^{\circ}C$. The same tendency has been found that the $V_2O_5(5wt%)-WO_3(10wt%)/TiO_2$ SCR powders obtained from the wet process with AMT precursor has shown the superior $NO_X$ conversion efficiency over 90 % in a wider temperature range of $300{\sim}500^{\circ}C$.

The Study for the CMP Automation with Nova Measurement System (NOVA System을 이용한 CMP Automation에 관한 연구)

  • Kim, Sang-Yong;Chung, Hun-Sang;Park, Min-Woo;Kim, Chang-Il;Chang, Eui-Goo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11b
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    • pp.176-180
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    • 2001
  • There are several factors causing re-work in CMP process such as improper polish time calculation by operator. removal rate decline of the polisher, unstable in-suit pad conditioning, slurry supply module problem and wafer carrier rotation inconsistancy. And conclusively those fundimental reason for the re-work rate increasement is mainly from the cycle time delay between wafer polish and post measurement. Therefore, Wafer thickness measurement in wet condition could be able to remove those improper process conditions which may happen during the process in comparison with the conventional dried wafer measurement system and it can be able to reduce the CMP process cycle time. CMP scrap reduction by overpolish, re-work rate reduction, thickness control efficiency also can be easily achieved. CMP Equipment manufacturer also trying to develop integrated system which has multi-head & platen, cleaner, pre & post thickness measure and even control the polish time from the calculated removal rate of each polishing head by software. CMP re-work problem such as over & under polish by target thickness may result in the cycle time delay. By reducing those inefficient factors during the process and establish of the automatic process control, CLC system need to be adopted to maximize the process performance. Wafer to Wafer Polish Time Feed Back Control by measuring the wafer right after the polish shorten the polish time calculation for the next wafer and it lead to the perfact Post CMP target thickness control capability. By Monitoring all of the processed the wafer, CMP process will also be stabilize itself.

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The Study for the CMP Automation wish Nova Measurement system (NOVA System을 이용한 CMP Automation에 관한 연구)

  • 김상용;정헌상;박민우;김창일;장의구
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11a
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    • pp.176-180
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    • 2001
  • There are several factors causing re-work in CMP process such as improper polish time calculation by operator, removal rate decline of the polisher, unstable in-suit pad conditioning, slurry supply module problem and wafer carrier rotation inconsistency. And conclusively those fundimental reason for the re-work rate increasement is mainly from the cycle time delay between wafer polish and post measurement. Therefore, Wafer thickness measurement in wet condition could be able to remove those improper process conditions which may happen during the process in comparison with the conventional dried wafer measurement system and it can be able to reduce the CMP process cycle time. CMP scrap reduction by overpolish, re-work rate reduction, thickness control efficiency also can be easily achieved. CMP Equipment manufacturer also trying to develop integrated system which has multi-head & platen, cleaner, pre & post thickness measure and even control the polish time from the calculated removal rate of each polishing head by software. CMP re-work problem such as over & under polish by target thickness may result in the cycle time delay. By reducing those inefficient factors during the process and establish of the automatic process control, CLC system need to be adopted to maximize the process performance. Wafer to Wafer Polish Time Feed Back Control by measuring the wafer right after the polish shorten the polish time calculation for the next wafer and it lead to the perfect Post CMP target thickness control capability. By Monitoring all of the processed the wafer, CMP process will also be stabilize itself.

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