• 제목/요약/키워드: Waste acid

검색결과 948건 처리시간 0.029초

정수슬러지로 합성한 인공제올라이트와 소석회의 수화응결특성 (Hydration-Setting Property of Slaked Lime and Artificial Zeolite Synthesized with Top Water Sludge)

  • 라정민;최덕진;김민길;김진만
    • 한국건설순환자원학회논문집
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    • 제5권4호
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    • pp.122-128
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    • 2010
  • 정수 슬러지는 해양투기가 금지됨에 따라 매립되거나, 성토재, 복토재 등과 부가가치가 거의 없는 용도로 활용되고 있다. 정수슬러지는 하수슬러지와는 달리 유기물의 함유량이 높지 않은 무기성 슬러지이며, 적절히 가공할 경우 유용한 자원으로 사용할 수 있음에도 불구하고 적절히 활용되지 못하고 있다. 본 연구팀은 정수슬러지를 인산으로 수열반응하여 인공제올라이트를 합성하였다. 합성된 제올라이트는 다공성으로 탈취능이 매우 우수한 분말이지만, 건축자재로 사용하기 위해서는 일정한 형상으로 고화할 필요성이 있다. 본 연구에서는 합성한 인공제올라이트의 특성과 이를 다양한 고화제로 고화하여 그 특성을 분석한 것이다. 실험결과 소석회가 가장 적절한 고화특성을 보이고 있었으며, 최적 사용조건은 전체 분말 중량의 30-60%인 것으로 나타났다. 고화체의 탈취 성능은 원료인 인공제올라이트에는 못미치지만 매우 우수한 것으로 나타나 건축물용 탈취 재료로서의 사용가능성을 확인할 수 있었다.

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느타리버섯 수확후 배지를 이용한 표고 배지 개발 (Application of spent oyster mushroom substrate for bag cultivation of Lentinula edodes)

  • 김정한;강영주;백일선;정윤경;이용선;이영순
    • 한국버섯학회지
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    • 제16권2호
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    • pp.70-73
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    • 2018
  • 느타리버섯 수확후 배지를 이용하여 표고 톱밥배지로 활용하기 위한 연구 수행결과 다음과 같다. 느타리버섯 수확후 배지를 톱밥 첨가량의 20~50%로 4처리로 혼합하여 분석한 결과 C/N은 62~76으로 나타났다. 느타리버섯 수확후 배지 첨가구는 대조구에 비해 질소와 폴리페놀 함량은 상대적으로 높고, 과당과 유기산 함량은 낮은 경향이었다. 특히, 미강이 첨가되지 않은 50% 처리구는 과당, 유기산 함량이 현저하게 낮았다. 초발이기간은 20, 25%가 7일로 대조구와 같았으나 30%와 50%는 각각 6일, 11일로 대조에 비해 각각 1, 4일 지연되었다. 표고버섯 3주기 수량은 20% 처리구가 268.7 g으로 대조와 비슷하였으나 첨가수준이 높을수록 감소하여 특히, 50% 첨가구에서는 버섯 발생이 거의 이루어지지 않았다. 따라서 느타리버섯 수확후 배지를 표고 배지로 이용하기 위해서는 톱밥 첨가량의 20% 수준이 바람직할 것으로 생각된다.

소금 첨가량에 따른 갈색 육수의 이화학적 및 관능적 특성 (Physiological and Sensory Characteristics of Brown Stock Depending on Salt Content)

  • 최수근;김동석
    • 한국식품조리과학회지
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    • 제26권5호
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    • pp.665-675
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    • 2010
  • This study applied high-pressure extraction cooking, which has been proven superior in processibility and stock extraction, for the preparation of stock, which is widely used as a basic material of dishes, and examined the physicochemical and sensory properties of the extracted stock by adding salt. We observed changes in the chromaticity of brown stock according to salt content, and pH decreased with increased the salt content, suggesting that stock was acidified. Regarding the mineral content, Na was the highest, followed by K and P. Regarding total free amino acid content, the content of essential amino acids, enhancing free amino acids, and other amino acids also showed the highest level in S2, which contented 0.3% salt. In the sensory test, saltiness grew stronger with an increase in salt content, and overall palatability was highest in S2. Regarding ranking, preference was highest for S2. Utilize to data that study finding of above is actual in development for mass production of brown stock product licensed cooks' traditional mesh dipper technology quality that make mass production direction that change and normalizes product that can keep excellent taste and improve conservative property develop. Culture formation and our country foodservice industry development that reduce damage of informed people ashes through development of brown stock product that is changed in large quantity, and improve quality of food more positively contributing to reappear diversification of menu, systematization and taste of specialty store as well as can contribute in rationalization of informed people ashes purchase, personnel expense (labor power) curtailment, waste decrease etc. but is developed still more being utilized.

