• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.20 no.4
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• pp.489-500
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• 2022

The decommissioning of nuclear facilities produces various types of radiologically contaminated waste. In addition, dismantlement activities, including cutting, packing, and clean-up at the facility site, result in secondary radioactive waste such as filters, resin, plastic, and clothing. Determining of the radionuclide content of this waste is an important step for the determination of a suitable management strategy including classification and disposal. In this work, we radiochemically characterized the radionuclide activities of filters used during the decommissioning of Korea Research Reactors (KRRs) 1 and 2. The results indicate that the filter samples contained mainly ³H (500-3,600 Bq·g^-1), ¹⁴C (7.5-29 Bq·g^-1), ⁵⁵Fe (1.1- 7.1 Bq·g^-1), ⁵⁹Ni (0.60-1.0 Bq·g^-1), ⁶⁰Co (0.74-70 Bq·g^-1), ⁶³Ni (0.60-94 Bq·g^-1), ⁹⁰Sr (0.25-5.0 Bq·g^-1), ¹³⁷Cs (0.64-8.7 Bq·g^-1), and ¹⁵²Eu (0.19-2.9) Bq·g^-1. In addition, the gross alpha radioactivity of the samples was measured to be between 0.32-1.1 Bq·g^-1. The radionuclide concentrations were below the concentration limit stated in the low- and intermediatelevel waste acceptance criteria of the Nuclear Safety and Security Commission, and used for the disposal of the KRRs waste drums to a repository site.

• Applied Chemistry for Engineering
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• v.34 no.5
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• pp.515-521
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• 2023

In this study, waste carbon fiber obtained by pyrolysis of carbon fiber reinforced plastic (CFRP) was used to produce carbon fluoride through vapor phase fluorination and recycled as a reducing electrode material for lithium primary batteries. First, the physicochemical properties of the waste carbon fiber obtained by pyrolysis were determined, and the structural and chemical properties of carbon fluoride were analyzed to evaluate the effect of vapor phase fluorination on the waste carbon fiber. XRD analysis confirmed that the hexagonal network carbon laminated structure (002 peak) of the waste carbon fiber was gradually converted into a carbon fluoride structure (CF_X, 001 peak) as the temperature of gas phase fluorination increased. The discharge capacity of the lithium primary battery produced using this carbon fluoride was up to 862 mAh/g. This was compared to the discharge capacity of carbon fluoride-based Li-ion batteries made of other carbon materials. These results suggest that carbon fluoride made from waste CFRP-based carbon fibers can be used as a reducing electrode material for Li-ion batteries.

• Elastomers and Composites
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• v.43 no.3
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• pp.191-198
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• 2008

It is said that polymer modified asphalt using polyethylene as modifier would show phase separation due to density difference and incompatibility between asphalt and polyethylene. In this study, to prevent coalescence of polyethylene in asphalt, we employed peroxides as phase separation inhibitor. On microscope, peroxides (dicumyl peroxide, lauroyl peroxide) with waste vinyl (comprising low density polyethylene) did not show phase separation, however, rheometer test showed phase separation at molecular level, i.e., polyethylene and asphalt are immiscible ultimately. Mechanical properties (tensile strength, Marshall stability, dynamic stability) showed waste vinyl-modified asphalts are highly resistant to plastic deformation and these properties are even better than those of Superphalt.

• Journal of the Korean Ceramic Society
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• v.47 no.5
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• pp.445-449
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• 2010

The purpose of this study is to improve recycling rate of the waste glasses by investigating bloating mechanism. In this study, we use waste glass(W/G) and hard clay(H/C) as raw materials. The artificial lightweight aggregates were formed by plastic forming($\phi$=10 mm) and sintered by fast firing method at different temperatures(between 700 and $1250^{\circ}C$). The physical properties of the aggregates such as bulk specific gravity, adsorption and microstructure of surface and cross-section are investigated with the sintering temperature and rate of W/G-H/C contents. As the result of the bulk specific gravity graphs, we can found out the inflection point at content of W/G 60 wt%. From the microstructure images, we considered the artificial lightweight aggregates content of W/ G over 60wt% are distributed numerous micro-pores by organic oxidation without Black Core and the artificial lightweight aggregates of W/G below 60 wt% are distributed macro-pores with Black Core.

• Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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• 2022.05a
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• pp.346-348
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• 2022

A monitoring system was constructed to identify the cause of occurrence based on data on the analysis of the ignition factors of fermentation heat generated from loading waste. Universal Middleware was used to provide a real-time run-time environment for the configuration and speed of scenarios for each type of fire early warning. It is necessary to dynamically recognize the loading height and pressure of the loading waste, the drying of wood, batteries, and plastic waste, which are representative compositional wastes, and the carbonization changes on the surface. Therefore, this IoT situation recognition platform for analyzing low-temperature-fired fire possibility data was dynamically configured and presented.

• Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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• 2021.10a
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• pp.382-384
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• 2021

In this study, we implement a system that automatically classifies types of plastics using YOLO (You Only Look Once), a real-time object recognition algorithm. The system consists of Nvidia jetson nano, a small computer for deep learning and computer vision, with model trained to recognize plastic separation emission marks using YOLO. Using a webcam, recycling marks of plastic waste were recognized as PET, HDPE, and PP, and motors were adjusted to be classified according to the type. By implementing this automatic classifier, it is convenient in that it can reduce the labor of separating and discharging plastic separation marks by humans and increase the efficiency of recycling through accurate recycling.

• Nuclear Engineering and Technology
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• v.55 no.12
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• pp.4647-4658
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• 2023

In this paper, elastic-plastic fracture mechanics analysis is performed to determine the critical crack sizes of the multipurpose canister (MPC) manufactured using austenitic stainless steel under dynamic loading conditions that simulate drop accidents. Firstly, dynamic finite element (FE) analysis is performed using Abaqus v.2018 with the KORAD (Korea Radioactive Waste Agency)-21 model under two drop accident conditions. Through the FE analysis, critical locations and through-thickness stress distributions in the MPC are identified, where the maximum plastic strain occurs during impact loadings. Then, the evaluation using the failure assessment diagram (FAD) is performed by postulating an external surface crack at the critical location to determine the critical crack depth. It is found that, for the drop cases considered in this paper, the principal failure mechanism for the circumferential surface crack is found to be the plastic collapse due to dominant high bending axial stress in the thickness. For axial cracks, the plastic collapse is also the dominant failure mechanism due to high membrane hoop stress, followed by the ductile tearing analysis. When incorporating the strain rate effect on yield strength and fracture toughness, the critical crack depth increases from 10 to 20%.

• Journal of Environmental Science International
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• v.11 no.4
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• pp.375-382
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• 2002

The total hydrocarbon distribution of oil products obtained from the pyrolysis of four kinds of mixtures of polyethylene-polystyrene waste has been studied by multidimensional chromatography(high performance liquid chromatography followed by capillary gas chromatography)/mass spectrometry. Saturated, unsaturated and aromatic hydrocarbons in oil products were selectively pre-separated according to structural groups by HPLC and the weight fraction of each group was estimated by analysis of each component using GC-FID response factors. The hydrocarbon distribution of aliphatic fraction consists of $C_{5}$ to $C_{25}$ saturated and unsaturated hydrocarbons. And that of aromatics fraction consists of benzene, toluene, xylene, styrene, propenyl benzene, naphthalene, and some of derivatives. Pyrolysis temperature did not affect the ratio of total weight fraction of aliphatic over aromatic hydrocarbon distribution in case of PS only and PE-PS mixtures (1:1 and 1:4 wt. ratio) as a feed while affected the ratio of total wt. fraction in case of PE only. The optimal temperature for the maximum oil production was $600^{\circ}C$ for pyrolysis of PS and 1:1 and 1:4 mixtures of PE and PS. The optimal condition for aromatic recovery was $600^{\circ}C$ with 1:1 mixture of PE and PS. In this condition, aromatic was produced up to 90% of total oil product. The maximum yield of toluene, xylene, styrene, and propenyl benzene were 8.6, 8.9, 51.0 and 7.4% of feed for pyrolysis PS at $700^{\circ}C$, respectively. However, only 1.3% naphthalene was recovered at $700^{\circ}C$ with 1:1 PE:PS(by wt.).

• Applied Chemistry for Engineering
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• v.22 no.1
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• pp.87-90
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• 2011

Copyrolysis of biomass/plastic mixture was carried out from room temperature to $600^{\circ}C$ with varing the heating rates of 10, 20, and $30^{\circ}C/min$ using a thermogravimetric analyzer. Waste wood chip (WWC) and linear low density polyethylene (LLDPE) were selected as a biomass and plastic, respectively. Individual pyrolysis temperature ranges were $430{\sim}550^{\circ}C$ and $230{\sim}600^{\circ}C$ for LLDPE and WWC, respectively. For the copyrolysis of WWC and LLDPE, the decomposition temperature range of WWC was not varied, while the decomposition temperature range of LLDEP was increased to a higher temperature. The results imply that the interaction might occur between LLDEP and WWC during copyolyis of LLDPE and WWC.

• Environmental and Resource Economics Review
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• v.30 no.2
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• pp.269-297
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• 2021

Bioplastics are attracting attention as a substitute for conventional petroleum-based plastics because they are carbon neutral and can be biodegradable. This study estimated economic and environmental impact of regulating the petroleum-based plastics industry and fostering the bioplastics industry using a Recursive Dynamic CGE Model of the Korean Economy. Results show that the regulation of the conventional plastics industry exhibits a positive environmental impact by reducing greenhouse gases and plastic waste and a negative economic impact with a decrease in GDP. Meanwhile, fostering the bioplastics industry with regulation on conventional plastics industry has similar levels of greenhouse gas and waste reduction effects when there is only regulation on the conventional plastics industry. It is also shown that expanding the production of bioplastics industry offsets existing economic losses as a form of increased GDP. If petroleum-based plastics are replaced through the expansion of bioplastics production, it can contribute to the decoupling of greenhouse gas emissions and plastic waste from economic growth.