• 한국해양환경ㆍ에너지학회지
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• 제3권1호
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• pp.25-34
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• 2000

이중유벽 사이에 가두어진 기름층과 전방 유벽의 끝에서 발생하는 보오텍스 거동간의 관계를 보기 위하여 파노라마 PIV 기법을 사용하였다. 물-기름 자유경계면 근처의 순간 및 시간평균 경계층 유속분포를 계측하여 경계면 상의 전단응력 도출가능성을 확인하였다. 본 기법을 사용하면 자유경계면의 거동이 작거나 규칙적인 경우 경계면상 전단층내 상세 유동구조를 파악하기 충분한 정도의 해상도를 가진 결과를 얻을 수 있다고 판단되었다.

• 대한화장품학회지
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• 제36권1호
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• pp.1-16
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• 2010

본 총설에서는 나노미터 크기의 고체 입자가 오일-물 계면에 흡착됨으로써 안정화된 에멀젼의 제조와 성질에 대하여 기술하였다. 이렇게 제조된 에멀젼을 Pickering 에멀젼이라 하며 이 에멀젼을 계면활성제로 안정화된 일반적인 에멀젼과 비교하였다. Pickering 에멀젼의 독특한 성질은 입자의 계면 흡착 에너지가 큰 점에 기인하며 일반 에멀젼과 주요한 차이점은 고체 입자가 비가역적으로 계면에 흡착한다는 사실이다. Pickering 에멀젼의 전상은 w/o (water-in-oil) 타입에서 o/w (oil-in-water)로 수상의 분율이 증가함에 따라 발생한다. 친수성의 입자는 o/w 에멀젼을 형성하는 경향을 보이고 친유성 입자는 w/o 에멀젼을 형성하는 경향을 보이며 이는 고체 입자의 오일-물 계면에서의 접촉각에 따른다. Pickering 에멀젼의 안정성은 많은 부분에서 일반적인 에멀젼과는 다른 거동을 보였다. 저자는 또한 Pickering 에멀젼의 화장품 응용 가능성에 대해서도 논의하였다.

• Bulletin of the Korean Chemical Society
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• 제8권5호
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• pp.398-403
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• 1987

A general theory of polymer adsorption at a semi-permeable oil-water interface of the biphasic solution is presented. The configurational factor of the solution in the presence of the semi-open boundary at the interface is evaluated by the quasicrystalline lattice model. The present theory gives the feature of the bulk concentration equilibria between oil-water subsystems and the surface excesses of ${\Gamma}^{\alpha}$ and ${\Gamma}^\{beta}$ of the polymer segments as a function of the degree of polymerization $\gamma$, the Flory-Huggins parameter in $\beta$-phase $x_{\rho}^{{\beta}_{\rho}}$, the differential adsorption energy parameter in $\beta$-phase $x_{\sigma}^{{\beta}_{\rho}}$, the differential interaction energy parameter ${\Delta}x_{\rho}$ and the bulk concentration of the polymer in ${\beta}-phase ${\varphi}_2^{{\beta(*)}_2}$. From our numerical results, the characteristics of ${\Gamma}^{\alpha}$ are shown to be significantly different from those of ${\Gamma}^{\beta}$ in the case of high polymers, and this would be the most apparent feature of the adsorption behavior of the polymer at a semi-permeable oil-water interface, which is sensitively dependent on ${\Delta}x_{\rho}$ and r.

• Journal of Mechanical Science and Technology
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• 제15권12호
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• pp.1845-1852
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• 2001

This paper deals with the experiment to obtain quantitative information about conditions of the interface between a water drop and surrounding oil. Velocity distributions in very close region of the interface are measured by introducing a new illumination technique and a telecentric lens. It enables precise measurements of velocity distributions in the close region to the interface. Although the measured velocity distributions exhibit strong influence from the solid wall of an experimental tube, the coincidence of inner and outside velocities on the interface is clearly confirmed for the clean interface. The shearing stresses on the interface, which are proportional to the velocity gradient normal to the interface, clearly show conditions of contaminated interface, which can be divided into two parts. From front stagnation point to somewhere near a separation point, the distribution of shearing stresses is well coincide with that of the Hadamard's analytical solution, while the distribution on the latter part of the interface sows quite different feature, which is supposed to be strongly influenced by contamination of the surface.

