• Journal of Biosystems Engineering
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• v.41 no.2
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• pp.75-84
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• 2016

Purpose: In-situ water quality monitoring based on ion-selective electrodes (ISEs) is a promising technique because ISEs can be used directly in the medium to be tested, have a compact size, and are inexpensive. However, signal drift can be a major concern with on-line management systems because continuous immersion of the ISEs in water causes electrode degradation, affecting the stability, repeatability, and selectivity over time. In this study, a computer-based nitrate monitoring system including automatic electrode rinsing and calibration was developed to measure the nitrate concentration in water samples in real-time. Methods: The capabilities of two different types of poly(vinyl chloride) membrane-based ISEs, an electrode with a liquid filling and a carbon paste-based solid state electrode, were used in the monitoring system and evaluated on their sensitivities, selectivities, and durabilities. A feasibility test for the continuous detection of nitrate ions in water using the developed system was conducted using water samples obtained from various water sources. Results: Both prepared ISEs were capable of detecting low concentrations of nitrate in solution, i.e., 0.7 mg/L $NO_3-N$. Furthermore, the electrodes have the same order of selectivity for nitrate: $NO_3{^-}{\gg}HCO_3{^-}$ > $Cl^-$ > $H_2PO_4{^-}$ > $SO{_4}^{2-}$, and maintain their sensitivity by > 40 mV/decade over a period of 90 days. Conclusions: The use of an automated ISE-based nitrate measurement system that includes automatic electrode rinsing and two-point normalization proved to be feasible in measuring $NO_3-N$ in water samples obtained from different water sources. A one-to-one relationship between the levels of $NO_3-N$ measured with the ISEs and standard analytical instruments was obtained.

• Journal of Fisheries and Marine Sciences Education
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• v.27 no.1
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• pp.253-261
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• 2015

The chemical water quality and fish assemblage of Dong Stream to assessment of environmental improvement after discharge seawater were investigated from July to December 2013. BOD and DO were significantly different between before and after discharge seawater, while pH and SS did not significant. A total of 11 fish species, 218 individuals and 10,525.1g were collected. Dominant fish species were Mugil cephalus, Konosirus punctatus, Acanthogobius flavimanus and Leiognathus nuchalis which account for 77.5% of total individuals collected, and they were estuarian species. Peak number of species and individuals, and biomass occurred in September, whereas diversity index were highest in November. The water ecosystem of Dong Stream have been changed estuarian environment. As a result of stream assessment on water quality and ecosystem, water quality have been improved as 'III' grade. These results suggested that stream restoration policies such as drain pipes maintenance, management of pollution sources and riverbed dredging to improve environment and recover habitate of Dong Stream were need for set up and establishment of regular monitoring system.

• Journal of Biosystems Engineering
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• v.42 no.4
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• pp.350-357
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• 2017

Purpose: In-situ monitoring of water quality is fundamental to most environmental applications. The high cost and long delays of conventional laboratory methods used to determine water quality, including on-site sampling and chemical analysis, have limited their use in efficiently managing water sources while preventing environmental pollution. The objective of this study was to develop an on-site water monitoring system consisting mainly of an Arduino board and a sensor array of multiple ion selective electrodes (ISEs) to measure the concentration of $NO_3$ ions. Methods: The developed system includes a combination of three ISEs, double-junction reference electrode, solution container, sampling system consisting of three pumps and solenoid valves, signal processing circuit, and an Arduino board for data acquisition and system control. Prior to each sample measurement, a two-point normalization method was applied for a sensitivity adjustment followed by an offset adjustment to minimize the potential drift that could occur during continuous measurement and standardize the response of multiple electrodes. To investigate its utility in on-site nitrate monitoring, the prototype was tested in a facility where drinking water was collected from a water supply source. Results: Differences in the electric potentials of the $NO_3$ ISEs between 10 and $100mg{\cdot}L^{-1}$ $NO_3$ concentration levels were nearly constant with negative sensitivities of 58 to 62 mV during the period of sample measurement, which is representative of a stable electrode response. The $NO_3$ concentrations determined by the ISEs were almost comparable to those obtained with standard instruments within 15% relative errors. Conclusions: The use of the developed on-site nitrate monitoring system based on automatic sampling and two-point normalization was feasible for detecting abrupt changes in nitrate concentration at various water supply sites, showing a maximum difference of $4.2mg{\cdot}L^{-1}$ from an actual concentration of $14mg{\cdot}L^{-1}$.

