• Title/Summary/Keyword: Waste solubility

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Surimi Processing Using Acid and Alkali Solubilization of Fish Muscle Protein (산과 알칼리 pH에서 어육 단백질의 용해를 이용한 수리미 제조)

  • 박주동;정춘희;김진수;조득문;조민성;최영준
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.32 no.3
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    • pp.400-405
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    • 2003
  • The surimi processing from jack mackerel and white croaker muscle using acidic and alkaline solubilization was evaluated. The optimum pH for solubilizing protein in acidic and alkaline range was around 2.5 and 10.5, respectively. The optimum pH value for recovery of protein was around 5. The protein solubility was decreased with increase of salt. The homogenized speed and time for maximum solubility were below 9,500 rpm and 30s, respectively The optimum ratio of water to minced muscle was 6 by evaluating breaking force, deformation and whiteness of cooked gel. The protein yield of alkaline processing is higher than that of conventional processing. In addition, the waste water of conventional processing had high solid, nitrogen content and chemical oxygen demand compare to those of acidic and alkaline processing.

Properties of Silk-Sericin Films Modified by Isocyanate Compounds (화학 개질된 실크세리신 필름의 특성)

  • Yoon, Heung-Soo;Takahashi, Kiyohisa
    • Textile Coloration and Finishing
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    • v.20 no.2
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    • pp.29-37
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    • 2008
  • Polar amino groups of the waste SS(silk-sericin) were modified by two isocyanate compounds of MOI[2-(methacryloyloxy)ethyl isocyanate] and AOI [2-(acryloyloxy)ethyl isocyanate]. When the MOISS (MOI-modified silk sericin) or AOISS(AOI-modified silk sericin) was pressed hot, vinyl groups in the MOI or AOI were polymerized and then the flexible and transparent films were obtained. Tensile moduli and strengths of the MOISS films were significantly improved as the MOI contents increased. By the addition of the isocyanate compounds, silk sericin films exhibited lower solubility to the distilled water($80^{\circ}C$) and also lower swell ratio to the distilled water(room temperature). In the effect of tensile properties and restraining the water swelling, MOI was better than AOI. BOD(biochemical oxygen demand)/TOD(theoretical oxygen demand) of the pure sericin film was almost 100% perfect level after 10 days immersion into the activated sludge. With increasing isocyanate content reacted with polar amino groups, BOD/TOD decreased. When more than 50 mol% of polar amino groups remained unreacted, sericin films could retain more biodegradability. Comparing with MOI from the viewpoint of biodegradability, AOI was more effective.

Evaluation of the Safty for the Disposal of High-level Nuclear Waste in the Granite (화강암지역에 고준위 원자력 폐기물 처리에 대한 안정성 평가)

  • Oh, Chang Whan
    • Economic and Environmental Geology
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    • v.29 no.2
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    • pp.215-225
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    • 1996
  • All the radionuclides in high-level nuclear waste will decay to harmless levels eventually but for some radionuclides decay is so slow that their radiation remains dangerous for times on the order of tens or hundreds of thousands of years. At the present time, the most favorite disposal plan for high-level radioactive waste is a mined geological disposal in which canister enclosing stable solid form of radioactive waste is placed in mined cavities locating hundred meters below the surface. The chief hazard in such disposal is dissolution of radionuclides from the waste in the groundwater that will eventually carry the dissolved radionuclides to surface environments. The hazard from possible escape of the radionuclides through groundwater can be delayed by engineered and geologic barriers. The engineered barriers can become useless by unexpected geologic catastrophe such as volcanism, earthquake, and tectonic movement and by fraudulent work such as careless construction, improperly welded canisters within the first few decades or centuries. As a result, dangerously radioactive waste which is still intensively radioactive is directly exposed to attack by moving groundwater. All the more, it is almost impossible to control repositories for times more than 10,000 years. Therefore, naturally controlled geologic, barriers whose properties will not be changed within 10,000 years are important to guarantee the safety of repositories of high-level radioactive waste. In Sweden and France, the suitability of granite for the mined geological disposal of high-level waste has been studied intensively. According to the research in Sweden and France, granites has the following physio-chemical characteristics which can delay the transportation of radionuclide by groundwater. First, the permeabilities of granites decreases as the depth increases and is $10^{-8}{\sim}10^{-12}m/s$ at depth below 300 m. Second, groundwater at depth below 300 m has pH=7-9 and reducing condition (Eh=-0.1~0.4). This geochemical condition is desirable to prevent both canister and solid waste from corrosion. Third most radionuclides are not transported by low solubilities and some radionuclide with high solubility such as Cs and Sr are retarded by absorption of geologic media through which ground water flows. Therefore, if high-level waste is disposed at depth below 300 m in the granite body which has a low permeability and is geologically stable more than 10,000 years, the safety of repositories from the hazard due to radionuclide escape can guaranteed for more than 10,000 years.

