• Environmental Engineering Research
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• v.23 no.1
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• pp.92-98
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• 2018

Suitability of aluminium-based water treatment sludge (WTS), a waste product from water treatment facilities, was assessed for removal of heavy metals from an electroplating wastewater which had high concentrations of copper and chromium along with other heavy metals. Batch tests with simulated wastewater in single- and multi-metal solutions indicated the influence of initial pH and WTS dose on removal of six metals namely Cu(II), Co(II), Cr(VI), Hg(II), Pb(II) and Zn(II). In general, removal of cationic metals such as Pb(II), Cu(II) and Zn(II) increased with increase in pH while that of anionic Cr(VI) showed a reduction with increased pH values. Tests with multi-metal solution showed that the influence of competition was more pronounced at lower WTS dosages. Column test with diluted (100 times) real electroplating wastewater showed complete removal of copper up to 100 bed volumes while chromium removal ranged between 78-92%. Other metals which were present in lower concentrations were also effectively removed. Mass balance for copper and chromium showed that the WTS media had Cu(II) and Cr(VI) sorption capacities of about 1.7 and 3.5 mg/g of dried sludge, respectively. The study thus indicates that WTS has the potential to be used as a filtration/adsorption medium for removal of metals from metal-bearing wastewaters.

• Advances in environmental research
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• v.3 no.4
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• pp.283-292
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• 2014

Iron precipitating organisms play a significant role in the formation of ferric hydroxide precipitate, which acts as strong adsorbent for toxic metal. In this respect four different iron precipitating cultures were isolated from Hutti gold mine surface winze water sample on citrate agar medium. The best isolate was screened out for metal removal study on the basis of fast visual iron precipitation. The selected isolate was identified as Enterobacter sp. based on routine biochemical tests and Biolog GN microplate results and as Enterobacter cloacae subsp. dissolvens by 16S rRNA gene sequence analysis (GenBank accession number EU429448). Influence of medium composition, medium initial pH, the influence of inoculum size, effect of various media and ferric ammonium citrate concentration were studied on metal removal in shake flask experiments. Under the optimized conditions studied, E. cloacae showed $94{\pm}2$, $95{\pm}2$ and $70{\pm}2%$ of cadmium, copper and mercury removal from a simulated waste in shake flask studies. In lab scale column reactor more than 85% of copper and mercury removal was achieved.

• Bulletin of the Korean Chemical Society
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• v.35 no.3
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• pp.715-720
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• 2014

A Cu(II) complex with an three nitrogens and one sulfur coordination environment was synthesized and characterized. Its redox potential was observed at 0.483 V vs. NHE, very similar to that of a Cu-containing fungal enzyme, galactose oxidase, which catalyzes the oxidation of alcohols to corresponding aldehydes with the concomitant reduction of molecular oxygen to water. The Cu(II) complex selectively oxidizes the benzylic alcohols using TEMPO/$O_2$ under mild reaction conditions to corresponding aldehydes without forming any over-oxidation product. Moreover, the catalyst can be recovered and reused multiple times for further oxidation reactions, thus minimizing the waste generation.

• Proceedings of the Korean Geotechical Society Conference
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• 2002.03a
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• pp.739-742
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• 2002

Immobilization of contaminants in contaminated soils by solidification processes is an attractive potential remediation process. In this study, the treatability of lead, copper, toluene, and COD was investigated by leaching test. Industrial sand was adopted as the test material and was contaminated with lead copper, and toluene to 100mg/kg, 500mg/kg, 200mg/kg respectively. P solidifying agent was used as the binder(20% by weight of contaminated soil) in the solidification treatment. The leachability of contaminants leached from the solidified soil was evaluated using column test. The percentage of contaminants leached from the solidified soil was significantly reduced by reaction of waste species with cement components and encapsulation reaction of binder. Based on the tests, it is ascertained solidification process can be a very effective method to control the elution of contaminants from the contaminated soil.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.21 no.5
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• pp.397-401
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• 2008

