• 제목/요약/키워드: Waste acceptance criteria

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Comparative Study Between Geopolymer and Cement Waste Forms for Solidification of Corrosive Sludge

  • Lee, Juhyeok;Kim, Byoungkwan;Kang, Jaehyuk;Kang, Jaeeun;Kim, Won-Seok;Um, Wooyong
    • 방사성폐기물학회지
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    • 제18권4호
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    • pp.465-479
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    • 2020
  • Two waste forms, namely cement and geopolymer, were investigated and tested in this study to solidify the corrosive sludge generated from the surface and precipitates of the tubes of steam generators in nuclear power plants. The compressive strength of the cement waste form cured for 28 days was inversely proportional to waste loading (24.4 MPa for 0wt% to 2.7 MPa for 60wt%). The corrosive sludge absorbed the free water in the hydration reaction to decrease the cementation reaction. When the corrosive sludge waste loading increased to 60wt%, the cement waste form showed decreased compressive strength (2.7 MPa), which did not satisfy the acceptance criteria of the repository (3.45 MPa). Meanwhile, the compressive strength of the geopolymer waste form cured for 7 days was proportional to waste loading (23.6 MPa for 0wt% to 31.9 MPa for 40wt%). The corrosive sludge absorbed the free water in the geopolymer when the water content decreased, such that a compact geopolymer structure could be obtained. Consequently, the geopolymer waste forms generally showed higher compressive strengths than cement waste forms.

처분방사능량제한치를 고려한 중저준위 방사성폐기물 처분시설의 핵종재고량 산정(안) (Prediction of Radionuclide Inventory for Low- and Intermediate-Level Radioactive Waste by Considering Concentration Limit of Waste Package)

  • 정강일;김민성;정노겸;박진백
    • 방사성폐기물학회지
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    • 제15권1호
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    • pp.65-82
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    • 2017
  • 방사성폐기물 발생기관의 가용데이터를 기반으로 산출된 핵종재고량을 적용하여 예비안전성평가를 수행한 결과 처분안전성과 운영측면에서 많은 어려움이 예상됨을 확인하였다. 본 논문에서는 전체처분시설 예비안전성평가를 수행하였으며, 평가결과 성능목표치 초과핵종에 대해 방사능량이 큰 비중을 차지하는 단위포장물을 선별하고, 높은 표면선량률의 포장물을 처분대상에서 제외하는 방식으로 처분시설의 처분방사능량제한을 도입하였다. 처분방사능량제한은 안전기준 만족을 위한 처분시설별 인수기준과 처분기준 설정에 기초자료로 활용할 것이며, 경주 처분시설의 안전한 종합개발계획수립 및 처분시설의 안전성 최적화를 위한 Safety Case 구축에 기여할 것으로 판단된다.

쓰레기 매립층에서 그라운드 앵커의 극한하중 및 하중분포 (Ultimate Load and Load Distribution of Ground Anchor in Waste Landfill)

  • 김성규;조규완;김웅규
    • 한국지반공학회:학술대회논문집
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    • 한국지반공학회 2005년도 춘계 학술발표회 논문집
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    • pp.1434-1441
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    • 2005
  • For anchored system applications, each ground anchor is tested after installation and prior to being put into service to loads that exceed the design. This load testing methodology, combined with specific acceptance criteria, is used to verify that the ground anchor can carry the design load without excessive deformations and that the assumed load transfer mechanisms have been properly developed behind the assumed critical failure surface. After acceptance, the ground anchor is stressed to a specified load and the load is locked-off. The two types of load tests conducted during the research program included performance test and creep test which were carried out in accordance with testing procedures by AASHTO(AASHTO 1990) and FHWA(Weatherby 1998) at Samsung-Dong 00 Site. Form the measurements, ultimate load and creep rate of anchors are proposed for straight shaft pressured grouted anchors in waste landfill. The load distribution on the grout was obtained from the measured strain data at each fraction of the ultimate load during the load tests.

