• Title/Summary/Keyword: Waste liquid

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Determination of Radiolysis Produce of DHOA by GC/MS (GC/MS를 이용한 DHOA의 방사선 분해생성물 분석)

  • Yang, Han-Beom;Lee, Eil-Hee;Lim, Jae-Kwan;Chung, Dong-Yong;Kim, Kwang-Wook;Kim, Jong-Seung
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.7 no.1
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    • pp.17-23
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    • 2009
  • Dihexyloctanamide(DHOA) was used as an extractant or phase modifier with the diamide extractants in a solvent extraction process for a radioactive liquid waste treatment. The degradation compounds of the DHOA extractant, irradiated with $^{60}Co$ gamma ray, were octanoic acid and dihexylamine which are identified by a Fourier transform infrared(FT-IR) and gas chromatograph/mass spectrometer(GC/MS) analysis, and determined by the GC/MS with selected ion monitoring(SIM) mode. Retention behavior of octanoic acid, tridecane (internal standard) and dihexylamine in total ion chromatogram (TIC) were 8.65 min., 9.79 min., and 10.27 min., respectively. With increasing the absorbed dose of the $\gamma$-ray irradiated DHOA, the concentration of octanoic acid was decreased and that of dihexylamine was increased.

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Review of Unplanned Release at Foreign Nuclear Power Plants and Radiological Monitoring at Korean Power Plants (해외원전 비계획적 방출 및 한국의 환경감시 현황 분석)

  • Park, Soo-Chan;Ham, Baknoon;Kwon, Jang-Soon;Cho, Dong-Keun;Jeong, Jihye;Kwon, Man Jae
    • Journal of Soil and Groundwater Environment
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    • v.23 no.4
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    • pp.1-15
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    • 2018
  • Despite of safety issues related to radiological hazards, 31 countries around the world are operating more than 450 nuclear power plants (NPPs). To operate NPPs safely, safety regulations from radiation protection organizations were developed and adopted in many countries. However, many cases of radionuclide releases at foreign NPPs have been reported. Almost all commercial NPPs routinely release radioactive materials to the surrounding environments as liquid and gas phases under control. These releases are called 'planned releases' which are planned, regularly monitored, and well documented. Meanwhile, the releases focused in this review, called 'unplanned releases', are neither planned nor monitored by regulatory and/or protection organizations. NPPs are generally composed of various structures, systems and components (SSCs) for safety. Among them, the SSCs near reactors are closely related to safety of NPPs, and typically fabricated to comply with stringent requirements. However, some non-safety related SSCs such as underground pipes may be constructed only according to commercial standards, causing the leakage of radioactive fluids usually containing tritium ($^3H$). This paper discusses SSCs of NPPs and introduces several cases of unplanned releases at foreign NPPs. The current regulation on the environmental radiological surveillance and assessment around the NPPs in South Korea are also examined.

Development of Thin-Film Thermo-Electrochemical Cell for Harvesting Waste Thermal Energy (폐열 에너지 수집을 위한 박막형 열-전기화학전지 개발)

  • Im, Hyeongwook;Kang, Tae June;Kim, Dae Weon;Kim, Yong Hyup
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.40 no.11
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    • pp.1010-1015
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    • 2012
  • In this study, a thin-film thermo-electrochemical cell that directly converts waste thermal energy into electrical energy was fabricated. Electrical conductivity of conducting carbon fiber, which was used as flexible electrode, was increased through coating of carbon nanotube, and resistance of the CNT-coated fiber electrode was not changed even after bending test with various curvatures. Maximum output power of the thermocell was increased quadratically with the temperature difference, and showed a value of about 2.5 mW/kg at temperature difference of $3.4^{\circ}C$. As a result of discharge test for 12 hours, it is confirmed that the cell can operates continuously. And thin-film thermocell wrapped around a pipe with hot liquid flowing within was demonstrated. Internal resistance of the cell was decreased with various curvature of heat pipe, and maximum output power was increased by 30 %. Therefore, the cell can be applied to various heat source.

