• Title/Summary/Keyword: Waste treatment

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Leaching of Iron and Aluminum from Red Mud and Preparation of Coagulants (적니로부터 철과 알루미늄의 침출 및 응집제의 제조)

  • Lee, Jae-Rok;Hwang, In-Gook;Bae, Jae-Heum
    • Clean Technology
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    • v.15 no.1
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    • pp.38-41
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    • 2009
  • Red mud is generated as a waste byproduct during the production of aluminum hydroxide/alumina from bauxite ore in the Bayer process. In this study coagulants for wastewater treatment were prepared by leaching iron and aluminum from red mud with hydrochloric acid. The removal efficiency of heavy metal ions by the red mud coagulant increased with increasing the adjusted pH value of the synthetic wastewater. When the red mud coagulant was prepared, the leaching efficiency of Fe decreased with increasing the weight of red mud, while the pH value of the red mud coagulant increased. The solution of the red mud coagulant mixed with water was reacted again with red mud to produce the leached solution, which had higher concentrations of Fe and Al and a higher pH value than the red mud coagulant. Also, its pH value was comparable to that of other coagulants: $FeCl_3$ and $Fe_2(SO_4)_3$.

Dental-derived cells for regenerative medicine: stem cells, cell reprogramming, and transdifferentiation

  • Young-Dan Cho;Kyoung-Hwa Kim;Yong-Moo Lee;Young Ku;Yang-Jo Seol
    • Journal of Periodontal and Implant Science
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    • v.52 no.6
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    • pp.437-454
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    • 2022
  • Embryonic stem cells have been a popular research topic in regenerative medicine owing to their pluripotency and applicability. However, due to the difficulty in harvesting them and their low yield efficiency, advanced cell reprogramming technology has been introduced as an alternative. Dental stem cells have entered the spotlight due to their regenerative potential and their ability to be obtained from biological waste generated after dental treatment. Cell reprogramming, a process of reverting mature somatic cells into stem cells, and transdifferentiation, a direct conversion between different cell types without induction of a pluripotent state, have helped overcome the shortcomings of stem cells and raised interest in their regenerative potential. Furthermore, the potential of these cells to return to their original cell types due to their epigenetic memory has reinforced the need to control the epigenetic background for successful management of cellular differentiation. Herein, we discuss all available sources of dental stem cells, the procedures used to obtain these cells, and their ability to differentiate into the desired cells. We also introduce the concepts of cell reprogramming and transdifferentiation in terms of genetics and epigenetics, including DNA methylation, histone modification, and non-coding RNA. Finally, we discuss a novel therapeutic avenue for using dental-derived cells as stem cells, and explain cell reprogramming and transdifferentiation, which are used in regenerative medicine and tissue engineering.

Evaluation on the Effect of Coal-ash as Landfill Cover Material of Mono-Layer Cover System through the Field Scale Test (현장 실험을 통한 단층형 매립복토시스템의 복토재로서 석탄회의 효과 검토)

  • Yun, Sung-Wook;Kang, Sin-Il;Jin, Hae-Geun;Kim, Pil-Joo;Kim, Soon-Oh;Yu, Chan
    • Journal of the Korean Geotechnical Society
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    • v.26 no.7
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    • pp.81-91
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    • 2010
  • In order to investigate the applicability and suitability of the coal ash (bottom ash) to landfill final cover, field pilot-scale lysimeter experiments were carried out. The mixture of loamy soil, bottom ash, and construction waste was placed as a cover material in lysimeter ($2m{\times}6m{\times}1.2m$) which were constructed with cement brick, and then volumetric water contents, pF value, and the quantity of runoff and seepage of treatment boxes filled with the mixture of loamy soil and the industrial by-products were monitored from July, 2007 to february, 2008. Among the cases tested, consequently, the case containing the mixture of bottom ash and loamy soil was most effective in plant growth and water retention ability.

Geochemical and S isotopic studies of pollutant evolution in groundwater after acid in situ leaching in a uranium mine area in Xinjiang