복숭아통조림의 가공중 에너지소비 (Energy Accounting in Peach Canning Operations)

  • 이동선;박노현;신휴년;신동화;민병용
    • 한국식품과학회지
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    • 제14권3호
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    • pp.232-235
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    • 1982
  • 산성(酸性)식품의 통조림가공에서의 에너지절감방안의 수립을 위하여 복숭아통조림 가공중에서의 에너지 소비를 조사하였다. 복숭아 가공에서의 에너지 소요량(所要量)을 조사하고 각 공정별 전기 및 열에너지 사용량(使用量)을 측정하였다. 복숭아 통조림가공에서의 에너지 소요량은 원료 1kg 기준 열에너지 864kcal, 전기에너지 0.045kcal가 각각 소요되었으며 이중 88%가 열에너지이었다. 복숭아14ton/day에 대하여 2060kg의 씨등의 폐기물과 1510kg의 저등품이 생산되었고 6240kg의 주입액즙이 소요되었다. 주(主)에너지소비공정은 저온살균(53%) 알칼리박피(35%) 순(順)이었다. 사용되는 증기의 건도는 라인별 차이없이 $87{\sim}88%$이고 저온살균에서 가열효율은 23%이었다.

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Lead Stabilization in Soil Amended with Lime Waste: An Extended X-ray Absorption Fine Structure (EXAFS) Investigation

  • Lim, Jung Eun;Lee, Sang Soo;Yang, Jae E.;Ok, Yong Sik
    • 한국토양비료학회지
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    • 제47권6호
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    • pp.443-450
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    • 2014
  • To determine Pb species in soils following the immobilization process, sequential extraction has been used despite the possibility of overestimating Pb species from unintended reactions during chemical extraction. Meanwhile, the application of extended X-ray absorption fine structure (EXAFS) has been shown to provide a more precise result than chemical extraction. In this study, the immobilization of Pb in contaminated soils treated with liming materials such as oyster shell (OS) or eggshell (ES) was evaluated with thermodynamic modelling and EXAFS analysis. Thermodynamic modelling by visual MINTEQ predicted the precipitation of $Pb(OH)_2$ in OS and ES treated soils. In particular, the values of saturation index (SI) for $Pb(OH)_2$ in OS (SI=0.286) and ES (SI=0.453) treated soils were greater than in the control soil (SI=0.281). Linear combination fitting (LCF) analysis confirmed the presence of $C_{12}H_{10}O_{14}Pb_3$ (lead citrate, 44.7%) by citric acid from plant root, Pb-gibbsite (Pb adsorbed gibbsite, 26.4%), and Pb-kaolinite (Pb adsorbed kaolinite, 20.3%) in the control soil. On the other hand, $Pb(OH)_2$ (16.8%), Pb-gibbsite (39.3%), and Pb-kaolinite (25.6%) were observed in the OS treated soil and $Pb(OH)_2$ (55.2%) and Pb-gibbsite (33.8%) were also confirmed in the ES treated soil. Our results indicate that the treatment with OS and ES immobilizes Pb by adsorption of Pb onto the soil minerals as a result of the increase in soil negative charge and the formation of stable $Pb(OH)_2$ under high pH condition of soils.

