• Advances in environmental research
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• v.12 no.1
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• pp.17-40
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• 2023

This article presents studies of the adsorption process in a continuous system of fluoride solutions at a concentration of 30 mg/L using a bone char packed in fixed-bed columns, as well as regeneration studies in the same system using HNO₃, HCl and NaOH at 0.01, 0.1 and 1 M. The Thomas Model, Artificial Neural Networks (ANNs), Numerical Integration and Mass Transfer Zone were used for the modeling of asyemmetrical breakthrough curves obtained from the fluoride adsorption on bone char. The maximum adsorption capacity of the breakthrough curves was estimated, and various design parameters of the columns were obtained for the different operating conditions. Results showed that an improvement in the modeling capabilities of the Thomas model can be obtained using ANNs. Moreover, ANNs are useful for determining reasonable and accurate design parameters of packed-bed adsorption columns. This modeling approach can be useful for the process system engineering of dynamic adsorption systems involved in the field of water treatment and purification. It is important to highlight that the obtained results indicate that, when using HCl or HNO₃ at a concentration of 0.1 M, a large number of adsorption-desorption cycles are obtained and, therefore, the highest values of adsorption capacity, which leads to a reduction in operation costs.

• Archives of Pharmacal Research
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• v.14 no.3
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• pp.249-254
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• 1991

Activated carbons from rice-straw can be used as an adsorbents for the purification of water were prepared and evaluated. The adsorptive capacities of activated carbons were measured by iodine, potassium permangante, phenol and metals. It was observed by electron microscope (SEM) and IR spectrum that organic components in the rice-straw and its carbonization product were disappeared. Slit-shaped and porousstructures were formed by activation. There was no relationship between temperature and adsorption of iodine but adsorption of potassium permanganate increased as temperature rose. The adsorption of the phenol was greater than 99%. The adsorption data of phenol at $25^\circ{C}$ obeyed the Freundlich's isotherm. Various metals except sodium were not removed by activated carbon.

• Proceedings of the KAIS Fall Conference
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• 2006.11a
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• pp.324-327
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• 2006

COD 제거효율은 각 조의 부처꽃을 제외한 대조군의 경우 물상추 56%, 달뿌리풀 48%, 미나리 41%의 제거효율을 보이고, 발포유리가 첨가된 조의 경우는 물상추 69%, 달뿌리풀 68% 미나리 62%의 제거효율을 보임으로써 발포유리를 첨가한 조의 COD 제거효율이 대조군 보다 높았다. T-N의 제거효율은 발포유리를 첨가한 조의 경우 부처꽃 91%, 달뿌리풀 93%와 발포유리를 첨가한 혼합조가 94%의 높은 T-N 제거효율 보임으로써 모든 질소성분이 제거된 것으로 사료된다. T-P의 제거효율은 대조군의 부처꽃 35%, 달뿌리풀 8%이며, 발포유리를 첨가한 조의 부처꽃 78%, 달뿌리풀 43%로 발포유리를 첨가한조의 T-P 제거효율이 대조군 보다 높았다.

• Water for future
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• v.10 no.2
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• pp.91-100
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• 1977

This is an experimental study to raise higher efficiency of filteration than conve ntional filteration by increasing of filteration capacity for per unit area and by extending of filteration lasting time with biflow filter system which was improved from the conventional rapid sand filteration method in the process of water purification treatment. In order to raise more efficient function of filteration and giving consideration to the filter layer at upper and lower parts of the filter, the fine sand & an thracite were used as a filter medium. Although there is some difficulty than previous fine sand in procurement, it could confirm that such filter medium (fine sand & anthracite) was more effective in the field of load, lasting time and back wash, etc. In consideration of practical effect of filteration. The raw water which was used for this experimental study was not coagulated. As a result of this experiment, the filteration volume could increase more than 2 times than that of conventional method. Besides, much more advantages could be obtained for instance, the requirement of installation area was not much and installation cost could economize. On the other hand, the following results were found. The quality of filtered water became worse as time goes by and the turbidity of filtered water was more influenced by raw water turbidity than by rate of filteration. Lasting time of filteration on change of filteration rate in the filter layer reached 2 times in comparison with previous filter basin, and until loss gead reached to 1.0 meter and 1.5 meter, the following relate formulas between lasting time and rate of filteration were formed. ($T_{1.5}=181.96V^{-0.46},\;T_{1.0}=121.31V^{-0.46}$) Even though the lasting time can be shorten in case of the increase of the filteration rate, but the lasting time was prolonged more than 2 times than of previous method. With taking aim at contribution to the development of water treatment technique, we are planning to study continuously for the future study basing on the results in this papers.

• Journal of Wetlands Research
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• v.9 no.1
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• pp.47-60
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• 2007

The rapid development of economy in China at the expense of consuming huge amount of energy and resources, water resource in particular, which has resulted in the production and discharge of increasing amount of wastewater to the water environment. In order to effectively control the increasing water pollution trend, the State Council has stipulated that all the cities with population over 500,000 should reach wastewater treatment rate of 60% by 2005, and all the cities should reach the rate of 60% by 2010, of which Capital Beijing and all the province capital cities and important tourism cities should reach 70% then. By the end of 2005, of the 661 cities in China, 393 have built and operated municipal wastewater treatments with a total number of 790 sets, total treatment capacity of $80.91{\times}106m^3/d$ and total treatment rate of > 48%. Other 73 cities have started the construction of municipal wastewater treatment plants, and other 168 cities have started to prepare, planning and design of wastewater treatment plants. Most of municipal wastewater treatment plants in big cities in China operate normally and perform well with good quality of effluent in terms of wastewater treatment train, but the sewage sludge treatment is usually poor with big problems. It has been found that the small scale WWTPs using activated sludge process in the towns are usually operated and maintained abnormally because of lack of fund, skilled operators and energy. It is therefore suggested that the small scale MWWTPs in small cities and towns adopt appropriate technologies, of which the most available ones are multi-stage ponds, constructed wetlands and the combination of them for further purification and reuse of treated wastewater.

