• Bulletin of the Korean Chemical Society
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• 제7권3호
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• pp.190-193
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• 1986

The structure of partially $Ag^+$-exchanged zeolite 4A, $Ag_{7.6}Na_{4.4}-A$, vacuum dehydrated at $370^{\circ}C$, has been determined by single-crystal x-ray diffraction techniques in the cubic space group, Pm3m (a = 12.311(1)${\AA}$) at $24(1)^{\circ}}C$. The structure was refined to the final error indices $R_1$ = $R_2$ (weighted) = 0.064 using 266 independent reflections for which $I_0$>$3{\sigma}(I_0)$. Three $Na^+$ ions occupy the 3 8-ring sites, and the remaining ions, 1.4 $Na^+$ and 6.6 $Ag^+$, fill the 8 6-ring sites; each $Ag^+$ ion is nearly in the [111] plane of its 3 O(3) ligands, and each $Na^+$ ion is 0.9${\AA}$ from its corresponding plane, on the large-cavity side. One reduced silver atom per unit cell was found inside the sodalite unit. It was presumably formed from the reduction of a $Ag^+$ ion by an oxide ion of a residual water molecule or of the zeolite framework. It may be present as a hexasilver cluster in 1/6 of the sodalite units, or, most attractively among several alternatives, as an isolated Ag atom coordinated to 4 Ag ions in each sodalite unit to give $(Ag_5)^{4+}$, symmetry 4mm.

• 한국의류학회지
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• 제37권3호
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• pp.413-423
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• 2013

Chlorophyll is an abundant pigment found in all green plants, algae, and cyanobacteria. This study uses methanol, acetone and water to extract spinach and mate powders in order to examine the possibility of dyeing animal fibers with chlorophyll without chemical alteration. It was shown that methanol extracts of spinach and mate powders can be effectively used to dye wool and silk fabrics if the extract is mixed with water by methanol:water 65:35 v/v. Compared to methanol extract, the acetone extract showed lower chlorophyll yield and lower dye uptake. Water was not an appropriate solvent for chlorophyll extraction and dyeing. Spinach powder showed a higher dye uptake than mate powder due to the higher chlorophyll content than mate powder. It is possible that the chlorophyll dyeing of wool and silk fabrics is due to the hydrogen bonding between the hydroxy amino acids in fiber and the carbonyl groups of chlorophyll. These carbonyl groups are on the heterocyclic ring and the methyl and ethyl side chains of chlorophyll.

• 항공우주기술
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• 제9권2호
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• pp.8-13
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• 2010

축추력의 효과적인 제어는 터보펌프의 작동 안정성을 확보하는 데 중요한 기술 중 하나이다. 현재 개발 중인 75톤급 로켓엔진용 연료펌프에 대한 축추력 측정을 상온의 물을 매질로 하여 실시하였다. 시험 결과, 연료펌프의 축추력은 펌프 베어링의 축방향 하중 조건을 만족하는 것으로 예상되었다. 또한 연료펌프의 축추력은 대체로 유량이 작을수록 커졌다. 그리고 플로팅 링 실과 임펠러 사이의 간극이 바뀌었을 때, 연료펌프의 축방향 하중과 후방 누설 유량이 변화하는 것을 확인하였다.

• 오토저널
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• 제5권1호
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• pp.45-53
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• 1983

There exist many kinds of frictions in internal combustion engine such as piston ring and skirt, cam and tappet, bearing friction etc. Among them, the frictions between piston ring, skirt and cylinder are particular. These frictions for motoring test are differ from that of firing test even though the temperature of cooling water and lubricating oil keep identically. The frictions for firing test are increased due to combustion pressure and products. The precise calculation of the friction is difficult. But we can assume that the friction is governed by the viscosity of lubricating oil and gas pressure of cylinder. And the viscosity of lubricating oil is dependant on gas temperature of cylinder, so the piston friction may be governed by gas pressure and temperature of cylinder. In this treatise, we propose the method of evaluating piston friction under the condition of constant engine speed, and we analyzed the behaviours and influence of factors concerned with the piston friction for output correction when the inlet pressure and temperature were varied. The main results are as follows: 1) The behaviours on the inlet conditions for the contact force of the piston rings and the viscosity of the lubricating oil concerned with piston friction are found. 2) The essential point the these behaviours is dependant on the cyclic variation following to the inlet conditions. 3) According to our analysis, It was observed that the viscosity of lubricating oil is more effective than the contact force to the piston rings.