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Leachability of lead, cadmium, and antimony in cement solidified waste in a silo-type radioactive waste disposal facility environment

  • Yulim Lee;Hyeongjin Byeon;Jaeyeong Park
    • Nuclear Engineering and Technology
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    • 제55권8호
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    • pp.2889-2896
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    • 2023
  • The waste acceptance criteria for heavy metals in mixed waste should be developed by reflecting the leaching behaviors that could highly depend on the repository design and environment surrounding the waste. The current standards widely used to evaluate the leaching characteristics of heavy metals would not be appropriate for the silo-type repository since they are developed for landfills, which are more common than a silo-type repository. This research aimed to explore the leaching behaviors of cementitious waste with Pb, Cd, and Sb metallic and oxide powders in an environment simulating a silo-type radioactive waste repository. The Toxicity Characteristic Leaching Procedure (TCLP) and the ANS 16.1 standard were employed with standard and two modified solutions: concrete-saturated deionized and underground water. The compositions and elemental distribution of leachates and specimens were analyzed using an inductively coupled plasma optical emission spectrometer (ICP-OES) and energy-dispersive X-ray spectroscopy combined with scanning electron microscopy (SEM-EDS). Lead and antimony demonstrated high leaching levels in the modified leaching solutions, while cadmium exhibited minimal leaching behavior and remained mainly within the cement matrix. The results emphasize the significance of understanding heavy metals' leaching behavior in the repository's geochemical environment, which could accelerate or mitigate the reaction.

Physicochemical Property of Borosilicate Glass for Rare Earth Waste From the PyroGreen Process

  • Young Hwan Hwang;Mi-Hyun Lee;Cheon-Woo Kim
    • 방사성폐기물학회지
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    • 제21권2호
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    • pp.271-281
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    • 2023
  • A study was conducted on the vitrification of the rare earth oxide waste generated from the PyroGreen process. The target rare earth waste consisted of eight elements: Nd, Ce, La, Pr, Sm, Y, Gd, and Eu. The waste loading of the rare earth waste in the developed borosilicate glass system was 20wt%. The fabricated glass, processed at 1,200℃, exhibited uniform and homogeneous surface without any crystallization and precipitation. The viscosity and electrical conductivity of the melted glass at 1,200℃ were 7.2 poise and 1.1 S·cm-1, respectively, that were suitable for the operation of the vitrification facility. The calculated leaching index of Cs, Co, and Sr were 10.4, 10.6, and 9.8, respectively. The evaluated Product Consistency Test (PCT) normalized release of the glass indicated that the glass satisfied the requirements for the disposal acceptance criteria. Furthermore, the pristine, 90 days water immersed, 30 thermal cycled, and 10 MGy gamma ray irradiated glasses exhibited good compressive strength. The results indicated that the fabricated glass containing rare earth waste from the PyroGreen process was acceptable for the disposal in the repository, in terms of chemical durability and mechanical strength.

Physical Model Investigation of a Compact Waste Water Pumping Station

  • Kirst, Kilian;Hellmann, D.H.;Kothe, Bernd;Springer, Peer
    • International Journal of Fluid Machinery and Systems
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    • 제3권4호
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    • pp.285-291
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    • 2010
  • To provide required flow rates of cooling or circulating water properly, approach flow conditions of vertical pump systems should be in compliance with state of the art acceptance criteria. The direct inflow should be vortex free, with low pre-rotation and symmetric velocity distribution. Physical model investigations are common practice and the best tool of prediction to evaluate, to optimize and to document flow conditions inside intake structures for vertical pumping systems. Optimization steps should be accomplished with respect to installation costs and complexity on site. The report shows evaluation of various approach flow conditions inside a compact waste water pumping station. The focus is on the occurrence of free surface vortices and the evaluation of air entrainment for various water level and flow rates. The presentation of the results includes the description of the investigated intake structure, occurring flow problems and final recommendations.

방사성고화체의 물리화학적 안정성 평가 (Evaluation on the Stability of Solidified Waste Forms)

  • 유영걸;김기홍;홍권표;정의영;고덕준
    • 한국방사성폐기물학회:학술대회논문집
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    • 한국방사성폐기물학회 2003년도 가을 학술논문집
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    • pp.60-70
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    • 2003
  • 중ㆍ저준위폐기물 처분장 인수조건 평가를 위한 미국 및 프랑스의 시험법을 사용하여 붕산 및 폐수지함유 시멘트 고화체와 파라핀 고화체의 안정성을 평가하였다. 고화체의 압축강도는 176.03 kgf/$\textrm{cm}^2$(시멘트), 15kgf/$\textrm{cm}^2$(파라핀) 이상으로 미국 및 프랑스의 천층 처분장 인수기준치보다 높았다. 온도내구성시험에서는 고화체의 외관 및 부피변화는 없었으며 무게 감소는 평균 6.15% 이었다. 120일간의 내수성 시험에서 파라핀 고화체의 무게 감소는 8.85~5.14%%, pH는 3.83이였다. 방사선 조사영향에서 흡수선량 $10^8rads$에서 시멘트 고화체의 무게 감소를 보였으며, 고화매질인 파라핀왁스의 수소와 메탄의 G 값은 각각 2.65, 0.016 이었다.

