• 제목/요약/키워드: Water splitting

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Effect of using recycled coarse aggregate and recycled asphalt pavement on the properties of pervious concrete

  • Shatarat, Nasim K.;Katkhuda, Hasan N.;Hyari, Khaled H.;Asi, Ibrahim
    • Structural Engineering and Mechanics
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    • v.67 no.3
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    • pp.283-290
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    • 2018
  • This paper presents the results of a study that investigated the influence of using recycled coarse aggregate (RCA) and recycled asphalt pavement (RAP) on the properties of pervious concrete (PC). The natural aggregate (NA) was replaced by RCA and RAP in the PC with replacement levels of 0%, 20%, 40%, 60% and 80% by the total weight of NA, respectively. In addition to incorporating RAP and RCA in the same mixes with replacement levels of: (1) 20% RAP and 80% RCA; (2) 60% RAP and 40% RCA; and (3) 80% RAP and 20% RCA. Water permeability, thermal conductivity, density, porosity, void content, and compressive, splitting tensile and flexural strengths were studied in this paper. The results showed that using RCA, RAP, and (RAP-RCA) enhanced the properties of PC in general and improved the mechanical properties significantly in particular. The optimum mix was reported to be the 60% RAP and 40% RCA. Accordingly, the RAP has the potential to be used in PC in order to reduce the negative impact of RAP on the human health and environment.

Effect of Viscosity of Binder and[ Storage Times of Pelleted Seed on Physical and Germination Characteristics of Tobacco Seeds. (종자피복용 binder 점도와 피복후 저장기간이 종자의 발아에 미치는 영향)

  • 신승구;백기현;이승철;목성균
    • Journal of the Korean Society of Tobacco Science
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    • v.22 no.1
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    • pp.45-50
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    • 2000
  • In order to improve the sowing practice, pelleted seeds of tobacco NC 82(Nicotiana tobacco L.) were manufactured in use of binders at the different levels of viscosity, and their physical properties according to pellet size and biological activity in seed germination were investigated while storage time elapsed. Proper range of the binder viscosity for the pellet formation was 20.3-37.2 m.pas. At the high level of viscosity(45.7 m.pas) took longer time to form the pellet and pelleting was not easy. The high binder viscosity and large pellet size revealed higher level in hardness of the pelleted tobacco seeds, which caused the longer splitting time of pellets in water. High level of binder viscosity(37.2 m.pas) in pelleted seeds led to decrease the biological activity of tobacco seed germination by the storage at 4 t over 30 days. But at the level of 20.3m.pas in binder viscosity, the germination of pelleted seeds was little affected by the long storage time to 120 days.

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Comparison of Toxic Effects of Mercury, Copper and Zinc on Photosystem II of Barley Cholroplasts (보리 엽록체의 광계 II에서 수은, 구리 및 아연의 저해효과 비교)

  • 전현식
    • Journal of Plant Biology
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    • v.36 no.3
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    • pp.195-201
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    • 1993
  • The room temperature fluorescence induction of chloroplasts was utilized as a probe to locate the site of inhibition by mercury, copper and zinc on PS II by mercury. Inhibitory effect of Hg2+ on electron transport activity was notable as compared with Cu2+ and Zn2+. At concentrations of HgCl2 over 50 $\mu$M, activities of PS II and whole-chain electron transport decreased more than 70%, while that of PS I decreased about 10~30%. This suggests that PS II is more susceptible to Hg2+ than PS I is. In the presence of diphenylcarbazide (DPC), 50 $\mu$M HgCl2 inhibited the reduction of dichlorophenolindophenol (DCPIP) about 50%. Addition of heavy metals induced marked decrease in maximal variable fluorescence/initial fluorescence [(Fv)m/Fo], but no changes in Fo. With various concentrations of heavy metals, changes of chlorophyll a fluorescence emitted by PS II showed gradual decrease in photochemical quenching (qQ), which indicates an increase in reduced state of electron acceptor, QA. Especially, the addition of HgCl2 caused a notable decrease of qQ. In the presence of 50 $\mu$M CuCl2, energy-depended quenching (qE) was completely reduced, whereas in the presence of 50 $\mu$M CuCl2 and ZnCl2 it was still remained. The above results are discussed on the effects of mercury in relation to water-splitting system and plastoquinone (PQ) shuttle system.