• 한국항행학회논문지
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• 제12권2호
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• pp.109-114
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• 2008

유비쿼터스 시대가 다가옴에 따라 핵심 기술 중 하나인 유비쿼터스 센서 네트워크에 대한 관심이 높아지고 있다. 현재 무선 통신 기술의 급속한 발전은 다양한 산업분야에서 편리성 및 용이성 측면에서 새로운 서비스들을 창출하고 있다. 특히, 환경 모니터링 분야에서 다양한 무선 통신 기술의 대두 및 발전은 설치 및 관련 비용의 대폭 절감뿐만 아니라 현장에서 실시간적으로 발생하는 자료의 수집주기, 신뢰성 및 전달성에 있어 획기적인 개선을 가능하게 하였다. 그러나 무선 통신 기술의 환경 모니터링 분야에 대한 지속적인 적용 및 성공은 신뢰할 수 있고 시기적절한 정보를 실시간적으로 제공 가능하느냐에 따를 것이다.

• 한국생물물리학회:학술대회논문집
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• 한국생물물리학회 2003년도 정기총회 및 학술발표회
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• pp.74-74
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• 2003

We report here the results on N-acetyl-N'-methylamide of oxazolidine (Ac-Oxa-NHMe) calculated using the ab initio molecular orbital method with the self-consistent reaction field (SCRF) theory at the HF level of theory with the 6-3l+G(d) basis set. The displacement of the $\square$-CH$_2$ group in proline ring by oxygen atom has affected the structure of proline, cis$\^$∼/ trans equilibrium, and rotational barrier. The up-puckered structure is found to be prevalent for the trans conformers of the Oxa amide. The higher cis populations of the Oxa amide can be interpreted due to the longer distance between the acetyl methyl group and the 5-methylene group of the ring for the trans conformer of the Oxa amide than that of the Pro amide. The changes in charge of the prolyl nitrogen and the decrease in electron overlap of the C$\^$∼/ N bond for TS structures seem to play a role in lowering rotational barriers of the Oxa amide compared to that of the Pro amide. The calculated preferences for cis conformers in the order of Oxa > Pro amides and for trans-to-cis rotational barriers in the order of Pro > Oxa amide in water are consistent with experimental results on Oxa-containing peptides. The pertinent distance between the prolyl nitrogen and the N$\^$∼/ H amide group to form a hydrogen bond might indicate that this intramolecular hydrogen bond could contribute in stabilizing the TS structures of Oxa and Pro amides and play a role in prolyl isomerization.

• 한국자기학회지
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• 제8권3호
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• pp.125-130
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• 1998

13Cr-1.5Nb-Fe합금분말이 수분사법으로 제조되엇다. 제조된 합금뷴말을 압축기를 이용하여 ring현상으로 성형한후, 진공중에서 소결하였다. as-prepared 분말의 현상, 입도분포, 성분분석 및 포화자화물 조사하였으며, 소결된 시편의 투자율, 교류자기이력손실이 조사되었다. as-prepared 13Cr-1.5Nb-Fe합금분말의 포화자화는 160emu/g이었으며, 산소함유량은 약 600ppm이었다. 입도분포는 약 70$\mu$m에서 50%vol.을 나타낸다. 교류투자율은 소결온도 및 성형온도가 증가할수록 증가한다. 주파수 20KHz에서 교류자기이력손실은 12ton/cm2성령압력 및 120$0^{\circ}C$ 소결온도 조건에서 107W/cc로 가장우수하다.

