• Title/Summary/Keyword: Water Glass

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Fabrication of Low Temperature Cofiring Substrate Containing Fluorine by Water Swelling (Water Swelling을 이용한 Fluorine함유 저온소결 기판의 제조)

  • 윤영진;최정헌;이용수;강원호
    • Journal of the Microelectronics and Packaging Society
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    • v.9 no.2
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    • pp.19-25
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    • 2002
  • Glass composed of $Li_2$O.MgO. $MgF_2$.$SiO_2$.$B_2O_3$ for the fabrication of green sheet was prepared by melting process, and glass ceramics was prepared by the process of nucleation and grystal growth for the glass of $Li_2$O.MgO. $MgF_2$.$SiO_2$.$B_2O_3$ system with Lithium fluorhectorite and Lithium boron fluorphlogopite crystal phase. Powderization of the glass ceramics was carried out by water swelling. The average particle size at this point was 2.574 $\mu\textrm{m}$. Slurry was prepared for green sheet using high viscous sol fabricated by water swelling, which shows cleavage phenomenon in prepared glass ceramics. The optimum ratio of powder to water for the tape casting was 18:100, and its viscosity was 11,000~14,000 cps.

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Bonding Performance of Glulam Reinforced with Textile Type of Glass- and Aramid-Fiber, GFRP and CFRP

  • Kim, Keon-Ho;Hong, Soon-Il
    • Journal of the Korean Wood Science and Technology
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    • v.39 no.2
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    • pp.156-162
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    • 2011
  • To evaluate the bonding performance of reinforced glulam, the textile type of glass fiber and aramid fiber, and the sheet type of glass fiber reinforced plastic (GFRP) and carbon fiber reinforced plastic (CFRP) were used as reinforcements. The reinforced glulam was manufactured by inserting reinforcement between the outmost and middle lamination of 5ply glulam. The types of adhesives used in this study were polyvinyl acetate resins (MPU500H, and MPU600H), polyurethane resin and resorcinol resin. The block shear strengths of the textile type in glass fiber reinforced glulam using MPU500H and resorcinol resin were higher than 7.1 N/$mm^2$, and these glulams passed the wood failure requirement of Korean standards (KS). In case of the sheet types, GFRP reinforced glulams using MPU500H, polyurethane resin and resorcinol resin, and CFRP reinforced glulams using MPU500H and polyurethane resin passed the requirement of KS. The textile type of glass fiber reinforced glulam using resorcinol resin after water and boiling water soaking passed the delamination requirement of KS. The only GFRP reinforced glulam using MPU500H after water soaking passed the delamination requirement of KS. We conclude that the bonding properties of adhesive according to reinforcements are one of the prime factors to determine the bonding performance of the reinforced glulam.

Correlations between Refractive Index and Retroreflectance of Glass Beads for Use in Road-marking Applications under Wet Conditions

  • Shin, Sang Yeol;Lee, Ji In;Chung, Woon Jin;Choi, Yong Gyu
    • Current Optics and Photonics
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    • v.3 no.5
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    • pp.423-428
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    • 2019
  • Visibility of road-surface markings is one of the critical issues that should be secured for self-driving cars as well as human drivers. Glass beads are taking on the role of retroreflectors, and therefore are considered a necessity in modern pavements. In this context, retroreflectance is sensitively dependent not only on the refractive index of glass beads but also on that of the surrounding medium. This implies that the optimum refractive index of glass beads immersed in water, i.e. under wet conditions, is different from that of glass beads surrounded by air, i.e. under dry conditions. A refractive index of approximately 1.9, which is known to maximize retroreflectance under dry conditions, actually exhibits much poorer retroreflectance under wet conditions. This suggests that glass beads with optimal refractive index for wet conditions need to be installed together with those for dry conditions. We propose a facile but practical model capable of calculating retroreflectance of glass beads surrounded by an arbitrary medium, here water in particular, and experimentally verify its capability of assessing the refractive index of commercial glass beads. Changes in retroreflectance according to the mixing ratio of glass beads with different refractive indices are also discussed, in an effort to propose the proper use of glass beads produced for dry and wet conditions.

