• 한국환경보건학회:학술대회논문집
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• 한국환경보건학회 2003년도 Challenges and Achievements in Environmental Health
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• pp.102-105
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• 2003

• 한국염색가공학회지
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• 제17권2호
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• pp.10-18
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• 2005

Silk fabrics mordanted with $Fe^{2+},\;Ni^{2+},\;and\;Cu^{2+}$ were dyed with the aqueous extract of Cassia tora L. seed which was known to include water soluble colorant kaempferol, one of flavonol compounds. Kaempferol can react with free radicals and chelate transition metal ions, which is thought to catalyze processes leading to the appearance of free radicals and have antioxidant activity. In relation to the coordinating and chelating mechanism of the ions with the silk protein and kaempferol, reasonable conclusions should be made on the colorant uptake and the water fastness of the fabric. The amount of the colorant on the fabric was in the order of $Fe^{2+}>Ni^{2+}>Cu^{2+}$. In case of dyeing through coordinaiton bonds between transition metal ions and silk protein and colorants, it was thought that the ions with the smaller secondary hydration shell, the higher preference to the atoms of the ligand coordinated, and the suitable bonding stability for the substitution of primarily hydrated water molecules for colorants led to the higher colorant uptake. The water fastnsess of the fabric was in the order of $Fe^{2+}>Cu^{2+}>Ni^{2+}$. It should be reasonable to choose transition metal ions with weak and strong tendency to the ionic and the coordination bond, respectively, to the carboxylate anion of the silk protein. Although further research needs to be done, the conclusions above may be generally applied to the natural dyeing through the coordination bond mechanism between transition metal ions and colorants and substrates.

• 한국환경과학회지
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• 제26권5호
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• pp.591-600
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• 2017

This study was carried out to elucidate the chemical compositions of water-soluble inorganic ions in $PM_{10}$ and $PM_{2.5}$ aerosols collected during summer and winter in downtown Jejusi city. The ratios of $NO_3^-$ to the total mass of ionic species in $PM_{10}$ and $PM_{2.5}$ aerosols largely increase in winter compared to summer, while $SO_4^{2-}$ ratios in both aerosols appear to follow the opposite trend. Moreover, concentrations of $Na^+$, $Mg^{2+}$, $Ca^{2+}$ and $Cl^-$ in $PM_{10}$ and $PM_{2.5-10}$ aerosols are higher in winter than in summer. The nitrate concentrations in $PM_{10}$ and $PM_{2.5}$ aerosols increase with an identical increase in excess ammonium during winter, however, nitrate formation during summer is not important owing to ammonium-poor conditions.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2003년도 학술.기술논문 발표회
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• pp.43-48
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• 2003

This paper investigate that the effect of the concrete containing mineral admixtures(pozzolanic materials such as fly-ash, ground granulated blast-furnace slag, silica fume and meta kaolin) on the resistance properties to chloride ion invasion. The purposed testing procedure was applied to the concrete added mineral admixtures for 3~4 replacement ratios under W/B ratios ranged from 0.40 to 0.55. For the electrical migration test, Tang and Nilsson's method was used to estimate the migration coefficient of chloride ion. As a results, the W/B ratios, kinds of admixture and replacement ratios, water curing periods had a great effect on the migration coefficient of chloride ion, and the optimal replacement ratios of admixture had a limitation for each admixtures. Also, the addition of mineral admixtures by mass(replacement of OPC) enhanced the resistance of the mixture to chloride penetration compared with the plain concrete. The amount of acid soluble chloride ions and water soluble chloride ions were varied with the kinds of mineral admixtures. The compressive strength was shown related to the migration coefficient of chloride ion, the compressive strength increased with the decreasing migration coefficient of chloride ion. Below the 50MPa, the variation of migration coefficient of concrete added mineral admixtures was bigger than plain concrete.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2003년도 학술.기술논문발표회
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• pp.43-48
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• 2003

This paper investigate that the effect of the concrete containing mineral admixtures(pozzaolanic materials such as fly-ash, ground granulated blast-furnace slag, silica fume and meta kaolin) on the resistance properties to chloride ion invasion. The purposed testing procedure was applied to the concrete added mineral admixtures for 3∼4 replacement ratios under W/B ratios ranged from 0.40 to 0.55. For the electrical migration test, Tang and Nilsson's method was used to estimate the migration coefficient of chloride ion. As a results, the W/B ratios, kinds of admixture and replacement ratios, water curing periods had a great effect on the migration coefficient of chloride ion, and the optimal replacement ratios of admixture had a limitation for each admixtures. Also, the addition of mineral admixtures by mass(replacement of OPC) enhanced the resistance of the mixture to chloride penetration compared with the plain concrete. The amount of acid soluble chloride ions and water soluble chloride ions were varied with the kinds of mineral admixtures. The compressive strength was shown related to the migration coefficient of chloride ion, the compressive strength increased with the decreasing migration coefficient of chloride ion. Below the 50MPa, the variation of migration coefficient of concrete added mineral admixtures was bigger than plain concrete.

• 한국식품영양과학회지
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• 제24권2호
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• pp.299-304
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• 1995

Antioxidative effect of tea extracts from green tea(steamed, roasted), oolong tea and black tea was investigated. Antioxidative activities of the crude catechin fraction were the most effective in oolong tea which contained the highest level of (-)-epigallocatechin gallate(EGCg). The water-soluble fraction obtained from oolong tea exhibited binding with more ferrous than copper ions. It showed a synergistic effect when used with an antioxidant such as BHT(0.5mg) and $\alpha$-tocopherol(2mg). Especially, this synergistic effect was exhibited more with BHT than with $\alpha$-tocopherol. Also steamed green tea, roasted green tea and oolong tea showed remarkable free radical scavenging action. The SC50(the concentration of a water-soluble fraction which is required to scavenge 50% of 100$\mu$M 1, 1-diphenyl-2-picryl hydrazyl radicals) of steamed and roasted green tea, oolong tea and black tea extracts were 11.3$\mu\textrm{g}$/ml, 11.4$\mu\textrm{g}$/ml, 12.7 $\mu\textrm{g}$/ml and 14.9$\mu\textrm{g}$/ml, respectively. It is assumed that the antioxidative activity of tea extracts is due to inhibition of peroxidation free radical scavenging and binding action of ferrous ions by mainly tea polyphenol compounds.

