• Title/Summary/Keyword: Water vapor permeability

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Development of Environmental Friendly Nanocomposites using Poly(lactic acid) and Nanomer®I.44P (Poly(lactic acid)와 Nanomer®I.44P를 이용한 친환경 나노복합체 개발)

  • Cho, Won-Ju;Whang, Key;Kim, Jun Tae
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.20 no.3
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    • pp.77-84
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    • 2014
  • Biodegradable nanocomposites were fabricated with poly (lactic acid) (PLA) and Nanomer$^{(R)}$ I.44P using ultrasonication (US). Processing conditions were optimized to obtain the maximum tensile properties of the nanocomposites. Poly (ethylene glycol) (PEG) was used as a plasticizer to avoid the brittleness of nanocompsoties. In order to disperse nanoclay into the PLA matrix, PEG and Nanomer$^{(R)}$ I.44P were firstly mixed and dispersed in the chloroform and followed by ultrasonication for 1 min With 10% PEG 400, tensile stress and Young's modulus of the nanocomposites decreased from 53.5 MPa and 2225 MPa to 37.0 MPa and 1757 MPa, respectively, while the elongation was increased from 4% to 21%. Tensile stress, Young's modulus, and elongation of nanocomposites were also increased with nanoclay concentration up to 2% (w/w) and were decreased with further increase in the nanoclay concentration. Transmittance of nanocomposites were significantly decreased from 62.5% for pure PLA film to 7.8% for 5% nanoclay containing nanocomposites. Water vapor permeability of the nanocomposites was also significantly decreased with nanoclay concentration and the minimum WVP of $3.5{\times}10^{-11}g{\cdot}m/m^2{\cdot}s{\cdot}Pa$ was obtained with 5% (w/w) nanoclay concentration. The PLA/Nanomer$^{(R)}$ I.44P nanocomposites showed a great potential as a environmental friendly food packaging material.

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Application of Edible Films to Food System Packaging (식품 포장재에 대한 가식성 필름의 응용성에 관한 연구)

  • Chun, Dong-Ho;Park, Jang-Woo
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.5 no.1
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    • pp.6-12
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    • 1999
  • This study was conducted to investigate the application of edible films to Raymyun soup packaging. The sorption isotherm curve and BET monolayer moisture content of Raymyun soup were estimated as a basic experiment. Also, the mechanical properties, water vapor permeability, and solubility of the films were investigated. Methylcellulose, sodium caseinate, and K-carrageenan films were used as edible films and glycerol and polyethylene glycol(MW 400) were used as plasticizers. In case tensile strength, methylcellulose films was 68.56 MPa and sodium caseinate film was 7.11 MPa. The elongations of sodium caseinate, methylcellulose, and K-carrageenan film were 115.41%, 23.79% and 0.60%, respectively. The water vapor permeabilties values of methylcellulose, sodium caseinate, and K-carrageenan film between 50% and 70% RH were $0.25-0.38ng{\cdot}m/m^2{\cdot}sec{\cdot}Pa,\;0.62-0.84ng{\cdot}m/m^2{\cdot}sec{\cdot}Pa\;and\;0.31-0.55ng{\cdot}m/m^2{\cdot}sec{\cdot}Pa$, respectively. For the solubility of films, sodium caseinate film showed the highest solubility and methylcellulose film showed the lowest solubility.

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Sorption Characteristics of Binary Mixture of Corn Starch- Soy Protein Isolates in Plastic film Packaging (Plastic필름 포장에 따른 옥수수 전분과 분리 대두단백질의 이성분 혼합물의 흡습특성)

  • Kim, Duck-Woong;Woo, Sang-Gyu
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.17 no.3
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    • pp.191-197
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    • 1988
  • Sorption properties of corn starch(CS) and Soy protein isolates(SPI) in plastic films packaging were investigates for binary system. The mixture were sealed in plastic films of low density polyethylene(LDPE), oriented polypropylene(OPP) and LDPE/OPP coated film and packaging effect on the changes of moisture sorption during storage at $40^{\circ}C$ were studied. The following results were obtained. The water vapor permeability of material films was $32.6g/m^2/24hrs(below\;g)$ for 0.02mm LDPE film, 14.01g for 0.04mm LDPE film, 7.30g for 0.02mm OPP film, 3.37g for 0.04mm OPP film and 4.869 for 0.02mm LDPE/0.02 mm OPP confine film at $40^{\cire}C$ 90%RH, therefore the OPP film was more effective than LDPE film on the resistance of relative humidity. And the OPP film packaging sealed mixture of food samples was also more elective then LDPE film, having same thickness for increase of water vapor permeability during storage at $40^{\cire}C$. A general increase in sorption rate was found more in SPI than CS in the packaged mixtures.