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A Study on the Long-Term Integrity of Polymer Concrete for High Integrity Containers

  • Young Hwan Hwang;Mi-Hyun Lee;Seok-Ju Hwang;Jung-Kwon Son;Cheon-Woo Kim;Suknam Lim
    • 방사성폐기물학회지
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    • 제21권3호
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    • pp.411-417
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    • 2023
  • During the operation of a nuclear power plant (NPP), the generation of radioactive waste, including dry active waste (DAW), concentrates, spent resin, and filters, mandates the implementation of appropriate disposal methods to adhere to Korea's waste acceptance criteria (WAC). In this context, this study investigates the potential use of polymer concrete (PC) as a high-integrity container (HIC) material for solidifying and packaging these waste materials. PC is a versatile composite material comprising binding polymers, aggregates, and additives, known for its exceptional strength and chemical stability. A comprehensive analysis of PC's long-term integrity was conducted in this study. First, its compressive strength, which is crucial for ensuring the structural stability of HICs over extended periods, was evaluated. Subsequently, the resilience of PC was tested under various stress conditions, including biological, radiological, thermal, and chemical stressors. The findings of this study indicate that PC exhibits remarkable long-term properties, demonstrating exceptional stability even when subjected to diverse stressors. The results therefore underscore the potential viability of PC as a reliable material for constructing high-integrity containers, thus contributing to the safe and sustainable management of radioactive waste in NPPs.

EVALUATION OF PROLIFERATION RESISTANCE USING THE INPRO METHODOLOGY

  • Yang, Myung-Seung;Park, Joo-Hwan;Ko, Won-Il;Song, Kee-Chan;Choi, Kun-Mo;Kim, Jin-Kyoung
    • Nuclear Engineering and Technology
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    • 제39권2호
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    • pp.149-160
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    • 2007
  • The IAEA launched the International Project on Innovative Nuclear Reactors and Fuel Cycles (INPRO) and developed the INPRO Methodology to provide guidelines and to assess the characteristics of a future innovative nuclear energy system in areas such as safety, economics, waste management, and proliferation resistance. The proliferation resistance area of the INPRO Methodology is reviewed here, and modifications for further improvements are proposed. The evaluation metrics including the evaluation parameters, evaluation scales and acceptance limits are developed for a practical application of the methodology to assess the proliferation resistance. The proliferation resistant characteristics of the DUPIC fuel cycle are assessed by applying the modified INPRO Methodology based on the developed evaluation metrics and acceptance criteria. The evaluation procedure and the metrics can be utilized as a reference for an evaluation of the proliferation resistance of a future innovative nuclear energy system.

Acceptable Decontamination Factor for Near-Surface Disposal of PEACER Wastes

  • Kim, Sung-Il;Lee, Kun-Jai
    • 한국방사성폐기물학회:학술대회논문집
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    • 한국방사성폐기물학회 2005년도 Proceedings of The 6th korea-china joint workshop on nuclear waste management
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    • pp.280-289
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    • 2005
  • A pyrochemical process has been introduced and utilized so that the transmutation of spent PWR fuel in PEACER can produce mainly low and intermediate level waste for near surface disposal. Major radioactive nuclides from PEACER pyroprocessing are composed of TRU and LLFP. In this study, the requirement for the final waste from PEACER is evaluated based on the methodology for establishment of waste acceptance criteria. Also, sensitivity analysis for several input parameters is conducted in order to determine acceptable decontamination factor (DF) and LLFP removal efficiency and to find out input parameter that extremely have an effect on DE As a result of the study, LLFP removal efficiency, especially Sr-90 and Tc-99, is proved to be a major nuclide which contributes to annual dose by human intrusion scenario rather than TRU DF. More than $98.5\%$ of LLFP have to be removed to meet below dose constraint within the DF more than 5.0E+03. Besides, because of the relative short half-life of Sr-90, the increasing of the institutional control period is recommended for most important input parameter to determine DF.

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