• 태양에너지
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• 제20권1호
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• pp.55-62
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• 2000

An experimental study on the stratified fluids with water and silicon oil of same volume in the cavity with upper cooling surface was carried out to investigate the flow characteristics, heat transfer through the interface of fluids, and the applications of thermal behaviors in a square cavity. The experiments were performed with variation of initial temperature and cooling surface temperature. The temperature drop of oil was faster than that of water and freezing was initiated from the interface of oil and water and propagated downward. For the water above $4^{\circ}C$, the cooling rate was faster than that below $4^{\circ}C$ and showed almost same temperature distribution but for the water that of below $4^{\circ}C$, it showed the stable stratified temperature distribution. The lower the initial temperature and the higher the cooling surface temperature was, the longer the supercooling duration.

• 한국전산유체공학회지
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• 제21권3호
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• pp.31-38
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• 2016

The FDS-HCIB method is expanded to simulate water-oil-air flows around oil booms under relative motion, which is intended to increase the thickness of contained oil. The FDS scheme captures discontinuity in the density field and abrupt change of the tangential velocity across an interface without smearing. The HCIB method handles relative motions of thin oil booms with ease. To validate the developed FDS-HCIB code for water-oil-air flow around a moving body, the computed results are compared with the reported experimental results on the shape, length, and thickness of the oil slicks under towing. It is observed that the increase in pressure field between two barriers lifts the oil slick and the interfacial wave propagates and reflects as one barrier gets closer to the other barrier.

• 한국해양환경ㆍ에너지학회지
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• 제1권2호
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• pp.40-51
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• 1998

유벽에 의하여 가두어진 오일의 조류중 거동을 회류수조에서 2차원적인 실험설비를 이용하여 살펴보았다. 유벽을 적정 깊이의 수직판으로 대치하고 레이저 광원을 이용하여 오일과 물과의 경계면 변형을 2 종류의 오일 (콩기름과 경유)에 대하여 관찰하였다. 적용된 조건으로 조류의 속도는 10 cm/s - 35 cm/s, 유벽의 깊이는 4 cm 와 8 cm, 그리고 유량은 2 liter - 8 liter 의 변화를 주었다. 다양한 경계면의 거동과 조건에 따른 누유의 손실 방식을 차원해석을 통하여 정리하고 유적누유와 연속누유의 발생 메카니즘을 설명하였다.

• Bulletin of the Korean Chemical Society
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• 제28권5호
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• pp.880-882
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• 2007

• Bulletin of the Korean Chemical Society
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• 제12권3호
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• pp.334-342
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• 1991

To investigate the phase equilibria and structural properties of microemulsions, we study a simple phenomenological model on the basis of the cubic lattice cell with which the oil- and water-filled cells are connected one another, respectively. The surfactant is assumed to be insoluble in both oil and water, and to be adsorbed at the oil-water interface. The Schulman condition, according to which the lateral pressure of the surfactant layer is compensated by the oil-water interfacial tension, is found to hold to good approximation in the middle-phase microemulsion. Our results show that the oil- and water-filled domains in that microemulsion are about 50-150 $\AA$ across, and depend sensitively on the curvature parameters. The phase diagram is not symmetric in this model. It may be asymmetrized intrinsically by non-equivalency of oil and water. The two- and tree-phase equilibria including critical points and critical endpoints are found.

• 한국철도학회:학술대회논문집
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• 한국철도학회 2007년도 춘계학술대회 논문집
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• pp.20-25
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• 2007

KTX is being operated on Kyung-Pu High Speed Railroad Line and Ho-Nam Railroad Line from April 2004. Reduction units is occurring water infiltration at heavy snow and oil leakage because of labyrinth structure. This paper describes design method and evaluation technology to improve structure to prevent water infiltration and oil leakage for reduction units of KTX. This reduction units need high power and high speed to run and they have to make optimal lubricant without change current interface.