• Membrane Journal
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• v.14 no.3
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• pp.185-191
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• 2004

It summarized about the properties of thermochemical water-splitting iodine-sulfur process that was hydrogen production using the waste heat from the High Temperature Gas-Cooled Reactor (HTGR) recycling the heat of nuclear power. It was mainly explained about the application of membrane separation technique in IS process. Thermochemical water-splitting hydrogen production method using the high temperature nuclear thermal energy could be realized and remained to be solved the investigation subject. And, it is possible for mass-production of hydrogen such as one of the clean energy in future.

• Journal of the Korea Organic Resources Recycling Association
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• v.23 no.4
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• pp.95-103
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• 2015

The purpose of this study was performed to quantitatively measure the thermal conductivity of poultry slaughter waste with variation of reaction temperature for optimal design of thermal hydrolysis reactor. We continuously quantified the thermal conductivity of dehydrated sludge related to the reaction temperature. As the reaction temperature increased, the dehydrated sludge is thermally liquefied under high temperature and pressure by the thermal hydrolysis reaction. Therefore, the bond water in the sludge cells comes out as free water, which changes the dehydrated sludge from a solid phase to slurry of a liquid phase. As a result, the thermal conductivity of the its sludge was more than 2.11 times lower than that of the water at $20^{\circ}C$. However, the thermal conductivity of the sludge approached to $0.677W/m{\cdot}^{\circ}C$ of water at $200^{\circ}C$, experimentally substantiating liquefaction of the dehydrated sludge. Therefore, we confirmed that the change in physical properties due to thermal hydrolysis appears to be an important factor for heat transfer efficiency. And the thermal conductivity function related to reaction temperature was derived to give the boundary condition for the optimal design of the thermal hydrolysis reactor. The consistency of the calculated function was 99.69%.

• Journal of the Korea Organic Resources Recycling Association
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• v.21 no.4
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• pp.88-100
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• 2013

This study evaluated the direct and indirect environmental impacts of various unit operations of a industrial waste incineration plant by using the life cycle assessment tool and reviewed the improvement plan. During the incineration process, the direct environmental impact was decreased with decrease in emission of various air pollutants by incorporating an air pollution prevention facilities. However, an increase in indirect environmental impacts was observed as a consequence of resources and energy of consumption at the various operational facilities. Consequently, quantitative direct and indirect impact were 89.1%, 10.9%, respectively. The environmental impact analysis of system revealed the highest impact of incineration followed by the impacts of other unit processes such as semidry reactor, and bag-filter. The various air pollutants and ashes generated during the incineration process caused the most significant environmental impact. Among the various categories of environmental impact, global warming accounted the highest impact(more than 85%) followed by eutrophication, and abiotic depletion. As a result of the avoided impact by the utilization of heat generated during the waste incineration process, using an incineration heat for steam and electricity obtained the impact reduction of 45.5%, 19.8%. So, during siting of new incineration plant, the utilization of steam generated from the waste combustion is highly considered to reduce the environmental impact.

• Journal of the Korean Ceramic Society
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• v.51 no.4
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• pp.317-323
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• 2014

People could not imagine living without tab water. However, the water filtering process at a purification plant used to produce tab water creates tons of sludge, which is generally wasted. This sludge waste consists of (1) mineral elements, such as sand, (2) organic materials, and (3) a coagulant, which agglomerates the two. As an enormous amount of sludge waste is generated every year, numerous studies have been carried out to identify how to deal with this problem. Currently, however, most of the sludge waste is directly discarded in landfills. In the present study, water-purified sludge waste received a heat treatment at $1300^{\circ}C$ and was then ground into particles to be used as a ceramic material. Next, the resultant particles were compounded with chamotte substitutes to produce grogged clay that is suitable for wheel-throwing ceramics. Consequently, the plasticity of the sludge waste decreased as the content of calcination increased. Thus, it is considered that wheel throwing is available only up to PBF-3. Thus, it is available for wheel throwing and has a high strength of 864 $kgf/cm^2$ with less than 0.2 percent of porosity and absorption ratio were displayed in PBF-2 at $1280^{\circ}C$ with 20 percent of calcination from the purified sludge. Therefore, the PBF-2 body produced in this study was considered to be capable of replacing grogged clay in the market.

• Resources Recycling
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• v.5 no.3
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• pp.24-30
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• 1996

The computcr s~mulatiun model in vanaus s~nelllng process for melling waste cashhg sand was developed by using energy and malcrial balance concept. This modcl can prcdict the coal, flux and oxygen conaumptron and thc volume and temperature of off-gas The ~niljor critical varlablcs for smclting process can be crplained by using the analysis of energy and malc~ialb alance. Thc Innst lmportarlt variables lor smelting process were h i ~ hpo st-combust~anr atla, high heat transfer crficiency and refractory pratcclion lechnalogy. For saving encrg), in this smelting proccss, selection of caw marerials i.e coal, flus was important, cspacially ubi~go f low volatile coal was prufitahle.

