• 제목/요약/키워드: Water Vapor Pressure

검색결과 422건 처리시간 0.023초

Hot Air Injection/Extraction Method for the Removal of Semi-Volatile Organic Contaminants from Soils (토양내 저휘발성 유류오염물 제거를 위한 고온공기 주입/추출기술 연구)

  • Gu Chung-Wan;Ko Seok-Oh
    • Journal of Soil and Groundwater Environment
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    • 제10권1호
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    • pp.6-12
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    • 2005
  • Contamination of soils and groundwater by leakage of petroleum compounds from underground storage tanks (USTs) has become great environmental issues. Conventional methods such as soil vapor extraction (SVE) used for the remediation of unsaturated soils contaminated with volatile organic compounds might not be applied for the removal of semi-volatile organic compounds such as diesel fuels and PCBs, which have low volatility and high hydrophobicity. The objective of this study is to develop a hot air injection method to remove semi-volatile compounds. Additionally, operation parameters such as temperature, air flow rate, and water content are evaluated. Experimental results show that diesel ranged organics (DROs) are removed in the order of volatility of organic compounds. As expected, removal efficiency of organics is highly dependent on the temperature. It is considered that more than $90\%$ of organic contaminants whose carbon numbers range between 17 and 22 can be removed efficiently by the hot air injection-extraction method (modified SVE) over the $100^{\circ}C$. It is also found that increased air flow rate resulted in high removal rate of contaminants. However, air flow rate over 40 cc/min is not effective for the operation aspects, due to mass transfer limitation on the volatilization rate of the contaminants. The effect of the water content on the decane removal is minimal, but some components show large dependence on the removal efficiency with increasing water content.

A Method for Critical Heat Flux Prediction in Vertical Round Tubes with Axially Non-uniform Heat Flux Profile

  • Shim, Jae-Woo
    • Journal of Ocean Engineering and Technology
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    • 제22권1호
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    • pp.13-21
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    • 2008
  • In this study a method to predict CHF(Critical heat flux) in vertical round tubes with axially non-uniform cosine heat flux distribution for water was examined. For this purpose a local condition hypothesis based CHF prediction correlation for uniform heat flux in vertical round tubes for water was developed from 9,366 CHF data points. The local correlation consisted of 4 local condition variables: the system pressure(P), tube diameter(D), mass flux of water(G), and 'true mass quality' of vapor($X_t$). The CHF data points used were collected from 13 different published sources having the following operation ranges: 1.01 ${\leq}$ P (pressure) ${\leq}$ 206.79 bar, 9.92${\leq}$ G (mass flux) ${\leq}$ 18,619.39 $kg/m^2s$, 0.00102 ${\leq}$ D(diameter) ${\leq}$ 0.04468 m, 0.0254${\leq}$ L (length) ${\leq}$ 4.966 m, 0.11 ${\leq}$ qc (CHF) ${\leq}$ 21.41 $MVW/m^2$, and -0.87 ${\leq}X_c$ (exit qualities) ${\leq}$ 1.58. The result of this work showed that a uniform CHF correlation can be easily extended to predict CHF in axially non-uniform heat flux heater. In addition, the location of the CHF in axially non-uniform tube can also be determined. The local uniform correlation predicted CHF in tubes with axially cosine heat flux profile within the root mean square error of 12.42% and average error of 1.06% for 297 CHF data points collected from 5 different published sources.

Review of Safety for Pressure-Relieving Systems of Small to Middle Scale Chemical Plants (중소규모 화학공장의 압력방출시스템에 대한 안전성 검토)

  • Yim, Ji-Pyo;Jin, Dae-Young;Ma, Byung-Chol;Kang, Sung-Ju;Chung, Chang-Bock
    • Journal of the Korean Society of Safety
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    • 제30권6호
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    • pp.48-55
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    • 2015
  • A variety of safety issues were investigated for chemical reactors using a toluene solvent in case of a fire at small to middle scale chemical plants. The issues covered the operation of pressure-relieving valves and the subsequent discharges of the toluene to the atmosphere either directly or through an absorber, which represent the current practice at most small chemical plants. It was shown that the safety valve on the reactor may not operate within about twenty minutes after an external fire breaks out, but, once relieved, the toluene vapor released directly to the atmosphere may form a large explosion range on the ground. It was also shown that if the discharge is routed to an existing absorber used for the scrubbing of volatile organic compounds or dusts, the column may not operate normally due to excessive pressure drops or flooding, resulting in the hazardous release of toluene vapors. This study proposed two ways of alleviating these risks. The first is to ruduce the discharge itself from the safety valve by using adequate insulation and protection covers on the reactor and then introduce it into the circulation water at the bottom of the absorber through a dip linet pipe equipped with a ring-shaped sparger. This will enhance the condensation of toluene vapors with the reduced effluent vapors treated in the packing layers above. The second is to install a separate quench drum to condense the routed toluene vapors more effectively than the existing absorber.