Simulation of Pervaporation Process Through Hollow Fiber Module for Treatment of Reactive Waste Stream from a Phenolic Resin Manufacturing Process (페놀수지 생산공정에서 배출되는 반응성 폐수처리를 위한 중공사막 모듈 투과증발 공정모사)

  • C. K Yeom;F. U. Baig
    • Membrane Journal
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    • v.13 no.4
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    • pp.257-267
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    • 2003
  • For the treatment of reactive phenolic resin waste, a simulation model of pervaporative dehydration process has been developed through hollow fiber membrane module. Some of basic parameters were determined directly from dehydration of the waste liquid through a flat sheet membrane to get realistic values. The simulation model was verified by comparing the simulated values with experimental data obtained from hollow fiber membrane module. Hollow fiber membranes with active layer coated on inside fiber were used, and feed flew through inside hollow fiber. Feed flow rate affected membrane performances and reaction by providing a corresponding temperature distribution of feed along with fiber length. Feed temperature is also a crucial factor to determine dehydration and reaction behavior by two competing ways; increasing temperature increases permeation rate as well as water formation rate. Once the permeate pressure is well below the saturated vapor pressure of feed, permeate pressure had a slightly negative effect on permeation performance by slightly reducing driving force. As the pressure approached the vapor pressure of feed, dehydration performances declined considerably due to the activity ratio of feed and permeate.

Trend on Recycling Technologies for Display Wastes analysed by the Patents and Literature Review (특허(特許)와 논문(論文)으로 본 폐(廢) 디스플레이 재활용(再活用) 기술(技術) 동향(動向))

  • Lee, Sung-Kyu;Lee, Chan-Gi;Hong, Hyun-Seon;Cho, Young-Ju;Cho, Bong-Gyoo
    • Resources Recycling
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    • v.21 no.3
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    • pp.65-73
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    • 2012
  • There are several kinds of displays such as liquid crystal display (LCD), cathode ray tube (CRT), plasma display panel(PDP), light emitting diode (LED), organic light emitting diode (OLED), etc. Nowadays, recycling technologies of waste displays have been widely studied from economy and efficiency points of view. In this paper, patents and literature on the recycling technologies of the waste displays have been comprehensively analyzed. The search was limited to the open patents of USA (US), European Union (EU), Japan (JP), and Korea (KR) and SCI journals published from 1980 to 2011. Patents and journals were systematically compiled and collected using key-words search and filtered by pre-set filtering criteria. The trends of the patents and journals were thus analyzed according to the years, countries, companies, and technologies.

Prediction of the Dynamic Adsorption Behaviors of the Uranium and Cobalt Ions in a Fixed Bed by Surface Modified Activated Carbon (표면개질 활성탄을 이용한 고정층에서 우라늄 및 코발트 이온의 동적 흡착거동 모사)

  • Geun-IL Park;Jung-Won Lee;Kee-Chan Song;In-Tae Kim;Kwang-Wook Kim;Myung-Seung Yang
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.1 no.1
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    • pp.81-92
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    • 2003
  • In order to predict the dynamic behaviors of uranium and cobalt in a fixed bed at various influent pH values of liquid waste, the adsorption system is regarded as a multi-component adsorption between each ionic species in the solution. Langmuir isotherm parameters of each species were extracted by incorporating equilibrium data with the solution chemistry of the uranium and cobalt using IAST. Prediction results were in good agreement with the experimental data, except for a high concentration and pH. Although there was some limitations in predicting the cobalt adsorption, this method may be useful in analyzing a complex adsorption system where various kinds of ionic species exist in a solution.

