• Resources Recycling
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• v.14 no.6 s.68
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• pp.44-59
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• 2005

In this paper the world wide patents on the recycling of used batteries were inspected. The trend and direction of on-going and future technologies on this matter were analyzed. The range of search was limited in the open patents and in DB of U.S.A.(USPTO, DLPHION), Japan(PAJ), Europe(EPO), and Korea(KIPRIS). For the search condition the keyword, battery, batteries, electric cell, patent, and recycling, and IPC classification were used. The total of 2,490 cases was found at the first search stage, then, through the 2 steps of filtering processes the total of 871 cases was selected for the final analysis. These 871 cases were classified by countries, companies, and technologies between the year 1971 and the you 2000.

• International Journal of Internet, Broadcasting and Communication
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• v.15 no.3
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• pp.118-121
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• 2023

Recently, green energy support policies have been announced around the world in accordance with environmental regulations, and asthe market grows rapidly, demand for batteries is also increasing. Therefore, various methodologies for battery diagnosis and recycling methods are being discussed, but current accurate life prediction of batteries has limitations due to the nonlinear form according to the internal structure or chemical change of the battery. In this paper, CS2 lithium-ion battery measurement data measured at the A. James Clark School of Engineering, University of Marylan was used to predict battery performance with high accuracy using a convolutional neural network (CNN) model among deep learning-based models. As a result, the battery performance was predicted with high accuracy. A data structure with a matrix of total data 3,931 ☓ 19 was designed as test data for the CS2 battery and checking the result values, the MAE was 0.8451, the RMSE was 1.3448, and the accuracy was 0.984, confirming excellent performance.

• Journal of Platform Technology
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• v.11 no.2
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• pp.54-65
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• 2023

Due to the nature of electric vehicles, the batteries used for electric vehicles have a very large rated capacity. If an electric vehicle runs for a long time or an electric vehicle is abandoned due to a traffic accident, the electric vehicle battery becomes a waste battery. Even in vehicles that are being abandoned, the remaining capacity of waste batteries for electric vehicles is sufficient for other purposes. Waste batteries for automobiles are very expensive, so they need to be recycled and reused, but there was a problem that the standards for measuring the performance grade of waste batteries for recycling and reuse were insufficient. As a method for measuring the remaining capacity of waste battery, the most stable and reliable method is to measure the remaining capacity of battery using full charge and discharge. However, the inspection method by the full charging and discharging method varies depending on the capacity of the battery, but it takes more than a day to inspect, and many people are making great efforts to solve this problem. In this paper, an electric vehicle battery residual capacity analysis technique using voltage deviation between cells was studied and analyzed as a method to reduce inspection time for electric vehicle batteries. To this end, a full charging and discharging-based capacity measurement system was constructed, experimental data were collected using a nose or waste battery, and the correlation between the voltage deviation and the remaining capacity of the battery pack was analyzed to verify whether it can be used for battery inspection.

• International Journal of Internet, Broadcasting and Communication
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• v.16 no.3
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• pp.228-235
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• 2024

Battery use is increasing worldwide to achieve carbon neutrality and improve energy efficiency, but batteries are a finite resource and their application is determined by capacity and specifications. Battery performance deteriorates as the number of uses increases. A certain level of battery performance degradation has become an issue in the field of reuse and recycling, and various studies are being conducted on reuse to solve power shortages. Waste batteries from electric vehicles are suitable for building ESS based on reusable batteries, and for stable use, technical skills are needed to accurately predict battery life and determine status information. Predicting battery life and determining status information are difficult due to non-linearity due to internal structure or chemical changes. In this paper, we manufactured a modular internal resistance measuring device and compared the measured values with Hioki equipment to minimize the error rate through a correction method. As a result of testing Hioki equipment and modular measuring instruments to ensure efficiency and safety based on reusable batteries, an accuracy of over 95% was confirmed.

• Korean Chemical Engineering Research
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• v.60 no.4
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• pp.473-477
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• 2022

In this study, candidate technologies for lithium recovery from the process waste liquid generated in the waste battery recycling process were reviewed, and technologies applicable to the process from the commercialization point of view were reviewed from a qualitative point of view. The evaporation method is difficult to apply because it requires a large-scale land and shows a low recovery rate due to the loss of Li during the concentration process. In the case of precipitation, a commercially available technology shows a high recovery rate due to the high Li/Na selectivity of phosphoric acid, but there are disadvantages in that the process is complicated due to the use of expensive phosphoric acid, requiring a recovery step, and continuous operation is impossible because solids are handled in the Li concentration process. In the case of solvent extraction, if we find an inexpensive extractant with high Li/Na selectivity, continuous operation is possible with the method used in extraction of other metals in the previous step, and when Li is concentrated, continuous operation is possible because it is in a liquid state. If it shows a similar recovery rate compared to precipitation technology, commercialization will be the most likely.

