• 한국염색가공학회지
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• 제5권4호
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• pp.29-41
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• 1993

In order to surface Hydrophobilization of Poly(ethylene terephthalate) (PET) fiber samples were treated in the atmosphere of CF$_{4}$ or $C_{2}$F$_{6}$glow discharge. The sample used in this study was PET film which is 75$\mu$m thick made by Teijin, O-Type(Japan). The cleaned samples were placed in plasma reactor made of pyrex glass cylinder, and plasma processing was carried out by glow discharge of CF$_{4}$ or $C_{2}$F$_{6}$ gas, being continuously fed by gas flow and continuously pumped out by a vacuum system. Electric power source for generate plasma state was sustained alternating current(60Hz) and voltage was sustained 600 volt. The duration of plasma treatment varied from 15 to 120 seconds except special case, the monomer gase pressure varied from 0.02 to 0.3 Torr and power range was 10 to 90 watts. The hydrophobic features of changed PET surface were evaluated by contact angle measurement and surface chemical characteristics were analyzed by ESCA. Results can be summerized as follows. 1. The most favorable setting position of substrate was the center area between the two electrodes. 2. $C_{2}$F$_{6}$ discharge current was lower than that of CF$_{4}$ when same voltage was sustained. Treated efficiency between CF$_{4}$ and $C_{2}$F$_{6}$ did not revealed significant differences under same electric power(wattage). 3. When monomer pressure is very low below 0.02 torr, as though substrate is exposed to CF$_{4}$ or $C_{2}$F$_{6}$ plasma, it tend to be hydrophilic through a little of fluorine bond and a great deal of oxidizing reaction. 4. There brought good hydrophobilization when monomer pressure was more 0.1 torr and duration of glow discharge treatment was over 45 seconds. When monomer pressure was too high, discharge current became low. Although prolong the duration, there was no more high hydrophobilization. 5. According to ESCA analysis, there were a little CF bond and a prevailing CF$_{2}$ bond in CF$_{4}$-treated substrate. There were CF$_{3}$, a little CF and a prevailing CF$_{2}$ bond in $C_{2}$F$_{6}$-treated substrate.d substrate.

• 분석과학
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• 제34권1호
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• pp.23-35
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• 2021

In order to measure the volatile organic compounds (VOCs) of a sample which is too large to use commercially available chamber, a stainless steel vacuum chamber (VC) (with an internal diameter of 205 mm and a height of 50 mm) was manufactured and the temperature of the chamber was controlled using an oven. After concentrating the volatiles of the sample in the chamber by helium gas, it was made possible to remove residual volatile substances present in the chamber under reduced pressure ((2 ± 1) × 10-2 mmHg). The chamber was connected to a purge & trap (P&T) using a 6 port valve to concentrate the VOCs, which were analyzed by gas chromatography-mass spectrometry (GC-MS) after thermal desorption (VC-P&T-GC-MS). Using toluene, the toluene recovery rate of this device was 85 ± 2 %, reproducibility was 5 ± 2 %, and the detection limit was 0.01 ng L-1. The method of removing VOCs remaining in the chamber with helium and the method of removing those with reduced pressure was compared using Korean drinking water regulation (KDWR) VOC Mix A (5 μL of 100 ㎍ mL-1) and butylated hydroxytoluene (BHT, 2 μL of 500 ㎍ mL-1). In case of using helium, which requires a large amount of gas and time, reduced pressure ((2 ± 1) × 10-2 mmHg) only during the GC-MS running time, could remove VOCs and BHT to less than 0.1 % of the original injection concentration. As a result of analyzing volatile substances using VC-P&T-GC-MS of six types of cell phone case, BHT was detected in four types and quantitatively analyzed. Maintaining the chamber at reduced pressure during the GC-MS analysis time eliminated memory effect and did not affect the next sample analysis. The volatile substances in a cell phone case were also analyzed by dynamic headspace (HT3) and GC-MS, and the results of the analysis were compared with those of VC-P&T-GC-MS. Considering the chamber volume and sample weight, the VC-P&T configuration was able to collect volatile substances more efficiently than the HT3. The VC-P&T-GC-MS system is believed to be useful for VOCs measurement of inhomogeneous large sample or devices used inside clean rooms.