THE EFFECT OF SURFACE METEOROLOGICAL MEASUREMENTS ON PRECISION GPS HEIGHT DETERMINATION

  • Wang Chuan-Sheng;Liou Yuei-An;Wang Cheng-Gi
    • Proceedings of the KSRS Conference
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    • 대한원격탐사학회 2005년도 Proceedings of ISRS 2005
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    • pp.178-181
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    • 2005
  • The positioning accuracy of the Global Positioning System (GPS) has been improved considerably during the past two decades. The main error sources such as ionospheric refraction, orbital uncertainty, antenna phase center variation, signal multipath, and tropospheric delay have been reduced substantially, if not eliminated. In this study, the GPS data collected by the GPS receivers that were established as continuously operating reference stations by International GNSS Service (IGS), Ministry of the Interior (MOl), Central Weather Bureau (CWB), and Industrial Technology Research Institute (ITRI) Of Taiwan are utilized to investigate the impact of atmospheric water vapor on GPS positioning determination. The surface meteorological measurements that were concurrently acquired by instruments co-located with the GPS receivers include temperature, pressure and humidity data. To obtain the influence of the GPS height on the proposed impact study. A hydrodynamic ocean tide model (GOTOO.2 model) and solid earth tide were used to improve the GPS height. The surface meteorological data (pressure, temperature and humidity) were introduced to the data processing with 24 troposphere parameters. The results from the studies associated with different GPS height were compared for the cases with and without a priori knowledge of surface meteorological measurements. The finding based on the measurements in 2003 is that the surface meteorological measurements have an impact on the GPS height. The associated daily maximum of the differences is 1.07 cm for the KDNM station. The impact is reduced due to smoothing when the average of the GPS height for the whole year is considered.

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Boiling CHF phenomena in water and FC-72

  • Park, Jongdoc;Fukuda, Katsuya;Liu, Qiusheng
    • Journal of Advanced Marine Engineering and Technology
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    • 제38권5호
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    • pp.581-588
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    • 2014
  • Extensive researches toward pool boiling characteristics have been widely investigated. However, the correct understanding of its boiling crisis by Critical Heat Flux (CHF) phenomenon during steady and transient heat transfer as a fundamental database for designing heat generation systems is still need to be clarified. The pool boiling CHFs were investigated to clarify the generalized phenomena of transition to film boiling at transient condition. The CHFs were measured on 1.0 mm diameter horizontal cylinder of platinum for exponential heat generation rates with various periods for saturated liquids at atmospheric pressure. The incipience of boiling processes was completely different depending on pre-pressurization. Also, the dependence of pre-pressure in transient CHFs changed due to the wettability of boiling liquids. The trend of typical CHFs were clearly divided into the first, second and third groups for long, short and intermediate periods, respectively. By the effect of pre-pressurization, the boiling incipience mechanism was replaced from that by active cavities entraining vapor to that by the HSN in originally flooded cavies.

A Preliminary Experimental Study on the Development of Oxy-Fuel Combustion Heating System with $CO_2$ Recycle ($CO_2$ 재순환형 산소연소 가열시스템개발에 관한 실험적 연구)

  • Lee, Eun-Kyung;Go, Chang-Bok;Jang, Byung-Lok;Han, Hyung-Kee;Noh, Dong-Soon;Jeong, Yu-Seok
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2006년도 제32회 KOSCO SYMPOSIUM 논문집
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    • pp.69-74
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    • 2006
  • An Experimental study was conducted on $CO_2$ recycle combustion heating system using pure oxygen instead of conventional air as an oxidant, which is thereby producing a flue gas of mostly $CO_2$ and water vapor($H_2O$) and resulting in higher $CO_2$ concentration. The advantages of the system are not only the ability to control high temperatures characteristic of oxygen combustion with recycling $CO_2$. but also the possibility to reduce NOx emission in the flue gas. A small scale industrial reheating furnace simulator and specially designed variable flame burner were used to characterize the $CO_2$ recycle oxy-fuel combustion, such as the variations of furnace pressure, temperature and composition in the flue gas during recycle. It was found that $CO_2$ concentration in the flue gas was about 80% without $CO_2$ recycle, but increased to $90{\sim}95%$ with $CO_2$ recycle. The furnace temperature and pressure was decreased due to recycle and the NOx emission was also reduced to maintain under 100ppm.

