• Title/Summary/Keyword: Water dip test

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Electrochemical Characteristics under Cavitation-Erosion Environment of STS 304 and Hot-Dip Aluminized STS 304 in Sea Water Solution (천연해수 용액에서 STS 304와 용융 알루미늄 도금된 STS 304의 캐비테이션-침식 환경 하에서의 전기화학적 특성)

  • Chong, Sang-Ok;Kim, Seong-Jong
    • Journal of the Korean institute of surface engineering
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    • v.49 no.1
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    • pp.26-31
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    • 2016
  • In this paper, the characteristics of a cavitation-erosion damage behavior on the STS 304 and hot-dip aluminized STS 304 under cavitation environment in sea water solution was investigated. The electrochemical experiments were carried out by potential measurement, anodic/cathodic polarization test, Tafel analysis, and also galvanostatic experiment in current density variables for the samples. The apparatus of cavitation-electrochemical experiment was manufactured in compliance with modified ASTM G-32 standard, with the conditions of sea water temperature of $25^{\circ}C$ and the measurement, amplitude of $30{\mu}m$. The damage behavior was analyzed by an observation of surface mophologies and a measurement of damage depth by a scanning electron microscope(SEM) and a 3D microscope, respectively, after electrochemical test. After polarization experiment under cavitation environment, much higher damage depths for the hot-dip aluminized STS 304 were observed comparing to the untreated STS 304. In addition, higher corrosion current density in hot-dip aluminized STS 304 presented than that of untreated STS 304 as a result of Tafel analysis.

Studies for ENIG surface behavior of FCBGA through the time by using water dip test method

  • Shin, An-Seob;Kim, Jeom-Sik;Ok, Dae-Yool;Jeong, Gi-Ho;Park, Chang-Sik;Heo, Cheol-Ho;Lee, Kum-Ro
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.412-412
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    • 2008
  • ENIG(Electroless Nickel Immersion Gold)is a surface treatment method that is used most widely at fine pitch's SMT and BGA packaging process. ENIG has good diffusion barrier of Ni against solder and good wettability due to Au finish. But when the discoloration occurred on the Au finish of ENIG, some key characteristics related to the quality and reliability of PCB such as bondability, solderability and electrical flowing of packaging process could be deteriorated. In this paper, we have performed the water dip test ($88^{\circ}C$ purified water) which accelerates the galvanic corrosion of Ni diffused from the Ni-P layer. That is, the excessive oxidation of the Ni layer could result in non-wetting of the solder because the flux may not be able to remove excessive oxides. Though Au discoloration have been reported to be caused by Ni oxides in many literature, it is still open to verify and discuss The microstructures and chemical compositions have been investigated using FE-SEM, TEM, FIB, EDS and XPS. As a result, authors have found that the Au discoloration in ENIG type is severely caused by the oxidation of the Ni and the mechanism of Au discoloration can be confirmed through the experiment result of water dip test.

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Preparation of the Anti-Reflective(AR) Coating Film by Sol-Gel Method to Improve the Efficiency of Solar Cell (태양전지 효율 향상용 졸-겔 법에 의한 반사방지 코팅막의 제조)

  • Kim, Hyosub;Kim, Youngho;Choi, Jaeyune
    • Transactions of the Korean hydrogen and new energy society
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    • v.25 no.2
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    • pp.145-150
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    • 2014
  • This study investigates the preparation of anti-reflective (AR) coating film to improve the efficiency of solar cell. The AR coating film was successfully obtained by dip-coating with AR coatings prepared by sol-gel method. Fluoroalkylsilane was additionally introduced into the coatings to give the self-cleaning effect of AR coating film. We performed the abrasion test, pencil scratch hardness test and cross-cut test to identify the mechanical strength of AR coating film. As the results, the transmittance of AR coating films with 9.07, 18.13 and 27.20 of IPA/MTMS molar ratios were 93.1, 93.6 and 95.3%, respectively. The water contact angle and transmittance of AR coating film increased by the introduction of hydrophobicity. The prepared AR coating film shows the high level of abrasion, hardness and adhesion. The IPA/MTMS molar ratio of 27.20 and the withdrawing speed range of 0.20 ~ 0.28cm/sec are the optimal coating condition in terms of the transmittance and mechanical strength of AR coating film.

Separation of Aqueous Ethanol Solution Using a PAA-PAN Composite Membrane Through Pervaporation (PAA-PAN 복합막을 이용한 에탄올 수용액의 투과증발 분리)

  • 원장묵;하백현;최호상
    • Membrane Journal
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    • v.6 no.3
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    • pp.182-187
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    • 1996
  • Hydrophilic poly(acrylonitrile) [PAN] membrane with good molecular weight cut-off characteristics were prepared by using the phase inversion method. Permeability and molecular weight cut-off of the membranes were measured through the ultrafiltration test. On the surface of the PAN support membranes, poly(acrylic acid) [PAA] was deposited by dip-coating. The water permeability of the PAN support membrane had $0.17~31\textrm{mm}^3/m^{2} \cdot s \cdot Pa$, the molecular weight cut-off 42, 000~150, 000. The transport characteristics of the prepared composite membranes were significantly affected by the variation of the support membrane mophology. The permeability of the composite membrane was decreased with increasing molecular weight cut-off of the support membrane, and the separation factor was slightly changed depending on the feed concentration.

