• Title/Summary/Keyword: Water diffusion coefficient

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A Study of the Transdermal Permeation of Lotion Formulations Containing Angelica gigas Nakai Extracts in Franz Diffusion Cells (Franz diffusion cell을 이용한 참당귀 추출물 함유한 로션제형의 피부 투과 연구)

  • Kim, Kang Min
    • Journal of Life Science
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    • v.31 no.11
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    • pp.1004-1009
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    • 2021
  • Angelica gigas Nakai (AGN) has been used in Korean herbal medicine for various pharmacological activities, such as to create antioxidant and skin whitening effects. Decursin and decursinol angelate of AGN extracts can be used as potential active drugs and cosmetic ingredients. This study investigated the possibility of topical delivery of AGN extracts using a manufactured emulsion system. Lotion was formulated by using Tefose® and paraffin for the oil phase, Kolliphor RH 40 for the surfactant and solubilizing agent-which showed high solubility in water (0.82 mg/ml)-and a water phase with a carbomer. In vitro skin permeation of decursin and decursinol angelate was determined using a Strat-M® membrane in Franz diffusion cells. Lotion samples as the experimental group (248.08±19.72 ug/cm2) significantly increased the permeation of decursin and decursinol angelate for up to 24 hr compared to the control group (119.18±19.23 ug/cm2). The permeability was also characterized by the flux (penetration rates) and Kp (permeability coefficient) values. The experimental group (17.20±1.23 ug/h/cm2 and 5.73±1.39 cm/h*10-3) had higher flux and Kp than the control group (8.22±1.24 ug/h/cm2 and 2.74±0.51 cm/h*10-3). Lotion with decursin and decursinol angelate of AGN extracts could be used for the topical application of drug and cosmetic products.

A Study on the Chloride ion Penetration Characteristic of Concrete containing Ground Granulated Blast Furnace Slag (고로슬래그미분말 치환 콘크리트의 염화물 침투특성에 관한 연구)

  • 김현수;지남용
    • Proceedings of the Korea Concrete Institute Conference
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    • 2001.05a
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    • pp.997-1002
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    • 2001
  • There are two types of chloride in concrete; one is added as concrete materials' chloride when concrete's mixing, and .the other is penetrated from the air and sea water in the sea-shore area. These chlorides penetrate into concrete, and they are accumulated inside the concrete with aging. This study aimed to evaluate the chloride ion penetration resistance of concrete containing GGBFS in the sea-shore area. Therefore, the specimens made with the replacement ratios(0, 0.30, 0.45, 0.60) of GGBFS were put into 3% NaCl solution according to the chloride accelerating test of JCI-SC3, and then investigated the weight changes, compressive strength, chloride ion with the depths of the specimens by aging. The result is that the diffusion coefficient of chloride ion is decreased with the increase of replacement ratios when compared to OPC

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The Experimental Study on $CO_2$ Diffusivity in Concrete (콘크리트 중으로의 $CO_2$ 확산에 관한 실험연구)

  • 오병환;정상화;이명규
    • Proceedings of the Korea Concrete Institute Conference
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    • 2002.05a
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    • pp.163-168
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    • 2002
  • Through the developing measuring system of gas diffusivity, the experiments on carbon dioxide diffusivity in concrete carry out. From this, some important results was achieved. First, the times of reaching the steady state condition don't depend on the water/cement ratio with linearity. But, for the 0.42 w/c ratio the duration of the non-steady state condition is long. Second, in constant relative humidity, the diffusion coefficient shows linearity for the w/c ratio. Third, for the same w/c ratio, the influence of relative humidity on the diffusivity is very large. This shows the importance of the environmental condition for the carbonation. This study on $CO_2$ diffusivity in concrete is the first attempt within a country and will be important data.

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A study on the distribution of airborne sea salt to the distance from seashore (해안으로부터 거리별 비래염분량의 분포에 대한 고찰)

  • Lee, Jong-Suk;Choi, Won-Sung;Moon, Han-Young
    • Proceedings of the Korea Concrete Institute Conference
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    • 2004.05a
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    • pp.842-845
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    • 2004
  • When the concrete structures are in contact with seawater, concentration of chloride for estimating chloride diffusion coefficient can be defined as the chloride concentration of sea water. However, in case the concrete structures, constructed in the seashore, aren't directly in contact with seawater, it is difficult to establish the interface concentration of chloride. In addition, marine concrete structures are greatly affected by salt attack such as rebar corrosion, among the cause of salt attack, airborne sea salt is primary factor. Therefore, in this study, salt attack environment by airborne sea salt was investigated in terms of the distance from seashore at 33 spots, 6 areas in East, West, South coast for 1 year. Results indicated that airborne sea salt is decreased by $y=a{\cdot}x^{-b}$ equation to the distance from seashore.