  • Zhenzhong Liu;Kaixuan Tan;Chunguang Li;Yongmei Li;Chong Zhang;Jing Song;Longcheng Liu
    • Nuclear Engineering and Technology
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    • v.55 no.4
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    • pp.1476-1484
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    • 2023
  • Laboratory experiments and point monitoring of reservoir sediments have proven that stable sulfate reduction (SSR) can lower the concentrations of toxic metals and sulfate in acidic groundwater for a long time. Here, we hypothesize that SSR occurred during in situ leaching after uranium mining, which can impact the fate of acid groundwater in an entire region. To test this, we applied a sulfur isotope fractionation method to analyze the mechanism for natural attenuation of contaminated groundwater produced by acid in situ leaching of uranium (Xinjiang, China). The results showed that δ34S increased over time after the cessation of uranium mining, and natural attenuation caused considerable, area-scale immobilization of sulfur corresponding to retention levels of 5.3%-48.3% while simultaneously decreasing the concentration of uranium. Isotopic evidence for SSR in the area, together with evidence for changes of pollutant concentrations, suggest that area-scale SSR is most likely also important at other acid mining sites for uranium, where retention of acid groundwater may be strengthened through natural attenuation. To recapitulate, the sulfur isotope fractionation method constitutes a relatively accurate tool for quantification of spatiotemporal trends for groundwater during migration and transformation resulting from acid in situ leaching of uranium in northern China.

Influence of palm oil fuel ash on behaviour of green high-performance fine-grained cement mortar

  • Sagr, Salem Giuma Ibrahim;Johari, M.A. Megat;Mijarsh, M.J.A.
    • Advances in materials Research
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    • v.11 no.2
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    • pp.121-146
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    • 2022
  • In the recent years, the use of agricultural waste in green cement mortar and concrete production has attracted considerable attention because of potential saving in the large areas of landfills and potential enhancement on the performance of mortar. In this research, microparticles of palm oil fuel ash (POFA) obtained from a multistage thermal and mechanical treatment processes of raw POFA originating from palm oil mill was utilized as a pozzolanic material to produce high-performance cement mortar (HPCM). POFA was used as a partial replacement material to ordinary Portland cement (OPC) at replacement levels of 0, 5, 10, 15, 20, 25, 30, 35, 40% by volume. Sand with particle size smaller than 300 ㎛ was used to enhance the performance of the HPCM. The HPCM mixes were tested for workability, compressive strength, ultrasonic pulse velocity (UPV), porosity and absorption. The results portray that the incorporation of micro POFA in HPCMs led to a slight reduction in the compressive strength. At 40% replacement level, the compressive strength was 87.4 MPa at 28 days which is suitable for many high strength applications. Although adding POFA to the cement mixtures harmed the absorption and porosity, those properties were very low at 3.4% and 11.5% respectively at a 40% POFA replacement ratio and after 28 days of curing. The HPCM mixtures containing POFA exhibited greater increase in strength and UPV as well as greater reduction in absorption and porosity than the control OPC mortar from 7 to 28 days of curing age, as a result of the pozzolanic reaction of POFA. Micro POFA with finely graded sand resulted in a dense and high strength cement mortar due to the pozzolanic reaction and increased packing effect. Therefore, it is demonstrated that the POFA could be used with high replacement ratios as a pozzolanic material to produce HPCM.

Synthesis of DMDBTDMA and determination of radiolysis products by GC/MS (DMDBTDMA의 합성 및 방사선 분해산물의 GC/MS 분석)

  • Yang, Han-Beom;Lee, Eil-Hee;Park, Gyo-Beom
    • Analytical Science and Technology
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    • v.21 no.5
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    • pp.403-411
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    • 2008
  • Dimethyldibutyltetradecylmalonamide (DMDBTDMA) extractant was used in a solvent extraction process for a radioactive liquid waste treatment. For the study of radiolysis phenomena, DMDBTDMA was synthesized and the degradation compounds (n-methylbutylamine, tetradecane, 1-tetradecanol) in the DMDBTDMA extractant, irradiated with $^{60}Co$ gamma ray, were identified and determined as radiolysis products by a Fourier transform infrared (FT-IR), gas chromatograph/mass spectrometer (GC/MS) analysis and GC/MS with selected ion monitoring (SIM) mode. Retention behavior of n-methylbutylamine, n-dodecane, tetradecane and 1-tetradecanol in the total ion chromatogram with the standard materials and n-dodecane as the internal standard (ISTD) were 2.35 min., 8.83 min., 10.68 min. and 12.75 min., respectively. In the case of tetradecane, there was a linear relationship between the concentration of the tetradecane and the absorbed dose of the ${\gamma}$-ray irradiated DMDBTDMA.

Alkali Recovery by Electrodialysis Process: A Review (전기투석 공정에 의한 알칼리 회수: 총설)

  • Sarsenbek Assel;Rajkumar Patel
    • Membrane Journal
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    • v.33 no.3
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    • pp.87-93
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    • 2023
  • Electrodialysis (ED) is essential in separating ions through an ion exchange membrane. The disposal of brine generated from seawater desalination is a primary environmental concern, and its recycling through membrane separation technology is highly efficient. Alkali is produced by several chemical industries such as leather, electroplating, dyeing, and smelting, etc. A high concentration of alkali in the waste needs treatment before releasing into the environment as it is highly corrosive and has a chemical oxygen demand (COD) value. The concentration of calcium and magnesium is almost double in brine and is the perfect candidate for carbon dioxide adsorption, a major environmental pollutant. Sodium hydroxide is essential for the metal carbonation process which, is easily produced by the bipolar membrane electrodialysis process. Various strategies are available for its recovery, like reverse osmosis (RO), nanofiltration (NF), ultrafiltration (UF), and ED. This review discusses the ED process by ion exchange membrane for alkali recovery are discussed.