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Solubility and Yield Characteristics of KCl in Cement By-Pass Dust (시멘트 바이패스 더스트에 존재하는 염화칼륨의 용해 및 수득 특성)

  • Yun, Youngmin;Jeong, Jaehyun;Chu, Yongsik
    • Resources Recycling
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    • v.25 no.3
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    • pp.43-48
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    • 2016
  • Cement manufacturing plant uses various kinds of industrial/municipal waste. The waste contains considerable amount of potassium, chlorine and small amount of heavy metal. Many researches were performed to fabricate valuable resources from the waste. In this study, various methods, which dissolves and crystallizes potassium/chlorine to extract potassium chloride, were experimented. Especially amount of water, slurry temperature, and stirring time were controlled. Then kind of heavy metal and content of potassium chloride were analyzed. The yield of potassium chloride increased, as the amount of water for slurry increased but it increased slightly, when the water content was over 200%. The yield tended to increase, when the temperature of slurry was over a certain point. The yield did not increase in case of over 10 minutes stirring time. The kind and content of heavy metal in potassium chloride were various according to stirring time. The main heavy metals were Pb, Cu, and $Cr^{6+}$.

A circular economical application of eggshell waste as a bio-filler in the fabrication of gum Arabic composite film

  • Blessing A. Oredokun-Lache;Esther B. Ibrahim;Adekemi G. Oluwafemi;Georgina O. Erifeta;Sunday J. Josiah;Olarewaju M. Oluba
    • Food Science and Preservation
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    • v.31 no.3
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    • pp.394-407
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    • 2024
  • The poultry industry faces disposal difficulty in waste, but recent advancements in material science and sustainability have enabled the innovative transformation of waste into valuable resources. In this study, eggshell (EC) was added as a bio-filler to gum Arabic (GA) to fabricate a GA-EC bio-composite film. Bio-composites containing 0.5 g (GA-EC0.5) and 1.0 g (GA-EC1.0) EC dispersed in 30 mL of 15% GA solution were fabricated and characterized using standard analytical techniques. The GA-EC0.5 composites showed significantly higher moisture content, transparency, water solubility, and water vapor permeability but lower tensile strength and thermal stability than GA-EC1.0. Following a post-harvest wrapping of tomato fruits with the GA-EC composite films and storage at 25±2℃ for 20 days, significant (p>0.05) reductions in weight loss, pH, lycopene content, and activities of polyphenol oxidase and pectin methylesterase compared to unwrapped fruits were recorded. Adding EC to GA has enabled the fabrication of composite films with improved mechanical, barrier, and thermal properties with potential application in the post-harvest storage of tomato fruits.

Production and Application of Domestic Input Data for Safety Assessment of Disposal (처분안전성평가를 위한 국내고유 입력자료의 확보와 적용)

  • Park, Chung-Kyun;Lee, Jae-Kwang;Baik, Min-Hoon;Lee, Youn-Myoung;Ko, Nak-Youl;Jeong, Jong-Tae
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.10 no.3
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    • pp.161-170
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    • 2012
  • To provide domestic values of input parameters in a safety assessment of radioactive waste disposal under domestic deep underground environments, various kinds of experiments have been carried out under KURT (KAERI Underground Research Tunnel) conditions. The input parameters were classified, and some of them were selected for this study by the criteria of importance. The domestic experimental data under KURT environments were given top priority in the data review process. Foreign data under similar conditions to KURT were also gathered. The collected data were arranged and the statistical calculations were processed. The properties and distribution of the data were explained and compared to foreign values in view of their validity. The following parameters were analysed: failure time and early time failure rate of a container, solubility of nuclides, porosity and density of the buffer, and distribution coefficients of nuclides in the geomedia, hydraulic conductivity, diffusion depth of nuclides, groundwater flow rate, fracture aperture, length of internal fracture, and width of faulted rock mass in the host rock.

Near-Field Transport of Radionuclide Decay Chains (방사성 핵종 붕괴 사슬의 Near-Field 이동)

  • Kang, Chul-Hyung
    • Nuclear Engineering and Technology
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    • v.26 no.2
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    • pp.277-284
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    • 1994
  • Much attention has been given to predict the near-field mass transfer of a single radioactive species from a waste solid into surrounding porous medium. But only limited considerations have been given to predict the coupled mass transfer of species with a radioactive decay chain. In this study we present an analysis assuming that the members of a decay chain dissolve congruently with a solubility-limited matrix. We give general, non-recursive analytic solutions for the transport of a radioactive decay chain in a finite porous medium when nuclides are released congruently with the matrix. As an illustration we consider the decay chain $^{234}$ Ulongrightarrow$^{230}$ Thlongrightarrow$^{226}$ Ra from spent fuel. These solutions may be useful and potentially important in performance assessment of radioactive waste repositories.