• 한국환경농학회지
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• 제28권4호
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• pp.397-402
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• 2009

In Korea, salt stress is one of the major problems limiting crop production and eco-environmental quality in greenhouse soil. The objective of this study was to evaluate the effectiveness of organic residues (Chinese milk vetch, maize stalk, rice straw, and rye straw) for reducing salt activity in greenhouse soil. Organic residues was incorporated with salt-accumulated soil (EC, 3.0 dS $m^{-1}$) at the rate of 5% (wt $wt^{-1}$) and the changes of electrical conductivity (EC) was determined weekly for 8 weeks under incubation condition at $30^{\circ}C$. The EC, microbial biomass carbon (MBC), and water soluble ions in soil was strongly affected by C/N ratio of organic residues. After 8 weeks incubation, the concentration of water soluble $NO_3{^-},\;Ca^{2+}$, and $Mg^{2+}$ was significantly decreased in organic residues having high C/N ratio (maize stalk, rice straw, and rye straw) incorporated soil compared to organic residues having lower C/N ratio (Chinese milk vetch) incorporated soil. The EC value in Chinese milk vetch incorporated soil was higher than control treatment. In contrast, maize stalk, rice straw, and rye straw amended soil was highly decreased the EC value compared to control and Chinese milk vetch applied soil after 4 weeks incubation. Our results indicated that incorporation of organic residues having high C/N ratio (>30) could reduce salt activity resulting from reducing concentration of water soluble ions.

• 공업화학
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• 제27권3호
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• pp.330-334
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• 2016

충북 지역 산림에서는 여러 가지 나무 수피들의 대량 생산으로 인하여, 이를 효과적으로 활용하는 기술 개발이 요구되고 있다. 본 연구에서는 3종류(아카시아, 소나무, 밤나무) 수피들을 이용한 회분식 실험에 의하여, 수중에 용해된 10, 20, 50, 100 mg/L 카드뮴 이온의 제거효율이 가장 우수한 생물흡착제로서 아카시아 수피를 선별하였다. 그리고, 아카시아 수피를 사용하여 100 mg/L 카드뮴 이온의 제거효율을 증가시키기 위하여 다양한 산과 염기 처리가 수행되었다. 0.5 M 수산화칼륨(KOH)으로 아카시아 수피가 개질되었을 때, 비교적 높은 카드뮴 이온 제거효율과 흡착량을 얻었다. 또한, 9 M KOH로 개질된 아카시아 수피를 사용하여 30 min 반응이 이루어졌을 때, 100 mg/L 카드뮴 이온의 최대 제거효율은 84.3%를 나타내었다. 따라서, 본 실험 결과들은 수계와 토양에 다양한 농도로 존재하는 카드뮴 이온을 친환경적으로 처리할 수 있는 생물복원(bioremediation) 기술로 유용하게 사용될 수 있을 것이다.

• 유기물자원화
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• 제25권3호
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• pp.79-89
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• 2017

경기도 포천시 관내 하수 및 인분 처리장들에서 발생하는 유기성 슬러지를 지렁이 먹이로 공급하였을 때, 지렁이 사육상의 수용성 양이온, 음이온 농도 및 pH, 전기전도도 등의 이화학 성상 변화를 추적하였다. 먹이로 공급된 슬러지의 pH, 전기전도도, 유기물 함량 및 함수율은 지렁이의 단기적 섭식이 가능한 범위였으나, 슬러지의 공급량이 늘어감에 따라 섭식속도가 느려지고 결국 지렁이 사멸현상이 나타났다. 또한 슬러지 공급량이 늘어감에 따라 지렁이 사육상이 산성화되었고, 전기전도도가 높아지는 것으로 보아 염류집적 현상이 일어난 것을 알 수 있었으며, 동시에 사육상의 수용성 음이온 및 양이온 농도가 높아졌다. 특히 수용성 이온 중 ${NO_3}^-$의 농도 집적이 두드러졌다.

• 한국대기환경학회지
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• 제13권6호
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• pp.475-486
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• 1997

The characteristics of atmospheric aerosols were investigated as a function of particle size and water solubility. The atmospheric aerosols were sampled with classifying into 12 size ranges by the use of Andersen low-pressure impactor. Collected aerosol particles were extracted by ultrapure water and filtered to be separated into water-soluble and insoluble components. The concentrations 12 elements in both components were determined by PIXE analysis. And the concentrations of 8 ions in the soluble component were analyzed by ion chromatography. In general, the mass size distribution of particulate matter was represented as a bimodal distribution. The mass size distributions of S$(SO_4^{2-}), K(K^+), Zn and NH_4^+$ skewed to the smaller size range and those of Si, Ca$(Ca^{2+}), Fe, Na^+ and Mg^{2+}$ skewed to the larger size range. They had roughly one peak in the fine and coarse particle region,respectively. On the other hand, the mass size distribution of Ti, Mn, Ni, Cu, $Cl^- and NO_3^-$ were represented as the bimodal distribution. Fe and Si in the aerosol particles extracted into pure water are existing in high insoluble state. Conversely, almost the whole of S is dissolved in water.