• Journal of Soil and Groundwater Environment
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• v.17 no.6
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• pp.1-8
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• 2012

This study is to suggest a few efficient ways of rainwater utilization, through monitoring and analyzing 143 rainwater storage systems and 110 artificial recharge systems, which are installed in the recommended facilities by law, among the rainwater harvesting systems in Jeju Island. In the case that catchment facilities are damaged, rainwater could be contaminated by leaves and debris so that the rates of rainwater usages come to be lower. It is possible that contaminated rainwater could contaminate artificial recharge wells or rainwater discharging out of the rainwater harvesting system could result in flood and damage for the downgradient area. For maintaining high quality of rainwater and increasing rainwater utilization rate, it is necessary to install screening facilities and purification plant functioning precipitation and filtration. Also, in order to efficiently preclude the overflowing rainwater exceeding storage capacity, it is recommended to associate rainwater storage tanks with artificial recharge well or infiltration trench facilities.

• Journal of Korean Society on Water Environment
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• v.23 no.5
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• pp.676-682
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• 2007

The bacterial number, extracellular enzyme activities and structure of bacterial community which are major constituent of aquatic ecosystem within the artificial vegetation island (AVI) were compared to those of the nearby pelagic lake waters in order to evaluate the possibility of the AVI as a eco-technological measure for water quality improvement and restoration of littoral zone in man-made reservoirs. There was not a significant difference in the total number of bacteria, but the number of active (viable) bacteria within the AVI was about 0.7 to 4.1 times higher than nearby pelagic lake water. The ratio of the number of active bacteria versus the total number of bacteria was also higher in the AVI than nearby pelagic lake water. The activities of ${\beta}$-glucosidase and phosphatase were 1.0 to 13.1 and 0.8 to 7.3 times higher respectively in the AVI than nearby pelagic lake water, showing that microorganisms were more active within the AVI. The bacterial communities of the two waters, examined by FISH method, did not indicate a clear difference in the springtime when the growth of macrophytes was immature, but during summer and fall it showed a clear difference indicating the formation of distinct bacterial community within the AVI compared to nearby lake water. From the results of this study, we conclude that AVI can contribute to make up the littoral ecosystem which show rapid cycling of matters through active detritus food chain in the dam reservoirs which have unstable aquatic ecosystem due to short hydraulic residence time and to strengthen the self-purification capacity of the lake.

• The Korean Journal of Ecology
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• v.17 no.3
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• pp.355-366
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• 1994

The purpose of this study was to investigate the changes of water quality and the patterns of self-purification with season in Gokneung stream. The vegetation in the ecosystem around Gokneung stream was dominated by Quercus species. In the physicochemical analysis based on the contents of DO, BOD, conductivity and total phosphorus, the upstream seemed to have been polluted, but the downstream was self-purified. In biological investigation by bentic macroinvertebrates, the result was similar to that in the physicochemical analysis. The self-purification constant based on BOD of the upstream, 1.013, was the highest. In the self-purification constants with month, that of September was 0.995 and that of January was 0.272. These results indicated that the self purification capacities of spring and autumn were larger than those of winter and summer in Gokneung stream.

• Environmental Engineering Research
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• v.24 no.3
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• pp.463-473
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• 2019

Nanoscale zero-valent iron (nZVI) has proved to be an effective tool in applied environmental nanotechnology, where the decreased particle diameter provides a drastic change in the properties and efficiency of nanomaterials used in water purification. However, the agglomeration and colloidal instability represent a problematic and a remarkable reduction in nZVI reactivity. In view of that, this study reports a simple and cost-effective new strategy for ultra-small (< 7.5%) distributed functionalized nZVI-EG (1-9 nm), with high colloidal stability and reduction capacity. These were obtained without inert conditions, using a simple, economical synthesis methodology employing two stabilization mechanisms based on the use of non-aqueous solvent (methanol) and ethylene glycol (EG) as a stabilizer. The information from UV-Vis absorption spectroscopy and Fourier transform infrared spectroscopy suggests iron ion coordination by interaction with methanol molecules. Subsequently, after nZVI formation, particle-surface modification occurs by the addition of the EG. Size distribution analysis shows an average diameter of 4.23 nm and the predominance (> 90%) of particles with sizes < 6.10 nm. Evaluation of the stability of functionalized nZVI by sedimentation test and a dynamic light-scattering technique, demonstrated very high colloidal stability. The ultra-small particles displayed a rapid and high nitrate removal capacity from water.

• Journal of the Mineralogical Society of Korea
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• v.19 no.4 s.50
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• pp.259-264
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• 2006

This work carried out to analyze the physicochemical properties and investigate the assessment of heavy metal contamination of stream sediments of the Yudeung and the Gab streams in the Daejeon area. The pH of stream sediments of the Yudeung stream shows the range of weak acid and weak alkaline. Most of stream sediments contain about 80% sand grain and have low water and cation retention capacity. Hence the stream sediments are not suitable fur various plans to grow up. The analysis of heavy metals in the stream sediments shows that the concentration of Pb, Cr and Cd increases from upstream to down stream. It is likely that the trend has a relationship with the water. Contamination of stream water. The authors recommend that clay materials be replenished in the stream sediments to increase the self-purification capacity and to make the suitable condition for growing up of various plants, and that water quality of the stream which can Influence into the contamination of stream sediments be monitored.