Production of Foamed Glass by Induction Heating Method (인덕션 가열법을 이용한 발포유리제조)

  • Sun, Hongshuai;Yoo, In-Sang
    • Applied Chemistry for Engineering
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    • v.28 no.5
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    • pp.513-520
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    • 2017
  • The application possibility of an alternative new method with low energy consumption was studied for the eco-friendly fabrication of foamed glasses from waste glasses. As a result, fabricating temperature can be reduced under $300^{\circ}C$ without using various expensive inorganic oxidants. The foamed glass can be fabricated at a proper mixing ratio of the waste glass powder, water glass, little surfactant and bubble stabilizer by induction heating method. In the experimental range, the assured optimal condition is 4 min heating on the induction machine with a steel-container ($100mm{\times}100mm{\times}20mm$) and followed by evaporating and drying process for 11 min with 110 g of glass powder, 80 g of water glass, 3 g of surfactant and 0.2 g of bubble stabilizer. When the foamed glass was fabricated at the optimal condition, the density of the glass was $0.85g/cm^3$ and the heat conduction was $0.052W/h{\cdot}K$. In addition, the compressive strength of the glass was above $50kg/cm^2$.

Minimizing the Water Leaching of Zincborate Glass by La2O3 Addition for LTCC Applications

  • Hong, Seung-Hyuk;Jung, Eun-Hee;Oh, Chang-Yong;Kim, Shin;Shin, Hyun-Ho
    • Journal of the Korean Ceramic Society
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    • v.45 no.3
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    • pp.157-160
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    • 2008
  • A series of $La_2O_3$-added zincborosilicate glasses was fabricated by systematically varying $La_2O_3$ addition up to 15mol% under the constraint of a ZnO:$B_2O_3$ ratio of 1:2. The degree of water leaching after ball milling of the prepared glasses in water medium was relatively quantified by the change in zinc peak intensity in energy dispersive spectroscopy. 8mol% of $La_2O_3$ was the most efficient addition in inhibiting the glass leaching by water. The role of $La_2O_3$ in inhibiting the leaching was explained in terms of change of structural units in the glass network. When the optimum 8mol% $La_2O_3$-added ZnO-$B_2O_3$ glass was used as sintering aid for $Al_2O_3$, the fabricated alumina-glass composite at $875^{\circ}C$ demonstrated dielectric constant of 6.11 and quality factor of 15470 GHz, indicating the potential of leaching-minimized $La_2O_3-ZnO-B_2O_3$ glass for application to low temperature co-firing ceramic technology.

Effect of HF and Plasma Treated Glass Surface on Vapor Phase-Polymerized Poly(3,4-ethylenedioxythiophene) Thin Film : Part II

  • Lee, Joonwoo;Kim, Sungsoo
    • Journal of Integrative Natural Science
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    • v.6 no.4
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    • pp.215-219
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    • 2013
  • In this study, in order to investigate how consecutive treatments of glass surface with HF acid and water vapor/Ar plasma affect the quality of 3-aminopropyltriethoxysilane self-assembled monolayer (APS-SAM), poly(3,4-ethylenedioxythiophene) (PEDOT) thin films were vapor phase-polymerized immediately after spin coating of FeCl3 and poly-urethane diol-mixed oxidant solution on the monolayer surfaces prepared at various treatment conditions. For the film characterization, various poweful tools were used, e.g., FE-SEM, an optical microscope, four point probe, and a contact angle analyzer. The characterization revealed that a well prepared APS-SAM on a glass surface treated with water vapor/Ar plasma is very useful for uniform coating of FeCl3 and DUDO mixed oxidant solution, regardless of HF treatment. On the other hand, a bare glass surface without APS-SAM but treated with HF and water vapor/Ar plasma generally led to a very poor oxidant film. As a result, PEDOT films vapor phase-polymerized on APS-SAM surfaces are far superior to those on bare glass surfaces in the quality and electrical characteristics aspects.