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Characteristics on the distribution of salinity of airborne sea salt by height (높이에 따른 비래염분량의 감소 특성)

  • Lee Jong Suk;Choi Won Sung;Kim Do Gyeum;Moon Han Young
    • Proceedings of the Korea Concrete Institute Conference
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    • 2005.05b
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    • pp.261-264
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    • 2005
  • For concrete structures immersed in seawater, the concentration of chloride used to estimate the chloride diffusion coefficient can be defined as the seawater chloride concentration. However, for seashore concrete structures which are not coming into direct contact with seawater, establishing the interface concentration of chloride becomes delicate. In addition, concrete structures are greatly affected by salt attack primarily due to airborne sea salt like it can be seen through the corrosion of rebar. This study intends to investigate characteristics on the salinity of airborne sea salt by height. Salinity measurement devices were installed at height of 2, 10 and 19m on the seashore water tower located in the area of Samchuk in the Eastern coast. Analysis results of the decrease of salinity with respect to the height above the ground at a distance of 30m from the seashore showed that the reduction reached about 40$\%$ at a height of 10m and 60$\%$ at 20m.

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On the material properties of shell plate formed by line heating

  • Lim, Hyung Kyun;Lee, Joo-Sung
    • International Journal of Naval Architecture and Ocean Engineering
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    • v.9 no.1
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    • pp.66-76
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    • 2017
  • This paper is concerned with investigating the plastic material properties of steel plate formed by line heating method, and is aimed at implementing more rational design considering the accidental limit states such as collision or grounding. For the present study, line heating test for marine grade steel plate has been carried out with varying plate thickness and heating speed, and then microscopic examination and tensile test have been carried out. From the microscopic, it is found that the grain refined zones like ferrite and pearlite are formed all around the heat affected zone. From the tensile test results, it is seen that yield strength, tensile strength, fracture strain, hardening exponent and strength coefficient vary with plate thickness and heat input quantity. The formulae relating the material properties and heat input parameter should be, therefore, derived for the design purpose considering the accidental impact loading. This paper ends with describing the extension of the present study.

Distribution properties of seasonal airborne sea salt in the seashore (해안가의 계절별 비래염분량의 분포 특성)

  • Lee, Jong-Suk;Choi, Won-Sung;Moon, Han-Young
    • Proceedings of the Korea Concrete Institute Conference
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    • 2004.11a
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    • pp.237-240
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    • 2004
  • When the concrete structures are in contact with seawater, concentration of chloride for estimating chloride diffusion coefficient can be defined as the chloride concentration of sea water. However, in case the concrete structures, constructed in the seashore, aren't directly in contact with seawater, it is difficult to establish the interface concentration of chloride. In addition, marine concrete structures are greatly affected by salt attack such as rebar corrosion, among the cause of salt attack, airborne sea salt is primary factor. Therefore, in this study, salt attack environment by airborne sea salt was investigated in terms of a seasonal distribution at 33 spots, 6 areas in the East, West, South coast for 1 year. Results indicated that in the South coast, the amount of the airborne sea salt is comparatively higher in summer. in the West coast. higher in winter. On the other hand, in the East coast, the amount of the airborne sea salt is rarely affected by a season.

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A Study on the Basic Properties of Exterior Insulation Plasterer Finishing Materials by Addition of Calcium Carbonate Powder (탄산칼슘계 분말 첨가에 따른 외단열 미장 마감재의 기초물성에 관한 연구)

  • Shin, Joung-Hyeon;Jo, Su-Yeon;Jung, Ui-In;Kim, Bong-Joo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2021.05a
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    • pp.213-214
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    • 2021
  • External insulation method is used to conserve energy of buildings. However, the current external insulation method uses organic insulating materials to become a diffusion path in case of fire. In this study, the purpose of this study is to provide basic data on the required performance of the plastering material according to the CaCO3 powder addition of the finishing material of the external insulation method. In Figure 1, when powder was added, the adhesion strength decreased by 30% to 35% at 10% and 0% to 50% at 20% compared to Plain. In Figure 2, the moisture permeability increases approximately twice when powder is added. The results for the water absorption coefficient are shown in Figure 3.

