• Title/Summary/Keyword: Water-to-gas ratio

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The Characteristics on Arc Pressure Distribution of TIG Welding with Shield Gas Mixing Ratio (TIG 용접에서의 실드 가스 혼합비에 따른 아크 압력분포 특성)

  • Oh Dong-Soo;Kim Yeong-Sik;Cho Sang-Myung
    • Journal of Welding and Joining
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    • v.23 no.1
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    • pp.41-47
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    • 2005
  • Arc pressure is one of important factors in understanding physical arc phenomena. Especially it affects on the penetration, size and shape of TIG welding. Some researches were reported on the effect of arc pressure in low and middle current region. But there are not any research in high current region. The purpose of this study is to investigate the arc pressure distribution with mixing ratio of shield gas such as Ar and He gases. A Cu block with water cooling was specifically designed and used as an anode electrode in order to measure the arc pressure in high current region. Then, the arc pressure distribution was measured with change in welding current and mixing ratio of shield gases. The arc force was obtained by numerically integrating the measured results. As the results, it was shown that the arc pressure was concentrated at the central part of the arc in middle and high current regions when a pure Ar gas was used. In case of Ar + He mixing gas, the arc pressure was much lower than that of pure Ar gas. In addition, it was widely distributed to radial direction.

Water Repellency on a Nanostructured Superhydrophobic Carbon Fibers Network

  • Ko, Tae-Jun;Her, Eun-Kyu;Shin, Bong-Su;Kim, Ho-Young;Lee, Kwang-Ryeol;Hong, Bo-Ki;Kim, Sae-Hoon;Oh, Kyu-Hwan;Moon, Myoung-Woon
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.08a
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    • pp.224-224
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    • 2012
  • For decades, carbon fiber has expanded their application fields from reinforced composites to energy storage and transfer technologies such as electrodes for super-capacitors and lithium ion batteries and gas diffusion layers for proton exchange membrane fuel cell. Especially in fuel cell, water repellency of gas diffusion layer has become very important property for preventing flooding which is induced by condensed water could damage the fuel cell performance. In this work, we fabricated superhydrophobic network of carbon fiber with high aspect ratio hair-like nanostructure by preferential oxygen plasma etching. Superhydrophobic carbon fiber surfaces were achieved by hydrophobic material coating with a siloxane-based hydrocarbon film, which increased the water contact angle from $147^{\circ}$ to $163^{\circ}$ and decreased the contact angle hysteresis from $71^{\circ}$ to below $5^{\circ}$, sufficient to cause droplet roll-off from the surface in millimeter scale water droplet deposition test. Also, we have explored that the condensation behavior (nucleation and growth) of water droplet on the superhydrophobic carbon fiber were significantly retarded due to the high-aspect-ratio nanostructures under super-saturated vapor conditions. It is implied that superhydrophobic carbon fiber can provide a passage for vapor or gas flow in wet environments such as a gas diffusion layer requiring the effective water removal in the operation of proton exchange membrane fuel cell. Moreover, such nanostructuring of carbon-based materials can be extended to carbon fiber, carbon black or carbon films for applications as a cathode in lithium batteries or carbon fiber composites.

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An Experimental Study on Investigation of the Main Factors to Improve the Formation Performance of Gas Hydrate (가스하이드레이트 생성성능 향상을 위한 주요인자별 특성 규명에 관한 실험적 연구)

  • Lee, Jeong-Hwan
    • Journal of the Korean Institute of Gas
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    • v.13 no.3
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    • pp.15-21
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    • 2009
  • Gas hydrate is an ice-like crystalline compound that forms at low temperature and high pressure conditions. It consists of gas molecules surrounded by cages of water molecules. Although hydrate formation was initially found to pose serious flow-assurance problems in the gas pipelines or facilities, gas hydrates have much potential for application in a wide variety of areas, such as natural gas storage and transportation. Its very high gas-to-solid ratio and remarkably stable characteristics makes it an attractive candidate for such use. However, it needs to be researched further since it has a slow and complex formation process and a high production cost. In this study, formation experiments have been carried out to investigate the effects of pressure, temperature, water-to-storage volume ratio, SDS concentration, heat transfer and stirring. The results are presented to clarify the relationship between the formation process and each factor, which consequently will help find the most efficient production method.

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A Study on the Generating feature of Hydrogen Oxygen Gas Using Current Controlled Pulse Power Supply (전류제어형 펄스전원장치를 이용한 수산화 가스 발생 특성 연구)

  • Yang S. H.;Kang B. H.;Jun Y. S.;Mok H. S.;Choe G. H.
    • Proceedings of the KIPE Conference
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    • 2002.07a
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    • pp.257-262
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    • 2002
  • Water-Electrolyzed gas is a mixed gas has the constant volume ratio 2 1 Hydrogen and Oxygen gained from electrolyzed water, and it has better characteristics in the field of economy, efficiency of energy, and environmental intimacy than acetylene gas and LPG used for existing gas welding equipment. So nowdays many studies of Water-Electrolyzed gas are progressed, and commercially used as a source of thermal energy for gas welding in the industry. For Water-Electrolyzed Source, it was used diode rectifier or SCR rectifier for get DC source. This method which is not looking to improve a source for impossible current control or voltage and limited control intervals. In this paper, it was relized and designed In source of pulse type for complementing existing - DC source type, also by experiment it was acquired producting characteristics of Hydrogen -Oxygen Gas through feature of source