Most of the topic in PCB industry was about increasing the volume of product for the development of electronics in numerous industrial application area. However, it has been emerged that yield improvement quality manufacturing via detecting any suspicious process in order to minimize the scrapped product and material waste. In addition, recently, restriction of hazardous substances (RoHS) claims that electronic manufacturing environment should reduce the harmful chemicals usage, thus the importance of monitoring copper etchant and detecting any mis-processing is crucial for electronics manufacturing. In this paper, we have developed real-time chemical monitoring system using RGB sensor, which is simpler but more accurate method than commercially utilized oxidation reduction potential (ORP) technique. The developed Cu etchant monitoring system can further be utilized for copper interconnect process in future nano-semiconductor process.

• Proceedings of the Korean Institute of Resources Recycling Conference
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• 2006.05a
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• pp.61-65
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• 2006

• Proceedings of the KSME Conference
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• 2000.04b
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• pp.7-12
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• 2000

The purpose of this study is to develop heat transfer analysis program of heat pipe elements and design a revolving heat pipe exchanger by the performance experiment of hot air production by means of middle-temperature waste heat. Experimental variables are the revolution per minute, normal velocity of inlet air and the temperature of waste heat. The revolving heat exchanger has designed as $2^{\circ}$ in inclination angle of heat pipe bundle and as 20% in working fluid quantity and as water in working fluid. Experimental value of the total heat transfer coefficient was $20w/m^2-^{\circ}C$

• Proceedings of the KAIS Fall Conference
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• 2001.05a
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• pp.47-48
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• 2001

본 연구의 목적은 폐 구리염화물 용액을 원료로 사용하여 분무열분해 공정에 의해 평균입도가 1㎛이하이며 입도분포가 균일하고 치밀한 조직을 나타내는 미립의 구리산화물 분말을 제조하는데 있다. 또한 본 연구에서는 분무열분해 공정에 의해 생성되는 분말의 특성에 영향을 미치는 반응 온도, 원료용액의 유입속도, 분위기 기체 및 공기의 유입속도, nezzle tip 크기 및 원료용액의 농도 등의 반응인자들의 영향을 검토하였다.

• International Journal of Air-Conditioning and Refrigeration
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• v.11 no.2
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• pp.73-81
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• 2003

The performance of heat exchanger using oscillating heat pipe (OHP) for low temperature waste heat recovery was evaluated. OHP used in this study was made from low finned copper tubes connected by many turns to become the closed loop of serpentine structure. The OHP heat exchanger was formed into shell and tube type. R-22 and R-141b were used as the working fluids of OHP with a fill ratio of 40 vol.%. Water was used as the working fluid of shell side. As the experimental parameters, the inlet temperature difference between heating and cooling water and the mass velocity of water were changed. The mass velocity of water was changed from 30 kg/$m^2$s to 92 kg/$m^2$s. The experimental results showed that the heat recovery rate linearly increased as the mass velocity and the inlet temperature difference of water increased. Finally, the performance of OHP heat exchanger was evaluated by $\varepsilon$-NTU method. It was found that the effectiveness would be 80% if NTU were about 1.5.

• Progress in Superconductivity and Cryogenics
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• v.19 no.1
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• pp.22-25
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• 2017

Steel slag has been considered as an industrial waste. A huge amount of slag is produced as a byproduct and the steel slag usually has been dumped in a landfill site. However the steel slag contains valuable resources such as iron, copper, manganese, and magnesium. Superconducting magnetic separation has been applied on recovery of the valuable resources from the steel slag and this process also has intended to reduce the waste to be dumped. Cryo-cooled Nb-Ti superconducting magnet with 100 mm bore and 600 mm of height was used as the magnetic separator. The separating efficiency was evaluated in the function of magnetic field. A steel slag was ground and analyzed for the composition. Iron containing minerals were successfully concentrated from less iron containing portion. The separation efficiency was highly dependent on the particle size giving higher separating efficiency with finer particle. The magnetic field also effects on the separation ratio. Current study showed that an appropriate grinding of slag and magnetic separation lead to the recovery of metal resources from steel slag waste rather than dumping all of the volume.