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Photocatalytic Performance of Barium-doped Strontium Tantalate

  • Kozu, Asuka;Fujimori, Hirotaka;Kim, Ki-Young;Oshiro, Kazunori;Yamamoto, Setsuo;Sakata, Yoshihisa;Imamura, Hayao
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.926-927
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    • 2006
  • [ $Sr_2Ta_2O_7$ ], a layered perovskite compound, has been reported to possess most excellent photocatalytic properties among the layered perovskite materials. Recently, we have demonstrated that $Ba_5Ta_4O_{15}$ that was prepared under a mol ratio of Ba: Ta=1:1 has high photocatalytic performance as well as $Sr_2Ta_2O_7$. In this study, the photocatalyst samples with a mol ratio of Sr: Ba: Ta = (1-x): x: 1 were prepared. The maximum photocatalytic performance was obtained for x= 0.2, which is three times as high as that of undoped $Sr_2Ta_2O_7$.

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Concrete Test for Creep and Shrinkage Properties on High Strength Concrete (고강도 콘크리트 크리프 및 건조수축 특성을 위한 재료실험)

  • Moon, Hyung-Jae;Cha, Han-Il;Seok, Won-Kyun;Park, Soon-Jeon
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.857-860
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    • 2008
  • This study shows systematic procedures for investigating creep and shrinkage properties of 50, 60, 70 MPa concrete mixes, which were developed by Lotte E&C R&D Ins. for Lotte Super Tower Jamsil. The concrete test was performed both local and foreign laboratory, S-Lab. and CTL Group respectively. The former have done for total five days. The procedures included the followings, specimen fabrication, mold removal, specimen marking, water bath curing, packaging, and shipment. The latter has been doing by CTL within PCA(Portland Cement Association). They are testing on static and dynamic modulus of elasticity, compressive strength, creep & shrinkage, splitting tensile strength. In the case of creep and shrinkage, the test will be doing for 18 months according to each loading age.

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Reduced Titania Films with Ordered Nanopores and Their Application to Visible Light Water Splitting

  • Shahid, Muhammad;Choi, Seo-Yeong;Liu, Jingling;Kwon, Young-Uk
    • Bulletin of the Korean Chemical Society
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    • v.34 no.8
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    • pp.2271-2275
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    • 2013
  • We report on the photoelectrochemical properties of partially reduced mesoporous titania thin films. The fabrication is achieved by synthesizing mesoporous titania thin films through the self-assembly of a titania precursor and a block copolymer, followed by aging and calcination, and heat-treatment under a $H_2$ (1 torr) environment. Depending on the temperature used for the reaction with $H_2$, the degree of the reduction (generation of oxygen vacancies) of the titania is controlled. The oxygen vacancies induce visible light absorption, and decrease of resistance while the mesoporosity is practically unaltered. The photoelectrochemical activity data on these films, by measuring their photocurrent-potential behavior in 1 M NaOH electrolyte under AM 1.5G 100 mW $cm^{-2}$ illumination, show that the three effects of the oxygen vacancies contribute to the enhancement of the photoelectrochemical properties of the mesoporous titania thin films. The results show that these oxygen deficient $TiO_2$ mesoporous thin films hold great promise for a solar hydrogen generation. Suggestions for the materials design for improved photoelectrochemical properties are made.

Absorption Spectra of a Methylene blue-Tetraphenylborate Ion Pair (Methylene Blue-Tetraphenylborate 이온쌍의 흡수스펙트럼)

  • Hyung-Soo Song;Young Joon Park;Kang-Jin Kim
    • Journal of the Korean Chemical Society
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    • v.28 no.6
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    • pp.355-360
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    • 1984
  • A new absorption spectrum observed from dilute aqueous solutions of methylene blue$(MB^+)$ and tetraphenylborate(TPB$^-$) ions was investigated by spectrophotometry. The species responsible for the spectrum can be a charge-transfer complex formed between the two, univalent, and poorly hydrated ions in order to minimize the disturbance to the water structure. However, as the absorption band of MB$^+$ is split into two bands with exciton splitting of about 2,000 cm$^{-1}$, the formation of double ion-pair, (MB-TPB)$_2$ appears to be more favorable than the charge transfer complex.

