• Title/Summary/Keyword: Water quality analyze

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Examination about evaluation method of odor active compounds in evaporator by using condensed water (응축수를 이용한 냉각기의 냄새원인물질 평가방법 검토)

  • Kim, Sun-Hwa;Kim, Kyung-Hwan;Jung, Young-Rim;Kim, Man-Goo;Kim, Jae-Ho;Park, Ha-Young;Ji, Yong-Jun
    • Analytical Science and Technology
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    • v.20 no.5
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    • pp.361-369
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    • 2007
  • Uncomfortable odor emitted from air conditioning system is the main cause of indoor air quality deterioration. To solve evaporator odor problems, odor active compounds, have to be identified then the quality of the product can be improved its quality. Because evaporator odor in exhaust gas has low odor intensity and discontinuity, it is very difficult to collect and analyze sample. In this study through the identification of odor compounds in condensed water, the evaluation of the eraporator was tested. Odor compounds were extracted from water by headspace-solid-phase microextraction (HS-SPME) method. The single odor was separated by GC/FID/Olfactometry (GC/FID/O) and odor active compounds were identified by GC/AED and GC/MS. Compared to air sample, result of sensory evaluation and the single odor compound appeared similarly. It was identified that odor active compounds have functional group containing oxygen such as alcohols and acids. Evaluation method of odor active compounds using condensed water in evaporator appeared effective on the side of simplicity of collection, low expanse and rapid analysis.

Development of water quality and aquatic ecosystem model for Andong lake using SWAT-WET (SWAT-WET을 이용한 안동호의 수질 및 수생태계 모델 구축)

  • Woo, Soyoung;Kim, Yongwon;Kim, Wonjin;Kim, Sehoon;Kim, Seongjoon
    • Journal of Korea Water Resources Association
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    • v.54 no.9
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    • pp.719-730
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    • 2021
  • The objective of this study is to develop the water quality and aquatic ecosystem model for Andong lake using SWAT-WET (Soil and Water Assessment Tool-Water Ecosystem Tool) and to evaluate the applicability of WET. To quantify the pollutants load flowing into Andong lake, a watershed model of SWAT was constructed for Andong Dam basin (1,584 km2). The calibration results for Dam inflow and water quality loads (SS, T-N, T-P) were analyzed that average R2 was more than 0.76, 0.69, 0.84, and 0.60 respectively. The calibrated SWAT results of streamflow and nutrients concentration was used into WET input data. WET was calibrated and validated for water temperature, dissolved oxygen, and water quality concentration (T-N, T-P) of Andong lake. The WET calibrated results was analyzed that PBIAS was +19%, -13%, +4%, and +26.5% respectively and showed that it was simulated to a significant level compared with the observation data. The observed dry weight (gDW/m2) of zoobenthos was less than 0.5, but the average value of simulation was analyzed to be 0.8, which is because the WET model considers zoobenthos with a broader concept. Although accurate calibration is difficult due to the lack of observed data, SWAT-WET can analyze the effects of environmental change in the upstream watershed on the lake based on long-term simulation based on watershed model. Therefore, the results of this study can be used as basic data for managing the aquatic environment of Andong lake.

Comparison of ACFAS method and DNPH-LC method for quantitative analysis of formaldehyde in Drinking water (자동연속흐름-흡광광도법과 DNPH-LC법에 의한 먹는물 중 포름알데히드 정량분석 비교)