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Transport Properties of PEBAX Blended Membranes with PEG and Glutaraldehyde for SO2 and Other Gases (SO2와 다른 기체에 대한 PEG와 Glutaraldehyde가 혼합된 PEBAX 막의 투과 특성)

  • Cho, Eun Hye;Kim, Kwang Bae;Rhim, Ji Won
    • Polymer(Korea)
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    • v.38 no.6
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    • pp.687-693
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    • 2014
  • Poly(ether-block-amide) 1657 (PEBAX 1657) blended membranes with molecular weight 400 poly(ethylene glycol) (PEG 400) were prepared and their permeability was tested for the gases $N_2$, $O_2$, $CH_4$, $CO_2$, and $SO_2$ by the time-lag method. The permeation characteristics were investigated in terms of diffusivity and solubility, which are dominant factors for gas transport. With the addition of PEG 400, the permeability of all the gases increased and also the ideal selectivity for several pair gases was enhanced. In particular, selectivity for $CO_2/N_2$ ranged from 53.2 (pristine PEBAX 1657 membrane) to 84.1 (50% PEG 400 added), for $SO_2/CO_2$ from 38.9 to 50.7, and for $CO_2/CH_4$ from 17.7 to 31.4. The increase of both permeability and selectivity is mainly because of the increase of solubility of the gases, especially $CO_2$ and $SO_2$. To obtain durability against water vapor, glutaraldehyde (GA) was added to the PEBAX 1657/PEG 400 blended membranes. As a result, permeability decreased owing to a reduction of the free volume and ether oxide units, which are the main factors in elevating the permeability for the blended membranes, and selectivity decrease however; we believe that the durability of the resulting membranes would be increased.

Improvement of Water Resistant Properties of a Linerboard for Corrugated Fiberboard Box by Coating with Na-alginate (알긴산 코팅에 의한 골판지 상자 제조용 라이너 원지의 수분저항성 증진)

  • Kim, Eun-Jung;Rhim, Jong-Whan;Kim, Byung-Yong
    • Korean Journal of Food Science and Technology
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    • v.38 no.6
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    • pp.762-766
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    • 2006
  • To improve water resistance of paperboard used to manufacture the corrugated boxes, effect of surface coating of the liner- board with Na-alginate was investigated by determining the optimum processing conditions such as a optimum alginate concentration for surface coating, plasticizer content, concentration of divalent cations their immersion times, For the surface coating of the liner-board, 2.5% Na-alginate solution was found to be the optimum concentration, and the concentration of glycerol used as plasticizer was effective when 35% alginate concentration was use was Used Immersion of the alginate coated paperboard for 3 min in a $CaCl_2$ solution improved the water resistance properties. As a divalent cation for the insolubilization of the alginate films, $Cu^{2+}$ was found to be as effective as $Ca^{2+}$. Among the platicizers tested, sorbitol was the most effective in reducing water vapor permeability and water solubility of alginate coated paperboard.

Effect of Water Resistance and Physical Properties of Soy Protein Isolate coated Liner Board (대두단백 코팅 종이의 수분저항성 및 물리적 성질)

  • Ha, Sang-Hyung;Park, Cheon-Seok;Kim, Byung-Yong
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.35 no.9
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    • pp.1251-1255
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    • 2006
  • To improve the water resistance and physical properties of soy protein isolate (SPI)-coated paper, effects of concentrations of soy protein isolate and plasticizer were examined. Physical properties such as elongation strength (ES), elongation rate (E), water vapor permeability (WVP), and water solubility (WS) were evaluated. The film made from 5% soy protein isolate (SPI) and 40% glycerol (plasticizer) suggested a good application for a film preparation. SPI coated paper showed the highest ES (21.62 MPa) and the lowest WVP $(2.06ng{\cdot}m/m^2{\cdot}s{\cdot}Pa)$ and WS (1.17%). This study suggested that soy protein isolate (SPI) can be used as a coating material for the coated paper to improve the water resistance.

Comport Sensation of Blue Jeans depending on Fiber Contents (청바지의 소재별 쾌적감에 관한 연구)

  • 홍문경;이미식;권계화;전정애
    • Journal of the Korean Society of Clothing and Textiles
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    • v.25 no.2
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    • pp.237-248
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    • 2001
  • The purpose of this study was to compare the comfort sensation depending on four different kinds of denim blue jeans: cotton, cotton/tencel, tencel, cotton/pp. The objective and subjective experiments were conducted to measure the comfort of blue jeans. To investigate the objective comfort, physical properties related to thermal insulation, moisture properties and hand were measured. For subjective comfort measurement, 5 healthy female college students were taken as subjects. The outcomes of the experiments are as follows: The higher the air permeability and bulk density of the denim, the lower the thermal insulation, the thicker the denim, the higher the thermal insulation. Tencel blending denim showed the higher bulk density, the lower air contents, and consequently the lower thermal insulation than the other denims. Tencel showed the highest moisture regain, and cotton/tencel blend showed the highest water vapor permeability. Tencel denim had relatively better flexibility, shape stability and elastic recovery than the other denims. The total hand values of the denims by KES-FB system were not significantly different. Cotton and cotton/pp denims raised the subjects body temperature after excercise more than tencel or cotton/tencel denims. Average skin temperature was found to have a correlation with micro climate temperature and micro climate humidity. The correlation coefficients were 0.749 and 0.767, respectively. However, average skin temperatures were not significantly different among the materials. Pulse rate was found to be the highest when wearing cotton/pp and the lowest in case of cotton/tencel denim. The energy was consumed in order of cotton>cotton/pp>tencel>cotton/tencel. There was no significant difference in preference before excercise, but, after the excercise, the order of preference changed as the following; cotton/tencel>tencel>cotton/pp>cotton.

