• Title/Summary/Keyword: Waste oil

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A Development of Recycling Technology of Solar Cell Wafering Slurry (태양전지 Wafering Slurry 재생기술 개발에 관한 연구)

  • Na, Won-Shik;Lee, Jae-Ha
    • Journal of Advanced Navigation Technology
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    • v.14 no.3
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    • pp.426-431
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    • 2010
  • 68% of the manufacturing costs of solar cell wafer can be attributed to the slurry. The recycling of slurries is mandatory for reducing the costs of manufacturing wafering production, and the disposal of industrial waste, as well as for cutting down pollution levels. Slurries are currently being recycled using the centrifuge(decanter) method. However, this method is less than optimal as it does not completely remove the fine particles, leading to low quality. Also, be cause of the incomplete separation from the oil, it causes the impurities in the dried slurries. This study aims to develope a new recycling technology that overcomes the flaws of the centrifuge by utilizing chemicals. It will provide a total solution to the crucial process of recycling slurries in the making of solar cell wafer, by increasing the efficiency and renewable rate.

Petrochemical effluent treatment using natural coagulants and an aerobic biofilter

  • Bandala, Erick R.;Tiro, Juan Bernardo;Lujan, Mariana;Camargo, Francisco J.;Sanchez-Salas, Jose Luis;Reyna, Silvia;Moeller, Gabriela;Torres, Luis G.
    • Advances in environmental research
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    • v.2 no.3
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    • pp.229-243
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    • 2013
  • Coagulation-flocculation (CF) was tested coupled with an aerobic biofilter to reduce total petroleum hydrocarbon (TPHs) concentration and toxicity from petrochemical wastewater. The efficiency of the process was followed using turbidity and chemical oxygen demand (COD). The biofilter was packed with a basaltic waste (tezontle) and inoculated with a bacterial consortium. Toxicity test were carried out using Lactuca sativa var. capitata seeds. Best results for turbidity removal were obtained using alum. Considerable turbidity removal was obtained when using Opuntia spp. COD removal with alum was 25%, for Opuntia powder it was 36%. The application of the biofilter allowed the removal of 70% of the remaining TPHs after 30 days with a biodegradation rate (BDR) value 47 $mgL^{-1}d^{-1}$. COD removal was slightly higher with BDR value 63 $mgL^{-1}d^{-1}$. TPH kinetics allowed a degradation rate constant equal to $4.05{\times}10^{-2}d^{-1}$. COD removal showed similar trend with $k=4.23{\times}10^{-2}d^{-1}$. Toxicity reduction was also successfully achieved by the combined treatment process.

The Effect of Soil Conditioners on the Rutin Biosynthesis and the Yield of Buckwheat(Fagopyrum esculentum moench) (메밀의 rutin 생합성과 수량에 대한 토양개량제의 효과)

  • Kim, Hee-Kwon;Lee, Yeen;Kim, Byoung-Ho;Yun, Bong-Ki
    • Korean Journal of Soil Science and Fertilizer
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    • v.32 no.1
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    • pp.7-11
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    • 1999
  • This experiment was conducted to investigate the effects of soil conditioners, such as lime, borax, poultry waste sawdust manure (P.W.S.M) and mixed oil cakes (M.O.C), on the rutin biosynthesis and the yield of buckwheat. The content of phosphorus ($P_2O_5$) in buckwheat plants before flowering was higher at before flowering than that of flowering time at all plots. The content of nitrogen (N), potassium ($K_2O$), calcium (CaO) and magnesium (MgO) was lower at before flowering than those of flowering time at all plots. The contents of rutin in buckwheat plant at flowering time was higher than that at before flowering content of rutin in leaf was higher than that in stem. The contents of rutin in buckwheat plant was the highest at the plot treated with borax (B) compared to other plots. Correlation between rutin and amino acid was positive in buckwheat leaf, while it was negative in buckwheat stem. The yield of buckwheat was 21 percent higher at the plot treated with borax than the plot applied with the other three ingredients.