• International Journal of Contents
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• v.7 no.1
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• pp.45-51
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• 2011

To protect water pollution and scarcity in lake and river, water quality monitoring applications have become important tools to understand the change of aquatic ecosystem. KLEON (Korean Lake Ecological Observatory Network) is designed to manage and share the ecological observations. The various kinds of water quality and phytoplankton observations are collected from the selected observatories such as seven lakes/rivers/wetlands. To deeply understand the collected observations with weather, KLEON also manages the observatory information such as lake, dam, floodgate, and weather. The accumulated observation and analyzed results are used to improve the water quality index of the observatories and encourage the ecologists' cooperation.

• Journal of Korean Society on Water Environment
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• v.26 no.4
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• pp.700-706
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• 2010

Along the 4 major rivers in korea, there are automatic water quality monitoring (AWQM) stations to immediately respond to any pollution incident. Real-time data (temperature, DO, pH, EC and TOC) collected at each station were statistically treated to exclude outliers and keep valid data using Dixon's test and Discordance test. These applied methods were compared in terms of the number of the outliers sorted out. There was no significant difference between these methods. On the other hand, more outliers were sorted out from EC and TOC data, comparing with other water quality items. EC data did not show partly any variation for a long time at H station. If measured signal does not exceed ${\pm}0.001mS/cm$ from the sectional mean, the signal should be treated as normal data. Therefore, another routine was added to the data screening system, some data which were removed as outlier were restored.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2003.06a
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• pp.1097-1100
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• 2003

Data Loggers for environmental monitoring are mostly dispersion in installation and systems located at long distance from monitoring system. And, it requests mostly flexible functions and high performances. that can fit to various sensor inputs, sensor interfaces and conditions or system working. In this research, we developed the micro controller based Data Logger with minimum hardware construction that allows the higher flexibility of application. Finally, we developed software function for water quality monitoring and tested in real system launched at Han river.

• Journal of Korean Society on Water Environment
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• v.21 no.6
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• pp.651-658
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• 2005

The Non-parametric Analysis is powerful in data test especially for the non- normality water quality data. The data at three monitoring stations of the Tam-Jin River were evaluated for their normality using Skewness, Q-Q plot and Shapiro-Willks tests. Various constituent of water quality data including temperature, pH, DO, SS, BOD, COD, TN and TP in the period of January 1994 to December 2004 were used as dataset. Shapiro-Willks normality test was carried out for a test 5% significance level. Most water quality data except DO at monitoring stations 1 and 2 showed that data does not normally distributed. It is indicating that non-parametric method must be used for a water quality data. Therefore, a homogeneity was conducted by Mann-Whitney U test (p<0.05). Two stations were paired in three pairs of such stations. Differences between stations 1, 2 and stations 1, 3 for pH, BOD, COD, TN and TP were meaningful, but Tam-Jin 2 and 3 stations did not meaningful. In addition, a narrow gap of the water quality ranges is not a difference. Categories in which all three pairs of stations (1 and 2, 2 and 3, 1 and 3) in the Tam-Jin River showed difference in water quality were analyzed on TN and TP. The results of in this research suggest a right analysis in the homogeneity test of water quality data and a reasonable management of pollutant sources.

