• Title/Summary/Keyword: Waste components

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Recycling of the Waste Cellulose ―II. Preparation of Hydroxyethyl Cellulose from Knit-Cotton-Waste― (셀룰로오스계 폐기물의 재활용 ―II. 폐면으로부터 hydroxyethyl cellulose 제조―)

  • Lee, Sung Goo;Ihm, Sung Dam;Kim, Byung Suk;Mun, Sung Phil;Rhee, John Moon
    • Textile Coloration and Finishing
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    • v.7 no.2
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    • pp.32-39
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    • 1995
  • Various grades of hydroxyethyl cellulose (HEC, MS 0.65-3.20) were prepared throngh reaction of the knit-cotton-waste with ethylene oxide(EO). The knit-cotton-waste was composed of 98% of $\alpha$-cellulose and 2% of other components, and the cellulose was highly pure. The molar ratio of EO to knit-cotton-waste and that of NaOH to knit-cotton-waste, and the agitation speed were the important factors determining the molar substitution(MS) during the preparation of HEC. The MS of HEC was remarkably increased with increasing molar ratio of EO' to knit-cotton-waste. When the molar ratio of EO to knit-cotton-waste was 3.5, that of NaOH to knit-cotton-waste was 1.25, and agitation speed was 450rpm, it was possible to prepare HEC of MS 2.5. The structure and crystallinity of HECs prepared were determined by FT-IR and X-ray diffraction.

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Development of an Integrated Monitoring System for the Low and Intermediate Level Radioactive Waste Near-surface Disposal Facility (방사성폐기물 표층처분시설 통합 모니터링 시스템 개발)

  • Se-Ho Choi;HyunGoo Kang;MiJin Kwon;Jae-Chul Ha
    • Journal of Radiation Industry
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    • v.17 no.4
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    • pp.359-367
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    • 2023
  • In this study, the function and purpose of the disposal cover, which is an engineering barrier installed to isolate the disposal vault of the near-surface disposal facility for radioactive waste from natural/man-made intrusion, and the design details of the demonstration facility for performance verification were described. The Demonstration facility was designed in a partially divided form to secure the efficiency of measurement while being the same as the actual size of the surface disposal facility to be built in the Intermediate & low-level radioactive waste disposal site of the Korea Radioactive Waste Agency (KORAD). The instruments used for measurement consist of a multi-point thermometer, FDR (Frequency Domain Reflectometry) sensor, inclinometer, acoustic sensor, flow meter, and meteorological observer. It is used as input data for the monitoring system. The 3D monitoring system was composed of 5 layers using the e-government standard framework, and was developed based on 4 components: screen, control module, service module, and DBIO(DataBase Input Output) module, and connected them to system operation. The monitoring system can provide real-time information on physical changes in the demonstration facility through the collection, analysis, storage, and visualization processes.

Dismantling of Components from Waste Printed Circuit Boards Using Stannic Chloride Solution (염화주석용액을 이용한 폐인쇄회로기판으로부터 부품의 분리)

  • Park, Yujin;Yoo, Kyoungkeun
    • Resources Recycling
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    • v.30 no.2
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    • pp.24-30
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    • 2021
  • Dismantling tests were performed to separate components from waste printed circuit boards (PCBs) using HCl solution with Sn4+. Then, the effects of agitation speed, reaction temperature, initial Sn4+ concentration, and HCl concentration on the dismantling of components were investigated. No significant effect on the dismantling speed was observed upon changing the agitation speed from 100 to 300 rpm. However, the dismantling rate increased with increasing reaction temperature, Sn4+ concentration, and HCl concentration. In the all-component dismantling tests, when the dismantling ratio increased to 100%, no solder was observed on the boards, and the Sn4+ concentration was ~1,500 mg/L. The dismantling ratio of the components from the PCB increased to 100% within 2 h when 1 mol/L HCl solution with 10,000 mg/L Sn4+ was used at an agitation speed and temperature of 200 rpm and 90 ℃, respectively.

Development of Urban Mine Recycling Technology by Machine Learning (머신러닝에 의한 도시광산 재활용 기술 개발)

  • Terada, Nozomi;Ohya, Hitoshi;Tayaoka, Eriko;Komori, Yuji;Tayaoka, Atsunori
    • Resources Recycling
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    • v.30 no.4
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    • pp.3-10
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    • 2021
  • The field of recycling for waste electronic components, which is the typical example of an urban mine, requires the development of useful sorting techniques. In this study, a sorter based on image identification by deep learning was developed to select electronic components into four groups. They were recovered from waste printed circuit boards and should be separated to depend on the difference after treatment. The sorter consists of a workstation with GPU, camera, belt conveyor, air compressor. A small piece (less than 3.5 cm) of electronic components on the belt conveyor (belt speed: 6 cm/s) was taken and learned as teaching data. The accuracy of the image identification was 96% as kinds and 99% as groups. The optimum condition of sorting was determined by evaluating accuracies of image identification and recovery rates by blowdown when changing the operating condition such as belt speed and blowdown time of compressed air. Under the optimum condition, the accuracy of image classification in groups was 98.7%. The sorting rate was more than 70%.