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Convergent Study on the Preparation of Sludge Modified Soils of Inorganic Consolidation Soil (무기계고화재의 슬러지 개량토 제조에 관한 융합연구)

  • Han, Doo Hee
    • Journal of the Korea Convergence Society
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    • v.8 no.2
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    • pp.157-162
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    • 2017
  • Inorganic stiffening agents were prepared by mixing paper sludge incineration ash, blast furnace slag fine powder quicklime, anhydrous gypsum and fly ash. The main components of the solidifying agent developed for sludge treatment were SiO, $Al_2O_3$, $TiO_2$, $Fe_2O_3$, $Mn_2O_3$, CaO, MgO, $Na_2O$, $K_2O$, $P_2O$, and $SO_3$. Unlike cement, the developed solidifying agent did not contain $Cr^{6+}$, which is known as a carcinogen. Heavy metals and oil contaminated soil were mixed with solidifying agent and cured for 7 days and the heavy metal content was below the environmental standard. Sewage sludge cake, food waste and solidifying agent were mixed with each other, and after 7 days curing, soil component test showed that the heavy metal content was below the environmental standard. After mixing the sludge, solidifying agent and additive mixture into the beaker, the ammonia concentration was measured to be 0 after 3 days.

The Characterization of PM, PM10, and PM2.5 from Stationary Sources (고정배출원의 먼지 크기별 (PM, PM10, PM2.5) 배출 특성 연구)

  • Kim, JongHo;Hwang, InJo
    • Journal of Korean Society for Atmospheric Environment
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    • v.32 no.6
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    • pp.603-612
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    • 2016
  • The objective of this study was to estimate the emission characteristics for PM, $PM_{10}$, and $PM_{2.5}$ in the various stationary sources. The particulate matters collected in the various stationary sources such as power plants (Coal and B-C oil), incinerators(municipal and industrial waste), and glass furnaces. The PM and $PM_{10}$, PM and $PM_{2.5}$, $PM_{10}$ and $PM_{2.5}$ samples were collected using the cyclone type $PM_{10}$, $PM_{2.5}$ samplers and 30 species(19 inorganic species, 9 ionic species, OC and EC) were analyzed by ICP, IC, and TOR/IMPROVE methods. The mass concentrations of PM, $PM_{10}$, $PM_{2.5}$ from nine stationary sources ranged $0.63{\sim}9.58mg/Sm^3$, $0.26{\sim}7.47mg/Sm^3$ and $0.13{\sim}6.34mg/Sm^3$, respectively. The level of $PM_{10}$, $PM_{2.5}$ portion in PM calculated 0.63~0.99, 0.38~0.94, respectively. In the case of emission trend for species, power plant showed high concentrations for Al, Mg, Na, Si, V and $SO_4{^{2-}}$, respectively. Also, Ca, Fe, K, Si, $Cl^-$, and $K^+$ showed high in incinerator. In the case of glass furnace, Na, Pb, K, Si, $Na^+$ and $SO_4{^{2-}}$ represented high concentrations. Power plant showed higher EC/OC concentrations than other sampling sites. These results suggest the possible role for complement establishment process of emission inventory and emission management for PM.

Farm Engine Characteristics of Biodiesel using Mixed Waste Vegetable Oil (폐식물성혼합유지 바이오디젤의 농용기관특성 평가)