  • Yi, Geon-Ho;Yun, In-Chul;Kim, Yeong-Kwan;Kim, Chong-Chaul;Choi, Geum-Jong;Lee, Teak-Soo
    • Journal of Korean Society of Water and Wastewater
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    • v.27 no.6
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    • pp.827-836
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    • 2013
  • Due to the stringent drinking water quality, formaldehyde will be included in Korean drinking water standard from year 2014. However, its standard analytical method has not yet been established. This study compares two analytical methods, DNPH-LC and ACFAS with respect to their analysis principles, Method Detection Limit (MDL), Limit Of Quantitation(LOQ), precision, accuracy, reproducibility, convenience, number of samples analyzed per hour and analysis cost. These methods measure absorption intensity at 360 nm by using HPLC after DNPH-derivatization (DNPH-LC) and at 410 nm by using Automated Continuous Flow Absorption Spectrophotometer (ACFAS), respectively. Reproducibility was tested by repeating the analysis 7 times using a standard solution for each method. For DNPH-LC method, MDL was $0.5{\mu}g/L$, LOQ was $1.58{\mu}g/L$ with standard deviation of $0.16{\mu}g/L$. For ACFAS method, they were $0.27{\mu}g/L$, $0.85{\mu}g/L$L with standard deviation of $0.09{\mu}g/L$, respectively. Both methods satisfied the requirement set by the Korean drinking water quality standard. Complexity of sample pretreatment procedure for DNPH-LC method may cause large error and, consequently, the analytical result will depend on the level of skill of analyst. In contrast, ACFAS method which used only one reagent equipped with an automated injection device showed little analytical error. It costs about $5.00 and $1.00 for one sample to analyze by the DNPH-LC method and the ACFAS method, respectively. Compared to the DNPH-LC method, ACFAS method provided more reliable analytical results. In terms of convenience, easiness and analytical cost, ACFAS method was demonstrated to be superior to the DNPH-LC method. The results of this study suggested that the ACFAS method could be adapted as a proper method for determining formaldehyde content in drinking water.

Analysis of Geosmin and 2-MIB in Water by Stir Bar Sorptive Extraction (SBSE) and GC/MS (교반막대추출법(SBSE)과 GC/MS를 이용한 수중의 Geosmin과 2-MIB의 분석)

  • Lee, Hwa-Ja;Kang, Lim-Seok
    • Journal of Korean Society of Environmental Engineers
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    • v.31 no.1
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    • pp.64-69
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    • 2009
  • Musty and earth odors caused by geosmin and 2-MIB are the major complaints from the drinking water consumers. Therefore, early detection of geosmin and 2-MIB is the key to prevent off-flavor occurrence. In this study, a rapid method using stir bar sorptive extraction (SBSE) in combination with the GC/MS was investigated to analyze geosmin and 2-MIB in water. The SBSE method, a solventless extraction technique, was optimized and then applied to the analysis of geosmin and 2-MIB in water. The SBSE technique was found to be a simple and fast procedure that allows many samples to be extracted simultaneously using very small volume (10~20 mL). In addition, the SBSE method offered high recovery and good linear regression coefficient for the geosmin and 2-MIB. The good repeatability of this method can be deduced from the low RSD (7.2~7.6%) at 10 ng/L for geosmin and 2-MIB. The limit of detection was determined 1~2 ng/L and the limit of quantitation was 3~6 ng/L. Above all, the SBSE method proved to be a very practical technique for the analysis of geosmin and 2-MIB in water.

Impact of the Mekong River Flow Alteration on the Tonle Sap Lake in Cambodia

  • Lee, Giha;Kim, Joocheol;Jung, Kwansue;Lee, Hyunseok
    • Proceedings of the Korea Water Resources Association Conference
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    • 2015.05a
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    • pp.231-231
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    • 2015
  • Rapid development in the upper reaches of the Mekong River, in the form of construction of large hydropower dams and reservoirs, large irrigation schemes, and rapid urban development, is putting water resources under stress. Many scientific reports have pointed out that cascade dams along the Mekong River lead to serious problems: not only hydrologically but also a decline of agricultural productivity due to a decrease of sediment supply in the Mekong Delta and a change of fish amount due to drastic change of the water environment. Cambodia and Vietnam, located in the lowest Mekong basin, are gravely affected by radical changes of hydrologic regime due to Mekong River developments. In particular, the Tonle Sap Lake in Cambodia is very sensitive to the flood cycle and flow variation of the Mekong River as well as inflow water quality from the Mekong River. More than 50% of Cambodian GDP depends on the primary industries such as agriculture, fishing, and forestry, and the Tonle Sap Lake plays an important role to support the national economy in Cambodia. In addition, Cambodian people usually take nourishment from the fish of Tonle Sap Lake. This research aims to assess the impacts of the Mekong river flow alternation on the hydrologic regime of the Mekong River - Tonle Sap Lake. We carried out rainfall-runoff-inundation simulation using CAESER-LISFLOOD for integrated water resource management in the Tonle Sap Basin and then analyze flood inundation variation of the Tonle Sap Lake due to the scenarios. Furthermore, the simulated inundation maps were compared to MODIS satellite images for model verification and hydrologic prediction.