Effects of Dietary Supplemental Lincomycin and Food Waste on Performance and Blood Components of Broiler Chicks (린코마이신과 남은 음식물의 첨가.급여가 육계의 생산성 및 혈액의 성상에 미치는 영향)

  • 박재홍;류경선
    • Korean Journal of Poultry Science
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    • v.27 no.1
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    • pp.43-50
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    • 2000
  • Two experiments were conducted to investigate the effect of dietary supplemental lincomycin at different food waste supplements on performance of broiler chicks. Diets were based corn, soybean meal and contained 3,078, 3,089 ㎉/kg ME, 21% CP for the first three weeks and 3,116 ㎉/kg and 19% CP for the rest two weeks. Three levels of lincomycin(LM; 0, 2.2, 4.4mg/kg) and food waste (FW;0, 5, 10%) were differently used for both experiments. Weight gain, feed intake, feed conversion ratio were weekly measured for five weeks. Blood components, liver and abdominal fat were sampled at the end of experiments. In experiment, 1 weight gain of birds fed 4.4mg/kg LM was significantly higher than that of no LM treatments (p<0.05). It was tended to decrease in 10% food waste treatment compared to that of control but was not significantly different. FCR of chocks fed LM supplement tended to improve as dietary LM level increased. It was not superior in 10% food waste treatment to that of control, but tended to improve compared to that of other treatments. Weight gain and FCR of birds fed 2.2mg/kg LM without food waste tended to improve compared to those of other treatments, but were not significantly different. Liver to body weight ratio birds fed LM supplements regardless of FW decreased significantly compared to that of control (p<0.05), but was not consistency in FW treatments. There was no significance in blood components except blood protein. In experiment 2, weight gain of chicks fed no FW showed quadratic, but increased as dietary supplemental LM increased. Birds fed 5% FW was not superior weight gain to that of other FW treatments. It also decreased in no LM treatment with 10% FW compared to that of control. However, the birds fed 4.4 mg/kg LM with 10% FW exhibited significantly higher weight gain the trend of weight gain. It tended to increase up to 10% FW combined with 4.4 mg/kg LM, but was not significantly different. Liver to body weight ratio of chicks fed LM was significantly decreased more than the control(p<0.05).The results of these experiments indicated that chicks fed 10% FW with 4.4 mg/kg LM supplements maximized growth rate of all treatments, but was not improve FCR in both experiments.

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A Development of Landfill Liner by Utilizing Waste Lime (폐석회를 이용한 매립지 차수재 개발)

  • 김준섭;이승학;박준범
    • Proceedings of the Korean Geotechical Society Conference
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    • 1999.03a
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    • pp.521-528
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    • 1999
  • As the size of our industry and population inclose, the byproducts such as municipal solid wastes, industrial wastes are in the increasing phase. The treatment of such things is rising as a social problem. Today, the final disposal of these wastes depends mostly on the landfill, and the sanitary landfill is required and designed for preventing soil and groundwater contamination. Clays have been used for a liner material of a sanitary landfill, however, the high quality clay is hard to come by and quite expensive as a lining material in our country. Using the waste lime produced abundantly every year from chemical processes was studied here, made from the proper mixing of the bentonite and the waste lime meets the regulations from the USEPA. The soil property index tests (sieve analysis, specific gravity test Atterberg limit test) were performed, and at last to confirm the sorption characteristics of the bentonite and the waste lime the sorption isotherm equilibrium test and the sorption isotherm were performed with Toluene and Ethylbenzene which are the main components of the leachate from the landfill.