• Resources Recycling
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• v.5 no.1
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• pp.3-8
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• 1996

CZS(2Ca0 , SiO\ulcorner) phase of cement clinkcr was obtaincd by melting mixcd four indnstrial wasles of limestone sludge, waste Foundry sand, coal lly ash fiorn power plants and chernicas glasses. The effect ot mixing ratio of four rvastc mater~als ou the composnlg phascs in melled slag was investigated. Thc mixed wastes were meltcd to slag by heat under a constant basicity at 1370C. The shg consisted of p -CIS and C,AS(2CaO - A I P , . SiO,). The ratio of two phases was varied with mixing ~atioo f the waste materials. In order Lo increasc the amount ot j -C2S phase, the coal fly ash content should be reduced, while amount of the chemical glass be increased. The coal fly ash contcnt was the most imporlant factor in controlling phases of thc melted-slag.

• Membrane and Water Treatment
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• v.15 no.3
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• pp.107-115
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• 2024

This study proposes the recycling of MVS as a value-added product for the removal of phosphate from aqueous solutions. By comparing the phosphate adsorption capacity of each calcined adsorbent at each temperature of MVS, it was determined that the optimal heat treatment temperature of MVS to improve the phosphate adsorption capacity was 800 ℃. MVS-800 suggests an adsorption mechanism through calcium phosphate precipitation. Subsequent kinetic studies with MVS-800 showed that the PFO model was more appropriate than the PSO model. In the equilibrium adsorption experiment, through the analysis of Langmuir and Freundlich models, Langmuir can provide a more appropriate explanation for the phosphate adsorption of MVS-800. This means that the adsorption of phosphate by MVS-800 is uniform over all surfaces and the adsorption consists of a single layer. Thermodynamic analysis of thermally activated MVS-800 shows that phosphate adsorption is an endothermic and involuntary reaction. MVS-800 has the highest phosphate adsorption capacity under low pH conditions. The presence of anions in phosphate adsorption reduces the phosphate adsorption capacity of MVS-800 in the order of CO 3 2-, SO 4 2-, NO 3- and Cl-. Based on experimental data to date, MVS-800 is an environmentally friendly adsorbent for recycling waste resources and is considered to be an adsorbent with high adsorption capacity for removing phosphates from aqueous solutions. This paper combines the advantages of gray predictor and AI fuzzy. The gray predictor can be used to predict whether the bear point exceeds the allowable deviation range, and then perform appropriate control corrections to accelerate the bear point to return to the boundary layer and achieve.

• Applied Chemistry for Engineering
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• v.27 no.6
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• pp.612-619
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• 2016

In this research, an alumino-borosilicate foamed glass with sound absorption property was prepared using the waste borosilicate glass obtained from the recycling process of waste liquid crystal display (LCD) panel. A 100 g of pulverized waste borosilicate glass with the particle size of under 325 mesh, was mixed with 0.3 g (wt/wt) of graphite, each 1.5 g (wt/wt) of $Na_2CO_3$, $Na_2SO_4$ and $CaCO_3$ as a foaming agent, and 6.0 g (wt/wt) of $H_3BO_3$ and 3.0 g (wt/wt) of $Al_2O_3$ as a pore control agent. Following mixture was under the foaming process for 20 minutes at a foaming temperature of $950^{\circ}C$. The result yielded the foaming agent with 45% of the opened porosity and 0.5-0.7 of the sound absorbing coefficient. This alumino-borosilicate foamed glass with the sound absorption property showed excellent physical and mechanical properties such as density of $0.21g/cm^3$, bending strength of $55N/cm^2$ and compression strength of $298N/cm^2$ which can be ideally used as sound absorption materials with heat-resisting and chemical-resisting property.

• Journal of the Korea Organic Resources Recycling Association
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• v.16 no.4
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• pp.57-63
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• 2008

The characteristics of the bio-oil produced by the pyrolysis process with pig feces was investigated in this paper. The continuous auger-type reactor produced bio-oil was maintained at the temperature range of 400 to $600^{\circ}C$, which was higher than a typical that in a conventional pyrolysis system. The pig feces was used as the feedstock. The bio-oil and its compositions were characterized by water analysis, heating values, elemental analysis, bio-oil compounds, by Gas Chromatography/Mass Spectrometry (GC/MS), and functional group by $^1H$ NMR spectroscopy. It was found that the maximum bio-oil yields of 21% w.t. was achieved at $550^{\circ}C$. This result suggested that this auger reactor might be a potential technology for livestock waste treatment to produce bio-oil because it is able to be improved to reach higher efficiency of bio-oil production in further study. The pyrolysis system reported herein had low heat transfer into the feedstock in the auger reactor so that it needs improve the heat conduction rate of the system in further study.

• Clean Technology
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• v.30 no.1
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• pp.28-36
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• 2024

As demand for electric vehicles increases, the market for lithium-ion batteries is also rapidly increasing. The battery life of lithium-ion batteries is limited, so waste lithium-ion batteries are inevitably generated. Accordingly, lithium was selectively preleached from waste lithium iron phosphate (LiFePO₄, hereafter referred to as the LFP) cathode material powder among lithium ion batteries, and iron phosphate (FePO₄) powder was recovered. The recovered iron phosphate powder was mixed with alkaline sodium carbonate (Na₂CO₃) powder and heat treated to confirm its crystalline phase. The heat treatment temperature was set as a variable, and then the leaching rate and powder characteristics of each ingredient were compared after water leaching using Di-water. In this study, lithium showed a leaching rate of approximately 100%, and in the case of powder heat-treated at 800 ℃, phosphorus was leached by approximately 99%, and the leaching residue was confirmed to be a single crystal phase of Fe₂O₃. Therefore, in this study, lithium, phosphorus, and iron components were individually separated and recovered from waste LFP powder.