Characterization of Urease-Producing Bacteria Isolated from Heavy Metal Contaminated Mine Soil

  • Park, Min-Jeong;Yoon, Min-Ho;Nam, In-Hyun
    • 한국토양비료학회지
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    • 제47권6호
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    • pp.391-397
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    • 2014
  • Acid mine drainage occurrence is a serious environmental problem by mining industry; it usually contain high levels of metal ions, such as iron, copper, zinc, aluminum, and manganese, as well as metalloids of which arsenic is generally of greatest concern. It causes mine impacted soil pollution with mining and smelting activities, fossil fuel combustion, and waste disposal. In the present study, three bacterial strains capable of producing urease were isolated by selective enrichment of heavy metal contaminated soils from a minei-mpacted area. All isolated bacterial strains were identified Sporosarcina pasteurii with more than 98% of similarity, therefore they were named Sporosarcina sp. KM-01, KM-07, and KM-12. The heavy metals detected from the collected mine soils containing bacterial isolates as Mn ($170.50mg\;kg^{-1}$), As ($114.05mg\;kg^{-1}$), Zn ($92.07mg\;kg^{-1}$), Cu ($62.44mg\;kg^{-1}$), and Pb ($40.29mg\;kg^{-1}$). The KM-01, KM-07, and KM-12 strains were shown to be able to precipitate calcium carbonate using urea as a energy source that was amended with calcium chloride. SEM-EDS analyses showed that calcium carbonate was successfully produced and increased with time. To confirm the calcium carbonate precipitation ability, urease activity and precipitate weight were also measured and compared. These results demonstrate that all isolated bacterial strains could potentially be used in the bioremediation of acidic soil contaminated by heavy metals by mining activity.

Determining Heavy Metal (loid) Stabilization Materials and Optimum Mixing Ratio: Aqueous Batch test

  • Oh, Seung Min;Oh, Se Jin;Kim, Sung Chul;Lee, Sang Hwan;Ok, Yong Sik;Yang, Jae E.
    • 한국토양비료학회지
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    • 제47권6호
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    • pp.540-546
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    • 2014
  • Acid mine drainage sludge (AMDS) has been classified as mine waste and generally deposited in land. For this reason, studies have been conducted to examine the possibility of recycling AMDS as an amendment for heavy metal stabilization in soil. The main objective of this study was to evaluate heavy metal stabilization efficiency of AMDS comparing with the widely used lime stone. Also, optimum mixing ratio was evaluated for enhancing heavy metal stabilization. AMDS and limestone were mixed at the ratio of 0:100, 25:75, 50:50, 75:25, and 100:0 with five different heavy metal solutions ($100mg\;L^{-1}$ of $NaAsO_2$, $CdCl_2$, $CuCl_2$, $Pb(NO_3)_2$, and $ZnSO_4{\cdot}7H_2O$). The amendments were added at a rate of 3% (w/v). In order to determine the stabilization kinetics, samples were collected at different reaction time of 0, 1, 2, 4, 8, 16, 32, 64, 128, 256, 512, 1024 minutes. The heavy metal stabilization by AMDS was faster and higher than those of limestone for all examined heavy metals. While limestone showed only 20% of arsenic (As) stabilization after 1,024 minutes, 96% of As was stabilized within 1 minute by AMDS. The highest effect on the stabilization of heavy metal (loid) was observed, when the two amendments were mixed at a ratio of 1:1. These results indicated that AMDS can be effectively used for heavy metal stabilization in soil, especially for As, and the optimum mixing ratio of AMDS and lime was 1:1 at a rate of 3% (w/v).

탈묵펄프용 표백약품에 따른 표백 특성 및 표백폐수의 환경부하 영향 (The effect of bleaching reagents on bleachabilities of DIP and environmental loads)

  • 안치덕;박정윤;황성준;홍석준;이진희;김형진;정성현
    • 펄프종이기술
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    • 제47권1호
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    • pp.66-74
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    • 2015
  • DIP(deinked pulp) was bleached by FAS, $Na_2S_2O_4$ and $H_2O_2$, which are widely used in DIP bleaching process, in order to improve optical properties of DIP, and the bleaching efficiencies of DIP and environmental loads of waste water were compared, depending on bleaching chemical dosages. With the application of different bleaching chemicals, some positive improvements were shown in optical and physical properties of bleached pulp. However, the physical properties of bleached DIP and their characteristics of wastewater were remarkably different, depending on dosages and bleaching reagents. DIP chemicals with FAS and $Na_2S_2O_4$ have higher improvement in optical and physical properties than $H_2O_2$. Also, environmental loads such as pH, turbidity, SCODcr and cationic demand were decreased in reductive bleaching process. Despite of higher effectiveness of reductive bleaching process, there were some environmental problems caused by sulfur ions from FAS and $Na_2S_2O_4$. With the method of sulfur ion controls, it would be more effective than $H_2O_2$ bleaching process.