• 한국진공학회지
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• 제6권S1호
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• pp.96-109
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• 1997

In order to simulate the corrosion behavior of Zr-4 alloy in pressurized water reactors it was implanted (or bombarded) with 190ke V $Zr^+\; and \;Ar^+$ ions at liquid nitrogen temperature and room temperature respectively up to a dose of $5times10^{15} \sim 8\times10^{16} \textrm{ions/cm}^2$ The oxidation behavior and electrochemical vehavior were studied on implanted and unimplanted samples. The oxidation kinetics of the experimental samples were measured in pure oxygen at 923K and 133.3Pa. The corrosion parameters were measured by anodic polarization methods using a princeton Applied Research Model 350 corrosion measurement system. Auger Electron Spectroscopy (AES) and X-ray Photoelectric Spectroscopy (XPS) were employed to investigate the distribution and the ion valence of oxygen and zirconium ions inside the oxide films before and after implantation. it was found tat: 1) the $Zr^+$ ion implantation (or bombardment) enhanced the oxidation of Zircaloy-4 and resulted in that the oxidation weight gain of the samples at a dose of $8times10^{16}\textrm{ions/cm}^2$ was 4 times greater than that of the unimplantation ones;2) the valence of zirconium ion in the oxide films was classified as $Zr^0,Zr^+,Zr^{2+},Zr^{3+}\; and \;Zr^{4+}$ and the higher vlence of zirconium ion increased after the bombardment ; 3) the anodic passivation current density is about 2 ~ 3 times that of the unimplanted samples; 4) the implantation damage function of the effect of ion implantation on corrosion resistance of Zr-4 alloy was established.

• 상하수도학회지
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• 제19권6호
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• pp.758-766
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• 2005

This study was conducted to evaluate the effect of the transverse troughs on hydrodynamic behavior within the a certain full-scale sedimentation basin (flow rate/one basin; $10,000m^3/d$) using CFD simulation and ADV technique. In order to verify the CFD simulation, we measured the factual velocity at 36 points in the full-scale sedimentation basin, whose outlet structure is inadequate, with ADV technique. Both the CFD simulation and the ADV measurement results were in good accordance with each other. From the CFD simulation results of the existing basin, it was investigated that extreme upward flow occurs in the near of two transverse troughs. It was suspected that since the transverse troughs converted the open channel flow into the local closed pipe flow, the increased pressure in this local closed pipe flow region made the extreme upward flow. For solving this problems, it was suggested to modify transverse-typed launder into finger-typed launder and to install a longitudinal baffle in the center in this study. The CFD simulation results of all suggested amendments told us that the extreme upward flow, had occurred especially in the beneath of transverse troughs, was much less in the case of finger typed launder basin than that in the existing basin. Also, it was predicted that installing a longitudinal baffle made the fully developed flow which is more effective for sedimentation.

• 한국산학기술학회논문지
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• 제14권10호
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• pp.5115-5122
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• 2013

본 논문은 급경사지(산사태 및 사면붕괴, 축대 등)붕괴 등으로 인하여 많은 생명과 재산피해 방지를 목적으로 붕괴 위험성을 감지하고 신속히 대응을 할 수 있도록 하기 위하여 u-IT기반의 급경사지 붕괴예측 감시용 실시간 모니터링 시스템을 개발하였다. 급경사지붕괴 감시에 중요한 계측기로서 강우량 계측기, 간극수압 계측기, 지표변위 계측기, 지중경사 계측기, 함수비계측기, 영상분석 계측기 등을 선정하고 테스트베드에 적용하였다. 각 계측기의 신뢰성 검증에 필요한 동작기능 및 성능확인은 현장에 설치된 계측기 별로 실험을 통하여 확인하였다. 본 연구에서 개발한 급경사지붕괴 감지를 위한 USN기반의 실시간 급경사지 모니터링 시스템을 급경사지 붕괴감지뿐만 아니라 도로변 절개사면과 암반사면 등에 상시계측을 통하여 붕괴위험 예측에도 적용할 수 있으므로 인명피해와 재산피해를 최소할 수 있을 것으로 판단되며, 이 시스템은 본 연구의 시범적용 결과를 바탕으로 급경사지 전역에 확산될 계획에 있다.

• 한방재활의학과학회지
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• 제30권2호
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• pp.67-75
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• 2020

Objectives SJ004 is a natural herbal medicine that contains Acyranthes japonica Nakai and Eucommia ulmoides Oliver traditionally used for joint and spinal diseases. This study aimed to establish an efficient method of extracting SJ004 to standardize using the yield, high-performance liquid chromatography (HPLC), and antioxidant assay. Methods SJ004 was extracted with distilled water, 70% and 100% of ethyl alcohol (EtOH). The method validation of 20-hydroxyecdysone and pinoresinol diglucoside was determined by HPLC-photo diode array and the content of SJ004 was calculated. The antioxidant activity of each extract was compared and measured using total flavonoids, total phenolic compounds, 2,2-azino-bis(3-ethylbenzothiazoline-6-sulfonic acid), and ferric reducing antioxidant power according to the standard protocol. Results The yield was highest in pure water extract and lowest in 100% EtOH. But, the content of marker compounds indicating 20-hydroxyecdysone and pinoresinol diglucoside was highest in 100% EtOH extract. In the physiological activity measurement using antioxidant activity, 100% ethanol extract was highest. The limit of detection indicating 20-hydroxyecdysone and pinoresinol diglucoside were analyzed 0.33 ㎍/mL, 0.1616 ㎍/mL, and the limit of quantification were analyzed 1.01 ㎍/mL and 0.49 ㎍/mL respectively. Conclusions The experimental results showed that the extraction conditions have a significant effect on content of marker compounds and antioxidant activity. As a result of method validation, SJ004 was standardized by 20-hydroxyecdysone and pinoresinol diglucoside.