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Characterizing Spatiotemporal Variations and Mass Balance of CO2 in a Stratified Reservoir using CE-QUAL-W2 (CE-QUAL-W2를 이용한 성층 저수지에서 CO2의 시공간적 분포 및 물질수지 분석)

  • Park, Hyungseok;Chung, Sewoong
    • Journal of Korean Society on Water Environment
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    • v.36 no.6
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    • pp.508-520
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    • 2020
  • Dam reservoirs have been reported to contribute significantly to global carbon emissions, but unlike natural lakes, there is considerable uncertainty in calculating carbon emissions due to the complex of emission pathways. In particular, the method of calculating carbon dioxide (CO2) net atmospheric flux (NAF) based on a simple gas exchange theory from sporadic data has limitations in explaining the spatiotemporal variations in the CO2 flux in stratified reservoirs. This study was aimed to analyze the spatial and temporal CO2 distribution and mass balance in Daecheong Reservoir, located in the mid-latitude monsoon climate zone, by applying a two-dimensional hydrodynamic and water quality model (CE-QUAL-W2). Simulation results showed that the Daecheong Reservoir is a heterotrophic system in which CO2 is supersaturated as a whole and releases CO2 to the atmosphere. Spatially, CO2 emissions were greater in the lacustrine zone than in the riverine and transition zones. In terms of time, CO2 emissions changed dynamically according to the temporal stratification structure of the reservoir and temporal variations of algae biomass. CO2 emissions were greater at night than during the day and were seasonally greatest in winter. The CO2 NAF calculated by the CE-QUAL-W2 model and the gas exchange theory showed a similar range, but there was a difference in the point of occurrence of the peak value. The findings provide useful information to improve the quantification of CO2 emissions from reservoirs. In order to reduce the uncertainty in the estimation of reservoir carbon emissions, more precise monitoring in time and space is required.

Researched and Analyzed Variables for Pollution Waters around the "Kosova B" Thermal Power Plant

  • Musliu, Adem;Musliu, Arber;Baftiu, Naim
    • International Journal of Computer Science & Network Security
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    • v.22 no.9
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    • pp.109-116
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    • 2022
  • The energy corporation of Kosovo continuously monitors and analyzes the impact of its own activities on the environment. Regarding the environmental situation, energy corporation of Kosovo- ECK regularly informs and reports objectively to the competent state institutions, local municipal institutions and interested parties. ECK, through numerous contacts with the competent authorities, firstly with different ministers, harmonizes the positions regarding environmental issues in the direction of achieving certain environmental standards or legal requirements in order to gradually be in accordance with them, based on the real possibilities, especially the financial ones. From this point of view, the environmental issue is very sensitive, quite complex and represents one of the biggest challenges of society currently and in the future. The researched variables show a continuous increase in the need for electricity production in Kosovo and this increase in production conditions a wide range of environmental impacts both at the local, regional and global levels. The aim of the work is to reduce the emission of pollutants through the main variables without inhibiting the economic development of the country, i.e. to bring the pollution as a result of the activities of the ECK operation into compliance with the permitted environmental norms. As a result of ECK's operational activities, the following follows: Air pollution mainly as a result of emissions from TCs in the air, transport, etc. Water pollution - as a result of technological water discharges, Land degradation - as a result of surface mining activities of the entire mining area. The purpose of the paper is to research and analyze the main water variables in the area of the Kosova B power plant, which is to determine the degree of their pollution from the activities of the power plants, as well as to assess the real state of surface water quality and control the degree of pollution of these waters. Methodology of the work: The analyzes of the water samples were done in the company Institute "INKOS" JSC by simultaneous methods using different reagents.

A Pilot Study on Environmental Understanding and Estimation of the Nak-Dong River Basin Using Fuyo-1 OPS Data (Fuyo-1 OPS 자료를 이용한 낙동강 하류지역의 환경계측 시고)