  • Choi, Hwon;Lim, HackKyu;Kim, TaeHan
    • Proceedings of the Korean Society for Agricultural Machinery Conference
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    • 2017.04a
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    • pp.60-60
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    • 2017
  • 화석연료의 고갈과 환경오염이 문제시 되면서 친환경 에너지개발에 대한 연구가 진행되고 있다. 그중 바이오디젤은 동,식물성유지 및 폐식용유를 이용하여 생산이 가능할뿐더러 농용엔진에 특별한 개조 없이 사용가능하다. 또한 바이오디젤 자체에 산소를 함유하고 있어 이산화탄소 저감에 효율적이다. 바이오 디젤에 관한 많은 연구가 수행되었으며, 기존의 연구는 단일유지의 폐식용유를 사용하여 바이오디젤을 생산하는 연구가 진행되었다. 하지만 가정에서 배출되는 식물성 폐식용유의 경우 여러 가지가 혼합되어 배출되고 있어, 혼합폐식용유지의 바이오디젤 특성평가가 필요하다. 따라서 본 연구에서는 폐식물성유지(폐대두유, 폐카놀라유, 폐해바라기유)를 중량비(1:4, 1:1.5 1:0.66, 1:0.25)로 혼합하여 바이오디젤을 생산하고, 생산한 바이오디젤을 농용기관에 이용하여 농용기관의 출력특성 및 배기배출물특성 평가를 실시하였다. 실험에 사용된 농용기관은 배기량이 673cc인 직접분사식 디젤기관(ND10DE, Daedong, Korea)이며, 엔진성능평가를 위해 토크는 토크센서(YDL-704s, Setech, Korea)를 사용하였다. 배기배출물 평가는 배기가스분석기(HG-550, Airlex, Germany)를 이용하여 이산화탄소, 질소산화물을의 배출량을 측정하였다. 폐식용유를 이용하여 생산한 바이오디젤과 경유의 기관성능을 비교한 결과 토크와 축출력의 경우 BD의 혼합량이 증가할수록 줄어들었다. 토크는 혼합된 유지에 따라 상용운전범위인 1500rpm~2400rpm에서 평균 대두와 카놀라유를 혼합하여 생산한 BD10은 7.2%, BD20은 12.1% 감소하였고, 대두와 해바라기유를 혼합하여 생산한 BD10은 11.3% BD20은 16.3% 감소하였다. 또한 해바라기와 카놀라유를 혼합하여 생산한 BD10은 8.3%, BD20은 14.6% 감소하였다. 이는 BD의 발열량이 경유에 비해 낮아 토크가 감소한 것으로 판단된다. 또한 배기배출물 평가의 경우 질소산화물은 BD의 함랑이 증가함에 따라 경유에 비해 배출량이 증가하는 경향을 보였고, 이산화탄소는 저감되는 것으로 나타났다. 이는 바이오디젤이 함산소연료이므로, 연료내의 산소로 인해 완전연소를 촉진시켜 이산화탄소를 저감시키고 질소산화물은 증가된 것으로 판단된다.

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An Experimental Study on the Combustion and Emission Characteristics of Blends of GTL / Biodiesel in Diesel Engine (GTL/바이오디젤 혼합 연료의 연소 및 배기배출물 특성에 관한 실험적 연구)

  • Moon, Gun-Feel;Lee, Yong-Gyu;Choi, Kyo-Nam;Jeong, Dong-Soo
    • Transactions of the Korean Society of Automotive Engineers
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    • v.17 no.5
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    • pp.39-45
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    • 2009
  • An experimental research with 2.0 liter 4-cylinder turbocharged diesel engine was carried out to investigate the combustion and emission characteristics for various alternative fuels. The conventional diesel fuel, neat GTL, blends of 80% of GTL and 20% of biodiesel derived from waste cooking oil are utilized without any modification of engine hardware and ECU data. For GTL and blends of GTL/biodiesel fuel, the ignition delay decreased at the same operating conditions, and overall combustion duration increased slightly. Also, the peak cylinder pressure increased for blends of GTL/biodiesel compared to diesel and GTL fuel. THC and CO emissions with blends of GTL/biodiesel compared to other fuels decreased for the low and middle load conditions. But NOx emission increased due to oxygen content in biodiesel. The number concentrations of PM are higher for blends of GTL/biodiesel than other test fuels in the nucleation mode, while it had an opposite tendency in the accumulation mode, which implies more reduction of PM for blends of GTL/biodiesel on the base of mass concentration.

Contributive Estimation of Polycyclic Aromatic Hydrocarbons by Emission Source in Seoul Area (서울지역 대기 중 다환방향족탄화수소의 발생원별 기여도 평가)

  • Park, Chan-Koo;Yun, Joong-Sup;Eo, Soo-Mi;Shin, Jeong-Sik;Kim, Min-Young;Sohn, Jong-Ryeul;Mo, Sae-Young
    • Journal of Korean Society for Atmospheric Environment
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    • v.22 no.3
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    • pp.287-295
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    • 2006
  • PAHs (Polycyclic Aromatic Hydrocarbons), one of the carcinogenic materials in environment, were investigated in this study. The standardized analysis conditions were tested, and then various factors which affect to the ambient PAHs concentration in Seoul were estimated. Moreover, the emissions of PAHs from major stationary sources were investigated to determine the quantitative relationships between ambient PAHs concentrations and emission sources. From the factor analysis, three factors relevant to the ambient PAHs in Seoul were found. Factor 1 was related to the concentrations of chrysene, pyrene, indeno (1, 2, 3-cd)pyrene, benzo[b]fluoranthene, benzo[k]fluoranthene, and benzo prerylene which were mainly emitted from gasoline and diesel fueled cars. Factor 2 showed higher loadings in phenanthrene and anthracene which were due to LNG and BC oil combustion in industry and home. And factor 3 included dibenz(a, h)anthracene and acenaphthene which were emitted from open burning and municipal solid waste incineration. Conclusively, all of three factors were consisted in 82% of total variance. The contribution of mobile sources in ambient air in Seoul was estimated at 64%, that of industrial and home sources at 17%, and that of open burning and municipal incineration at 1%.