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AN ANALYSIS OF THE FACTORS AFFECTING THE HYDRAULIC CONDUCTIVITY AND SWELLING PRESSURE OF KYUNGJU CA-BENTONITE FOR USE AS A CLAY-BASED SEALING MATERIAL FOR A HIGH-LEVEL WASTE REPOSITORY

  • Cho, Won-Jin;Lee, Jae-Owan;Kwon, Sang-Ki
    • Nuclear Engineering and Technology
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    • v.44 no.1
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    • pp.89-102
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    • 2012
  • The buffer and backfill are important components of the engineered barrier system in a high-level waste repository, which should be constructed in a hard rock formation at a depth of several hundred meters below the ground surface. The primary function of the buffer and backfill is to seal the underground excavation as a preferred flow path for radionuclide migration from the deposited high-level waste. This study investigates the hydraulic conductivity and swelling pressure of Kyungju Ca-bentonite, which is the candidate material for the buffer and backfill in the Korean reference high-level waste disposal system. The factors that influence the hydraulic conductivity and swelling pressure of the buffer and backfill are analyzed. The factors considered are the dry density, the temperature, the sand content, the salinity and the organic carbon content. The possibility of deterioration in the sealing performance of the buffer and backfill is also assessed.

Determination of reaction kinetics during vitrification of radioactive liquid waste for different types of base glass

  • Suneel, G.;Rajasekaran, S.;Selvakumar, J.;Kaushik, Chetan P.;Gayen, J.K.;Ravi, K.V.
    • Nuclear Engineering and Technology
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    • v.51 no.3
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    • pp.746-754
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    • 2019
  • Vitrification of radioactive liquid waste (RLW) provides a feasible solution for isolating radionuclides from the biosphere for an extended period. In vitrification, base glass and radioactive waste are added simultaneously into the melter. Determination of heat and mass transfer rates is necessary for rational design and sizing of melter. For obtaining an assured product quality, knowledge of reaction kinetics associated with the thermal decomposition of waste constituents is essential. In this study Thermogravimetry (TG) - Differential Thermogravimetry (DTG) of eight kinds of nitrates and two oxides, which are major components of RLW, is investigated in the temperature range of 298-1273 K in the presence of base glasses of five component (5C) and seven component (7C). Studies on thermal behavior of constituents in RLW were carried out at heating rates ranging from 10 to $40\;K\;min^{-1}$ using TG - DTG. Thermal behavior and related kinetic parameters of waste constituents, in the presence of 5C and 7C base glass compositions were also investigated. The activation energy, pre-exponential factor and order of the reaction for the thermal decomposition of 24% waste oxide loaded glasses were estimated using Kissinger method.

Production of Bioethanol by Using Beverage Waste (식음료폐기물을 이용한 바이오에탄올 생산)

  • Jeon, Hyung-Jin;Lee, Byung-Oh;Kang, Kyung-Woo;Jeong, Jun-Seong;Chung, Bong-Woo;Choi, Gi-Wook
    • KSBB Journal
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    • v.26 no.5
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    • pp.417-421
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    • 2011
  • Because beverage waste contains a lot of sugar, it can be used as a valuable resource for energy. But beverage waste is discharged through the water treatment. To prevent the waste of the energy resource, we produced bioethanol by using beverage waste in this study. In order to produce bioethanol, we added distillers stillage and NaOH for fermentation condition (nutrients and pH adjustment). As a results, ethanol concentration was 5.92 vol%. In contrast, ethanol concentration of blank (not added nutrients) was low and fermentation rate was very slow. Because components of the distillers stillage help the yeast growth, fermentation yield and rate was improved. Finally, we operated distillation and dehydration process by using fermented mash and produced fuel bioethanol (more than 99.5 wt%). We think that this results may provide useful information with application of commercial ethanol production using beverage waste.

Simulation of the Migration of 3H and 14C Radionuclides on the 2nd Phase Facility at the Wolsong LILW Disposal Center

  • Ha, Jaechul;Son, Yuhwa;Cho, Chunhyung
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.18 no.4
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    • pp.439-455
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    • 2020
  • Numerical model was developed that simulates radionuclide (3H and 14C) transport modeling at the 2nd phase facility at the Wolsong LILW Disposal Center. Four scenarios were simulated with different assumptions about the integrity of the components of the barrier system. For the design case, the multi-barrier system was shown to be effective in diverting infiltration water around the vaults containing radioactive waste. Nevertheless, the volatile radionuclide 14C migrates outside the containment system and through the unsaturated zone, driven by gas diffusion. 3H is largely contained within the vaults where it decays, with small amounts being flushed out in the liquid state. Various scenarios were examined in which the integrity of the cover barrier system or that of the concrete were compromised. In the absence of any engineered barriers, 3H is washed out to the water table within the first 20 years. The release of 14C by gas diffusion is suppressed if percolation fluxes through the facility are high after a cover failure. However, the high fluxes lead to advective transport of 14C dissolved in the liquid state. The concrete container is an effective barrier, with approximately the same effectiveness as the cover.