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Long-term Trends of Summer Season of Water Quality in Lake Doam (도암호에서 하절기 수질의 장기적인 경향)

  • Kwak, Sungjin;Bhattrai, Bal Dev;Lee, Changkeun;Heo, Woomyung
    • Korean Journal of Ecology and Environment
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    • v.46 no.1
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    • pp.128-134
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    • 2013
  • In the summer season (June~August) during the study period of Lake Doam, average concentrations of major water quality parameters, COD, SS, TN, and TP were 4.0, 16.2, 3.129 and $0.077mg\;L^{-1}$, respectively, and Chl-a was $11.8mg\;m^{-3}$. The result has indicated that Lake Doam was a meso-eutrotrophic lake. Lake Doam data from the summer season (June~August), precipitation from 2001 to 2012, and water quality (COD, SS, TN, TP, Chl-a etc.) of seven years (2001, 2002, 2004 and 2009~2012), were statistically analyzed for long-term trends by Mann-Kendall test and Sen's slope estimator methods. The statistical results showed that precipitation, SD, COD, TN, $NO_3-N$, $NH_3-N$ and Chl-a had decreasing trends, and EC, turbidity, SS, TP and DIP had increasing trends. Suspended solids and total phosphorus were directly affected by precipitation. In the case of suspended solids, more aggressive and constructive plans need to be implemented than the current turbidity reduction project to achieve the targeted water quality ($5mg\;L^{-1}$ of SS) in Lake Doam. In particular, we need to specify a project that considers the steep topographic characteristics of high, land farming areas and precipitation conditions of the Lake Doam watershed, which can increase the efficiency of a turbidity reduction project.

Application of Dissolved Air Flotation Technique to Improve Eutrophic Reservoir Water Quality (가압부상법을 이용한 부영양저수지의 수질개선)

  • Kim, Ho-Sub;Jung, Dong-Il;Lee, Il-Kuk;Hwang, Soon-Jin
    • Korean Journal of Ecology and Environment
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    • v.38 no.3 s.113
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    • pp.372-381
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    • 2005
  • This study was conducted to test the efficiency of water quality improvement using the dissolved air flotation (DAF) technique in a shallow eutrophic reservoir. The application of DAF was followed by the addition of a chemical coagulant (poly aluminum chloride; PAC). The experiment was conducted in the mesocosm scale (wide ${\times}$ length ${\times}$ depth: 6 m ${\times}$ 6 m ${\times}$ 3 m). Suspended solids (SS) and volatile SS (VSS) concentration decreased by 54 ${\sim}$ 71% and 57 ${\sim}$ 79% of the initial concentrations, respectively. Total phosphorus and Chl- a concentration also decreased by 74 ${\sim}$ 92% and 54 ${\sim}$ 98%, respectively. BOD decreased by>86% while COD decrease ranged 29 ${\sim}$ 63%. Dissolved inorganic P (DIP) and dissolved total P (DTP) concentration decreased by 34 ${\sim}$ 88% and 62 ${\sim}$ 88%, respectively. After DAF application further onto the sediment, DIP-release rates from the sediment decreased by 17% (0.82 ${\to}$ 0.68 mg $m^{-2}$$day^{-1}$ in the oxic condition and 23% (2.27 ${\to}$ 1.76 mg $m^{-2}$$day^{-1}$) in the anoxic condition, compared to the release rate from the untreated sediment. DTP-release rate from both the oxic and anoxic sediments also decreased by 33% (5.62 ${\to}$ 3.78 mg $m^{-2}$$day^{-1}$) and 20% (6.23 ${\to}$ 4.99 mg $m^{-2}$$day^{-1}$), respectively. These results suggest that the DAF application both to the water column and onto the sediment be effective to improve water quality by removing particulate matters in the water column as well as reducing P-release from the sediment.

Enhanced Moisture Resistance of Salt Core through 2D Kaolinite Colloidal Solution Coating

  • So-Yeon Yoo;Ahrom Ryu;Min-Seok Jeon;Dongkyun Kim;Kiwon Hong;Sahn Nahm;Ji-Won Choi
    • Journal of Sensor Science and Technology
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    • v.32 no.3
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    • pp.154-158
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    • 2023
  • This study aimed to improve the moisture resistance of salt cores by investigating the suitability of a two-dimensional kaolinite colloidal solution and a commercially available SiO2 ink solution as coating agents. X-ray diffraction analysis (XRD) results showed that the intercalation of urea into kaolinite did not significantly change its layer structure. Scanning electron microscopy (SEM) images revealed that the dip-coating only affected the surface of the salt core, and the texture of the surface is differ depending on the coating solution. The humidity absorption test results showed that both coatings reduced the hygroscopicity of the salt core by more than 50%. However, in the water-solubility test, the kaolinite dissolved with the salt core, whereas the SiO2-coated salt core left a residue. These results strongly suggest that with the coating of the exfoliated kaolinite solution, salt core will remain stable in humid environments.