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Simulation Based Investigation of Focusing Phased Array Ultrasound in Dissimilar Metal Welds

  • Kim, Hun-Hee;Kim, Hak-Joon;Song, Sung-Jin;Kim, Kyung-Cho;Kim, Yong-Buem
    • Nuclear Engineering and Technology
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    • v.48 no.1
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    • pp.228-235
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    • 2016
  • Flaws at dissimilar metal welds (DMWs), such as reactor coolant systems components, Control Rod Drive Mechanism (CRDM), Bottom Mounted Instrumentation (BMI) etc., in nuclear power plants have been found. Notably, primary water stress corrosion cracking (PWSCC) in the DMWs could cause significant reliability problems at nuclear power plants. Therefore, phased array ultrasound is widely used for inspecting surface break cracks and stress corrosion cracks in DMWs. However, inspection of DMWs using phased array ultrasound has a relatively low probability of detection of cracks, because the crystalline structure of welds causes distortion and splitting of the ultrasonic beams which propagates anisotropic medium. Therefore, advanced evaluation techniques of phased array ultrasound are needed for improvement in the probability of detection of flaws in DMWs. Thus, in this study, an investigation of focusing and steering phased array ultrasound in DMWs was carried out using a time reversal technique, and an adaptive focusing technique based on finite element method (FEM) simulation. Also, evaluation of focusing performance of three different focusing techniques was performed by comparing amplitude of phased array ultrasonic signals scattered from the targeted flaw with three different time delays.

Photoelectrochemical Properties of Electrodeposited Cu2O Photocathode with Tailored Microstructures (미세구조가 제어된 전해도금 Cu2O 광양극의 광전기화학 특성)

  • Jeong, Dasol;Jo, Woohyeon;Jeong, Jaebum;Jung, Hyunsung
    • Journal of Surface Science and Engineering
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    • v.53 no.5
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    • pp.232-240
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    • 2020
  • Cu2O films as a photocathode for photoelectrochemical water splitting were potentiostatically deposited on FTO glasses. The morphology and composition of the electrodeposited Cu2O films were adjusted by the applied potentials. The potential-dependent grain size of Cu2O films was characterized by XRD and SEM analysis. Photoelectrochemical properties of the fabricated Cu2O photocathodes were investigated with photocurrents as a function of potentials under 1 sun condition of 100mW/㎠. Photocurrents of the electrodeposited Cu2O films were controlled with the tailored surface morphologies of Cu2O photocathodes.

H2-MHR PRE-CONCEPTUAL DESIGN SUMMARY FOR HYDROGEN PRODUCTION

  • Richards, Matt;Shenoy, Arkal
    • Nuclear Engineering and Technology
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    • v.39 no.1
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    • pp.1-8
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    • 2007
  • Hydrogen and electricity are expected to dominate the world energy system in the long term. The world currently consumes about 50 million metric tons of hydrogen per year, with the bulk of it being consumed by the chemical and refining industries. The demand for hydrogen is expected to increase, especially if the U.S. and other countries shift their energy usage towards a hydrogen economy, with hydrogen consumed as an energy commodity by the transportation, residential and commercial sectors. However, there is strong motivation to not use fossil fuels in the future as a feedstock for hydrogen production, because the greenhouse gas carbon dioxide is a byproduct and fossil fuel prices are expected to increase significantly. An advanced reactor technology receiving considerable international interest for both electricity and hydrogen production, is the modular helium reactor (MHR), which is a passively safe concept that has evolved from earlier high-temperature gas-cooled reactor (HTGR) designs. For hydrogen production, this concept is referred to as the H2-MHR. Two different hydrogen production technologies are being investigated for the H2-MHR; an advanced sulfur-iodine (SI) thermochemical water splitting process and high-temperature electrolysis (HTE). This paper describes pre-conceptual design descriptions and economic evaluations of full-scale, nth-of-a-kind SI-Based and HTE-Based H2-MHR plants. Hydrogen production costs for both types of plants are estimated to be approximately $2 per kilogram.