Impact of Land-based Pollution Sources on Seawater and Shellfish after Rainfall Event in the Jindongman Area (강우 발생에 의한 진동만해역의 육상오염원이 해수 및 패류에 미치는 영향 분석)

  • Jang Won Lee;Minchul Yoon;Ji Hoon Kim;Sung Rae Jo;Ki Ho Nam;Kwang Soo Ha;Kunbawui Park
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.56 no.6
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    • pp.798-809
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    • 2023
  • In this study, we evaluated the impacts of land-based pollution sources on seawater and shellfish in the Jindongman area after 20.5 mm and 90.6 mm rainfall events. We analyzed sanitary indicator microorganisms used in survey management, such as total coliform, fecal coliform, Escherichia coli, and male-specific coliphage in Waste water treatment plant (WWTP), major inland pollution source,s seawater, and shellfish for 4 days after rainfall events. Our results showed that the range of coliform group and fecal coliform was 1.8-49 and <1.8-4.5 MPN (most probable number)/100 mL, respectively, after rainfall events in WWTP discharge water. Furthermore, the radius of the calculated impacted area of major inland pollution sources ranged from 5 to 798 m after 20.5 mm of rainfall and 30 to 1,031 m after 90.6 mm of rainfall. The fecal coliform of seawater at 30 stations in the shellfish growing area and areas adjacent to four stations was <1.8-130 and from <1.8-79 MPN/100 mL, respectively. The E. coli level of shellfish at 7 stations in the shellfish growing area was <18-220 MPN/100 g.

Hydrophobic modification conditions of Al2O3 ceramic membrane and application in seawater desalination

  • Lian li;Zhongcao Yang;Lufen Li
    • Membrane and Water Treatment
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    • v.15 no.1
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    • pp.21-29
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    • 2024
  • 1H,1H,2H,2H-perfluorodecytriethoxysilane (C16H19F17O3Si) be successfully applied to the hydrophobic modification of Al2O3 tubular ceramic membrane. Taking the concentration of modification solution, modification time, and modification temperature as factors, orthogonal experiments were designed to study the hydrophobicity of the composite membranes. The experiments showed that the modification time had the greatest impact on the experimental results, followed by the modification temperature, and the modification solution concentration had the smallest impact. Concentration of the modified solution 0.012 mol·L-1, modification temperature 30 ℃ and modification time 24 h were considered optimal hydrophobic modification conditions. And the pure water flux reached 274.80 kg·m-2·h-1 at 0.1MPa before hydrophobic modification, whereas the modified membrane completely blocked liquid water permeation at pressures less than 0.1MPa. Air gap membrane distillation experiments were conducted for NaCl (2wt%) solution, and the maximum flux reached 4.20 kg·m-2·h-1, while the retention rate remained above 99.8%. Given the scarcity of freshwater resources in coastal areas, the article proposed a system for seawater desalination using air conditioning waste heat, and conducted preliminary research on its freshwater production performance using Aspen Plus. Finally, the proposed system achieved a freshwater production capacity of 0.61 kg·m-2·h-1.

Development of Bonding Dispenser and Press Machine to Regenerate Retainer Ring for Semiconductor CMP Process (반도체 CMP 공정용 리테이너 링 재생을 위한 본딩 디스펜서 및 프레스 머신 개발)

  • Hyoung-Keun Park
    • The Journal of the Korea institute of electronic communication sciences
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    • v.19 no.3
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    • pp.507-514
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    • 2024
  • In the semiconductor manufacturing line, continuous efforts are being made to reduce the cost of products produced, and the demand for this is accelerating in the chemical mechanical polishing(CMP) process, and a representative example of these cost reduction items is the 5-Zone Ring. After about 150 hours of use in the CMP process, the thickness of the ring decreases to less than 1 mm and must be replaced with a new product. Therefore, in this study, bonding dispensers and press machines with a dispensing amount error of 10g±0.8% or less and a pressure uniformity of ±1.8% or less were developed to reduce semiconductor manufacturing costs by repeatedly regenerating worn parts of the retainer ring, and to minimize environmental pollution caused by industrial waste treatment.