• Magazine of the Korean Society of Agricultural Engineers
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• v.44 no.5
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• pp.96-105
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• 2002

As an useful water purification system for non-point source pollution in rural watersheds, interests in constructed wetlands are growing at home and abroad. It is well known that constructed wetlands are easily installed, no special managemental needs, and more flexible at fluctuating influent loads. They have a capacity for purification against nutrient materials such as phosphorus and nitrogen causing eutrophication of lentic water bodies. The Constructed Wetland Design Model (CWDM), developed through this study is consisted mainly of Database System, Runoff-discharge Prediction Submodel, Water Quality Prediction Submodel, and Area Assessment Submodel. The Database System includes data of watershed, discharge, water quality, pollution source, and design factors for the constructed wetland. It supplies data when predicting water quality and calculating the required areas of constructed wetlands. For the assessment of design flow, the GWLF (Generalized Watershed Loading Function) is used, and for water quality prediction in streams estimating influent pollutant load, Water Quality Prediction Submodel, that is a submodel of DSS-WQMRA model developed by previous works is amended. The calculation of the required areas of constructed wetlands is achieved using effluent target concentrations and area calculation equations that developed from the monitoring results in the United States. The CWDM is applied to Bokha watershed to appraise its application by assessing design flow and predicting water quality. Its application is performed through two calculations: one is to achieve each target effluent concentrations of BOD, SS, T-N and T-P, the other is to achieve overall target effluent concentrations. To prove the validity of the model, a comparison of unit removal rates between the calculated one from this study and the monitoring result from existing wetlands in Korea, Japan and United States was made. As a result, the CWDM could be very useful design tool for the constructed wetland in rural watersheds and for the non-point source pollution management.

• Journal of Korean Society of Environmental Engineers
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• v.33 no.8
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• pp.617-622
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• 2011

The policy of total maximum daily load (TMDL) was introduced to manage wasteload within the loading capacity to achieve water quality standards in the watershed. While the TMDL was implemented, the institutional and technical correction for the improvement of procedure was accomplished even though there were various problems and basically through the process of trial & error. However, a fundamental improvement of this policy is needed to implement the TMDL. This study has come up with a new viewpoint on improving this procedure for reasonable implementation of TMDL. First of all, the water quality and flowrate monitoring of the tributaries should be implemented. This should be done through the establishment of a monitoring system which will include standards of scope, a set time period, water quality parameters and frequency follow ups for the implementation of TMDL. The basic plan in all of the watersheds should be developed based on the establishment of water quality parameters and standards for water use and ecological purposes according to the results of the water quality and flowrate monitoring in the watersheds. The implementation plan for water quality improvement should be established in the watersheds where exceeds the targeted water quality standards. The performance assessment of TMDL should be conducted every year to meet the satisfaction assessment of water quality standards in the watersheds. Finally, if the water quality standards in the watersheds can not be attained or the water quality parameters and standards should be changed, the implementation procedure will be performed according to the iterative process. On the contrary, the policy of TMDL in the watersheds where the water quality standards have been met the goal will be finished.

• Spatial Information Research
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• v.10 no.1
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• pp.45-59
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• 2002

The author argues that the current Government Information System for river water quality appears to be non-user friendly due to lack of the cartographic representation for the field monitoring data. Acknowledging these constraints, an operational, user-friendly information system has been developed by combining Internet technology with GIS. A digital map for water quality has been generated by overlaying monitoring data on existing cartographic data such as road, topography and administrative boundary etc. A user interface was designed to address the need to querry the large spatial databases by non-GIS and non-environmental experts. The system has been checked experimentally and enabled the users to querry data required simply. And detailed visual maps for water quality can be generated over large areas quickly and easily. A visual mapping system for water quality was developed by reframing the monitoring data as graphic symbols and it was ideally suited to exploring area-wide water quality at a user-friendly manner due to extensibility and scalability along the various survey points. This system based on Web GIS could be accessed anywhere if internet is available. It would play a crucial role in improving the quality of public information service if it is operationally introduced into the Government since the highly user-friendly interface provides a completely new means for disseminating information far water pollution in a visual and interactive manner to the general public.