Nondestructive determination of physico-chemical properties in compost by NIRS

  • Seo, Sang-Hyun;Lee, Chang-Hee;Park, Sung-Hun;Cho, Rae-Kwang;Park, Woo-Churl
    • 한국근적외분광분석학회:학술대회논문집
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    • 한국근적외분광분석학회 2001년도 NIR-2001
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    • pp.1622-1622
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    • 2001
  • The purpose of this research was to develop a the reflection technique with near infrared (NIR) radiation for estimating physico-chemical properties in compost. The composts (cattle, pig, chicken and waste composts) were air dried and then ground to pass through a 0.5 or 2mm sieve for the physico-chemical properties and spectroscopic determinations. The physico-chemical properties of compost were shown high values ; moisture(30-60%), T-N(0.8-2.9%), organic matter(29-89%), pH(5.89-9.60) K$_2$O(0.27-5.66%), P2O$\sub$5/(0.07-2.62%), CaO(0.03-4.80%), MgO(0.09-1.56%), NaCl(0.01-1.13%), EC(1.41-13.76dS/m). Generally, we should select a simple calibration and prediction method for determining physico-chemical properties in compost under similar accuracy and precision of prediction. It should be remembered that the NIRS approach will never replace the traditional methods. However, NIRS technique may be an effective method for rapid and nondestructive measurements of a large number of compost samples. Near infrared reflectance spectra of composts was obtained by Infra Alyzer 500 scanning spectrophotometer at 2-nm intervals from 1100 to 2500nm. Multiple linear regression(MLR) or partial least square regression (PLSR) was used to evaluate a NIRS method for the rapid and nondestructive determination of physico-chemical properties and humic acid contents in composts. The standard error of prediction(SEP) for finely sized sample(<0.5mm) and coarsely sized sample(<2mm) did not show much difference. The NIR instrument of filter type showed the same accuracy of the monochromator scanning type to estimate the compost properties. The results summarized that NIR spectroscopy can be used as a routine testing method to determine quantitatively the OM, moisture, T-N, color, pH, cation content in the compost samples nondestructively.

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어류의 아기미의 조직학적 구조와 병변 (The histological structure and the pathological lesions of gill in teleosts)

  • 허민도;정현도
    • 한국어병학회지
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    • 제6권1호
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    • pp.65-70
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    • 1993
  • 아가미는 체조직 중에서도 가장 섬세하고도 미묘하게 적응된 조직학적 구조를 갖고 있을 뿐 아니라 환경수에 직접 노출되어 있기 때문에 수중의 각종 생물학적 및 물리화학적 유해인자에 쉽게 영향을 받을 수 있는 곳이다. 아가미를 구성하는 조직성분중에서도 특히 이차새변상피는 단층 내지 두층의 얇은 상피세포로 구성되어 있어 효율적인 가스교환을 할 수 있게 하지만, 이러한 구조의 특수성이 오히려 각종 유해 인자의 침입 또는 이들에 의한 손상을 쉽게 할 수 있다. 아가미는 호흡기능 뿐만 아니라, 장 및 신장과 함께 삼투압의 조절, 노폐물의 배설의 기능도 갖는다. 그러므로, 새변상피의 괴사나 비후와 같은 형태학적 변화는 호흡, 분비 및 배설기능의 장애를 야기할 수 있으므로 새변상피의 기능적 및 형태학적 유지는 무엇보다 중요하다 하겠다. 여기에서는 어떤 특정질병 또는 원인체에 관련한 병리조직학적 변화보다는 일반적으로 아가미조직의 조직학적 특수성을 우선 깊이 이해하고, 그 특성에 관련된 비특이적인 병리조직학적 변화를 중심으로 기술함으로써, 특정 원인체와의 병리조직학적 반응에 대한 보다 정확한 해석을 기하고자 이미 보고 및 출판된 정보를 토대로 하여 여기에 정리하였다.

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