• Resources Recycling
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• v.31 no.6
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• pp.81-91
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• 2022

The use of lithium-ion batteries increases significantly with the rapid spread of electronic devices and electric vehicle and thereby an increase in the amount of waste batteries is expected in the near future. Therefore, studies are continuously being conducted to recover various resources of cathode active material (Ni, Co, Mn, Li) from waste battery. In order to recover the cathode active material, black mass is generally recovered from waste battery. The general process of recovering black mass is a waste battery collection - discharge - dismantling - crushing - classification process. This study focus on the crushing/classification process among the processes. Specifically, the particle size distribution of various samples at each crushing/classification step were evaluated, and the particle shape of each particle fraction was analyzed with a microscope and SEM (Scanning Electron Microscopy)-EDS(Energy Dispersive Spectrometer). As a result, among the black mass particle, fine particle less than 74 ㎛ was the mixture of cathode and anode active material which are properly liberated from the current metals. However, coarse particle larger than 100 ㎛ was present in a form in which the current metal and active material were combined. In addition, this study developed a PBM(Population Balance Model) system that can simulate two-species mixture sample with two different crushing properties. Using developed model, the breakage parameters of two species was derived and predictive performance of breakage distribution was verified.

• Journal of Powder Materials
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• v.21 no.4
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• pp.286-293
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• 2014

The electrochemical properties of cells assembled with the $LiNiO_2$ (LNO) recycled from cathode materials of waste lithium secondary batteries ($Li[Ni,Co,Mn]O_2$), were evaluated in this study. The leaching, neutralization and solvent extraction process were applied to produce high-purity $NiSO_4$ solution from waste lithium secondary batteries. High-purity NiO powder was then fabricated by the heat-treatment and mixing of the $NiSO_4$ solution and $H_2C_2O_4$. Finally, $LiNiO_2$ as a cathode material for lithium ion secondary batteries was synthesized by heat treatment and mixing of the NiO and $Li_2CO_3$ powders. We assembled the cells using the $LiNiO_2$ powders and evaluated the electrochemical properties. Subsequently, we evaluated the recycling possibility of the cathode materials for waste lithium secondary battery using the processes applied in this work.

• Resources Recycling
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• v.17 no.2
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• pp.30-35
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• 2008

Mixed acidophilic bacteria were approached for leaching of cobalt and lithium from wastes of lithium ion battery industries. The growth substrates for the mixed mesophilic bacteria are elemental sulfur and ferrous ion. Bioleaching of the metal was due to the protonic action of sulfate ion on the metals present in the waste. It was investigated that bioleaching of cobalt was faster than lithium. Bacterial action could leach out about 80 % of cobalt and 20 % of lithium from the solid wastes within 12 days of the experimental period. Higher solid/liquid ratio was found to be detrimental for bacterial growth due to the toxic nature of the metals. At high elemental sulfur concentration, the sulfur powder was observed to be in undissolved form and hence the leaching rate also decreased with increase of sulfur amount.

• Resources Recycling
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• v.27 no.4
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• pp.36-43
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• 2018

In order to recycle waste nickel-cadmium batteries, cadmium was selectively removed by ion substitution reaction so that cadmium and nickel could be separated efficiently. The electrode powder obtained by crushing the electrode in the waste nickelcadmium battery was leached with sulfuric acid. The cadmium in the nickel-cadmium solution was precipitated with cadmium sulfide by the addition of sodium sulfide. Ion substitution experiments were carried out under various conditions. At the optimum condition with pH = -0.1 and $Na_2S/Cd=2.3$ at room temperature, the residual Cd in the solution was about 100 ppm, and most of it was precipitated with CdS.

• Journal of the Korean Electrochemical Society
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• v.4 no.2
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• pp.77-81
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• 2001

Recently, used batteries are causing an environmental contamination and a waste of limited resources with increasing demand of portable secondary batteries in market. In developed countries, their governments have legally required the manufacture to collect and recycle the used batteries, so the related companies have formed an organization for collecting the used batteries and they are effectively recycling them. Unfortunately, an infrastructure for collecting and recycling the used batteries are not established at home yet, while volume of the used batteries are increasing. Therefore, we need an effective measure to ensure the recycling of the used batteries as soon as possible.