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Performance Evaluation of Protective Clothing Materials for Welding in a Hazardous Shipbuilding Industry Work Environment (조선업의 유해 작업환경 대응을 위한 용접 보호복 소재의 성능평가 연구)

  • Kim, Min Young;Bae, Hyun Sook
    • Fashion & Textile Research Journal
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    • v.15 no.3
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    • pp.452-460
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    • 2013
  • This study conducted a performance evaluation of protective clothing materials used for welding in a hazardous shipbuilding industry work environment. The welding process was selected as the one that most requires industrial protective clothing according to work environment characteristics. Flame proofing and convection heat protection performance (HTI) in the heat transfer characteristics of protective clothing material were indicated in the order of SW1(Oxidant carbon)>SW2(silica coated Oxidant carbon)>SW4(Oxidant carbon/p-aramid)>SW3(flame proofing cotton). However, radiant heat protection performance (RHTI) and the heat transfer factor (TF) were indicated in the order of SW1>SW4>SW2>SW3 and showed different patterns from the convection heat protection performance. SW1 showed superior air permeability and water vapor permeability. The tensile strength and tear strength of welding protective clothing material were indicated in the order of SW4>SW2>SW3>SW1 and showed that a blend fabric of p-aramid was the most superior for the mechanical properties of SW4. SW1 had excellent heat transfer properties in yet met the minimum performance requirements of tensile strength proved to be inappropriate as being a material for welding protective clothing. The abrasion resistance of woven fabric proved superior compared to nonwoven fabric; however, seam strength and dimensional change both met the minimum performance requirements and indicated that all samples appeared non-hazardous. Finally, oxidant carbon/p-aramid blend fabric appeared appropriate as a protective clothing materials for welding.

Study on the Fabric Trend in Hi-Tech Functional Active Sportswear (하이테크 기능성 액티브 스포츠웨어의 소재경향에 관한 연구)

  • Baik Cheon-Eui;Kim So-Young
    • Journal of the Korea Fashion and Costume Design Association
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    • v.7 no.1
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    • pp.55-63
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    • 2005
  • The outcome of modem sports events are reliant on not only the athletic ability and technology of individual players but their sportswear proterties. State-of-the-Hitech sportswear has started to be introduced in the 1950s, and in addition to the athletic capability of players, sportswear is one of the primary factors to affect the results of sports games, as a wide variety of Hi-Tech functional materials have come out since the 1990s. The purpose of this study was to development into the concept of active sportswear, to sort out hitech functional product lines in this field, to look into sports stars and Hi-Tech functional sports brands, and finally to identify the major characteristics of recent active sportswear. The result of this study were as follows: 1. There were largely four characteristics in recent functional sportswear materials: fast-drying cooling, minimized resistance, ultralight comfortableness, and water vapor permeable/waterproof function. 2. Besides the athletic capability and technology of players, Hi-Tech functional products are one of the major factors to determine the outcome of modem sports events. Functional synthetic fiber is preferred, instead of cotton, since the former is easier to manage and retains humidity better. 3. The major features of recent trend in active sportswear products are, functional, diversity and value. That is, those products are functional, since they are easy to manage and retain proper humidity, and they are for multipurpose, since they are fashionable and practical at the same time. And they are valuable, being expensive but appropriate for the movement of the body and having a high quality.

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Experiments on Sedimentation of Particles in a Water Pool with Gas Inflow

  • Kim, Eunho;Jung, Woo Hyun;Park, Jin Ho;Park, Hyun Sun;Moriyama, Kiyofumi
    • Nuclear Engineering and Technology
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    • v.48 no.2
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    • pp.457-469
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    • 2016
  • During the late phase of severe accidents of light water reactors, a porous debris bed is expected to develop on the bottom of the flooded reactor cavity after breakup of the melt in water. The geometrical configuration, i.e., internal and external characteristics, of the debris bed is significant for the adequate assessment of the coolability of the relocated corium. The internal structure of a debris bed was investigated experimentally using the DAVINCI (Debris bed research Apparatus for Validation of the bubble-Induced Natural Convection effect Issue) test facility. Particle sedimentation under the influence of a two-phase natural convection flow due to the decay heat in the debris bed was simulated by dropping various sizes of particles into a water vessel with air bubble injection from the bottom. Settled particles were collected and sieved to obtain the particle mass, size distribution in the radial and axial positions, and the bed porosity and permeability. The experimental results showed that the center part of the particle bed tended to have larger particles than the peripheral area. For the axial distribution, the lower layer had a higher fraction of larger particles. As the sedimentation progressed, the size distribution in the upper layers can shift to larger sizes because of the higher vapor generation rate and stronger flow intensity.