Preliminary Study of the Leaching Resistance of Boron from Borate Treated Wood by the Dual Treatment with Water-Repellent Preservative and Methyl Metacrylate (방부성(防腐性) 발수제(撥水劑)와 methyl metacrylate 이중처리(二重處理)에 의(依)한 붕소화합물(硼素化合物) 처리재(處理材)로부터 붕소(硼素)의 용탈(溶脫) 저항성(抵抗性)에 관(關)한 기초연구(基礎硏究))

  • Kim, Gyu-Hyeok;Ra, Jong-Bum
    • Journal of the Korean Wood Science and Technology
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    • v.22 no.4
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    • pp.13-18
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    • 1994
  • Sapwood samples of pitch pine were treated with disodium octaborate alone by dip-diffusion, or in combination with water-repellent preservative(WRP) and methyl metacrylate(MMA). Treated samples were subjected to an accelerated leaching test for determining the improvement of leaching resistance and to soft rot and mold tests for evaluating the increase in bioefficacy, due to the addition of WRP and MMA applied as a second treatment. The addition of WRP and MMA retarded leaching of boron to some extent from treated samples and this retardation can be explained by improved water repellency of WRP and MMA treated samples. Borate /WRP and borate /MMA systems will not qualify borate treated wood for ground and fresh water contact use but may improve performance of borate treated wood in above-ground applications not subjected to continuous wetting conditions. Bioefficacy against soft rot fungi and mold fungi was improved by a second treatment with WRP. However, improvement in the performance of borate /MMA systems was not observed. Considering improvement in both resistance of leaching and bioefficacy against micro fungi by the treatment of WRP and MMA, simultaneously, the dual treatment of borate treated wood by MMA containing co-biocides might be believed as an ideal treatment system.

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Characterization of Ceramic Composite-Membranes Prepared by TEOS-PEG Coating Sol (TEOS-PEG계 Sol-Gel코팅에 의한 세라믹 분리 막의 제조 및 특성)

  • Kim, Tae-Bong;Choi, Se-Young;Kim, Goo-Dae
    • Journal of the Korean Ceramic Society
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    • v.42 no.3 s.274
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    • pp.165-170
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    • 2005
  • Sol-gel methods offer many advantages over conventional slip-casting, including the ability to produce ceramic membranes. They are purer, more homogeneous, more reactive and contain a wider variety of compositions. We produced ormosil sol using sol-gel process under various molecular weight of polymer species[polyethylene glycol(PEG)] in total system [Tetraethyl ortho silicate(TEOS)-polyethylene glycol(PEG)]. The properties of as-prepared ormosil sol such as viscosity and gelation time are characterized. Also, the ceramic membrane was prepared by dip-coating with synthetic sol and its microstructure was observed by scanning electron microscopy. The permeability and rejection efficiency of membrane for oil/water emulsion were evaluated as cross­flow apparatus. The ormosil sol coated membrane was easily formed by steric effect of polymer and it improved flux efficiency because infiltration into porous support decreased. Its flux efficiency was elevated about $200\;l/m^2h$ compared with colloidal sol coated membrane at point of five minutes from starting test.

Performance Characteristics of Anode-Supported Tubular Solid Oxide Fuel Cell (연료극 지지체식 원통형 고체산화물 연료전지의 성능 특성)

  • Song Rak-Hyun;Song Keun-Suk
    • Korean Journal of Materials Research
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    • v.14 no.5
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    • pp.368-373
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    • 2004
  • To improve the conventional cathode-supported tubular solid oxide fuel cell (SOFC) from the viewpoint of low cell power density, expensive fabrication process and high operation temperature, the anode-supported tubular solid oxide fuel cell was investigated. The anode tube of Ni-8mol% $Y_2$O$_3$-stabilized $ZrO_2$ (8YSZ) was manufactured by extrusion process, and, the electrolyte of 8YSZ and the multi-layered cathode of $LaSrMnO_3$(LSM)ILSM-YSZ composite/$LaSrCoFeO_3$ were coated on the surface of the anode tube by slurry dip coating process, subsequently. Their cell performances were examined under gases of humidified hydrogen with 3% water and air. In the thermal cycle condition of heating and cooling rates with $3.33^{\circ}C$/min, the anode-supported tubular cell showed an excellent resistance as compared with the electrolyte-supported planar cell. The optimum hydrogen flow rate was evaluated and the air preheating increased the cell performance due to the increased gas temperature inside the cell. In long-term stability test, the single cell indicated a stable performance of 300 mA/$\textrm{cm}^2$ at 0.85 V for 255 hr.