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Reaction Characteristics of WGS Catalyst for SEWGS Process in a Pressurized Fluidized Bed Reactor (가압 유동층 반응기에서 SEWGS 공정을 위한 WGS 촉매의 반응특성)

  • Kim, Ha-Na;Lee, Dong-Ho;Lee, Seung-Yong;Hwang, Taek-Sung;Ryu, Ho-Jung
    • Transactions of the Korean hydrogen and new energy society
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    • v.23 no.4
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    • pp.337-345
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    • 2012
  • To check effects of operating variables on reaction characteristics of WGS catalyst for SEWGS process, water gas shift reaction tests were carried out in a pressurized fluidized bed reactor using commercial WGS catalyst and sand(as a substitute for $CO_2$ absorbent) as bed materials. Simulated syngas(mixed with $N_2$) was used as a reactant gas. Operating temperature was $210^{\circ}C$ and operating pressure was 20 bar. WGS catalyst content, steam/CO ratio, gas velocity, and syngas concentration were considered as experimental variables. CO conversion increased as the catalyst content and steam/CO ratio increased. CO conversion at fluidized bed condition was higher than that of fixed bed condition. However, CO conversion were maintained almost same value within the fluidized bed condition. CO conversion decreased as the syngas concentration increased. The optimum operation condition was confirmed and long time water gas shift reaction test up to 24 hours at the optimum operating conditions was carried out.

Seismic AVO Analysis, AVO Modeling, AVO Inversion for understanding the gas-hydrate structure (가스 하이드레이트 부존층의 구조파악을 위한 탄성파 AVO 분석 AVO모델링, AVO역산)

  • Kim Gun-Duk;Chung Bu-Heung
    • 한국신재생에너지학회:학술대회논문집
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    • 2005.06a
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    • pp.643-646
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    • 2005
  • The gas hydrate exploration using seismic reflection data, the detection of BSR(Bottom Simulating Reflector) on the seismic section is the most important work flow because the BSR have been interpreted as being formed at the base of a gas hydrate zone. Usually, BSR has some dominant qualitative characteristics on seismic section i.e. Wavelet phase reversal compare to sea bottom signal, Parallel layer with sea bottom, Strong amplitude, Masking phenomenon above the BSR, Cross bedding with other geological layer. Even though a BSR can be selected on seismic section with these guidance, it is not enough to conform as being true BSR. Some other available methods for verifying the BSR with reliable analysis quantitatively i.e. Interval velocity analysis, AVO(Amplitude Variation with Offset)analysis etc. Usually, AVO analysis can be divided by three main parts. The first part is AVO analysis, the second is AVO modeling and the last is AVO inversion. AVO analysis is unique method for detecting the free gas zone on seismic section directly. Therefore it can be a kind of useful analysis method for discriminating true BSR, which might arise from an Possion ratio contrast between high velocity layer, partially hydrated sediment and low velocity layer, water saturated gas sediment. During the AVO interpretation, as the AVO response can be changed depend upon the water saturation ratio, it is confused to discriminate the AVO response of gas layer from dry layer. In that case, the AVO modeling is necessary to generate synthetic seismogram comparing with real data. It can be available to make conclusions from correspondence or lack of correspondence between the two seismograms. AVO inversion process is the method for driving a geological model by iterative operation that the result ing synthetic seismogram matches to real data seismogram wi thin some tolerance level. AVO inversion is a topic of current research and for now there is no general consensus on how the process should be done or even whether is valid for standard seismic data. Unfortunately, there are no well log data acquired from gas hydrate exploration area in Korea. Instead of that data, well log data and seismic data acquired from gas sand area located nearby the gas hydrate exploration area is used to AVO analysis, As the results of AVO modeling, type III AVO anomaly confirmed on the gas sand layer. The Castagna's equation constant value for estimating the S-wave velocity are evaluated as A=0.86190, B=-3845.14431 respectively and water saturation ratio is $50\%$. To calculate the reflection coefficient of synthetic seismogram, the Zoeppritz equation is used. For AVO inversion process, the dataset provided by Hampson-Rushell CO. is used.