  • Kim, Cheon
    • Korean Journal of Remote Sensing
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    • v.12 no.2
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    • pp.169-198
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    • 1996
  • The objectives of this investigation are : 1. To analyze spectral signature and the associated vegetation index for geometric illumination conditions inf1uenced by low solar elevation and high slope orientations in mountainous forest. 2. To assess the accuracy of the spectral angle mapper classification for the a winter land cover in comparison with the maximum likelihood classification. 3. To produce the image of water quality and water properties that could be used to estimate the water pollution sources and the tide-included by turbid water in estuarine and coastal areas. These objectives are to characterize environmental and ecological monitoring applications of the Nak-Dong River Basin by using Fuyo-1 OPS VNIR data acquired on December 26, 1992. The results of this paper are as follows : 1. The spectral digital numbers and vegetation indexes (NDVI and TVI) of mountainous forest are higher on the slope facing the sun than on the slope hidden the sun under low sun elevation condition. 2. The spectral angle mapper algorithm produces a more accurate land cover classification of areas with steep slope, various aspects and low solar elevation than the maximum likelihood classifier. 3. The maximum likelihood classification images can be used for identifying the location and movement of both freshwater and salt water, regardless of geometric illumination conditions. 4. The color-coded density sliced image of selected water bodies by using the near-infrared band 3 can provide distribution of the water quality of the Lower Nak-Dong River. 5. The color-coded normalized difference vegetation index image of the selected mountain forest is suitable to classify winter vegetation cover types, i.e., forest canopy densities for slope orientations.

Quality Characteristic and Optimization of Iced Cookie with Addition of Jinuni bean(Rhynchosia volubilis) (쥐눈이콩(鼠目太) 첨가 냉동쿠키의 품질특성 및 최적화)

  • Ko, Young-Joo;Joo, Na-Mi
    • Korean journal of food and cookery science
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    • v.21 no.4 s.88
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    • pp.514-527
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    • 2005
  • The purposes of this study were firstly to optimize the recipe for iced cookies by cooking with five different ingredient levels of $Jinuni\;bean(X_1),\;butter(X_2)\;&\;sugar(X_3)$ and secondly to analyze the chemical and sensory test results by using RSM(Response Surface Methodology). As a result of this test, water activity decreased with increasing contents of butter or sugar, while hydrophilic browning decreased independently with increasing sugar content. There was a positive correlation(p<.001) between specific gravity and hardness, although the result was not uniform due to the interaction of each factor. There was a negative correlation(p<.001) between the spread ratio and gravity or hardness, and it tended to increase with increasing each content. Color value L and color value a had positive correlation (p<.001) and the value tended to decrease with increasing the quantity of Jinuni bean. Generally, the strength of the cookies showed a saddle point at the peak of the 3d graph. As a result of sensory evaluation, the color was sensitive to the contents of sugar and Jinuni bean, the texture was sensitive to the contents of butter and sugar, and the taste and overall quality were sensitive to all three factors. Color had a positive correlation(p<.05) with the taste, texture and overall quality. There were high positive correlations(p<.001) between the taste, texture and overall quality. The preference data showed an up-swollen, parabolic shape in the center of the 34 graph, which enabled the optimum value to be determined and the optimum mixture ratio which fulfilled all sensory items was Jinuni bean 93g, butter 188.5g and sugar 155g, indicating a substitution of flour by $44\%$.

Regional Trend Analysis for Groundwater Quality in Jeju Island - Focusing on Chloride and Nitrate Concentrations - (제주도 지하수 수질의 광역적 추세 특성 분석 - 염소 및 질산성질소를 대상으로 -)

  • Kim, Gyoo-Bum;Kim, Ji-Wook;Won, Jong-Ho;Koh, Gi-Won
    • Journal of Korea Water Resources Association
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    • v.40 no.6 s.179
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    • pp.469-483
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    • 2007
  • Nitrate and chloride are the most common contaminants in groundwater and their concentrations increase easily due to fertilizer consumption and urbanization. The number of time series data for groundwater quality at a single site was not sufficient to analyze trends on Jeju Island. Therefore rectangle grids were drawn for the whole island and single grid was determined to be $500m{\times}500m$ after considering similar stream density, homogeneous hydraulic coefficients, geologic features of volcanic rock and low topographic slopes. All data within each lattice were collected and arranged in time series order and analyzed using Sen's method. 10.6 % of the total lattices for chloride and 22.4% for nitrate showed upward trends from the early 1990's to the early 2000's. Especially, upward trends for nitrate concentration are distinct in the low mid-mountainous areas of western and southern watersheds. Many septic tanks and much domestic waste from the urbanization of the low mid-mountainous area have produced this upward trend. Additionally, the agricultural region has dramatically increased since the 1990's and this has led to an increase of fertilizer consumption and, as a result, nitrate concentration. Therefore, the target of any management plan for groundwater quality on Jeiu Island needs to be focused on careful land use decisions in the mid-mountainous areas which are near Halla Mountain.