EXHAUST GAS HEAT RECOVERY SYSTEM FOR PLANT BED HEATING IN GREENHOUSE PRODUCTION

  • Kim, Y.J.;Ryou, Y.S.;Rhee, K.J.;Kang, G.C.
    • Proceedings of the Korean Society for Agricultural Machinery Conference
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    • 2000.11c
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    • pp.639-646
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    • 2000
  • Hot air heater with light oil combustion is the most common heater for greenhouse heating in the winter season in Korea. However, since the heat efficiency of the heater is about 80%, considerable unused heat in the form of exhaust gas heat discharges to atmosphere. In order to capture this exhaust gas heat a heat recovery system for plant bed heating in the greenhouse was built and tested in the hot air heating system of greenhouse. The system consists of a heat exchanger made of copper pipes, ${\phi}\;12.7{\times}0.7t$ located inside the rectangular column of $330{\times}330{\times}900mm$, a water circulation pump, circulation plastic pipe and a water tame The total heat exchanger area is $1.5m^2$, calculated considering the heat exchange amount between flue gas and water circulated in the copper pipes. The system was attached to the exhaust gas path. The heat recovery system was designed as to even recapture the latent heat of flue gas when exposing to low temperature water in the heat exchanger. According to performance test it can recover 45,200 to 51,000kJ/hr depending on the water circulation rates of 330 to $690{\ell}$/hr from the waste heat discharged. The exhaust gas temperature left from the heat exchanger dropped to $100^{circ}C$ from $270^{circ}C$ by the heat exchange between the water and the flue gas, while water gained the difference and temperature increased to $38^{circ}C$ from $21^{circ}C$ at the water flow rate of $690{\ell}$/hr. And, the condensed water amount varies from 16 to $43m{\ell}$ at the same water circulation rates. This condensing heat recovery system can reduce boiler fuel consumption amount in a day by 34% according to the feasibility study of the actual mimitomato greenhouse. No combustion load was observed in the hot air heater.

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Estimation of Quantitative Source Contribution of Ambient PM-10 Using the PMF Model (PMF모델을 이용한 대기 중 PM-10 오염원의 정량적 기여도 추정)

  • 황인조;김동술
    • Journal of Korean Society for Atmospheric Environment
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    • v.19 no.6
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    • pp.719-731
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    • 2003
  • In order to maintain and manage ambient air quality, it is necessary to identify sources and to apportion its sources for ambient particulate matters. The receptor methods were one of the statistical methods to achieve reasonable air pollution strategies. Also, receptor methods, a field of chemometrics, is based on manifold applied statistics and is a statistical methodology that analyzes the physicochemical properties of gaseous and particulate pollutant on various atmospheric receptors, identifies the sources of air pollutants, and quantifies the apportionment of the sources to the receptors. The objective of this study was 1) after obtaining results from the PMF modeling, the existing sources of air at the study area were qualitatively identified and the contributions of each source were quantitatively estimated as well. 2) finally efficient air pollution management and control strategies of each source were suggested. The PMF model was intensively applied to estimate the quantitative contribution of air pollution sources based on the chemical information (128 samples and 25 chemical species). Through a case study of the PMF modeling for the PM-10 aerosols, the total of 11 factors were determined. The multiple linear regression analysis between the observed PM-10 mass concentration and the estimated G matrix had been performed following the FPEAK test. Finally the regression analysis provided quantitative source contributions (scaled G matrix) and source profiles (scaled F matrix). The results of the PMF modeling showed that the sources were apportioned by secondary aerosol related source 28.8 %, soil related source 16.8%, waste incineration source 11.5%, field burning source 11.0%, fossil fuel combustion source 10%, industry related source 8.3%, motor vehicle source 7.9%, oil/coal combustion source 4.4%, non-ferrous metal source 0.3%. and aged sea- salt source 0.2%, respectively.