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Catalytic Activity Tests in Gas-Liquid Interface over Cu-ZnO/Al2O3 Catalyst for High Pressure Water-Gas-Shift Reaction (고압 WGS 반응을 위한 Cu-ZnO/Al2O3 촉매상에서 기-액 계면 촉매 반응 특성 연구)

  • Kim, Se-Hun;Park, No-Kuk;Lee, Tae-Jin
    • Transactions of the Korean hydrogen and new energy society
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    • v.22 no.6
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    • pp.905-912
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    • 2011
  • In this study, the novel concept catalytic reactor was designed for water-gas shift reaction (WGS) under high pressure. The novel concept catalytic reactor was composed of an autoclave, the catalyst, and liquid water. Cu-ZnO/$Al_2O_3$ as the low temperature shift catalyst was used for WGS reaction. WGS in the novel concept catalytic reactor was carried out at the ranges of 150~$250^{\circ}C$ and 30~50 atm. The liquid water was filled at the bottom of the autoclave catalytic reactor and the catalyst of pellet type was located at the gas-liquid water interface. It was concluded that WGS reaction occurred over the surface of catalysts partially wetted with liquid water. The conversion of CO for WGS was also controlled with changing content of Cu and ZnO used as the catalytic active components. Meanwhile, the catalyst of honey comb type coated with Cu-ZnO/$Al_2O_3$ was used in order to increase the contact area between wet-surface of catalyst and the reactants of gas phase. It was confirmed from these experiments that $H_2$/CO ratio of the simulated coal gas increased from 0.5 to 0.8 by WGS at gas-liquid water interface over the wet surface of honey comb type catalyst at $250^{\circ}C$ and 50 atm.

A Study on the Generating feature of Hydrogen Oxygen Gas Using Pulse Power Supply (펄스전원장치를 이용한 수산화 가스 발생 특성 연구)

  • Yang S. H.;Kim K. H.;Jun Y. S.;Mok H. S.;Choe G. H.
    • Proceedings of the KIPE Conference
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    • 2002.11a
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    • pp.89-93
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    • 2002
  • Hydrogen - Oxygen gas has obtained from water electrolysis reaction. It is mixed gas havingconstant volume ratio 2:1 Hydrogen and Oxygen, and it is used as a source of thermal energy by combustion reaction. This gas has betterristics in the field of economy, efficiency of energy, and environmental intimacy than used both of acetylene gas and LPG for gas welding machin. So nowdays many studies of Water-Electrolyzed gas are progressed, and commercially used as a source of thermal energy for gas welding In the industry. For Water-Electrolyzed Source, it was used diode rectifier or SCR rectifier for get DC source. This method which is not looking to improve a source for impossible current control or voltage and limited control intervals. In this paper, it was relized and designed in source of pulse type for complementing existing-DC source type, also by experiment it was acquired producting characteristics of Hydrogen -Oxygen Gas through feature of source

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A Study on the Effect of Recirculated Exhaust Gas with Scrubber EGR System upon Exhaust Emissions in Diesel Engines (디젤기관의 배기 배출물에 미치는 스크러버형 EGR 시스템 재순환 배기의 영향에 관한 연구)

  • Bae, Myung-Whan;Ha, Jung-Ho
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.24 no.9
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    • pp.1247-1254
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    • 2000
  • The effects of recirculated exhaust gas on the characteristics of $NO_x$ and soot emissions under a wide range of engine load have been experimentally investigated by a water-cooled, four-cylinder, indirect injection, four cycle and marine diesel engine operating at two kinds of engine speeds. The simultaneous control of $NO_x$ and soot emissions in diesel engines is targeted in this study. The EGR system is used to reduce $NO_x$ emissions, and a novel diesel soot removal device with a cylinder-type scrubber for the experiment system which has 6 water injectors(A water injector has 144 nozzles in 1.0 mm diameter) is specially designed and manufactured to reduce the soot contents in the recirculated exhaust gas to intake system of the engines. The intake oxygen concentration and the mean equivalence ratio calculated by the intake air flow and fuel consumption rate, and the exhaust oxygen concentration measured are used to analyse and discuss the influences of EGR rate on $NO_x$ and soot emissions. The experiments are performed at the fixed fuel injection timing of $15.3^{\circ}$ BTDC regardless of experimental conditions. It is found that $NO_x$ emissions are decreased and soot emissions are increased owing to the drop of intake oxygen concentration and exhaust oxygen concentration, and the rise of equivalence ratio as the EGR rate rises.

A Study on Desulfurization and Denitrification of Flue Gas in Industry Boiler (산업용 보일러의 배연탈황 및 탈질에 관한 연구)

  • 이태호;정순형;정흥기
    • Journal of environmental and Sanitary engineering
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    • v.10 no.3
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    • pp.99-104
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    • 1995
  • The objective of this study was to investigate the effect on denuclearization and decertification of flue gas by utilizing Mg( OH)$_{2}$ and NaOH as reagents in industrial boiler. We used packed absorber with Tellerette in all cases. And pH of circulation solution, rate of liquid per gas in absorber, COD concentration by pH variation in oxidation basin were inves- tigated. The following conclusions were obtained from experimental results: 1. Concerning running cost for reagents, Mg( OH)$_{2}$ reagent for treatment of flue gas was more economical than NaOH. 2. While Mg( OH )$_{2}$ and NaOH as absorbents were used, then the ratio of denuclearization was 96 and 97% respectively and nitrification was recorded 29 and 25% . 3. In this absorption tests the optimum condition for ratio of liquid per gas, pH and nonregenerable salt concentration of circulation solution were 3.6ℓ /Nm$^{3}$, 6.0, 0.5∼1.0% respectively, 4. Initial COD in oxidation basin was 800 ∼ 1,00099ut after adjusting to pH 7.0, COD of effluent water was less than 20ppm.

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