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Study on the Radioactive Liquid Waste Treatment of Cooling and Decompression Process of Spent Fuel Assembly Cask (사용후핵연료 집합체 캐스크 감온, 감압 공정의 방사성 액체폐기물 처리 대한 연구)

  • 손영준;전용범;김은가;엄성호;권형문;민덕기;양송열;이은표;이형권
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2003.11a
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    • pp.83-89
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    • 2003
  • A temperature- and pressure-reducing process is utilized to handle the spent fuel assembly in the post-irradiation examination facility. This process includes three separated unit processes. First one is the decontamination process to clean the spent fuel assembly casks. The second process is the temperature-reducing process to reduce the temperature elevated by decay process in the spent fuel assembly. The third process is the filtration process to remove insoluble particles existed in the casks using filters. Up-to-date technologies as well as practical theories related to the temperature- and pressure-reducing process is reviewed in this report. The test-operation process for various tests and the test results of the temperature- and pressure-reducing process for J-44 and K-23 spent fuel assemblies are also described in detail. This report must be effectively used for the normal operation of the facility with the awareness of unprecedented problems which could occur by continuing operation of the PIE facility.

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Evaluation through Photochemical Response Analysis on Growth Enhancing Effect of Decomposed Hatchery Waste Egg for Red Pepper (광화학적 반응 분석을 통한 부화장 폐달걀 분해 액비의 고추 생장촉진효과 평가)

  • Yoo, Sung Yung;Kang, Hong Gyu;Yoo, Jae Hong;Lee, Jeon Gyu;Shim, Myoung Yong
    • Korean Journal of Environmental Biology
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    • v.34 no.3
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    • pp.161-168
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    • 2016
  • In this study, growth enhancing effect of hatchery waste egg decomposed liquid fertilizer in pepper plant cultivation through chlorophyll fluorescence (O-J-I-P) analysis. In a whole growth period, egg decomposed fertilizer treated pepper grew well than non treated plant, though it was not statistically significantly different. Amount of chlorophyll fluorescence of non treated plant was higher thant that of fertilizer treated plant. It is determined that eventually lead to increased photosynthesis. In this study, six parameters, Fo, ABS/RC, RC/ABS, TRo/RC, DI0/RC, and DF Total ABS were the important factors represent efficiency of photochemical responses of pepper plant treated with hatchery waste egg decomposed fertilizer.

Analysis of Oil Species of Illegally Disposed Oil (무단 투기 유류에 대한 유종 해석)

  • Lim, Young-Kwan;Lee, Eun-Yul;Seong, Sang-Rae;Kim, Jong-Ryeol
    • Applied Chemistry for Engineering
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    • v.27 no.6
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    • pp.664-668
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    • 2016
  • The contamination in soil, underground water and river environment became serious due to illegal waste dumping. In this study, our research group analyzed the oil species of illegally disposed oils from J City. After pretreating the mixture of oil, water and solid phases to obtain homogeneous phase components, the physical property analysis, atom analysis, and gas chromatography were performed. From the results showing 11.8% of oxygen content, $-6^{\circ}C$ of pour point and chromatogram pattern. the contaminated oil was identified as a vegetable one. High performance liquid chromatography (HPLC) analysis was also performed in order to know what kind of vegetable oil was, and the ratio of LLO, OOL and POL was found to be high indicating that the disposed oil is majorly the used soybean oil with some vegetable oil mixtures. This study can be used for identifying contaminators for oils from the illegal waste dumping.

A Review on the Application of Ionic Liquids for the Radioactive Waste Processing (방사성 폐기물 처리를 위한 이온성 액체 활용)

  • Park, Byung Heung
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.12 no.1
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    • pp.45-57
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    • 2014
  • Academic interests in ionic liquid (IL) technologies have been extended to the nuclear industry and the applicability of ionic liquids for processing radioactive materials have been investigated by many researchers. A number of studies have reported interesting results with respect to the spectroscopic and electrochemical behaviors of metal elements included in spent nuclear fuels. The measured and observed properties of metal ions in TBP(tri-butyl phosphate) dissolved ILs have led the development of alternative technologies to traditional aqueous processes. On the other hand, the electrochemical deposition of metal ions in ILs have been investigated for the application of the solvents to aqueous as well as to non-aqueous processes. In this work, a review on the application of ILs in nuclear fuel cycle is presented for the purpose of categorizing and summarizing the notable researches on ILs.