• 한국물환경학회지
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• 제23권3호
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• pp.303-308
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• 2007

Three types dyeing wastewater (dark, medium, light color) discharged from cotton textile dyeing with reactive dye was collected at each step of process. Each process dying wastewater was analyzed and treated by ionized gas. The analysis focused on $COD_{Cr}$, SS and color. Bleaching & scouring process wastewater has the highest $COD_{Cr}$ value in the three type dyeing wastewater. SS shows the highest value at dyeing process wastewater in dark and medium color but light color has at finishing process wastewater. The result of process wastewater treatment by ionized gas was that the ionized gas was effective in $COD_{Cr}$ removing of bleaching & scouring process and finishing process wastewater but was not good at dyeing process wastewater. From that result it is estimated that the ionized gas could not work in opening the aromatic ring and react only in aliphatic component of the molecule. Because the surfactants contained in bleaching & scouring process and finishing process wastewater have only one aromatic ring in its molecular structure, in contrast with the reactive dye compounds consist of aromatic rings great part of its molecular structure. The color almost removed in 1.5 hrs reaction time but $COD_{Cr}$ removal effiency was only 30.7% through 3hrs in 1500 mL of total dyeing wastewater treated by 10 L/min ionized gas.

• 한국염색가공학회지
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• 제11권5호
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• pp.44-54
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• 1999

Poly(ethylene 2,6-naphthalate), PEN, is a relatively well-known polymer used for engineering purposes. Naphthalene ring provides rigidity to the polymer backbone, thus, it elevated the glass transition temperature and enhanced mechanical properties. The structure and properties of PEN affect a processing conditions severely, and the high-thermal stability have been had a poor thermal processibility. Hence, the basic mechanism of solvent drawing, is very much the same as that of thermal drawing from glassy state since both involve the inducement of segmental mobility. The former achieves the goal by use of chemical energy, and the latter does so by use of thermal energy. Generally, the sorption of the solvent by the polymer has a plasticizing effect, and leads to a lowering of the glass transition temperature, $T_g$. In this paper, the dynamic viscoelasticity behavior in liquid-drawing process of an unoriented amorphous PEN films were investigated using Rheovibron. The results are as follows ： (1) For the drawing in silicone oil, the drawing below $T_g$. had $\alpha{2}$-dispersion due to an inhomogeneous taut structure. (2) For the drawing in water, the inhomogeneous taut structure reduced by the effect of plasticization even below $T_g$. (3) For the drawing in butanol, the only aliphatic segment in PEN have some molecular mobility but the mobility of the aromatic segment having naphthalene ring is nearly impossible. (4) For the drawing in dioxane/water mixing solvent, the solvent effect is complementary each other and accordingly the entire molecular conformation have stable state. (5) For the drawing in dioxane/butanol mixing solvent, the inhomogeneity of the taut structure and the aromatic segment increase with increasing the temperature and this tendencies correspond with that of the draw ratio.

• 한국지반환경공학회 논문집
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• 제21권11호
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• pp.21-26
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• 2020

자연상태의 흙은 다양한 크기의 입자로 구성되어 있으며, 이 흙의 역학적 거동 중 전단거동은 입도 분포에 크게 영향을 받는다. 그리고 자연상태의 흙은 조립토와 세립토가 다양하게 혼합되어 존재하기 때문에 그 역학적 성질인 전단특성을 명확히 파악하기 어렵다. 이에 본 연구에서는 흙의 입도 분포가 흙의 전단특성에 미치는 영향을 확인하기 위한 목적으로 조립토는 모래를 세립토는 실트를 이용해 모래에 대한 실트의 함유량을 변화시켜 입도 분포가 다른 사질토를 조성한 후 링 전단시험을 수행하였다. 그리고 물 공급 시 입도 분포가 다른 사질토의 전단특성 변화를 확인하기 위해 링 전단시험 중 물을 공급하여 실험을 수행하였다. 그 결과 실트 함유량이 증가할수록 전단강도는 점차 증가하다 실트 함유량이 모래보다 많아지면 전단강도는 감소하는 것으로 나타났다. 그리고 수분 공급 시 실트 함유량에 따라 잔류전단강도는 완만한 경사를 나타내며 감소하는 것으로 나타났다.