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Development of Fluorine-free MOD Precursor Solution for fabricating REBCO Superconducting Films (REBCO 초전도 박막제조를 위한 Fluorine-free MOD 전구체 용액 개발)

  • Kim, Byeong-Joo;Lim, Sun-Weon;Kim, Ho-Jin;Hong, Gye-Won;Lee, Hee-Gyoun
    • Progress in Superconductivity
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    • 제7권2호
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    • pp.152-157
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    • 2006
  • New precursor solution with dichloroacetic acid (DCA) was developed for fabricating high $J_c$ REBCO film. DCA based-precursor solution was coated on $LaAlO_3$(001) substrate by dip coating method. Processing parameters such as oxygen partial pressure, water vapor, ramping rate and pyrolysis temperature were controlled in order to obtain a good epitaxial film. The film with thickness of 0.5 micrometer was obtained by single coating and no crack was observed at calcined films. Oxygen partial pressure was controlled in the range of $100{\sim}1,000$ ppm and conversion heat treatment was carried out at the temperature range of $705-765^{\circ}C$. A critical transition temperature ($T_c$) of 90 K and a critical transport current density ($J_c$) of $>0.5\;MA/cm^2$ (77 K and self-field) were obtained for the GdBCO film. It is thought that fluorine-free MOD solution using DCA is promising precursor solution for fabricating high quality REBCO films.

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New MOD solution for the preparation of high $J_c$ REBCO superconducting films (고특성 REBCO 초전도 박막 제조를 위한 새로운 MOD 전구 용액 제조)

  • Kim, Byeong-Joo;Hong, Gye-Won;Lee, Hee-Gyoun
    • Proceedings of the KIEE Conference
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    • 대한전기학회 2005년도 제36회 하계학술대회 논문집 C
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    • pp.2001-2003
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    • 2005
  • Various organic acid were used in order to prepare new metalorganic deposition solution for high quality $REBa_2Cu_3O_{7-{\delta}}$ (RE=Y, Eu, Gd) films. Prepared fluorine free MO precursor solution was coated on single crystal (001) $LaAlO_3$ (LAO) by dip coating method. Processing parameters such as oxygen partial pressure, water vapor, ramping rate and pyrolysis temperature etc havebeen controlled in order to make high $J_c$ films with a good epitaxial relationship with substrate. 0.5 micron-thick film was obtained by single coating and no crack appeared after calcination. Oxygen partial pressure was varied in the range of $100{\sim}1,000 ppm$ and conversion heat treatment was carried out at the temperature of $725{\sim}765^{\circ}C$. A critical transition temperature $(T_{c0})$ of 90K and a critical transport current density $(J_c)$ of $>0.5MA/cm^2$ (77K and self-field) were demonstrated for the YBCO film on (001) oriented LAO substrates with a thickness of 0.5 micron. $I_c$ was determined by utilizing a transport measurement. SEM and XRD investigations confirmed that films were grown epitaxially onto the LAO single crystal substrate. It is thought that fluorine free new MOD solutionis promising for high quality REBCO films.

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An investigation of autoignition characteristics of kerosene by decomposed hydrogen peroxide (분해된 과산화수소를 이용한 케로신의 자연점화특성 조사)

  • Jo, Sung-Kwon;Kwon, Se-Jin
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 한국추진공학회 2008년도 제31회 추계학술대회논문집
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    • pp.397-400
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    • 2008
  • Traditional propellants which have a hypergolic characteristic have a high performance but also have disadvantages of toxicity and complex handling requirement. In order to replace these propellants, one of the alternatives is hydrogen peroxide which generates high temperature oxygen and water vapor after catalytic reaction. In this paper, autoignition characteristics of kerosene by decomposed hydrogen peroxide were investigated to perform fundamental research for designing a thruster using hydrogen peroxide and kerosene propellants. Contraction ratio, whether flame holder exists or not, and feeding pressure of propellants were selected as variables. From the experiments for different mixture ratio, we confirmed the ignition stability is strongly affected by a feeding pressure of propellants.

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Local Enhancement Mechanism of Cold Surges over the Korean Peninsula (한반도 한파의 지역적 강화 메커니즘)

  • Lee, Hye-Young;Kim, Joowan;Park, In-Gyu;Kang, Hyungyu;Ryu, Hosun
    • Atmosphere
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    • 제28권4호
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    • pp.383-392
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    • 2018
  • This study investigates synoptic characteristics of cold surges over South Korea during winter season (December-February). A total of 63 cold events are selected by quantile regression analysis using daily mean temperature observations from 11 KMA stations for 38 years (1979/80-2016/17). Large-scale pressure pattern during the cold surges is well characterized by high over Siberia and low over Aleutian regions, which elucidates cold advection over the Korean peninsula. However, the large-scale pattern cannot successfully explain the observed sudden decrease of temperature during the cold surges. Composite analyses reveal that a synoptic-scale cyclone developing over the northern Japan is a key feature that significantly contribute to the enhancement of cold advection by increasing pressure gradient over the Korean peninsula. Enhanced sensible and latent heat fluxes are observed over the southern ocean of Korea and Japan during the cold surges due to temperature and humidity differences between the near surface and the lower atmosphere over the ocean. The evaporated water vapor transported toward the center of the surface cyclone and condenses in the lower-to-middle troposphere. The released energy likely promotes the development of the surface cyclone by inducing positive PV near the surface of the heating region.