The study on dielectric Properties of Li$_2$O-MgO-MgF$_2$-SiO$_2$system glass ceramics (Li$_2$O-MgO-MgF$_2$-SiO$_2$계 Glass-Ceramics 의 유전특성에 관한 연구)

  • 이승준;강원호
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1995.11a
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    • pp.18-21
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    • 1995
  • In this study, crystallization, water swelling and dielectric properties of Li$_2$O-MgO-MgF$_2$-SiO$_2$System glass ceramics were investigated. Base glass melted at 1450$^{\circ}C$ and crystallized through heat treatment. The optimum heat treatment schedule was 460$^{\circ}C$ for nucleation and 640$^{\circ}C$, 1100$^{\circ}C$ for crystallization. The Principle crystalline phase was lithium fluorhectorite. Lithium fluorhectorite was the crystal phase which it was influenced water swelling. Samples progressed 2 minutes later they have rapid hydration at forced water swelling condition. Also value of dielectric constants have approximately 10 at 100kHz.

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Surface properties of epoxy/glass Eber composites by environmental conditions (사용 환경조건에 따른 Epoxy/Glass Fiber 복합재료의 표면특성)

  • 임경범;이백수;황명환;김윤선;유도현;이덕출
    • Journal of the Korean Vacuum Society
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    • v.9 no.3
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    • pp.279-284
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    • 2000
  • In order to analysis the degradation process of epoxy/glass fiber for outdoor condition, FRP laminate was exposed to high temperature and water. Then the degradation process was evaluated by comparing contact angle, surface potential decay, and surface resistivity. For the change of wettability, the contact angle of thermal-treated specimen with the high temperature of $200^{\circ}C$ increased. But that of water-treated specimen decreased. The characteristic of surface potential decay shows the tendency of the remarkable decrease on water-treated specimens, but increase on thermal-treated specimen compared with untreated one. Also, for the surface resistivity, it shows the same trend compared with the change of contact angle.

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An experimental study on the preparation and property of the sintering aggregate using fly ash (플라이애쉬를 이용한 소성골재의 제조 및 특성에 관한 연구)

  • 박대영;김도수;박종현;임채영;노재성
    • Proceedings of the Korea Concrete Institute Conference
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    • 1998.10a
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    • pp.239-244
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    • 1998
  • Fusion temperature of fly ash was determined with wasted glass wool and borax using ash fusion determinator, 0.5wt% of bentonite and water glass used as binder, 50wt% of wasted glass wool added to fly ash, fusion temperature of fly ash was 1, 156$^{\circ}C$. Pellet was prepared, and then sintered at 1, 00$0^{\circ}C$ and 1, 10$0^{\circ}C$. Water-absorption rate, specific gravity, porosity and pore structure of sintering aggregate was determined.

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Effect of Acid Catalyst Kinds on the Pore Structural Characteristics of Water Glass based Silica Aerogel (산 촉매가 물유리 기반 실리카 에어로겔의 기공구조에 미치는 영향)

  • Nah, Ha-Yoon;Jung, Hae-Noo-Ree;Lee, Kyu-Yeon;Ku, Yang Seo;Park, Hyung-Ho
    • Journal of the Microelectronics and Packaging Society
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    • v.24 no.3
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    • pp.13-18
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    • 2017
  • Water glass is much cheaper than silicon alkoxide, so it has advantage for commercialization. A condensation by acid catalyst makes considerable effect about the properties of water glass based silica aerogel among many factors in silica aerogel process. The pore structural properties of water glass based silica aerogel such as specific surface area and pore size distribution have been investigated through the changes in the amount and the kinds of acid catalyst. It has been confirmed that water glass based silica aerogel is affected by various conditions of catalyst in the condensation reaction such as the kind, concentration, and the amount of mole of acid catalyst on the properties of final products. Especially, it is checked that the effect of mole of acid is more prominent than that of concentration. In the case for conventional method with introducing 4M HCl in condensation step, the silica aerogel could be synthesized which has $394m^2/g$ of specific surface area, 2.20 cc/g of pore volume, 22.3 nm of average pore size, and 92.53% of porosity. On the other hand, when 4M sulfuric acid was used with 73 mmol at the condensation step of water glass based silica aerogel, the pore structural characteristics of water based silica aerogel showed better properties than the case of using HCl, for example, specific surface area was measured as $516m^2/g$, and pore volume, average pore diameter, and porosity were obtained as 3.10 cc/g, 24.1 nm, and 96.1%, respectively.