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Functional Properties of Sunmul (Soybean Curd Whey) Concentrate by Ultrafiltration (한외여과에 의한 순물 농축액의 기능적 특성)

  • Kim, You-Pung;Eom, Sang-Mi;Chang, Eun-Jung;Kim, Woo-Jung;Oh, Hoon-Il
    • Korean Journal of Food Science and Technology
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    • v.38 no.4
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    • pp.488-494
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    • 2006
  • This study was carried out in order to investigate the feasibility of utilizing concentrated sunmul (soybean curd whey), which is a waste by-product of soybean curd processing, as a functional food ingredient. Sunmul Powder was concentrated by ultrafiltration and spray dried with or without dextrin. Oil adsorption capacity of UF retentate powder was similar to that of ISP (Isolated Soy Protein) and higher than that of sunmul powder, whereas water holding capacity of UF retentate powder was lower than that of ISP. Protein solubility of all types of UF retentate powder was significantly higher than that of ISP at pH 2.0-10.0 with the lowest protein solubility seen at pH 4.0 and solubility increasing as the conditions became more acidic or alkaline. Emulsifying activity indexes of UF retentate powder at pH 2.0-10.0 were not influenced by pH. Emulsion stability of 4% sunmul solution was lowest at pH 4.0, but that of UF retentate powder was higher at acidic pH values and decreased with increasing pH. Foaming capacities of sunmul and UF retentate powder were high at pH 4.0-6.0, but the foam of UF retentate powder disappeared within 20 minutes in all conditions of pH.

Fermentative Hydrogen Production from the Pretreated Food-Processing Waste and Sewage Sludge using Chemical/Ultra-Sonication (두부제조폐기물과 하수슬러지의 화학/초음파 전처리에 의한 가용화 및 혐기발효 수소생산)

  • Kim, Mi-Sun;Lee, Dong-Yeol;Kim, Dong-Hun;Kim, Ok-Sun;Lim, So-Yung
    • Transactions of the Korean hydrogen and new energy society
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    • v.21 no.6
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    • pp.580-586
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    • 2010
  • Acid and alkali pretreatments were applied to tofu processing waste (TPW) to increase the solubility of ingredients in TPW. Pretreatment at 1.0% of HCl and 2.5% of NaOH condition resulted in the increase of SCOD concentration from 3.2 g COD/L to 27 g COD/L and 33 g COD/L, respectively. The acid and alkali-pretreated TPW was studied for its fermentative $H_2$ production capacity in batch mode using a thermophillic mixed culture. Alkali pretreatment on presence of 2.5% NaOH exhibited more soluble portion released compared to acid pretreatment using HCl, however the $H_2$ production from acid pretreated TPW was better than alkali-pretreated TPW probably due to the sodium inhibition on microbial activity. In addition, sewage sludge was externally added to the acid-pretreated (1.0% HCl) TPW by 20% (on volume basis). Average H2 production rate was increased from 31 to 78 ml/L-broth/hr, and it was attributed to the high buffer capacity and abundant nutrients especially divalent cation in sewage sludge.

Recovery of Zirconium from Spent Pickling Acid through Precipitation Using BaF2 and Electrowinning in Fluoride Molten Salt (BaF2 침전 및 불화물 용융염 전해 제련을 통한 폐 산세액 내 지르코늄 회수)

  • Han, Seul Ki;Nersisyan, Hayk H.;Lee, Young Jun;Choi, Jeong Hun;Lee, Jong Hyeon
    • Korean Journal of Materials Research
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    • v.26 no.12
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    • pp.681-687
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    • 2016
  • Zirconium(Zr) nuclear fuel cladding tubes are made using a three-time pilgering and annealing process. In order to remove the oxidized layer and impurities on the surface of the tube, a pickling process is required. Zr is dissolved in HF and $HNO_3$ mixed acid during the process and pickling waste acid, including dissolved Zr, is totally discarded after being neutralized. In this study, the waste acid was recycled by adding $BaF_2$, which reacted with the Zr ion involved in the waste acid; $Ba_2ZrF_8$ was subsequently precipitated due to its low solubility in water. It is very difficult to extract zirconium from the as-recovered $Ba_2ZrF_8$ because its melting temperature is $1031^{\circ}C$. Hence, we tried to recover Zr using an electrowinning process with a low temperature molten salt compound that was fabricated by adding $ZrF_4$ to $Ba_2ZrF_8$ to decrease the melting point. Change of the Zr redox potential was observed using cyclic voltammetry; the voltage change of the cell was observed by polarization and chronopotentiometry. The structure of the electrodeposited Zr was analyzed and the electrodeposition characteristics were also evaluated.