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Prediction of Water-Quality Enhancement Effects of Gates Operation in the West-Nakdong River Using RMA2/RMA4 Models (RMA2/RMA4 모형을 이용한 서낙동간 수문연계운영의 수질개선 효과 예측)

  • Lee, Keum-Chan;Yoon, Young-Sam;Lee, Nam-Joo
    • Journal of Environmental Science International
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    • v.18 no.9
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    • pp.971-981
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    • 2009
  • An objective of this study is as follows: 1) performing sensitivity analysis and parameter estimation of RMA2 and RMA4 models for the West-Nakdong River, 2) drawing up alternatives of gates-operation for water-quality enhancement, and 3) quantitative evaluation of methodology of 'flow-restoration by gates-operation' among 'Comprehensive Plan Improving Water-Quality in the West-Nakdong River(WNR)' with the target water-quality(BOD at Nakbon-N point: below 4.3 mg/L). The parameters for the RMA2 (depth-averaged two-dimensional flow model) and RMA4 (depth-averaged two-dimensional water-quality model) were determined by sensitivity analysis. Result of parameter estimation for RMA2 and RMA4 models is $1,000\;Pa{\cdot}s$ of the eddy viscosity, 20 of the Peclet number, 0.025 of the Manning coefficient, and $1.0\;m^2/s$ of the diffusion coefficient. We have evaluated the effects of water-quality enhancement of the selected alternatives by numerical simulation technique with the models under the steady-state flow condition and the time-variant transport condition. Because of no-resuspension from river bottom and considering BOD as conservative matter, these simulation results slightly differ from real phenomena. In the case of $50\;m^3/s$ of Daejeo-gate inflow, two-dimensional flow pn results result represents that small velocity occurs in the Pyungkang Stream and no flow in the Maekdo River. In the WNR, there occurs the most rapid flow near timhae-bridge. In the WNR, changes of water-quality for the four selected simulation cases(6, 10, 30, $50\;m^3/s$ of the Daejeo-gate inflow) were predicted. Since the Daejeo-Gate and the Noksan-Gate can be opened up to 7 days, it would be found that sustainable inflow of $30\;m^3/s$ at the Daejeo-gate makes BOD in the WNR to be under the target of water-quality.

Pervaporation Characteristics of Water/Ethanol and Water/Isopropyl Alcohol Mixtures through Zeolite 4A Membranes: Activity Coefficient Model and Maxwell Stefan Model (제올라이트 4A 분리막을 이용한 물/에탄올, 물/이소프로필알코올 혼합물의 투과증발 특성 연구 : 활동도계수모형 및 Generalized Maxwell Stefan 모형)

  • Oh, Woong Jin;Jung, Jae-Chil;Lee, Jung Hyun;Yeo, Jeong-gu;Lee, Da Hun;Park, Young Cheol;Kim, Hyunuk;Lee, Dong-Ho;Cho, Churl-Hee;Moon, Jong-Ho
    • Clean Technology
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    • v.24 no.3
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    • pp.239-248
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    • 2018
  • In this study, pervaporation experiments of water, ethanol and IPA (Isopropyl alcohol) single components and water/ethanol, water/IPA mixtures were carried out using zeolite 4A membranes developed by Fine Tech Co. Ltd. Those membranes were fabricated by hydrothermal synthesis (growth in hydrothermal condition) after uniformly dispersing the zeolite seeds on the tubular alumina supports. They have a pore size of about $4{\AA}$ by ion exchange of $Na^+$ to the LTA structure with Si/Al ratio of 1.0, and shows strong hydrophilic property. Physical characteristics of prepared membranes were evaluated by using SEM (surface morphology), porosimetry (macro- or meso- pore analysis), BET (micropore analysis), and load tester (compressive strength). Pervaporation experiments with various temperature and concentration conditions confirmed that the zeolite 4A membrane can selectively separate water from ethanol and IPA. Water/ethanol separation factor was over 3,000 and water/IPA separation factor was over 1,500 (50 : 50 wt%, initial feed concentration). Pervaporation behaviors of single components and binary mixtures were predicted using ACM (activity coefficient model), GMS (generalized Maxwell Stefan) model and DGM (Dusty Gas Model). The adsorption and diffusion coefficients of the zeolite top layer were obtained by parameter estimation using GA (Genetic Algorithm, stochastic optimization method). All the calculations were carried out using MATLAB 2018a version.