• 한방재활의학과학회지
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• 제30권4호
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• pp.31-39
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• 2020

Objectives Danggwisoo-san and Jakyakgamcho-tang are frequently prescribed for traffic accident patients in Korea. The aim of this study was to examine index compound analysis, antioxidant activity and amount of starch measurement by extraction method. Methods Danggwisoo-san and Jakyakgamcho-tang were extracted with water and 70% ethanol. Antioxidant activity was measured by 2,2-Diphenyl-1-picrylhydrazyl, 2,2-azino-bis(3-ethylbenzothiazoline-6-sulfonic acid) and ferric reducing antioxidant power according to the standard protocol. The contents of the indicator components nodakenin, paeoniflorin, and glycyrrhizin were measured by high-performance liquid chromatography, respectively. All starches were hydrolyzed and then total D-glucose was measured and compared. Results Antioxidant activity was excellent in 70% ethanol in all assays. The index component was jagged because its solubility was different depending on the extraction solvent. Starch content was significantly lower in 70% alcohol extract than water extract. Conclusions The results of this study showed that physiological activities and components are different according to extraction conditions. Each herbal medicine has a suitable extraction solvent. Also, the difference in starch content is an object to be considered as it may affect digestion and absorption.

• 대한기계학회논문집B
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• 제20권1호
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• pp.266-274
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• 1996

An experimental work was conducted to investigate the characteristics of the onset of flooding in vertical annuli with a direct injection mode using air and water. The onset of flooding was determined by means of pressure drop measurement while the air velocity was increased gradually under fixed liquid flow rates. Data of the onset of flooding were collected for various combinations of the tube size and the nozzle number. A theoretical analysis of the onset of flooding was also performed based on an envelope theory. The result shows that the onset of flooding in small-scale annuli can be predicted relatively well by the theory. A modified Wallis parameter was used to investigate the scaling effect of flooding phenomena in the annuli, indicating a relatively reasonable result. The number of nozzle has no effect on the flooding velocity when liquid was injected through 2, 3, 4 and 6 nozzles but the initiation of flooding was significantly expedited when 12 nozzles were employed for liquid injection.

• 대한화장품학회지
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• 제30권2호
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• pp.207-210
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• 2004

유용성 감초산은 강한 항염 작용으로 주름개선용 기능성 화장품에서 널리 사용되어지는 물질이다. 그러나 용해성이 좋지 않고 빛, 열, 산소에 의하여 변질되기 쉽다. 본 연구에서는 유용성감초산을 PG/hydrogenated lecithin/MCT/glycerine/water를 microfluidzer를 이용해 30-50nm인 nanosolve-licorice를 만들고, 잘 용해된 nanosolve-licorice를 다공성 PMMA에 에탄올과 함께 넣은 후 microfluidzer를 1000 BAR에서 연속 3회 처리하여 안정화시켰다. 이 실험에서 글라블리딘 함량을 HPLC로 측정한 결과 기존의 리포좀에 비하여 3-5배 정도 안정성을 보였으며, PMMA 캡슐로 된 리코러스는 피부의 침투가 기존 리포솜에 비하여 월등히 우수하여 항염 효과를 더욱 증가시켰다. 이러한 실험을 image analyzer, particle size analyzer, FF-TEM, chromameter, HPLC등의 분석장비를 사용하였다.

• 한국세라믹학회지
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• 제39권4호
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• pp.367-376
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• 2002

$SrZr_{1-x}Y_xO_{3-\delta}$(x=0.05, 0.10)-금속전극 계에서 임피던스법과 d.c.법으로 전기전도도를 측정함으로써 고체전해질 및 전극전도도를 고찰하였다. 고체전해질과 anode를 통한 전기전도도는 $P_W^{1/2}$(PW는 수증기분압)에 의존하여 증가함을 보였다. Cathode 전도도는 $P_{O2}^{1/4}$에 비례함을 보였으며, 수증기분압 증가와 함께 감소하여 고체전해질내의 전자 결함의 농도와 함께 증가하는 것을 알 수 있었다. 수소분위기에서는 수증기의 첨가가 anode와 cathode 두 방향의 전극반응 속도 모두를 촉진하였다. 도펀트 첨가량이 5%에서 10%로 증가될 때 anode와 고체전해질의 전기전도도가 3배 이상 크게 증가하여 유효 산소이온공공의 농도가 급격히 증가함을 알 수 있었다. Pt와 Ag전극을 통한 cathode 전도도의 활성화에너지가 거의 같은 값을 나타냈으며 이는 cathode반응의 속도가 금속전극이 아니라 고체전해질표면에서 일어나는 반응에 의하여 결정되는 것으로 해석되었다.